Information card for entry 7151494

Structure parameters

• Formula: C17 H24 O Si
• Calculated formula: C17 H24 O Si
• SMILES: [Si]([C@H]1C(=C\C)/C(=O)C[C@@H](C1)C)(C)(C)c1ccccc1
• Title of publication: Stereocontrol of 1,5-related stereocentres using an intermediate silyl group?the diastereoselectivity of nucleophilic attack on a double bond adjacent to a stereogenic centre carrying a silyl group
• Authors of publication: Fleming, Ian; Maiti, Pranab; Ramarao, Chandrashekar
• Journal of publication: Organic & Biomolecular Chemistry
• Year of publication: 2003
• Journal volume: 1
• Journal issue: 22
• Pages of publication: 3989
• a: 12.1915 ± 0.0003 Å
• b: 15.2706 ± 0.0006 Å
• c: 8.8616 ± 0.0003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 1649.78 ± 0.09 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 4
• Space group number: 18
• Hermann-Mauguin space group symbol: P 21 21 2
• Hall space group symbol: P 2 2ab
• Residual factor for all reflections: 0.0487
• Residual factor for significantly intense reflections: 0.0333
• Weighted residual factors for all reflections: 0.1175
• Weighted residual factors for significantly intense reflections: 0.0763
• Goodness-of-fit parameter for all reflections: 1.044
• Goodness-of-fit parameter for significantly intense reflections: 1.056
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No