#------------------------------------------------------------------------------
#$Date: 2025-07-06 17:07:34 +0200 (Sun 06 de Jul de 2025) $
#$Revision: 300712 $
#$URL: svn://www.crystallography.net/cod/cif/7/25/05/7250539.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7250539
loop_
_publ_author_name
'Lin, Yang'
'Zhang, Wenxi'
'Lv, Yanjie'
'Zhao, Yihe'
'Cui, Hongtao'
'Sun, Jing'
'Li, Xiao'
'Zhou, Dongling'
'Su, Zhongmin'
_publ_section_title
;
 Lanthanide metal--organic frameworks as multifunctional sensors for
 chemicals and temperature
;
_journal_issue                   25
_journal_name_full               CrystEngComm
_journal_page_first              4351
_journal_page_last               4359
_journal_paper_doi               10.1039/D5CE00382B
_journal_volume                  27
_journal_year                    2025
_chemical_formula_moiety         'C23 H11 Eu N3 O11'
_chemical_formula_sum            'C23 H11 Eu N3 O11'
_chemical_formula_weight         657.31
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_audit_creation_date             2024-11-06
_audit_creation_method
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_audit_update_record
;
2024-11-12 deposited with the CCDC.	2025-05-23 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 118.632(2)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   28.4963(16)
_cell_length_b                   10.0575(5)
_cell_length_c                   27.113(2)
_cell_measurement_reflns_used    9940
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.055
_cell_measurement_theta_min      2.483
_cell_volume                     6820.4(7)
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.967
_diffrn_measured_fraction_theta_max 0.967
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0404
_diffrn_reflns_av_unetI/netI     0.0317
_diffrn_reflns_Laue_measured_fraction_full 0.967
_diffrn_reflns_Laue_measured_fraction_max 0.967
_diffrn_reflns_limit_h_max       33
_diffrn_reflns_limit_h_min       -33
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            24599
_diffrn_reflns_point_group_measured_fraction_full 0.967
_diffrn_reflns_point_group_measured_fraction_max 0.967
_diffrn_reflns_theta_full        24.999
_diffrn_reflns_theta_max         24.999
_diffrn_reflns_theta_min         2.522
_diffrn_source_current           0.9
_diffrn_source_power             0.0405
_diffrn_source_voltage           45.0
_exptl_absorpt_coefficient_mu    1.887
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.5671
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details
;
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.280
_exptl_crystal_description       block
_exptl_crystal_F_000             2568
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.21
_refine_diff_density_max         1.891
_refine_diff_density_min         -0.707
_refine_diff_density_rms         0.113
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.086
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     353
_refine_ls_number_reflns         5798
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.085
_refine_ls_R_factor_all          0.0454
_refine_ls_R_factor_gt           0.0375
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0418P)²+49.1404P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0947
_refine_ls_wR_factor_ref         0.0975
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5038
_reflns_number_total             5798
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5ce00382b2.cif
_cod_data_source_block           CUST-924
_cod_depositor_comments
'Adding full bibliography for 7250536--7250544.cif.'
_cod_original_cell_volume        6820.3(8)
_cod_database_code               7250539
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(Eu1) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(O4) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
3. Others
 Sof(O4A)=1-FVAR(1)
 Sof(O4)=FVAR(1)
4.a Aromatic/amide H refined with riding coordinates:
 N3(H3), C23(H23), C20(H20), C17(H17), N2(H2), C3(H3A), C8(H8), C6(H6),
 C11(H11), C12(H12), C13(H13)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.35966(2) 0.68116(2) 0.66949(2) 0.02352(10) Uani 1 1 d . U . . .
O1 O 0.23368(14) 0.8108(3) 0.36261(14) 0.0324(8) Uani 1 1 d . . . . .
O10 O 0.62699(19) 0.5343(3) 0.75663(15) 0.0493(11) Uani 1 1 d . . . . .
O7 O 0.62947(17) -0.1769(3) 0.75492(15) 0.0396(9) Uani 1 1 d . . . . .
