Information card for entry 7150525

Structure parameters

• Formula: C28 H54 O6 Si2
• Calculated formula: C28 H54 O6 Si2
• SMILES: C1[C@H]([C@@H]2CC[C@H]([C@@H](CC[C@@H]([C@@H]3CC[C@H]([C@@H]4CO4)O3)O[Si](C)(C)C(C)(C)C)O[Si](C)(C)C(C)(C)C)O2)O1
• Title of publication: Synthesis of the non-adjacent bis-THF core of cis-sylvaticin using a double oxidative cyclisation.
• Authors of publication: Bhunnoo, Riaz A; Hobbs, Heather; Lainé, Dramane I; Light, Mark E; Brown, Richard C D
• Journal of publication: Organic & biomolecular chemistry
• Year of publication: 2009
• Journal volume: 7
• Journal issue: 5
• Pages of publication: 1017 - 1024
• a: 7.417 ± 0.005 Å
• b: 10.385 ± 0.005 Å
• c: 10.651 ± 0.005 Å
• α: 68.383 ± 0.005°
• β: 83.788 ± 0.005°
• γ: 82.9 ± 0.005°
• Cell volume: 755.1 ± 0.7 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0665
• Residual factor for significantly intense reflections: 0.0455
• Weighted residual factors for significantly intense reflections: 0.0981
• Weighted residual factors for all reflections included in the refinement: 0.1072
• Goodness-of-fit parameter for all reflections included in the refinement: 1.018
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No