#------------------------------------------------------------------------------
#$Date: 2025-11-29 22:59:17 +0100 (Sat 29 de Nov de 2025) $
#$Revision: 303902 $
#$URL: svn://www.crystallography.net/cod/cif/7/16/07/7160790.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7160790
loop_
_publ_author_name
'Kishii, Hyu'
'Inagaki, Yusuke'
'Ohara, Kazuaki'
'Yamaguchi, Kentaro'
'Setaka, Wataru'
_publ_section_title
;
 Tuning rotational barriers through substituent modification in
 catechol-diyl molecular gyrotops.
;
_journal_issue                   44
_journal_name_full               'Organic & biomolecular chemistry'
_journal_page_first              10100
_journal_page_last               10105
_journal_paper_doi               10.1039/d5ob01474c
_journal_volume                  23
_journal_year                    2025
_chemical_formula_moiety         'C50 H92 O2 Si2'
_chemical_formula_sum            'C50 H92 O2 Si2'
_chemical_formula_weight         781.41
_chemical_melting_point          429.1(10)
_chemical_name_common            C14Ph(OMe)2cage
_chemical_name_systematic        C14Ph(OMe)2cage
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2025-09-12 deposited with the CCDC.	2025-10-13 downloaded from the CCDC.
;
_cell_angle_alpha                114.7100(10)
_cell_angle_beta                 90.6160(10)
_cell_angle_gamma                104.5210(10)
_cell_formula_units_Z            4
_cell_length_a                   11.9574(3)
_cell_length_b                   20.9583(6)
_cell_length_c                   23.0968(6)
_cell_measurement_reflns_used    9054
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      77.5113
_cell_measurement_theta_min      3.8520
_cell_volume                     5046.1(2)
_computing_cell_refinement       'SAINT V8.40B (Bruker AXS LLC, 2019)'
_computing_data_collection       'Bruker Instrument Service vV6.2.16'
_computing_data_reduction        'SAINT V8.40B (Bruker AXS LLC, 2019)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 2020)'
_computing_publication_material  'WinGX (Farrugia, 2020)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'Sir-2019 (IUCr, 2019)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 7.3910
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.945
_diffrn_measurement_device_type  'Bruker D8 goniometer'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  'multilayered conforcal mirror'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0389
_diffrn_reflns_av_unetI/netI     0.0388
_diffrn_reflns_Laue_measured_fraction_full 0.982
_diffrn_reflns_Laue_measured_fraction_max 0.945
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            72665
_diffrn_reflns_point_group_measured_fraction_full 0.982
_diffrn_reflns_point_group_measured_fraction_max 0.945
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         78.360
_diffrn_reflns_theta_min         2.124
_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    0.880
_exptl_absorpt_correction_T_max  0.92
_exptl_absorpt_correction_T_min  0.76
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Krause, L., Herbst-Irmer, R., Sheldrick, G. M., Stalke, D. (2015).
"Comparison of silver and molybdenum microfocus X-ray sources for
single-crystal structure determination"
J. Appl. Cryst. 48, 3-10.
doi:10.1107/S1600576714022985
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.029
_exptl_crystal_description       plate
_exptl_crystal_F_000             1744
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: a mixture of tetrahydrofuran and methanol'
_exptl_crystal_size_max          0.390
_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.092
_refine_diff_density_min         -0.446
_refine_diff_density_rms         0.046
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.013
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1075
_refine_ls_number_reflns         20488
_refine_ls_number_restraints     177
_refine_ls_restrained_S_all      1.019
_refine_ls_R_factor_all          0.0637
_refine_ls_R_factor_gt           0.0551
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0652P)²+3.3671P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1409
_refine_ls_wR_factor_ref         0.1474
_reflns_Friedel_coverage         0.000
_reflns_number_gt                17606
_reflns_number_total             20488
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5ob01474c2.cif
_cod_data_source_block           C14Ph(OMe)2cage
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_chemical_melting_point' value '155-157 oC' was changed to
'429.1(10)' -- it was converted from degrees Celsius (C) to kelvins
(K), the average value was taken and precision was estimated.

data item '_exptl_absorpt_correction_type' value 'Multi-Scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 8170 2020-07-09 18:12:32Z antanas 

 Adding full bibliography for 7160788--7160790.cif.
;
_cod_database_code               7160790
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.725
_shelx_estimated_absorpt_t_max   0.917
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Si1 Si 0.17688(4) 0.18843(3) 0.37365(2) 0.03226(12) Uani 1 1 d . . . . .
Si2 Si 0.10260(5) 0.30632(3) 0.68089(2) 0.03508(12) Uani 1 1 d . . . . .
O1 O 0.23389(13) 0.34296(7) 0.47772(6) 0.0398(3) Uani 1 1 d . . . . .
O2 O 0.18451(15) 0.39341(7) 0.60632(6) 0.0478(4) Uani 1 1 d . . . . .
C1 C 0.14217(16) 0.22012(10) 0.45918(8) 0.0313(4) Uani 1 1 d . . . . .
C2 C 0.17679(16) 0.29440(10) 0.50140(9) 0.0315(4) Uani 1 1 d . . . . .
C3 C 0.15293(17) 0.31930(10) 0.56504(8) 0.0334(4) Uani 1 1 d . . . . .
C4 C 0.10303(16) 0.27056(10) 0.59077(8) 0.0318(4) Uani 1 1 d . . . . .
C5 C 0.07084(17) 0.19628(10) 0.54882(9) 0.0341(4) Uani 1 1 d . . . . .
H5 H 0.036651 0.161642 0.564602 0.041 Uiso 1 1 calc R U . . .
C6 C 0.08747(17) 0.17158(10) 0.48450(9) 0.0342(4) Uani 1 1 d . . . . .
H6 H 0.061245 0.120658 0.456953 0.041 Uiso 1 1 calc R U . . .
C7 C 0.09591(18) 0.08883(11) 0.32811(9) 0.0374(4) Uani 1 1 d . . . . .
H7A H 0.126818 0.069048 0.286588 0.045 Uiso 1 1 calc R U . . .
H7B H 0.112931 0.062714 0.352782 0.045 Uiso 1 1 calc R U . . .
C8 C -0.03666(18) 0.07131(11) 0.31433(9) 0.0393(4) Uani 1 1 d . . . . .
H8A H -0.066344 0.099691 0.354113 0.047 Uiso 1 1 calc R U . . .
H8B H -0.054819 0.087362 0.281538 0.047 Uiso 1 1 calc R U . . .
C9 C -0.1004(2) -0.01004(11) 0.29052(10) 0.0448(5) Uani 1 1 d . . . . .
H9A H -0.056547 -0.039457 0.258995 0.054 Uiso 1 1 calc R U . . .
H9B H -0.178452 -0.020303 0.268159 0.054 Uiso 1 1 calc R U . . .
C10 C -0.1145(2) -0.03390(12) 0.34557(11) 0.0447(5) Uani 1 1 d . . . . .
H10A H -0.132182 -0.087864 0.326804 0.054 Uiso 1 1 calc R U . . .
H10B H -0.039350 -0.013014 0.373982 0.054 Uiso 1 1 calc R U . . .
C11 C -0.2084(2) -0.01109(13) 0.38581(12) 0.0491(5) Uani 1 1 d . . . . .
H11A H -0.283413 -0.031065 0.357392 0.059 Uiso 1 1 calc R U . . .
H11B H -0.189876 0.042951 0.405566 0.059 Uiso 1 1 calc R U . . .
C12 C -0.2227(2) -0.03648(13) 0.43861(12) 0.0504(5) Uani 1 1 d . . . . .
H12A H -0.153783 -0.008691 0.471879 0.060 Uiso 1 1 calc R U . . .
H12B H -0.225105 -0.088855 0.420248 0.060 Uiso 1 1 calc R U . . .
C13 C -0.3319(2) -0.02684(15) 0.47020(12) 0.0536(6) Uani 1 1 d . . . . .
H13A H -0.400256 -0.051407 0.436496 0.064 Uiso 1 1 calc R U . . .
H13B H -0.326590 0.025970 0.491499 0.064 Uiso 1 1 calc R U . . .
C14 C -0.3511(2) -0.05777(14) 0.51994(12) 0.0563(6) Uani 1 1 d . . . . .
H14A H -0.434583 -0.067156 0.525724 0.068 Uiso 1 1 calc R U . . .
H14B H -0.332987 -0.105418 0.502520 0.068 Uiso 1 1 calc R U . . .
C15 C -0.2795(2) -0.00939(12) 0.58519(10) 0.0450(5) Uani 1 1 d . . . . .
H15A H -0.197443 0.007815 0.579098 0.054 Uiso 1 1 calc R U . . .
H15B H -0.281494 -0.038858 0.609500 0.054 Uiso 1 1 calc R U . . .
C16 C -0.3220(2) 0.05701(13) 0.62490(11) 0.0477(5) Uani 1 1 d . . . . .
H16A H -0.305666 0.091147 0.604665 0.057 Uiso 1 1 calc R U . . .
H16B H -0.407526 0.040508 0.623611 0.057 Uiso 1 1 calc R U . . .
C17 C -0.26683(19) 0.09818(13) 0.69466(11) 0.0463(5) Uani 1 1 d . . . . .
H17A H -0.303729 0.137810 0.716859 0.056 Uiso 1 1 calc R U . . .
H17B H -0.285550 0.064127 0.714928 0.056 Uiso 1 1 calc R U . . .
C18 C -0.13576(18) 0.13171(11) 0.70638(9) 0.0383(4) Uani 1 1 d . . . . .
H18A H -0.098243 0.092835 0.682706 0.046 Uiso 1 1 calc R U . . .
H18B H -0.108819 0.151086 0.752774 0.046 Uiso 1 1 calc R U . . .
C19 C -0.09571(18) 0.19370(11) 0.68558(10) 0.0395(4) Uani 1 1 d . . . . .
H19A H -0.118823 0.174058 0.638750 0.047 Uiso 1 1 calc R U . . .
H19B H -0.135314 0.231879 0.707824 0.047 Uiso 1 1 calc R U . . .
C20 C 0.03603(18) 0.22811(11) 0.70097(9) 0.0388(4) Uani 1 1 d . . . . .
H20A H 0.073489 0.188885 0.678317 0.047 Uiso 1 1 calc R U . . .
H20B H 0.057320 0.245212 0.747629 0.047 Uiso 1 1 calc R U . . .
C21 C 0.13369(18) 0.24298(12) 0.33486(9) 0.0385(4) Uani 1 1 d . . . . .
H21A H 0.197190 0.288790 0.347268 0.046 Uiso 1 1 calc R U . . .
H21B H 0.126546 0.214781 0.287630 0.046 Uiso 1 1 calc R U . . .
C22 C 0.01994(18) 0.26289(12) 0.35177(10) 0.0396(4) Uani 1 1 d . . . . .
H22A H -0.045165 0.217295 0.334802 0.048 Uiso 1 1 calc R U . . .
H22B H 0.023329 0.286263 0.399149 0.048 Uiso 1 1 calc R U . . .
C23 C -0.0062(2) 0.31403(13) 0.32572(11) 0.0453(5) Uani 1 1 d . . . . .
H23A H -0.013569 0.289740 0.278189 0.054 Uiso 1 1 calc R U . . .
H23B H 0.060395 0.358739 0.341019 0.054 Uiso 1 1 calc R U . . .
C24 C -0.1170(2) 0.33615(13) 0.34560(11) 0.0473(5) Uani 1 1 d . . . . .
H24A H -0.136379 0.360750 0.320019 0.057 Uiso 1 1 calc R U . . .
H24B H -0.181760 0.291244 0.334675 0.057 Uiso 1 1 calc R U . . .
C25 C -0.1100(2) 0.38663(13) 0.41656(11) 0.0476(5) Uani 1 1 d . . . . .
