Information card for entry 7151812

Structure parameters

• Formula: C42 H49 N O3 Si
• Calculated formula: C42 H49 N O3 Si
• SMILES: C(C)(C)(C)[Si](c1ccccc1)(c1ccccc1)O[C@@H]1CC[C@]23CCC=C[C@@H]([C@H]([C@@H]12)[C@H](CC3)C)OC(=O)Nc1cccc2ccccc12.C(C)(C)(C)[Si](c1ccccc1)(c1ccccc1)O[C@H]1CC[C@@]23CCC=C[C@H]([C@@H]([C@H]12)[C@@H](CC3)C)OC(=O)Nc1cccc2ccccc12
• Title of publication: A stereoselective, Sm(II)-mediated approach to decorated cis-hydrindanes: synthetic studies on faurinone and pleuromutilin.
• Authors of publication: Findley, Thomas J. K.; Sucunza, David; Miller, Laura C.; Helm, Matthew D.; Helliwell, Madeleine; Davies, David T.; Procter, David J.
• Journal of publication: Organic & biomolecular chemistry
• Year of publication: 2011
• Journal volume: 9
• Journal issue: 7
• Pages of publication: 2433 - 2451
• a: 10.4285 ± 0.0015 Å
• b: 12.4428 ± 0.0015 Å
• c: 14.7188 ± 0.0015 Å
• α: 86.41 ± 0.003°
• β: 72.131 ± 0.002°
• γ: 86.886 ± 0.003°
• Cell volume: 1813 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.2302
• Residual factor for significantly intense reflections: 0.0756
• Weighted residual factors for significantly intense reflections: 0.1387
• Weighted residual factors for all reflections included in the refinement: 0.1795
• Goodness-of-fit parameter for all reflections included in the refinement: 0.775
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No