Information card for entry 7135306

Structure parameters

• Formula: C75.53 H106.59 La S2
• Calculated formula: C75.53 H106.59 La S2
• Title of publication: <i>In crystallo</i> homolytic cleavage of a terminal lanthanum(III)-methyl bond by Cu Kα X-radiation forms a La(II) complex.
• Authors of publication: Stennett, Cary R.; Luevano, Makayla R.; Ziller, Joseph W.; Evans, William J.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2025
• a: 21.0895 ± 0.0008 Å
• b: 18.2926 ± 0.0006 Å
• c: 36.1914 ± 0.0016 Å
• α: 90°
• β: 92.017 ± 0.002°
• γ: 90°
• Cell volume: 13953.3 ± 0.9 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 4
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.072
• Residual factor for significantly intense reflections: 0.0699
• Weighted residual factors for significantly intense reflections: 0.1628
• Weighted residual factors for all reflections included in the refinement: 0.1637
• Goodness-of-fit parameter for all reflections included in the refinement: 1.201
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No