H25A H -0.075962 0.366675 0.442244 0.057 Uiso 1 1 calc R U . . .
H25B H -0.056359 0.435121 0.425654 0.057 Uiso 1 1 calc R U . . .
C26 C -0.2258(2) 0.39689(12) 0.43844(11) 0.0461(5) Uani 1 1 d . . . . .
H26A H -0.278726 0.348655 0.430701 0.055 Uiso 1 1 calc R U . . .
H26B H -0.261047 0.415493 0.411959 0.055 Uiso 1 1 calc R U . . .
C27 C -0.2169(2) 0.44939(12) 0.50919(12) 0.0481(5) Uani 1 1 d . . . . .
H27A H -0.161196 0.440174 0.534714 0.058 Uiso 1 1 calc R U . . .
H27B H -0.185577 0.500245 0.514540 0.058 Uiso 1 1 calc R U . . .
C28 C -0.3330(2) 0.44185(14) 0.53521(13) 0.0547(6) Uani 1 1 d . . . . .
H28A H -0.361694 0.391617 0.531723 0.066 Uiso 1 1 calc R U . . .
H28B H -0.389621 0.447764 0.507582 0.066 Uiso 1 1 calc R U . . .
C29 C -0.3309(3) 0.49597(16) 0.60470(14) 0.0649(7) Uani 1 1 d . . . . .
H29A H -0.322959 0.544851 0.606262 0.078 Uiso 1 1 calc R U . . .
H29B H -0.406551 0.480876 0.619129 0.078 Uiso 1 1 calc R U . . .
C30 C -0.2334(3) 0.50235(13) 0.65154(12) 0.0578(6) Uani 1 1 d . . . . .
H30A H -0.242095 0.536506 0.695327 0.069 Uiso 1 1 calc R U . . .
H30B H -0.158184 0.524611 0.640794 0.069 Uiso 1 1 calc R U . . .
C31 C -0.2274(2) 0.43118(12) 0.65300(11) 0.0488(5) Uani 1 1 d . . . . .
H31A H -0.296983 0.412404 0.670278 0.059 Uiso 1 1 calc R U . . .
H31B H -0.229436 0.394336 0.608494 0.059 Uiso 1 1 calc R U . . .
C32 C -0.1190(2) 0.44017(12) 0.69343(11) 0.0490(5) Uani 1 1 d . . . . .
H32A H -0.130374 0.462269 0.739308 0.059 Uiso 1 1 calc R U . . .
H32B H -0.052610 0.474772 0.687115 0.059 Uiso 1 1 calc R U . . .
C33 C -0.0875(2) 0.36910(11) 0.67830(10) 0.0426(5) Uani 1 1 d . . . . .
H33A H -0.150114 0.336351 0.688973 0.051 Uiso 1 1 calc R U . . .
H33B H -0.083779 0.344361 0.631580 0.051 Uiso 1 1 calc R U . . .
C34 C 0.0279(2) 0.38038(11) 0.71468(9) 0.0435(5) Uani 1 1 d . . . . .
H34A H 0.014504 0.387603 0.758941 0.052 Uiso 1 1 calc R U . . .
H34B H 0.082200 0.426374 0.717983 0.052 Uiso 1 1 calc R U . . .
C35 C 0.33733(18) 0.19787(12) 0.37541(9) 0.0386(4) Uani 1 1 d . . . . .
H35A H 0.379430 0.246577 0.409674 0.046 Uiso 1 1 calc R U . . .
H35B H 0.353794 0.160643 0.387377 0.046 Uiso 1 1 calc R U . . .
C36 C 0.3870(2) 0.18960(13) 0.31242(10) 0.0436(5) Uani 1 1 d . . . . .
H36A H 0.340160 0.143282 0.276944 0.052 Uiso 1 1 calc R U . . .
H36B H 0.379695 0.230326 0.302833 0.052 Uiso 1 1 calc R U . . .
C37 C 0.5145(2) 0.18947(13) 0.31485(11) 0.0461(5) Uani 1 1 d . . . . .
H37A H 0.548240 0.200352 0.279924 0.055 Uiso 1 1 calc R U . . .
H37B H 0.557744 0.229014 0.356239 0.055 Uiso 1 1 calc R U . . .
C38 C 0.5316(2) 0.11725(12) 0.30803(11) 0.0454(5) Uani 1 1 d . . . . .
H38A H 0.500419 0.079594 0.263662 0.054 Uiso 1 1 calc R U . . .
H38B H 0.485195 0.101930 0.337626 0.054 Uiso 1 1 calc R U . . .
C39 C 0.6580(2) 0.11933(13) 0.32201(12) 0.0507(5) Uani 1 1 d . . . . .
H39A H 0.660497 0.069398 0.313607 0.061 Uiso 1 1 calc R U . . .
H39B H 0.703909 0.133421 0.291673 0.061 Uiso 1 1 calc R U . . .
C40 C 0.7160(2) 0.17181(12) 0.39045(12) 0.0472(5) Uani 1 1 d . . . . .
H40A H 0.793985 0.165299 0.396022 0.057 Uiso 1 1 calc R U . . .
H40B H 0.727562 0.222612 0.396050 0.057 Uiso 1 1 calc R U . . .
C41 C 0.64861(19) 0.16204(12) 0.44283(11) 0.0434(5) Uani 1 1 d . . . . .
H41A H 0.629329 0.110006 0.434746 0.052 Uiso 1 1 calc R U . . .
H41B H 0.574403 0.174342 0.440762 0.052 Uiso 1 1 calc R U . . .
C42 C 0.7152(2) 0.20925(14) 0.50983(12) 0.0527(6) Uani 1 1 d . . . . .
H42A H 0.742701 0.260533 0.515821 0.063 Uiso 1 1 calc R U . . .
H42B H 0.784720 0.192895 0.513340 0.063 Uiso 1 1 calc R U . . .
C43 C 0.6436(2) 0.20688(14) 0.56370(11) 0.0506(5) Uani 1 1 d . . . . .
H43A H 0.607704 0.155101 0.554601 0.061 Uiso 1 1 calc R U . . .
H43B H 0.696799 0.230072 0.604570 0.061 Uiso 1 1 calc R U . . .
C44 C 0.54797(19) 0.24499(12) 0.57238(10) 0.0437(5) Uani 1 1 d . . . . .
H44A H 0.490553 0.218969 0.533005 0.052 Uiso 1 1 calc R U . . .
H44B H 0.582659 0.295540 0.577641 0.052 Uiso 1 1 calc R U . . .
C45 C 0.4847(2) 0.24798(12) 0.63006(10) 0.0448(5) Uani 1 1 d . . . . .
H45A H 0.443661 0.197395 0.622669 0.054 Uiso 1 1 calc R U . . .
H45B H 0.543234 0.269374 0.668652 0.054 Uiso 1 1 calc R U . . .
C46 C 0.3977(2) 0.29189(13) 0.64334(10) 0.0447(5) Uani 1 1 d . . . . .
H46A H 0.338013 0.269798 0.605183 0.054 Uiso 1 1 calc R U . . .
H46B H 0.438327 0.342189 0.649748 0.054 Uiso 1 1 calc R U . . .
C47 C 0.33685(19) 0.29610(13) 0.70210(10) 0.0466(5) Uani 1 1 d . . . . .
H47A H 0.397030 0.313050 0.739132 0.056 Uiso 1 1 calc R U . . .
H47B H 0.289805 0.246199 0.693631 0.056 Uiso 1 1 calc R U . . .
C48 C 0.25751(19) 0.34658(13) 0.72080(9) 0.0452(5) Uani 1 1 d . . . . .
H48A H 0.293179 0.388784 0.711577 0.054 Uiso 1 1 calc R U . . .
H48B H 0.256433 0.365883 0.767850 0.054 Uiso 1 1 calc R U . . .
C49 C 0.3488(2) 0.38534(14) 0.50921(12) 0.0573(6) Uani 1 1 d . . . . .
H49A H 0.382300 0.417900 0.489478 0.086 Uiso 1 1 calc R U . . .
H49B H 0.345829 0.414625 0.554858 0.086 Uiso 1 1 calc R U . . .
H49C H 0.397357 0.352640 0.504938 0.086 Uiso 1 1 calc R U . . .
C50 C 0.1249(3) 0.43451(13) 0.58760(12) 0.0611(7) Uani 1 1 d . . . . .
H50A H 0.151172 0.486152 0.618673 0.092 Uiso 1 1 calc R U . . .
H50B H 0.141923 0.429851 0.544836 0.092 Uiso 1 1 calc R U . . .
H50C H 0.040756 0.415659 0.586486 0.092 Uiso 1 1 calc R U . . .
Si3 Si 0.19637(4) 0.21305(2) 0.96014(2) 0.02457(10) Uani 1 1 d . . . . .
Si4 Si 0.74957(4) 0.22585(2) 0.92115(2) 0.02398(10) Uani 1 1 d . . . . .
O3 O 0.30536(10) 0.16205(7) 0.83872(5) 0.0298(3) Uani 1 1 d . . . . .
O4 O 0.53645(10) 0.15772(7) 0.82199(5) 0.0309(3) Uani 1 1 d . . . . .
C101 C 0.35517(14) 0.21895(9) 0.95253(8) 0.0233(3) Uani 1 1 d . . . . .
C102 C 0.39031(14) 0.19080(9) 0.89138(7) 0.0231(3) Uani 1 1 d . . . . .
C103 C 0.50488(14) 0.18926(9) 0.88322(7) 0.0236(3) Uani 1 1 d . . . . .
C104 C 0.59312(14) 0.22143(9) 0.93553(8) 0.0231(3) Uani 1 1 d . . . . .
C105 C 0.55849(14) 0.25201(9) 0.99664(8) 0.0263(3) Uani 1 1 d . . . . .
H105 H 0.615692 0.275288 1.033465 0.032 Uiso 1 1 calc R U . . .
C106 C 0.44286(15) 0.24918(9) 1.00477(8) 0.0265(3) Uani 1 1 d . . . . .
H106 H 0.422583 0.268360 1.047123 0.032 Uiso 1 1 calc R U . . .
C107 C 0.17805(16) 0.25205(10) 1.04795(8) 0.0295(4) Uani 1 1 d . . . . .
H10C H 0.239150 0.299140 1.070611 0.035 Uiso 1 1 calc R U . . .
H10D H 0.101778 0.262878 1.052314 0.035 Uiso 1 1 calc R U . . .
C108 C 0.18407(18) 0.20379(10) 1.08232(9) 0.0355(4) Uani 1 1 d . . . . .
H10E H 0.128488 0.154866 1.057554 0.043 Uiso 1 1 calc R U . . .
H10F H 0.263290 0.197354 1.082523 0.043 Uiso 1 1 calc R U . . .
C109 C 0.1562(2) 0.23487(11) 1.15182(10) 0.0427(5) Uani 1 1 d . . . . .
H10G H 0.077971 0.242666 1.151478 0.051 Uiso 1 1 calc R U . . .
H10H H 0.152551 0.197778 1.168253 0.051 Uiso 1 1 calc R U . . .
C110 C 0.24265(19) 0.30657(11) 1.19855(9) 0.0404(5) Uani 1 1 d . . . . .
H11C H 0.242025 0.344765 1.184046 0.049 Uiso 1 1 calc R U . . .
H11D H 0.215785 0.321844 1.241434 0.049 Uiso 1 1 calc R U . . .
C111 C 0.3672(2) 0.30294(12) 1.20523(10) 0.0447(5) Uani 1 1 d . . . . .
H11E H 0.401131 0.299832 1.165564 0.054 Uiso 1 1 calc R U . . .
H11F H 0.366382 0.257825 1.209632 0.054 Uiso 1 1 calc R U . . .
C112 C 0.4453(2) 0.36966(14) 1.26355(11) 0.0538(6) Uani 1 1 d . . . . .
H11G H 0.437777 0.414708 1.261573 0.065 Uiso 1 1 calc R U . . .