N3 N 0.57425(19) 0.1889(4) 0.61046(16) 0.0325(10) Uani 1 1 d . . . . .
H3 H 0.551727 0.252475 0.594772 0.039 Uiso 1 1 calc R U . . .
O8 O 0.64937(18) -0.0777(4) 0.83197(14) 0.0462(11) Uani 1 1 d . . . . .
O5 O 0.40952(19) 0.4255(5) 0.38130(16) 0.0594(13) Uani 1 1 d . . . . .
O2 O 0.2641(2) 0.6921(5) 0.31913(16) 0.0612(14) Uani 1 1 d . . . . .
C23 C 0.60967(19) 0.0607(5) 0.69703(19) 0.0264(10) Uani 1 1 d . . . . .
H23 H 0.602737 -0.018646 0.677150 0.032 Uiso 1 1 calc R U . . .
O3 O 0.3205(2) 0.7206(6) 0.56950(17) 0.0710(16) Uani 1 1 d . . . . .
C21 C 0.63019(19) 0.0592(4) 0.75420(19) 0.0237(10) Uani 1 1 d . . . . .
O6 O 0.6139(2) 0.0134(4) 0.59446(17) 0.0595(13) Uani 1 1 d . . . . .
O9 O 0.65666(19) 0.4322(4) 0.83560(14) 0.0497(11) Uani 1 1 d . . . . .
C16 C 0.59933(19) 0.1811(5) 0.66905(19) 0.0256(10) Uani 1 1 d . . . . .
N1 N 0.51030(16) 0.2436(4) 0.50138(16) 0.0266(9) Uani 1 1 d . . . . .
C20 C 0.6407(2) 0.1769(4) 0.78330(19) 0.0263(10) Uani 1 1 d . . . . .
H20 H 0.654829 0.175721 0.822135 0.032 Uiso 1 1 calc R U . . .
C17 C 0.6101(2) 0.2996(5) 0.6983(2) 0.0286(11) Uani 1 1 d . . . . .
H17 H 0.603404 0.380181 0.679309 0.034 Uiso 1 1 calc R U . . .
N2 N 0.43057(17) 0.4288(4) 0.47093(16) 0.0325(10) Uani 1 1 d . . . . .
H2 H 0.452270 0.399294 0.503889 0.039 Uiso 1 1 calc R U . . .
C5 C 0.3565(2) 0.6550(5) 0.5688(2) 0.0321(12) Uani 1 1 d . . . . .
C18 C 0.6305(2) 0.2976(4) 0.7552(2) 0.0281(11) Uani 1 1 d . . . . .
C4 C 0.3540(2) 0.6325(5) 0.51537(19) 0.0289(11) Uani 1 1 d . . . . .
C3 C 0.3127(2) 0.6917(5) 0.4658(2) 0.0298(11) Uani 1 1 d . . . . .
H3A H 0.287199 0.746365 0.467489 0.036 Uiso 1 1 calc R U . . .
C22 C 0.6368(2) -0.0713(5) 0.78187(19) 0.0276(11) Uani 1 1 d . . . . .
C8 C 0.3507(2) 0.5828(5) 0.41779(19) 0.0286(11) Uani 1 1 d . . . . .
H8 H 0.350404 0.566034 0.383934 0.034 Uiso 1 1 calc R U . . .
C2 C 0.3117(2) 0.6666(5) 0.4171(2) 0.0268(10) Uani 1 1 d . . . . .
C6 C 0.3930(2) 0.5475(5) 0.51620(19) 0.0313(11) Uani 1 1 d . . . . .
H6 H 0.419195 0.510862 0.549569 0.038 Uiso 1 1 calc R U . . .
C7 C 0.39101(19) 0.5210(5) 0.46711(19) 0.0285(11) Uani 1 1 d . . . . .
C19 C 0.6393(2) 0.4283(4) 0.7846(2) 0.0275(11) Uani 1 1 d . . . . .
C11 C 0.4855(2) 0.2176(6) 0.4066(2) 0.0401(13) Uani 1 1 d . . . . .
