Chemoenzymatic synthesis of chiral 2,2'-bipyridine ligands and their N-oxide derivatives: applications in the asymmetric aminolysis of epoxides and asymmetric allylation of aldehydes.
Authors of publication
Boyd, D. R.; Sharma, N. D.; Sbircea, L.; Murphy, D.; Malone, J. F.; James, S. L.; Allen, C. C. R.; Hamilton, J. T. G.
Journal of publication
Organic & biomolecular chemistry
Year of publication
2010
Journal volume
8
Journal issue
5
Pages of publication
1081 - 1090
a
36.354 ± 0.007 Å
b
6.0133 ± 0.0011 Å
c
16.828 ± 0.003 Å
α
90°
β
117.068 ± 0.003°
γ
90°
Cell volume
3275.8 ± 1.1 Å3
Cell temperature
150 ± 2 K
Ambient diffraction temperature
150 ± 2 K
Number of distinct elements
4
Space group number
5
Hermann-Mauguin space group symbol
C 1 2 1
Hall space group symbol
C 2y
Residual factor for all reflections
0.0356
Residual factor for significantly intense reflections
0.0311
Weighted residual factors for significantly intense reflections
0.0717
Weighted residual factors for all reflections included in the refinement
0.0738
Goodness-of-fit parameter for all reflections included in the refinement