H11H H 0.415418 0.369302 1.303254 0.065 Uiso 1 1 calc R U . . .
C113 C 0.5736(3) 0.37356(15) 1.26880(12) 0.0586(6) Uani 1 1 d . . . . .
H11I H 0.581443 0.325462 1.263186 0.070 Uiso 1 1 calc R U . . .
H11J H 0.611738 0.410211 1.312412 0.070 Uiso 1 1 calc R U . . .
C114 C 0.6360(2) 0.39392(15) 1.21945(12) 0.0557(6) Uani 1 1 d . . . . .
H11K H 0.635373 0.444337 1.228475 0.067 Uiso 1 1 calc R U . . .
H11L H 0.591439 0.360871 1.176409 0.067 Uiso 1 1 calc R U . . .
C115 C 0.7622(2) 0.39016(13) 1.21726(11) 0.0485(5) Uani 1 1 d . . . . .
H11M H 0.809733 0.426909 1.258546 0.058 Uiso 1 1 calc R U . . .
H11N H 0.764893 0.341170 1.211838 0.058 Uiso 1 1 calc R U . . .
C116 C 0.81366(19) 0.40427(11) 1.16296(10) 0.0417(5) Uani 1 1 d . . . . .
H11O H 0.829195 0.457077 1.174465 0.050 Uiso 1 1 calc R U . . .
H11P H 0.754852 0.377169 1.124186 0.050 Uiso 1 1 calc R U . . .
C117 C 0.92579(18) 0.38276(11) 1.14604(10) 0.0423(5) Uani 1 1 d . . . . .
H11Q H 0.985702 0.410550 1.184296 0.051 Uiso 1 1 calc R U . . .
H11R H 0.911162 0.330072 1.134820 0.051 Uiso 1 1 calc R U . . .
C118 C 0.97272(18) 0.39702(11) 1.09037(10) 0.0429(5) Uani 1 1 d . . . . .
H11S H 1.044244 0.380784 1.081622 0.052 Uiso 1 1 calc R U . . .
H11T H 0.995175 0.450451 1.103693 0.052 Uiso 1 1 calc R U . . .
C119 C 0.88805(18) 0.35915(10) 1.02775(9) 0.0377(4) Uani 1 1 d . . . . .
H11U H 0.819456 0.378565 1.035439 0.045 Uiso 1 1 calc R U . . .
H11V H 0.926860 0.372024 0.994891 0.045 Uiso 1 1 calc R U . . .
C120 C 0.84563(15) 0.27557(9) 1.00082(8) 0.0290(3) Uani 1 1 d . . . . .
H12C H 0.802462 0.263078 1.032730 0.035 Uiso 1 1 calc R U . . .
H12D H 0.914783 0.256807 0.996423 0.035 Uiso 1 1 calc R U . . .
C121 C 0.14381(15) 0.26560(10) 0.92188(9) 0.0307(4) Uani 1 1 d . . . . .
H12E H 0.152615 0.243056 0.875652 0.037 Uiso 1 1 calc R U . . .
H12F H 0.059349 0.258256 0.924767 0.037 Uiso 1 1 calc R U . . .
C122 C 0.20096(17) 0.34745(10) 0.94805(9) 0.0333(4) Uani 1 1 d . . . . .
H12G H 0.286479 0.356414 0.949390 0.040 Uiso 1 1 calc R U . . .
H12H H 0.184014 0.372016 0.992634 0.040 Uiso 1 1 calc R U . . .
C123 C 0.15886(17) 0.38106(11) 0.90768(10) 0.0373(4) Uani 1 1 d . . . . .
H12I H 0.189754 0.363292 0.865967 0.045 Uiso 1 1 calc R U . . .
H12J H 0.072806 0.362677 0.898622 0.045 Uiso 1 1 calc R U . . .
C124 C 0.1928(2) 0.46425(13) 0.93735(12) 0.0533(6) Uani 1 1 d D . . . .
H12K H 0.159216 0.478588 0.906834 0.064 Uiso 1 1 calc R U . A 1
H12L H 0.154599 0.481235 0.976654 0.064 Uiso 1 1 calc R U . A 1
C125 C 0.3183(2) 0.50510(15) 0.95498(14) 0.0407(7) Uani 0.846(6) 1 d D . P B 1
H12M H 0.355014 0.487586 0.981892 0.049 Uiso 0.846(6) 1 calc R U P B 1
H12N H 0.325352 0.557580 0.981394 0.049 Uiso 0.846(6) 1 calc R U P B 1
C126 C 0.3855(2) 0.49769(15) 0.89755(12) 0.0381(7) Uani 0.846(6) 1 d . . P B 1
H12O H 0.353543 0.518952 0.872384 0.046 Uiso 0.846(6) 1 calc R U P B 1
H12P H 0.374488 0.445157 0.869299 0.046 Uiso 0.846(6) 1 calc R U P B 1
C225 C 0.3396(11) 0.4705(9) 0.9217(8) 0.046(4) Uani 0.154(6) 1 d D . P B 2
H22C H 0.376203 0.451627 0.947398 0.055 Uiso 0.154(6) 1 calc R U P B 2
H22D H 0.339094 0.438294 0.875742 0.055 Uiso 0.154(6) 1 calc R U P B 2
C226 C 0.4125(11) 0.5447(8) 0.9359(8) 0.046(4) Uani 0.154(6) 1 d D . P B 2
H22E H 0.378499 0.565256 0.910736 0.055 Uiso 0.154(6) 1 calc R U P B 2
H22F H 0.419337 0.577682 0.982200 0.055 Uiso 0.154(6) 1 calc R U P B 2
C127 C 0.5185(2) 0.53689(13) 0.91887(11) 0.0491(5) Uani 1 1 d D . . . .
H12Q H 0.528583 0.586427 0.953914 0.059 Uiso 1 1 calc R U . B 1
H12R H 0.553133 0.509291 0.936314 0.059 Uiso 1 1 calc R U . B 1
C128 C 0.5833(2) 0.54372(13) 0.86563(12) 0.0511(5) Uani 1 1 d D . . . .
H12S H 0.553404 0.576038 0.852093 0.061 Uiso 1 1 calc R U . C 3
H12T H 0.666142 0.569094 0.883668 0.061 Uiso 1 1 calc R U . C 3
C129 C 0.5791(2) 0.47676(14) 0.80774(12) 0.0440(6) Uani 0.840(4) 1 d D . P D 3
H12U H 0.627400 0.490523 0.777994 0.053 Uiso 0.840(4) 1 calc R U P D 3
H12V H 0.497747 0.454387 0.786086 0.053 Uiso 0.840(4) 1 calc R U P D 3
C130 C 0.6205(3) 0.41895(15) 0.81891(13) 0.0405(6) Uani 0.840(4) 1 d . . P D 3
H13C H 0.568274 0.401899 0.845640 0.049 Uiso 0.840(4) 1 calc R U P D 3
H13D H 0.613793 0.376433 0.776948 0.049 Uiso 0.840(4) 1 calc R U P D 3
C131 C 0.7457(3) 0.44603(19) 0.85168(19) 0.0380(7) Uani 0.840(4) 1 d . . P D 3
H13E H 0.747586 0.477466 0.897954 0.046 Uiso 0.840(4) 1 calc R U P D 3
H13F H 0.794302 0.476579 0.833109 0.046 Uiso 0.840(4) 1 calc R U P D 3
C132 C 0.7991(2) 0.38442(13) 0.84492(12) 0.0367(6) Uani 0.840(4) 1 d . . P D 3
H13G H 0.882838 0.406142 0.862144 0.044 Uiso 0.840(4) 1 calc R U P D 3
H13H H 0.793433 0.351657 0.798638 0.044 Uiso 0.840(4) 1 calc R U P D 3
C229 C 0.6910(10) 0.5262(6) 0.8395(6) 0.037(3) Uani 0.160(4) 1 d D . P D 4
H22G H 0.755074 0.572374 0.856974 0.045 Uiso 0.160(4) 1 calc R U P D 4
H22H H 0.678268 0.508902 0.792357 0.045 Uiso 0.160(4) 1 calc R U P D 4
C230 C 0.7327(18) 0.4696(10) 0.8527(10) 0.034(3) Uani 0.160(4) 1 d . . P D 4
H23C H 0.816730 0.476961 0.848414 0.041 Uiso 0.160(4) 1 calc R U P D 4
H23D H 0.723101 0.477391 0.897465 0.041 Uiso 0.160(4) 1 calc R U P D 4
C231 C 0.6669(13) 0.3921(8) 0.8075(6) 0.036(3) Uani 0.160(4) 1 d . . P D 4
H23E H 0.659356 0.387914 0.763215 0.043 Uiso 0.160(4) 1 calc R U P D 4
H23F H 0.587372 0.380945 0.819297 0.043 Uiso 0.160(4) 1 calc R U P D 4
C232 C 0.7258(11) 0.3362(6) 0.8087(5) 0.032(3) Uani 0.160(4) 1 d D . P D 4
H23G H 0.803341 0.345422 0.794160 0.039 Uiso 0.160(4) 1 calc R U P D 4
H23H H 0.678802 0.286615 0.777988 0.039 Uiso 0.160(4) 1 calc R U P D 4
C133 C 0.74182(17) 0.33835(11) 0.87930(9) 0.0354(4) Uani 1 1 d D . . . .
H13I H 0.657226 0.318797 0.863925 0.042 Uiso 1 1 calc R U . D 3
H13J H 0.751611 0.370438 0.925986 0.042 Uiso 1 1 calc R U . D 3
C134 C 0.79193(15) 0.27426(10) 0.86878(9) 0.0307(4) Uani 1 1 d . . . . .
H13K H 0.877990 0.292808 0.875089 0.037 Uiso 1 1 calc R U . . .
H13L H 0.767971 0.237709 0.823385 0.037 Uiso 1 1 calc R U . . .
C135 C 0.10355(15) 0.11552(10) 0.91750(9) 0.0315(4) Uani 1 1 d . . . . .
H13M H 0.035356 0.110197 0.940761 0.038 Uiso 1 1 calc R U . . .
H13N H 0.073630 0.107174 0.874041 0.038 Uiso 1 1 calc R U . . .
C136 C 0.15862(17) 0.05436(10) 0.90967(11) 0.0390(4) Uani 1 1 d D . . . .
