Information card for entry 7218790

Structure parameters

• Chemical name: [Pt(bpy){NH=C(pz)NC(Ph)=NH}]BF4.H2O
• Formula: C21 H20 B F4 N7 O Pt
• Calculated formula: C21 H18 B F4 N7 O Pt
• SMILES: [Pt]12([n]3c(c4[n]2cccc4)cccc3)NC(=NC(=[NH]1)c1ccccc1)n1nccc1.[B](F)(F)(F)[F-].O
• Title of publication: Highly luminescent imidoylamidinato platinum(ii) complexes formed by the coupling of 1H-pyrazole-1-carboxamidine with nitriles used as reaction solvents
• Authors of publication: Tanaka, Tomohiro; Nouchi, Rie; Nakao, Yoshihide; Arikawa, Yasuhiro; Umakoshi, Keisuke
• Journal of publication: RSC Adv.
• Year of publication: 2014
• Journal volume: 4
• Journal issue: 107
• Pages of publication: 62186
• a: 7.6686 ± 0.0018 Å
• b: 21.278 ± 0.005 Å
• c: 13.326 ± 0.004 Å
• α: 90°
• β: 90.037 ± 0.005°
• γ: 90°
• Cell volume: 2174.4 ± 1 ų
• Cell temperature: 93 K
• Ambient diffraction temperature: 93 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.0322
• Weighted residual factors for all reflections included in the refinement: 0.0692
• Goodness-of-fit parameter for all reflections included in the refinement: 1.056
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No