Information card for entry 7134740

Structure parameters

• Formula: C300 H224 Cl8 Ir8 O8 P16
• Calculated formula: C300 H224 Cl8 Ir8 O8 P16
• Title of publication: Selective hydrosilylation of olefins by a two-dimensional Rh(I) low-valent metal-organic framework.
• Authors of publication: Mandal, Dipendu; Esposito, Madison R.; Griffin, Samuel E.; Domecus, Grant P.; Cohen, Seth M.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2025
• Journal volume: 61
• Journal issue: 57
• Pages of publication: 10526 - 10529
• a: 11.573 ± 0.002 Å
• b: 22.229 ± 0.004 Å
• c: 46.579 ± 0.01 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 11983 ± 4 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 70
• Hermann-Mauguin space group symbol: F d d d :2
• Hall space group symbol: -F 2uv 2vw
• Residual factor for all reflections: 0.0947
• Residual factor for significantly intense reflections: 0.0645
• Weighted residual factors for significantly intense reflections: 0.1589
• Weighted residual factors for all reflections included in the refinement: 0.1761
• Goodness-of-fit parameter for all reflections included in the refinement: 1.124
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Diffraction radiation X-ray symbol: K-L~3~
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No