H13O H 0.178906 0.056833 0.952370 0.047 Uiso 1 1 calc R U . E 5
H13P H 0.231133 0.060689 0.889872 0.047 Uiso 1 1 calc R U . E 5
C137 C 0.0712(4) -0.0218(2) 0.86619(18) 0.0350(8) Uani 0.720(5) 1 d . . P F 5
H13Q H 0.006000 -0.031265 0.890253 0.042 Uiso 0.720(5) 1 calc R U P F 5
H13R H 0.038393 -0.019586 0.827783 0.042 Uiso 0.720(5) 1 calc R U P F 5
C138 C 0.1241(3) -0.08612(15) 0.84395(15) 0.0388(7) Uani 0.720(5) 1 d D . P F 5
H13S H 0.194732 -0.074631 0.824137 0.047 Uiso 0.720(5) 1 calc R U P F 5
H13T H 0.067478 -0.129962 0.810623 0.047 Uiso 0.720(5) 1 calc R U P F 5
C139 C 0.1565(3) -0.1035(2) 0.89895(16) 0.0424(8) Uani 0.720(5) 1 d D . P F 5
H13U H 0.087662 -0.110347 0.921448 0.051 Uiso 0.720(5) 1 calc R U P F 5
H13V H 0.218698 -0.061430 0.930246 0.051 Uiso 0.720(5) 1 calc R U P F 5
C140 C 0.1989(3) -0.17289(18) 0.87527(18) 0.0523(9) Uani 0.720(5) 1 d D . P F 5
H14C H 0.202638 -0.187122 0.910921 0.063 Uiso 0.720(5) 1 calc R U P F 5
H14D H 0.140712 -0.213252 0.839997 0.063 Uiso 0.720(5) 1 calc R U P F 5
C141 C 0.3159(4) -0.1646(2) 0.8517(2) 0.0584(11) Uani 0.720(5) 1 d D . P F 5
H14E H 0.318905 -0.140281 0.822864 0.070 Uiso 0.720(5) 1 calc R U P F 5
H14F H 0.327081 -0.213604 0.826685 0.070 Uiso 0.720(5) 1 calc R U P F 5
C237 C 0.0808(9) -0.0195(5) 0.8933(6) 0.040(2) Uani 0.280(5) 1 d D . P F 6
H23I H 0.035288 -0.037528 0.850725 0.048 Uiso 0.280(5) 1 calc R U P F 6
H23J H 0.024767 -0.014976 0.925063 0.048 Uiso 0.280(5) 1 calc R U P F 6
C238 C 0.1392(9) -0.0777(5) 0.8911(7) 0.058(3) Uani 0.280(5) 1 d . . P F 6
H23K H 0.173771 -0.063722 0.935322 0.069 Uiso 0.280(5) 1 calc R U P F 6
H23L H 0.077842 -0.124751 0.877344 0.069 Uiso 0.280(5) 1 calc R U P F 6
C239 C 0.2317(7) -0.0902(4) 0.8481(4) 0.050(2) Uani 0.280(5) 1 d . . P F 6
H23M H 0.303044 -0.048834 0.868491 0.060 Uiso 0.280(5) 1 calc R U P F 6
H23N H 0.205432 -0.090994 0.806990 0.060 Uiso 0.280(5) 1 calc R U P F 6
C240 C 0.2612(9) -0.1614(4) 0.8343(4) 0.043(2) Uani 0.280(5) 1 d D . P F 6
H24C H 0.189230 -0.201771 0.812449 0.052 Uiso 0.280(5) 1 calc R U P F 6
H24D H 0.317803 -0.166943 0.802773 0.052 Uiso 0.280(5) 1 calc R U P F 6
C241 C 0.3103(7) -0.1739(4) 0.8884(4) 0.045(2) Uani 0.280(5) 1 d D . P F 6
H24E H 0.258863 -0.167691 0.922497 0.054 Uiso 0.280(5) 1 calc R U P F 6
H24F H 0.322659 -0.223052 0.872329 0.054 Uiso 0.280(5) 1 calc R U P F 6
C142 C 0.4189(3) -0.11712(17) 0.9109(2) 0.0905(11) Uani 1 1 d D . . . .
H14G H 0.404847 -0.069623 0.938333 0.109 Uiso 1 1 calc R U . F 5
H14H H 0.422031 -0.143608 0.937413 0.109 Uiso 1 1 calc R U . F 5
C143 C 0.5331(2) -0.10460(15) 0.88356(15) 0.0680(8) Uani 1 1 d . . . . .
H14I H 0.545674 -0.152700 0.856526 0.082 Uiso 1 1 calc R U . . .
H14J H 0.526641 -0.080407 0.855415 0.082 Uiso 1 1 calc R U . . .
C144 C 0.6372(2) -0.05909(13) 0.93332(13) 0.0516(5) Uani 1 1 d . . . . .
H14K H 0.646453 -0.084931 0.959662 0.062 Uiso 1 1 calc R U . . .
H14L H 0.622211 -0.012343 0.962124 0.062 Uiso 1 1 calc R U . . .
C145 C 0.7500(2) -0.04217(12) 0.90701(12) 0.0495(5) Uani 1 1 d . . . . .
H14M H 0.763276 -0.089015 0.877057 0.059 Uiso 1 1 calc R U . . .
H14N H 0.814271 -0.017857 0.943133 0.059 Uiso 1 1 calc R U . . .
C146 C 0.75746(19) 0.00642(10) 0.87161(10) 0.0384(4) Uani 1 1 d . . . . .
H14O H 0.833385 0.011685 0.854809 0.046 Uiso 1 1 calc R U . . .
H14P H 0.695499 -0.018618 0.834298 0.046 Uiso 1 1 calc R U . . .
C147 C 0.74507(17) 0.08262(10) 0.91299(9) 0.0334(4) Uani 1 1 d . . . . .
H14Q H 0.799432 0.105382 0.953386 0.040 Uiso 1 1 calc R U . . .
H14R H 0.664812 0.078117 0.924389 0.040 Uiso 1 1 calc R U . . .
C148 C 0.77059(15) 0.13232(10) 0.87861(8) 0.0296(4) Uani 1 1 d . . . . .
H14S H 0.720281 0.106736 0.836638 0.035 Uiso 1 1 calc R U . . .
H14T H 0.852364 0.138205 0.869592 0.035 Uiso 1 1 calc R U . . .
C149 C 0.32491(19) 0.19989(13) 0.79877(10) 0.0430(5) Uani 1 1 d . . . . .
H14U H 0.261934 0.176756 0.762753 0.064 Uiso 1 1 calc R U . . .
H14V H 0.326562 0.251142 0.824107 0.064 Uiso 1 1 calc R U . . .
H14W H 0.399595 0.197603 0.782159 0.064 Uiso 1 1 calc R U . . .
C150 C 0.48277(18) 0.08035(11) 0.78838(10) 0.0463(5) Uani 1 1 d . . . . .
H15C H 0.508411 0.061519 0.745783 0.069 Uiso 1 1 calc R U . . .
H15D H 0.505391 0.055927 0.812792 0.069 Uiso 1 1 calc R U . . .
H15E H 0.397849 0.070766 0.783628 0.069 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C21 Si1 C35 110.82(9) . . ?
C21 Si1 C7 110.44(9) . . ?
C35 Si1 C7 108.46(9) . . ?
C21 Si1 C1 111.15(9) . . ?
C35 Si1 C1 108.04(8) . . ?
C7 Si1 C1 107.82(8) . . ?
C34 Si2 C48 107.15(10) . . ?
C34 Si2 C20 111.40(10) . . ?
C48 Si2 C20 107.06(10) . . ?
C34 Si2 C4 112.98(9) . . ?
C48 Si2 C4 108.52(9) . . ?
C20 Si2 C4 109.49(9) . . ?
C2 O1 C49 115.06(16) . . ?
C3 O2 C50 113.73(17) . . ?
C2 C1 C6 116.83(16) . . ?
C2 C1 Si1 120.06(13) . . ?
C6 C1 Si1 123.01(14) . . ?
O1 C2 C1 117.65(16) . . ?
O1 C2 C3 121.11(16) . . ?
C1 C2 C3 121.24(16) . . ?
O2 C3 C2 121.03(16) . . ?
O2 C3 C4 117.31(16) . . ?
C2 C3 C4 121.55(17) . . ?
C5 C4 C3 116.87(16) . . ?
C5 C4 Si2 123.17(13) . . ?
C3 C4 Si2 119.35(13) . . ?
C6 C5 C4 121.66(17) . . ?
C6 C5 H5 119.2 . . ?
C4 C5 H5 119.2 . . ?
C5 C6 C1 121.61(17) . . ?
C5 C6 H6 119.2 . . ?
C1 C6 H6 119.2 . . ?
C8 C7 Si1 115.88(14) . . ?
C8 C7 H7A 108.3 . . ?
Si1 C7 H7A 108.3 . . ?
C8 C7 H7B 108.3 . . ?
Si1 C7 H7B 108.3 . . ?
H7A C7 H7B 107.4 . . ?
C9 C8 C7 113.56(18) . . ?
C9 C8 H8A 108.9 . . ?
C7 C8 H8A 108.9 . . ?
C9 C8 H8B 108.9 . . ?
C7 C8 H8B 108.9 . . ?
H8A C8 H8B 107.7 . . ?
C8 C9 C10 112.73(17) . . ?
C8 C9 H9A 109.0 . . ?
C10 C9 H9A 109.0 . . ?
C8 C9 H9B 109.0 . . ?
C10 C9 H9B 109.0 . . ?
H9A C9 H9B 107.8 . . ?
C11 C10 C9 114.58(19) . . ?
C11 C10 H10A 108.6 . . ?
C9 C10 H10A 108.6 . . ?
C11 C10 H10B 108.6 . . ?
C9 C10 H10B 108.6 . . ?
H10A C10 H10B 107.6 . . ?
C10 C11 C12 113.8(2) . . ?
C10 C11 H11A 108.8 . . ?
C12 C11 H11A 108.8 . . ?
C10 C11 H11B 108.8 . . ?
C12 C11 H11B 108.8 . . ?
H11A C11 H11B 107.7 . . ?
C11 C12 C13 113.5(2) . . ?
C11 C12 H12A 108.9 . . ?
C13 C12 H12A 108.9 . . ?
C11 C12 H12B 108.9 . . ?
C13 C12 H12B 108.9 . . ?
H12A C12 H12B 107.7 . . ?
C12 C13 C14 113.4(2) . . ?
C12 C13 H13A 108.9 . . ?
C14 C13 H13A 108.9 . . ?
C12 C13 H13B 108.9 . . ?
C14 C13 H13B 108.9 . . ?
H13A C13 H13B 107.7 . . ?
C15 C14 C13 115.26(19) . . ?
C15 C14 H14A 108.5 . . ?
C13 C14 H14A 108.5 . . ?
C15 C14 H14B 108.5 . . ?
C13 C14 H14B 108.5 . . ?
H14A C14 H14B 107.5 . . ?
C14 C15 C16 113.5(2) . . ?
C14 C15 H15A 108.9 . . ?
C16 C15 H15A 108.9 . . ?
C14 C15 H15B 108.9 . . ?
C16 C15 H15B 108.9 . . ?
H15A C15 H15B 107.7 . . ?
C17 C16 C15 114.4(2) . . ?
C17 C16 H16A 108.7 . . ?
C15 C16 H16A 108.7 . . ?
C17 C16 H16B 108.7 . . ?
C15 C16 H16B 108.7 . . ?
H16A C16 H16B 107.6 . . ?
C18 C17 C16 116.30(18) . . ?
C18 C17 H17A 108.2 . . ?
C16 C17 H17A 108.2 . . ?
C18 C17 H17B 108.2 . . ?
C16 C17 H17B 108.2 . . ?
H17A C17 H17B 107.4 . . ?
C17 C18 C19 113.75(18) . . ?
C17 C18 H18A 108.8 . . ?
C19 C18 H18A 108.8 . . ?
C17 C18 H18B 108.8 . . ?
C19 C18 H18B 108.8 . . ?
H18A C18 H18B 107.7 . . ?
C20 C19 C18 111.99(17) . . ?
C20 C19 H19A 109.2 . . ?
C18 C19 H19A 109.2 . . ?
C20 C19 H19B 109.2 . . ?
C18 C19 H19B 109.2 . . ?
H19A C19 H19B 107.9 . . ?
C19 C20 Si2 118.79(15) . . ?
C19 C20 H20A 107.6 . . ?
Si2 C20 H20A 107.6 . . ?
C19 C20 H20B 107.6 . . ?
Si2 C20 H20B 107.6 . . ?
H20A C20 H20B 107.0 . . ?
C22 C21 Si1 115.45(13) . . ?
C22 C21 H21A 108.4 . . ?
Si1 C21 H21A 108.4 . . ?
C22 C21 H21B 108.4 . . ?
Si1 C21 H21B 108.4 . . ?
H21A C21 H21B 107.5 . . ?
C23 C22 C21 114.35(17) . . ?
C23 C22 H22A 108.7 . . ?
C21 C22 H22A 108.7 . . ?
C23 C22 H22B 108.7 . . ?
C21 C22 H22B 108.7 . . ?
H22A C22 H22B 107.6 . . ?
C22 C23 C24 113.68(17) . . ?
C22 C23 H23A 108.8 . . ?
C24 C23 H23A 108.8 . . ?
