Information card for entry 7246159

Structure parameters

• Formula: C51 H39 Cl2 O7 Os3 P2 Sb
• Calculated formula: C51 H39 Cl2 O7 Os3 P2 Sb
• SMILES: [Os]1234([Os]5([Os]1([Sb](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])([c]13c([P]5(C[P]2(c2ccccc2)c2ccccc2)c2ccccc2)cccc1)[H]4)(C#[O])(C#[O])C#[O])(C#[O])C#[O].C(Cl)Cl
• Title of publication: Reactions of diphosphine-stabilized Os3 clusters with triphenylantimony: syntheses and structures of new antimony-containing Os3 clusters via Sb–Ph bond cleavage
• Authors of publication: Islam, Fahmida; Hasan, Md. Sohag; Ghosh, Shishir; Richmond, Michael G.; Kabir, Shariff E.; Roesky, Herbert W.
• Journal of publication: RSC Advances
• Year of publication: 2023
• Journal volume: 13
• Journal issue: 5
• Pages of publication: 2841 - 2851
• a: 19.6929 ± 0.001 Å
• b: 13.9599 ± 0.0007 Å
• c: 20.1424 ± 0.001 Å
• α: 90°
• β: 113.639 ± 0.001°
• γ: 90°
• Cell volume: 5072.7 ± 0.4 ų
• Cell temperature: 210 ± 1 K
• Ambient diffraction temperature: 210 ± 1 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0522
• Residual factor for significantly intense reflections: 0.029
• Weighted residual factors for significantly intense reflections: 0.0498
• Weighted residual factors for all reflections included in the refinement: 0.0559
• Goodness-of-fit parameter for all reflections included in the refinement: 1.025
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No