C22 C23 H23B 108.8 . . ?
C24 C23 H23B 108.8 . . ?
H23A C23 H23B 107.7 . . ?
C25 C24 C23 114.86(19) . . ?
C25 C24 H24A 108.6 . . ?
C23 C24 H24A 108.6 . . ?
C25 C24 H24B 108.6 . . ?
C23 C24 H24B 108.6 . . ?
H24A C24 H24B 107.5 . . ?
C26 C25 C24 114.49(19) . . ?
C26 C25 H25A 108.6 . . ?
C24 C25 H25A 108.6 . . ?
C26 C25 H25B 108.6 . . ?
C24 C25 H25B 108.6 . . ?
H25A C25 H25B 107.6 . . ?
C25 C26 C27 113.91(19) . . ?
C25 C26 H26A 108.8 . . ?
C27 C26 H26A 108.8 . . ?
C25 C26 H26B 108.8 . . ?
C27 C26 H26B 108.8 . . ?
H26A C26 H26B 107.7 . . ?
C28 C27 C26 113.0(2) . . ?
C28 C27 H27A 109.0 . . ?
C26 C27 H27A 109.0 . . ?
C28 C27 H27B 109.0 . . ?
C26 C27 H27B 109.0 . . ?
H27A C27 H27B 107.8 . . ?
C27 C28 C29 115.4(2) . . ?
C27 C28 H28A 108.4 . . ?
C29 C28 H28A 108.4 . . ?
C27 C28 H28B 108.4 . . ?
C29 C28 H28B 108.4 . . ?
H28A C28 H28B 107.5 . . ?
C30 C29 C28 114.4(2) . . ?
C30 C29 H29A 108.6 . . ?
C28 C29 H29A 108.6 . . ?
C30 C29 H29B 108.6 . . ?
C28 C29 H29B 108.6 . . ?
H29A C29 H29B 107.6 . . ?
C29 C30 C31 116.2(2) . . ?
C29 C30 H30A 108.2 . . ?
C31 C30 H30A 108.2 . . ?
C29 C30 H30B 108.2 . . ?
C31 C30 H30B 108.2 . . ?
H30A C30 H30B 107.4 . . ?
C32 C31 C30 113.0(2) . . ?
C32 C31 H31A 109.0 . . ?
C30 C31 H31A 109.0 . . ?
C32 C31 H31B 109.0 . . ?
C30 C31 H31B 109.0 . . ?
H31A C31 H31B 107.8 . . ?
C31 C32 C33 114.48(18) . . ?
C31 C32 H32A 108.6 . . ?
C33 C32 H32A 108.6 . . ?
C31 C32 H32B 108.6 . . ?
C33 C32 H32B 108.6 . . ?
H32A C32 H32B 107.6 . . ?
C34 C33 C32 113.53(18) . . ?
C34 C33 H33A 108.9 . . ?
C32 C33 H33A 108.9 . . ?
C34 C33 H33B 108.9 . . ?
C32 C33 H33B 108.9 . . ?
H33A C33 H33B 107.7 . . ?
C33 C34 Si2 117.59(14) . . ?
C33 C34 H34A 107.9 . . ?
Si2 C34 H34A 107.9 . . ?
C33 C34 H34B 107.9 . . ?
Si2 C34 H34B 107.9 . . ?
H34A C34 H34B 107.2 . . ?
C36 C35 Si1 115.77(15) . . ?
C36 C35 H35A 108.3 . . ?
Si1 C35 H35A 108.3 . . ?
C36 C35 H35B 108.3 . . ?
Si1 C35 H35B 108.3 . . ?
H35A C35 H35B 107.4 . . ?
C37 C36 C35 113.04(18) . . ?
C37 C36 H36A 109.0 . . ?
C35 C36 H36A 109.0 . . ?
C37 C36 H36B 109.0 . . ?
C35 C36 H36B 109.0 . . ?
H36A C36 H36B 107.8 . . ?
C38 C37 C36 113.44(19) . . ?
C38 C37 H37A 108.9 . . ?
C36 C37 H37A 108.9 . . ?
C38 C37 H37B 108.9 . . ?
C36 C37 H37B 108.9 . . ?
H37A C37 H37B 107.7 . . ?
C37 C38 C39 114.72(19) . . ?
C37 C38 H38A 108.6 . . ?
C39 C38 H38A 108.6 . . ?
C37 C38 H38B 108.6 . . ?
C39 C38 H38B 108.6 . . ?
H38A C38 H38B 107.6 . . ?
C40 C39 C38 114.79(18) . . ?
C40 C39 H39A 108.6 . . ?
C38 C39 H39A 108.6 . . ?
C40 C39 H39B 108.6 . . ?
C38 C39 H39B 108.6 . . ?
H39A C39 H39B 107.5 . . ?
C41 C40 C39 114.74(19) . . ?
C41 C40 H40A 108.6 . . ?
C39 C40 H40A 108.6 . . ?
C41 C40 H40B 108.6 . . ?
C39 C40 H40B 108.6 . . ?
H40A C40 H40B 107.6 . . ?
C40 C41 C42 113.10(19) . . ?
C40 C41 H41A 109.0 . . ?
C42 C41 H41A 109.0 . . ?
C40 C41 H41B 109.0 . . ?
C42 C41 H41B 109.0 . . ?
H41A C41 H41B 107.8 . . ?
C41 C42 C43 113.85(19) . . ?
C41 C42 H42A 108.8 . . ?
C43 C42 H42A 108.8 . . ?
C41 C42 H42B 108.8 . . ?
C43 C42 H42B 108.8 . . ?
H42A C42 H42B 107.7 . . ?
C44 C43 C42 114.2(2) . . ?
C44 C43 H43A 108.7 . . ?
C42 C43 H43A 108.7 . . ?
C44 C43 H43B 108.7 . . ?
C42 C43 H43B 108.7 . . ?
H43A C43 H43B 107.6 . . ?
C43 C44 C45 113.34(19) . . ?
C43 C44 H44A 108.9 . . ?
C45 C44 H44A 108.9 . . ?
C43 C44 H44B 108.9 . . ?
C45 C44 H44B 108.9 . . ?
H44A C44 H44B 107.7 . . ?
C46 C45 C44 114.14(18) . . ?
C46 C45 H45A 108.7 . . ?
C44 C45 H45A 108.7 . . ?
C46 C45 H45B 108.7 . . ?
C44 C45 H45B 108.7 . . ?
H45A C45 H45B 107.6 . . ?
C45 C46 C47 113.80(18) . . ?
C45 C46 H46A 108.8 . . ?
C47 C46 H46A 108.8 . . ?
C45 C46 H46B 108.8 . . ?
C47 C46 H46B 108.8 . . ?
H46A C46 H46B 107.7 . . ?
C46 C47 C48 114.96(18) . . ?
C46 C47 H47A 108.5 . . ?
C48 C47 H47A 108.5 . . ?
C46 C47 H47B 108.5 . . ?
C48 C47 H47B 108.5 . . ?
H47A C47 H47B 107.5 . . ?
C47 C48 Si2 117.32(15) . . ?
C47 C48 H48A 108.0 . . ?
Si2 C48 H48A 108.0 . . ?
C47 C48 H48B 108.0 . . ?
Si2 C48 H48B 108.0 . . ?
H48A C48 H48B 107.2 . . ?
O1 C49 H49A 109.5 . . ?
O1 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
O1 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
O2 C50 H50A 109.5 . . ?
O2 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
O2 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C135 Si3 C121 106.72(8) . . ?
C135 Si3 C107 110.14(8) . . ?
C121 Si3 C107 109.56(8) . . ?
C135 Si3 C101 110.81(8) . . ?
C121 Si3 C101 110.85(8) . . ?
C107 Si3 C101 108.73(8) . . ?
C148 Si4 C134 107.40(8) . . ?
C148 Si4 C120 108.52(8) . . ?
C134 Si4 C120 110.87(8) . . ?
C148 Si4 C104 111.79(8) . . ?
C134 Si4 C104 109.23(8) . . ?
C120 Si4 C104 109.03(8) . . ?
C102 O3 C149 113.93(14) . . ?
C103 O4 C150 113.46(14) . . ?
C106 C101 C102 116.27(14) . . ?
C106 C101 Si3 124.22(12) . . ?
C102 C101 Si3 119.50(12) . . ?
O3 C102 C103 120.90(14) . . ?
O3 C102 C101 117.38(14) . . ?
C103 C102 C101 121.68(14) . . ?
O4 C103 C102 120.62(14) . . ?
O4 C103 C104 117.55(14) . . ?
C102 C103 C104 121.79(14) . . ?
C103 C104 C105 116.26(14) . . ?
C103 C104 Si4 119.93(12) . . ?
C105 C104 Si4 123.73(12) . . ?
C106 C105 C104 121.72(15) . . ?
C106 C105 H105 119.1 . . ?
C104 C105 H105 119.1 . . ?
C105 C106 C101 122.04(15) . . ?
C105 C106 H106 119.0 . . ?
C101 C106 H106 119.0 . . ?
C108 C107 Si3 116.33(12) . . ?
C108 C107 H10C 108.2 . . ?
Si3 C107 H10C 108.2 . . ?
C108 C107 H10D 108.2 . . ?
Si3 C107 H10D 108.2 . . ?
H10C C107 H10D 107.4 . . ?
C109 C108 C107 113.98(16) . . ?
C109 C108 H10E 108.8 . . ?
C107 C108 H10E 108.8 . . ?
C109 C108 H10F 108.8 . . ?
C107 C108 H10F 108.8 . . ?
H10E C108 H10F 107.7 . . ?
C110 C109 C108 115.45(16) . . ?
C110 C109 H10G 108.4 . . ?
C108 C109 H10G 108.4 . . ?
C110 C109 H10H 108.4 . . ?
C108 C109 H10H 108.4 . . ?
H10G C109 H10H 107.5 . . ?
C111 C110 C109 114.65(18) . . ?
C111 C110 H11C 108.6 . . ?
C109 C110 H11C 108.6 . . ?
C111 C110 H11D 108.6 . . ?
C109 C110 H11D 108.6 . . ?
H11C C110 H11D 107.6 . . ?
C110 C111 C112 113.02(19) . . ?
C110 C111 H11E 109.0 . . ?
C112 C111 H11E 109.0 . . ?
C110 C111 H11F 109.0 . . ?
C112 C111 H11F 109.0 . . ?
H11E C111 H11F 107.8 . . ?
C113 C112 C111 115.6(2) . . ?
C113 C112 H11G 108.4 . . ?
C111 C112 H11G 108.4 . . ?
C113 C112 H11H 108.4 . . ?
C111 C112 H11H 108.4 . . ?
H11G C112 H11H 107.4 . . ?
C112 C113 C114 112.9(2) . . ?
C112 C113 H11I 109.0 . . ?
C114 C113 H11I 109.0 . . ?
C112 C113 H11J 109.0 . . ?
C114 C113 H11J 109.0 . . ?
H11I C113 H11J 107.8 . . ?
C113 C114 C115 115.3(2) . . ?
C113 C114 H11K 108.4 . . ?
C115 C114 H11K 108.4 . . ?
C113 C114 H11L 108.4 . . ?
C115 C114 H11L 108.4 . . ?
H11K C114 H11L 107.5 . . ?
C116 C115 C114 111.72(19) . . ?
C116 C115 H11M 109.3 . . ?
C114 C115 H11M 109.3 . . ?
C116 C115 H11N 109.3 . . ?
C114 C115 H11N 109.3 . . ?
H11M C115 H11N 107.9 . . ?
C115 C116 C117 115.37(18) . . ?
C115 C116 H11O 108.4 . . ?
C117 C116 H11O 108.4 . . ?
C115 C116 H11P 108.4 . . ?
C117 C116 H11P 108.4 . . ?
H11O C116 H11P 107.5 . . ?
C118 C117 C116 113.16(18) . . ?
C118 C117 H11Q 108.9 . . ?
C116 C117 H11Q 108.9 . . ?
C118 C117 H11R 108.9 . . ?
C116 C117 H11R 108.9 . . ?
H11Q C117 H11R 107.8 . . ?
C117 C118 C119 115.14(17) . . ?
C117 C118 H11S 108.5 . . ?
C119 C118 H11S 108.5 . . ?
C117 C118 H11T 108.5 . . ?
C119 C118 H11T 108.5 . . ?
H11S C118 H11T 107.5 . . ?
C120 C119 C118 114.58(16) . . ?
C120 C119 H11U 108.6 . . ?
C118 C119 H11U 108.6 . . ?
C120 C119 H11V 108.6 . . ?
C118 C119 H11V 108.6 . . ?
H11U C119 H11V 107.6 . . ?
C119 C120 Si4 116.33(13) . . ?
C119 C120 H12C 108.2 . . ?
Si4 C120 H12C 108.2 . . ?
C119 C120 H12D 108.2 . . ?
Si4 C120 H12D 108.2 . . ?
H12C C120 H12D 107.4 . . ?
C122 C121 Si3 118.70(13) . . ?
C122 C121 H12E 107.6 . . ?
Si3 C121 H12E 107.6 . . ?
C122 C121 H12F 107.6 . . ?
Si3 C121 H12F 107.6 . . ?
H12E C121 H12F 107.1 . . ?
C121 C122 C123 112.72(16) . . ?
C121 C122 H12G 109.0 . . ?
C123 C122 H12G 109.0 . . ?
C121 C122 H12H 109.0 . . ?
C123 C122 H12H 109.0 . . ?
H12G C122 H12H 107.8 . . ?
C124 C123 C122 115.98(17) . . ?
C124 C123 H12I 108.3 . . ?
C122 C123 H12I 108.3 . . ?
C124 C123 H12J 108.3 . . ?
C122 C123 H12J 108.3 . . ?
H12I C123 H12J 107.4 . . ?
C125 C124 C123 118.7(2) . . ?
C123 C124 C225 92.7(6) . . ?
C125 C124 H12K 107.6 . . ?
C123 C124 H12K 107.6 . . ?
C125 C124 H12L 107.6 . . ?
C123 C124 H12L 107.6 . . ?
H12K C124 H12L 107.1 . . ?
C124 C125 C126 114.4(2) . . ?
C124 C125 H12M 108.7 . . ?
C126 C125 H12M 108.7 . . ?
C124 C125 H12N 108.7 . . ?
C126 C125 H12N 108.7 . . ?
H12M C125 H12N 107.6 . . ?
C125 C126 C127 112.1(2) . . ?
C125 C126 H12O 109.2 . . ?
C127 C126 H12O 109.2 . . ?
C125 C126 H12P 109.2 . . ?
C127 C126 H12P 109.2 . . ?
H12O C126 H12P 107.9 . . ?
C226 C225 C124 115.2(12) . . ?
C226 C225 H22C 108.5 . . ?
C124 C225 H22C 108.5 . . ?
C226 C225 H22D 108.5 . . ?
C124 C225 H22D 108.5 . . ?
H22C C225 H22D 107.5 . . ?
C127 C226 C225 105.6(12) . . ?
C127 C226 H22E 110.6 . . ?
C225 C226 H22E 110.6 . . ?
C127 C226 H22F 110.6 . . ?
C225 C226 H22F 110.6 . . ?
H22E C226 H22F 108.7 . . ?
C226 C127 C128 132.9(7) . . ?
C128 C127 C126 113.62(19) . . ?
C128 C127 H12Q 108.8 . . ?
C126 C127 H12Q 108.8 . . ?
C128 C127 H12R 108.8 . . ?
C126 C127 H12R 108.8 . . ?
H12Q C127 H12R 107.7 . . ?
C129 C128 C127 118.5(2) . . ?
C229 C128 C127 135.0(5) . . ?
C129 C128 H12S 107.7 . . ?
C127 C128 H12S 107.7 . . ?
C129 C128 H12T 107.7 . . ?
C127 C128 H12T 107.7 . . ?
H12S C128 H12T 107.1 . . ?
C128 C129 C130 115.6(2) . . ?
C128 C129 H12U 108.4 . . ?
C130 C129 H12U 108.4 . . ?
C128 C129 H12V 108.4 . . ?
C130 C129 H12V 108.4 . . ?
H12U C129 H12V 107.4 . . ?
C131 C130 C129 114.0(2) . . ?
C131 C130 H13C 108.8 . . ?
C129 C130 H13C 108.8 . . ?
C131 C130 H13D 108.8 . . ?
C129 C130 H13D 108.8 . . ?
H13C C130 H13D 107.7 . . ?
C130 C131 C132 113.8(3) . . ?
C130 C131 H13E 108.8 . . ?
C132 C131 H13E 108.8 . . ?
C130 C131 H13F 108.8 . . ?
C132 C131 H13F 108.8 . . ?
H13E C131 H13F 107.7 . . ?
C131 C132 C133 114.6(2) . . ?
C131 C132 H13G 108.6 . . ?
C133 C132 H13G 108.6 . . ?
C131 C132 H13H 108.6 . . ?
C133 C132 H13H 108.6 . . ?
H13G C132 H13H 107.6 . . ?
C128 C229 C230 117.9(11) . . ?
C128 C229 H22G 107.8 . . ?
C230 C229 H22G 107.8 . . ?
C128 C229 H22H 107.8 . . ?
C230 C229 H22H 107.8 . . ?
H22G C229 H22H 107.2 . . ?
C231 C230 C229 112.5(15) . . ?
C231 C230 H23C 109.1 . . ?
C229 C230 H23C 109.1 . . ?
C231 C230 H23D 109.1 . . ?
C229 C230 H23D 109.1 . . ?
H23C C230 H23D 107.8 . . ?
C230 C231 C232 112.9(13) . . ?
C230 C231 H23E 109.0 . . ?
C232 C231 H23E 109.0 . . ?
C230 C231 H23F 109.0 . . ?
C232 C231 H23F 109.0 . . ?
H23E C231 H23F 107.8 . . ?
C231 C232 C133 112.9(8) . . ?
C231 C232 H23G 109.0 . . ?
C133 C232 H23G 109.0 . . ?
C231 C232 H23H 109.0 . . ?
C133 C232 H23H 109.0 . . ?
H23G C232 H23H 107.8 . . ?
C132 C133 C134 113.77(16) . . ?
C134 C133 C232 104.5(4) . . ?
C132 C133 H13I 108.8 . . ?
C134 C133 H13I 108.8 . . ?
C132 C133 H13J 108.8 . . ?
C134 C133 H13J 108.8 . . ?
H13I C133 H13J 107.7 . . ?
C133 C134 Si4 117.10(12) . . ?
C133 C134 H13K 108.0 . . ?
Si4 C134 H13K 108.0 . . ?
C133 C134 H13L 108.0 . . ?
Si4 C134 H13L 108.0 . . ?
H13K C134 H13L 107.3 . . ?
C136 C135 Si3 118.45(13) . . ?
C136 C135 H13M 107.7 . . ?
Si3 C135 H13M 107.7 . . ?
C136 C135 H13N 107.7 . . ?
Si3 C135 H13N 107.7 . . ?
H13M C135 H13N 107.1 . . ?
C237 C136 C135 118.5(4) . . ?
C135 C136 C137 109.9(2) . . ?
C135 C136 H13O 109.7 . . ?
C137 C136 H13O 109.7 . . ?
C135 C136 H13P 109.7 . . ?
C137 C136 H13P 109.7 . . ?
H13O C136 H13P 108.2 . . ?
C138 C137 C136 114.7(3) . . ?
C138 C137 H13Q 108.6 . . ?
C136 C137 H13Q 108.6 . . ?
C138 C137 H13R 108.6 . . ?
C136 C137 H13R 108.6 . . ?
H13Q C137 H13R 107.6 . . ?
C137 C138 C139 112.7(3) . . ?
C137 C138 H13S 109.0 . . ?
C139 C138 H13S 109.0 . . ?
C137 C138 H13T 109.0 . . ?
C139 C138 H13T 109.0 . . ?
H13S C138 H13T 107.8 . . ?
C138 C139 C140 112.5(3) . . ?
C138 C139 H13U 109.1 . . ?
C140 C139 H13U 109.1 . . ?
C138 C139 H13V 109.1 . . ?
C140 C139 H13V 109.1 . . ?
H13U C139 H13V 107.8 . . ?
C141 C140 C139 114.5(3) . . ?
C141 C140 H14C 108.6 . . ?
C139 C140 H14C 108.6 . . ?
C141 C140 H14D 108.6 . . ?
C139 C140 H14D 108.6 . . ?
H14C C140 H14D 107.6 . . ?
C140 C141 C142 110.9(4) . . ?
C140 C141 H14E 109.5 . . ?
C142 C141 H14E 109.5 . . ?
C140 C141 H14F 109.5 . . ?
C142 C141 H14F 109.5 . . ?
H14E C141 H14F 108.0 . . ?
C136 C237 C238 116.8(8) . . ?
C136 C237 H23I 108.1 . . ?
C238 C237 H23I 108.1 . . ?
C136 C237 H23J 108.1 . . ?
C238 C237 H23J 108.1 . . ?
H23I C237 H23J 107.3 . . ?
C239 C238 C237 116.5(10) . . ?
C239 C238 H23K 108.2 . . ?
C237 C238 H23K 108.2 . . ?
C239 C238 H23L 108.2 . . ?
C237 C238 H23L 108.2 . . ?
H23K C238 H23L 107.3 . . ?
C238 C239 C240 113.0(8) . . ?
C238 C239 H23M 109.0 . . ?
C240 C239 H23M 109.0 . . ?
C238 C239 H23N 109.0 . . ?
C240 C239 H23N 109.0 . . ?
H23M C239 H23N 107.8 . . ?
C241 C240 C239 120.7(7) . . ?
C241 C240 H24C 107.2 . . ?
C239 C240 H24C 107.2 . . ?
C241 C240 H24D 107.2 . . ?
C239 C240 H24D 107.2 . . ?
H24C C240 H24D 106.8 . . ?
C142 C241 C240 101.2(6) . . ?
C142 C241 H24E 111.5 . . ?
C240 C241 H24E 111.5 . . ?
C142 C241 H24F 111.5 . . ?
C240 C241 H24F 111.5 . . ?
H24E C241 H24F 109.3 . . ?
C241 C142 C143 134.3(5) . . ?
C143 C142 C141 108.1(3) . . ?
C143 C142 H14G 110.1 . . ?
C141 C142 H14G 110.1 . . ?
C143 C142 H14H 110.1 . . ?
C141 C142 H14H 110.1 . . ?
H14G C142 H14H 108.4 . . ?
C144 C143 C142 114.3(3) . . ?
C144 C143 H14I 108.7 . . ?
C142 C143 H14I 108.7 . . ?
C144 C143 H14J 108.7 . . ?
C142 C143 H14J 108.7 . . ?
H14I C143 H14J 107.6 . . ?
C143 C144 C145 114.9(2) . . ?
C143 C144 H14K 108.5 . . ?
C145 C144 H14K 108.5 . . ?
C143 C144 H14L 108.5 . . ?
C145 C144 H14L 108.5 . . ?
H14K C144 H14L 107.5 . . ?
C144 C145 C146 116.02(19) . . ?
C144 C145 H14M 108.3 . . ?
C146 C145 H14M 108.3 . . ?
C144 C145 H14N 108.3 . . ?
C146 C145 H14N 108.3 . . ?
H14M C145 H14N 107.4 . . ?
C147 C146 C145 114.42(17) . . ?
C147 C146 H14O 108.7 . . ?
C145 C146 H14O 108.7 . . ?
C147 C146 H14P 108.7 . . ?
C145 C146 H14P 108.7 . . ?
H14O C146 H14P 107.6 . . ?
C146 C147 C148 112.25(15) . . ?
C146 C147 H14Q 109.2 . . ?
C148 C147 H14Q 109.2 . . ?
C146 C147 H14R 109.2 . . ?
C148 C147 H14R 109.2 . . ?
H14Q C147 H14R 107.9 . . ?
C147 C148 Si4 117.33(12) . . ?
C147 C148 H14S 108.0 . . ?
Si4 C148 H14S 108.0 . . ?
C147 C148 H14T 108.0 . . ?
Si4 C148 H14T 108.0 . . ?
H14S C148 H14T 107.2 . . ?
O3 C149 H14U 109.5 . . ?
O3 C149 H14V 109.5 . . ?
H14U C149 H14V 109.5 . . ?
O3 C149 H14W 109.5 . . ?
H14U C149 H14W 109.5 . . ?
H14V C149 H14W 109.5 . . ?
O4 C150 H15C 109.5 . . ?
O4 C150 H15D 109.5 . . ?
H15C C150 H15D 109.5 . . ?
O4 C150 H15E 109.5 . . ?
H15C C150 H15E 109.5 . . ?
H15D C150 H15E 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Si1 C21 1.876(2) . ?
Si1 C35 1.877(2) . ?
Si1 C7 1.879(2) . ?
Si1 C1 1.8907(18) . ?
Si2 C34 1.874(2) . ?
Si2 C48 1.877(2) . ?
Si2 C20 1.877(2) . ?
Si2 C4 1.8954(18) . ?
O1 C2 1.388(2) . ?
O1 C49 1.426(3) . ?
O2 C3 1.387(2) . ?
O2 C50 1.432(3) . ?
C1 C2 1.395(3) . ?
C1 C6 1.406(2) . ?
C2 C3 1.399(3) . ?
C3 C4 1.401(2) . ?
C4 C5 1.393(3) . ?
C5 C6 1.389(3) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.532(3) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 C9 1.532(3) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 C10 1.546(3) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 C11 1.508(3) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 C12 1.517(3) . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C12 C13 1.519(4) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 C14 1.532(3) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C15 1.514(3) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 C16 1.528(3) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 C17 1.518(3) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 C18 1.518(3) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 C19 1.537(3) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 C20 1.527(3) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C22 1.529(3) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C22 C23 1.520(3) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C23 C24 1.525(3) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C24 C25 1.521(3) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C25 C26 1.514(3) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 C27 1.525(3) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 C28 1.517(3) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 C29 1.525(4) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 C30 1.523(4) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 C31 1.526(3) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C32 1.514(4) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C32 C33 1.527(3) . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C33 C34 1.520(3) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C35 C36 1.536(3) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 C37 1.526(3) . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
C37 C38 1.521(3) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 C39 1.528(3) . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C39 C40 1.527(3) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C40 C41 1.517(3) . ?
C40 H40A 0.9900 . ?
C40 H40B 0.9900 . ?
C41 C42 1.518(3) . ?
C41 H41A 0.9900 . ?
C41 H41B 0.9900 . ?
C42 C43 1.528(4) . ?
C42 H42A 0.9900 . ?
C42 H42B 0.9900 . ?
C43 C44 1.522(3) . ?
C43 H43A 0.9900 . ?
C43 H43B 0.9900 . ?
C44 C45 1.525(3) . ?
C44 H44A 0.9900 . ?
C44 H44B 0.9900 . ?
C45 C46 1.508(3) . ?
C45 H45A 0.9900 . ?
C45 H45B 0.9900 . ?
C46 C47 1.527(3) . ?
C46 H46A 0.9900 . ?
C46 H46B 0.9900 . ?
C47 C48 1.528(4) . ?
C47 H47A 0.9900 . ?
C47 H47B 0.9900 . ?
C48 H48A 0.9900 . ?
C48 H48B 0.9900 . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
Si3 C135 1.8803(18) . ?
Si3 C121 1.8809(18) . ?
Si3 C107 1.8822(18) . ?
Si3 C101 1.8867(17) . ?
Si4 C148 1.8743(18) . ?
Si4 C134 1.8790(18) . ?
Si4 C120 1.8820(18) . ?
Si4 C104 1.8896(17) . ?
O3 C102 1.3886(19) . ?
O3 C149 1.435(2) . ?
O4 C103 1.3910(18) . ?
O4 C150 1.435(2) . ?
C101 C106 1.399(2) . ?
C101 C102 1.400(2) . ?
C102 C103 1.391(2) . ?
C103 C104 1.401(2) . ?
C104 C105 1.401(2) . ?
C105 C106 1.387(2) . ?
C105 H105 0.9500 . ?
C106 H106 0.9500 . ?
C107 C108 1.538(2) . ?
C107 H10C 0.9900 . ?
C107 H10D 0.9900 . ?
C108 C109 1.536(2) . ?
C108 H10E 0.9900 . ?
C108 H10F 0.9900 . ?
C109 C110 1.527(3) . ?
C109 H10G 0.9900 . ?
C109 H10H 0.9900 . ?
C110 C111 1.519(3) . ?
C110 H11C 0.9900 . ?
C110 H11D 0.9900 . ?
C111 C112 1.545(3) . ?
C111 H11E 0.9900 . ?
C111 H11F 0.9900 . ?
C112 C113 1.517(4) . ?
C112 H11G 0.9900 . ?
C112 H11H 0.9900 . ?
C113 C114 1.517(4) . ?
C113 H11I 0.9900 . ?
C113 H11J 0.9900 . ?
C114 C115 1.531(4) . ?
C114 H11K 0.9900 . ?
C114 H11L 0.9900 . ?
C115 C116 1.508(3) . ?
C115 H11M 0.9900 . ?
C115 H11N 0.9900 . ?
C116 C117 1.523(3) . ?
C116 H11O 0.9900 . ?
C116 H11P 0.9900 . ?
C117 C118 1.520(3) . ?
C117 H11Q 0.9900 . ?
C117 H11R 0.9900 . ?
C118 C119 1.534(3) . ?
C118 H11S 0.9900 . ?
C118 H11T 0.9900 . ?
C119 C120 1.533(2) . ?
C119 H11U 0.9900 . ?
C119 H11V 0.9900 . ?
C120 H12C 0.9900 . ?
C120 H12D 0.9900 . ?
C121 C122 1.520(3) . ?
C121 H12E 0.9900 . ?
C121 H12F 0.9900 . ?
C122 C123 1.528(3) . ?
C122 H12G 0.9900 . ?
C122 H12H 0.9900 . ?
C123 C124 1.521(3) . ?
C123 H12I 0.9900 . ?
C123 H12J 0.9900 . ?
C124 C125 1.483(4) . ?
C124 C225 1.780(14) . ?
C124 H12K 0.9900 . ?
C124 H12L 0.9900 . ?
C125 C126 1.531(4) . ?
C125 H12M 0.9900 . ?
C125 H12N 0.9900 . ?
C126 C127 1.560(4) . ?
C126 H12O 0.9900 . ?
C126 H12P 0.9900 . ?
C225 C226 1.47(2) . ?
C225 H22C 0.9900 . ?
C225 H22D 0.9900 . ?
C226 C127 1.359(13) . ?
C226 H22E 0.9900 . ?
C226 H22F 0.9900 . ?
C127 C128 1.498(3) . ?
C127 H12Q 0.9900 . ?
C127 H12R 0.9900 . ?
C128 C129 1.468(4) . ?
C128 C229 1.492(11) . ?
C128 H12S 0.9900 . ?
C128 H12T 0.9900 . ?
C129 C130 1.530(4) . ?
C129 H12U 0.9900 . ?
C129 H12V 0.9900 . ?
C130 C131 1.525(5) . ?
C130 H13C 0.9900 . ?
C130 H13D 0.9900 . ?
C131 C132 1.532(4) . ?
C131 H13E 0.9900 . ?
C131 H13F 0.9900 . ?
C132 C133 1.534(3) . ?
C132 H13G 0.9900 . ?
C132 H13H 0.9900 . ?
C229 C230 1.531(19) . ?
C229 H22G 0.9900 . ?
C229 H22H 0.9900 . ?
C230 C231 1.51(2) . ?
C230 H23C 0.9900 . ?
C230 H23D 0.9900 . ?
C231 C232 1.52(2) . ?
C231 H23E 0.9900 . ?
C231 H23F 0.9900 . ?
C232 C133 1.620(9) . ?
C232 H23G 0.9900 . ?
C232 H23H 0.9900 . ?
C133 C134 1.535(3) . ?
C133 H13I 0.9900 . ?
C133 H13J 0.9900 . ?
C134 H13K 0.9900 . ?
C134 H13L 0.9900 . ?
C135 C136 1.530(3) . ?
C135 H13M 0.9900 . ?
C135 H13N 0.9900 . ?
C136 C237 1.479(9) . ?
C136 C137 1.566(5) . ?
C136 H13O 0.9900 . ?
C136 H13P 0.9900 . ?
C137 C138 1.527(5) . ?
C137 H13Q 0.9900 . ?
C137 H13R 0.9900 . ?
C138 C139 1.531(4) . ?
C138 H13S 0.9900 . ?
C138 H13T 0.9900 . ?
C139 C140 1.543(5) . ?
C139 H13U 0.9900 . ?
C139 H13V 0.9900 . ?
C140 C141 1.502(5) . ?
C140 H14C 0.9900 . ?
C140 H14D 0.9900 . ?
C141 C142 1.609(6) . ?
C141 H14E 0.9900 . ?
C141 H14F 0.9900 . ?
C237 C238 1.535(16) . ?
C237 H23I 0.9900 . ?
C237 H23J 0.9900 . ?
C238 C239 1.493(14) . ?
C238 H23K 0.9900 . ?
C238 H23L 0.9900 . ?
C239 C240 1.523(11) . ?
C239 H23M 0.9900 . ?
C239 H23N 0.9900 . ?
C240 C241 1.520(11) . ?
C240 H24C 0.9900 . ?
C240 H24D 0.9900 . ?
C241 C142 1.437(8) . ?
C241 H24E 0.9900 . ?
C241 H24F 0.9900 . ?
C142 C143 1.519(5) . ?
C142 H14G 0.9900 . ?
C142 H14H 0.9900 . ?
C143 C144 1.495(4) . ?
C143 H14I 0.9900 . ?
C143 H14J 0.9900 . ?
C144 C145 1.508(3) . ?
C144 H14K 0.9900 . ?
C144 H14L 0.9900 . ?
C145 C146 1.538(3) . ?
C145 H14M 0.9900 . ?
C145 H14N 0.9900 . ?
C146 C147 1.527(3) . ?
C146 H14O 0.9900 . ?
C146 H14P 0.9900 . ?
C147 C148 1.532(3) . ?
C147 H14Q 0.9900 . ?
C147 H14R 0.9900 . ?
C148 H14S 0.9900 . ?
C148 H14T 0.9900 . ?
C149 H14U 0.9800 . ?
C149 H14V 0.9800 . ?
C149 H14W 0.9800 . ?
C150 H15C 0.9800 . ?
C150 H15D 0.9800 . ?
C150 H15E 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C21 Si1 C1 C2 -49.38(18) . . . . ?
C35 Si1 C1 C2 72.41(17) . . . . ?
C7 Si1 C1 C2 -170.56(15) . . . . ?
C21 Si1 C1 C6 134.22(17) . . . . ?
C35 Si1 C1 C6 -103.99(17) . . . . ?
C7 Si1 C1 C6 13.05(19) . . . . ?
C49 O1 C2 C1 -119.6(2) . . . . ?
C49 O1 C2 C3 61.6(3) . . . . ?
C6 C1 C2 O1 178.21(17) . . . . ?
Si1 C1 C2 O1 1.6(2) . . . . ?
C6 C1 C2 C3 -3.0(3) . . . . ?
Si1 C1 C2 C3 -179.57(15) . . . . ?
C50 O2 C3 C2 64.8(3) . . . . ?
C50 O2 C3 C4 -119.0(2) . . . . ?
O1 C2 C3 O2 0.7(3) . . . . ?
C1 C2 C3 O2 -178.09(18) . . . . ?
O1 C2 C3 C4 -175.28(18) . . . . ?
C1 C2 C3 C4 5.9(3) . . . . ?
O2 C3 C4 C5 179.55(18) . . . . ?
C2 C3 C4 C5 -4.3(3) . . . . ?
O2 C3 C4 Si2 -9.2(3) . . . . ?
C2 C3 C4 Si2 166.94(15) . . . . ?
C34 Si2 C4 C5 -131.72(17) . . . . ?
C48 Si2 C4 C5 109.59(18) . . . . ?
C20 Si2 C4 C5 -6.9(2) . . . . ?
C34 Si2 C4 C3 57.58(18) . . . . ?
C48 Si2 C4 C3 -61.10(19) . . . . ?
C20 Si2 C4 C3 -177.64(16) . . . . ?
C3 C4 C5 C6 0.1(3) . . . . ?
Si2 C4 C5 C6 -170.85(16) . . . . ?
C4 C5 C6 C1 2.8(3) . . . . ?
C2 C1 C6 C5 -1.3(3) . . . . ?
Si1 C1 C6 C5 175.21(16) . . . . ?
C21 Si1 C7 C8 -50.96(16) . . . . ?
C35 Si1 C7 C8 -172.59(14) . . . . ?
C1 Si1 C7 C8 70.65(16) . . . . ?
Si1 C7 C8 C9 -167.46(14) . . . . ?
C7 C8 C9 C10 79.0(2) . . . . ?
C8 C9 C10 C11 76.4(2) . . . . ?
C9 C10 C11 C12 178.70(18) . . . . ?
C10 C11 C12 C13 -168.5(2) . . . . ?
C11 C12 C13 C14 175.6(2) . . . . ?
C12 C13 C14 C15 79.8(3) . . . . ?
C13 C14 C15 C16 73.7(3) . . . . ?
C14 C15 C16 C17 169.01(19) . . . . ?
C15 C16 C17 C18 61.9(3) . . . . ?
C16 C17 C18 C19 66.0(3) . . . . ?
C17 C18 C19 C20 177.45(17) . . . . ?
C18 C19 C20 Si2 -178.78(14) . . . . ?
C34 Si2 C20 C19 51.92(18) . . . . ?
C48 Si2 C20 C19 168.76(16) . . . . ?
C4 Si2 C20 C19 -73.78(18) . . . . ?
C35 Si1 C21 C22 -158.50(15) . . . . ?
C7 Si1 C21 C22 81.28(17) . . . . ?
C1 Si1 C21 C22 -38.35(18) . . . . ?
Si1 C21 C22 C23 173.58(15) . . . . ?
C21 C22 C23 C24 -177.33(19) . . . . ?
C22 C23 C24 C25 69.6(3) . . . . ?
C23 C24 C25 C26 -169.05(19) . . . . ?
C24 C25 C26 C27 -178.27(18) . . . . ?
C25 C26 C27 C28 -162.6(2) . . . . ?
C26 C27 C28 C29 -176.6(2) . . . . ?
C27 C28 C29 C30 -48.5(3) . . . . ?
C28 C29 C30 C31 -55.1(3) . . . . ?
C29 C30 C31 C32 171.9(2) . . . . ?
C30 C31 C32 C33 -159.75(19) . . . . ?
C31 C32 C33 C34 174.25(18) . . . . ?
C32 C33 C34 Si2 -158.64(15) . . . . ?
C48 Si2 C34 C33 163.83(15) . . . . ?
C20 Si2 C34 C33 -79.38(17) . . . . ?
C4 Si2 C34 C33 44.36(18) . . . . ?
C21 Si1 C35 C36 -46.17(18) . . . . ?
C7 Si1 C35 C36 75.21(17) . . . . ?
C1 Si1 C35 C36 -168.17(15) . . . . ?
Si1 C35 C36 C37 -173.66(15) . . . . ?
C35 C36 C37 C38 77.0(2) . . . . ?
C36 C37 C38 C39 -169.72(18) . . . . ?
C37 C38 C39 C40 61.9(3) . . . . ?
C38 C39 C40 C41 52.3(3) . . . . ?
C39 C40 C41 C42 173.57(19) . . . . ?
C40 C41 C42 C43 173.3(2) . . . . ?
C41 C42 C43 C44 -70.3(3) . . . . ?
C42 C43 C44 C45 -174.86(19) . . . . ?
C43 C44 C45 C46 174.34(19) . . . . ?
C44 C45 C46 C47 -178.64(18) . . . . ?
C45 C46 C47 C48 174.04(18) . . . . ?
C46 C47 C48 Si2 87.2(2) . . . . ?
C34 Si2 C48 C47 178.91(15) . . . . ?
C20 Si2 C48 C47 59.29(17) . . . . ?
C4 Si2 C48 C47 -58.80(17) . . . . ?
C135 Si3 C101 C106 -122.43(15) . . . . ?
C121 Si3 C101 C106 119.26(15) . . . . ?
C107 Si3 C101 C106 -1.24(17) . . . . ?
C135 Si3 C101 C102 56.56(15) . . . . ?
C121 Si3 C101 C102 -61.76(15) . . . . ?
C107 Si3 C101 C102 177.75(13) . . . . ?
C149 O3 C102 C103 -64.3(2) . . . . ?
C149 O3 C102 C101 117.72(17) . . . . ?
C106 C101 C102 O3 -178.52(14) . . . . ?
Si3 C101 C102 O3 2.4(2) . . . . ?
C106 C101 C102 C103 3.6(2) . . . . ?
Si3 C101 C102 C103 -175.51(13) . . . . ?
C150 O4 C103 C102 -65.2(2) . . . . ?
C150 O4 C103 C104 117.14(18) . . . . ?
O3 C102 C103 O4 -1.1(2) . . . . ?
C101 C102 C103 O4 176.79(15) . . . . ?
O3 C102 C103 C104 176.53(15) . . . . ?
C101 C102 C103 C104 -5.6(3) . . . . ?
O4 C103 C104 C105 -179.29(15) . . . . ?
C102 C103 C104 C105 3.1(2) . . . . ?
O4 C103 C104 Si4 3.6(2) . . . . ?
C102 C103 C104 Si4 -174.01(13) . . . . ?
C148 Si4 C104 C103 -62.39(15) . . . . ?
C134 Si4 C104 C103 56.34(15) . . . . ?
C120 Si4 C104 C103 177.63(13) . . . . ?
C148 Si4 C104 C105 120.79(15) . . . . ?
C134 Si4 C104 C105 -120.49(15) . . . . ?
C120 Si4 C104 C105 0.80(17) . . . . ?
C103 C104 C105 C106 1.3(2) . . . . ?
Si4 C104 C105 C106 178.19(13) . . . . ?
C104 C105 C106 C101 -3.2(3) . . . . ?
C102 C101 C106 C105 0.8(2) . . . . ?
Si3 C101 C106 C105 179.77(13) . . . . ?
C135 Si3 C107 C108 46.50(16) . . . . ?
C121 Si3 C107 C108 163.61(14) . . . . ?
C101 Si3 C107 C108 -75.10(15) . . . . ?
Si3 C107 C108 C109 -174.10(14) . . . . ?
C107 C108 C109 C110 -65.1(3) . . . . ?
C108 C109 C110 C111 -59.2(2) . . . . ?
C109 C110 C111 C112 -166.51(17) . . . . ?
C110 C111 C112 C113 -173.56(19) . . . . ?
C111 C112 C113 C114 72.9(3) . . . . ?
C112 C113 C114 C115 -173.3(2) . . . . ?
C113 C114 C115 C116 174.6(2) . . . . ?
C114 C115 C116 C117 -164.94(19) . . . . ?
C115 C116 C117 C118 179.08(17) . . . . ?
C116 C117 C118 C119 -57.0(2) . . . . ?
C117 C118 C119 C120 -58.5(2) . . . . ?
C118 C119 C120 Si4 -176.01(14) . . . . ?
C148 Si4 C120 C119 151.27(14) . . . . ?
C134 Si4 C120 C119 33.54(16) . . . . ?
C104 Si4 C120 C119 -86.75(15) . . . . ?
C135 Si3 C121 C122 178.23(13) . . . . ?
C107 Si3 C121 C122 59.00(16) . . . . ?
C101 Si3 C121 C122 -61.00(16) . . . . ?
Si3 C121 C122 C123 173.62(13) . . . . ?
C121 C122 C123 C124 168.34(18) . . . . ?
C122 C123 C124 C125 58.5(3) . . . . ?
C122 C123 C124 C225 75.1(5) . . . . ?
C123 C124 C125 C126 69.9(3) . . . . ?
C124 C125 C126 C127 -175.7(2) . . . . ?
C123 C124 C225 C226 173.3(11) . . . . ?
C124 C225 C226 C127 -178.2(8) . . . . ?
C225 C226 C127 C128 110.4(10) . . . . ?
C125 C126 C127 C128 -168.6(2) . . . . ?
C127 C128 C129 C130 -56.8(3) . . . . ?
C128 C129 C130 C131 -58.6(3) . . . . ?
C129 C130 C131 C132 -162.7(3) . . . . ?
C130 C131 C132 C133 -65.9(3) . . . . ?
C127 C128 C229 C230 21.9(16) . . . . ?
C128 C229 C230 C231 80.6(17) . . . . ?
C229 C230 C231 C232 165.7(12) . . . . ?
C230 C231 C232 C133 59.0(15) . . . . ?
C131 C132 C133 C134 176.7(2) . . . . ?
C231 C232 C133 C134 175.1(8) . . . . ?
C132 C133 C134 Si4 168.29(15) . . . . ?
C232 C133 C134 Si4 -147.4(5) . . . . ?
C148 Si4 C134 C133 157.98(14) . . . . ?
C120 Si4 C134 C133 -83.62(16) . . . . ?
C104 Si4 C134 C133 36.55(16) . . . . ?
C121 Si3 C135 C136 147.34(15) . . . . ?
C107 Si3 C135 C136 -93.80(16) . . . . ?
C101 Si3 C135 C136 26.55(17) . . . . ?
Si3 C135 C136 C237 163.1(6) . . . . ?
Si3 C135 C136 C137 -173.40(19) . . . . ?
C135 C136 C137 C138 168.5(2) . . . . ?
C136 C137 C138 C139 69.2(4) . . . . ?
C137 C138 C139 C140 174.6(3) . . . . ?
C138 C139 C140 C141 70.1(4) . . . . ?
C139 C140 C141 C142 74.7(5) . . . . ?
C135 C136 C237 C238 -175.3(8) . . . . ?
C136 C237 C238 C239 -54.9(15) . . . . ?
C237 C238 C239 C240 -164.1(9) . . . . ?
C238 C239 C240 C241 -61.9(12) . . . . ?
C239 C240 C241 C142 -63.2(10) . . . . ?
C240 C241 C142 C143 -70.6(8) . . . . ?
C140 C141 C142 C143 -174.5(3) . . . . ?
C241 C142 C143 C144 -152.8(6) . . . . ?
C141 C142 C143 C144 178.4(3) . . . . ?
C142 C143 C144 C145 -176.3(2) . . . . ?
C143 C144 C145 C146 65.6(3) . . . . ?
C144 C145 C146 C147 61.1(3) . . . . ?
C145 C146 C147 C148 171.72(17) . . . . ?
C146 C147 C148 Si4 176.13(13) . . . . ?
C134 Si4 C148 C147 178.20(13) . . . . ?
C120 Si4 C148 C147 58.28(15) . . . . ?
C104 Si4 C148 C147 -62.00(15) . . . . ?