H11 H 0.464835 0.241289 0.369016 0.048 Uiso 1 1 calc R U . . .
C1 C 0.2672(2) 0.7271(5) 0.3623(2) 0.0307(11) Uani 1 1 d . . . . .
C10 C 0.4796(2) 0.2788(5) 0.44725(19) 0.0272(10) Uani 1 1 d . . . . .
C15 C 0.5821(2) 0.1079(5) 0.5776(2) 0.0315(11) Uani 1 1 d . . . . .
C9 C 0.4370(2) 0.3855(5) 0.4301(2) 0.0330(12) Uani 1 1 d . . . . .
C14 C 0.5473(2) 0.1460(5) 0.5165(2) 0.0278(11) Uani 1 1 d . . . . .
C12 C 0.5240(3) 0.1168(7) 0.4228(2) 0.0500(16) Uani 1 1 d . . . . .
H12 H 0.528647 0.073694 0.395177 0.060 Uiso 1 1 calc R U . . .
C13 C 0.5554(2) 0.0783(6) 0.4783(2) 0.0426(14) Uani 1 1 d . . . . .
H13 H 0.580418 0.010253 0.488492 0.051 Uiso 1 1 calc R U . . .
O11 O 0.4561(2) 0.7096(7) 0.7260(3) 0.097(2) Uani 1 1 d . . . . .
O4 O 0.383(2) 0.575(3) 0.6064(19) 0.044(8) Uani 0.30(8) 1 d . U P A 1
O4A O 0.3990(9) 0.617(4) 0.6151(5) 0.067(6) Uani 0.70(8) 1 d . . P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O7 87.48(13) 7_566 2_666 ?
O1 Eu1 O8 82.47(14) 7_566 2_666 ?
O1 Eu1 O3 75.47(15) 7_566 . ?
O1 Eu1 O9 82.51(14) 7_566 2_656 ?
O1 Eu1 C22 85.58(13) 7_566 2_666 ?
O1 Eu1 C19 88.04(13) 7_566 2_656 ?
O1 Eu1 O11 162.76(17) 7_566 . ?
O10 Eu1 O1 91.67(14) 2_656 7_566 ?
O10 Eu1 O7 75.25(12) 2_656 2_666 ?
O10 Eu1 O8 127.40(11) 2_656 2_666 ?
O10 Eu1 O3 148.32(18) 2_656 . ?
O10 Eu1 O9 51.81(11) 2_656 2_656 ?
O10 Eu1 C22 101.62(12) 2_656 2_666 ?
O10 Eu1 C19 26.14(13) 2_656 2_656 ?
O10 Eu1 O11 82.3(2) 2_656 . ?
O10 Eu1 O4 110.1(6) 2_656 . ?
O7 Eu1 O8 52.38(11) 2_666 2_666 ?
O7 Eu1 O3 131.52(14) 2_666 . ?
O7 Eu1 O9 125.47(11) 2_666 2_656 ?
O7 Eu1 C22 26.39(12) 2_666 2_666 ?
O7 Eu1 C19 100.93(12) 2_666 2_656 ?
O7 Eu1 O11 75.38(18) 2_666 . ?
O8 Eu1 O9 164.92(16) 2_666 2_656 ?
O8 Eu1 C22 26.04(12) 2_666 2_666 ?
O8 Eu1 C19 151.83(12) 2_666 2_656 ?
O8 Eu1 O11 88.4(2) 2_666 . ?
O3 Eu1 O8 80.22(15) . 2_666 ?
O3 Eu1 O9 97.28(16) . 2_656 ?
O3 Eu1 C22 106.00(16) . 2_666 ?
O3 Eu1 C19 122.92(17) . 2_656 ?
O3 Eu1 O11 117.4(2) . . ?
O9 Eu1 C22 150.22(13) 2_656 2_666 ?
O9 Eu1 C19 25.73(12) 2_656 2_656 ?
C22 Eu1 C19 127.07(13) 2_666 2_656 ?
O11 Eu1 O9 105.8(2) . 2_656 ?
O11 Eu1 C22 79.89(19) . 2_666 ?
O11 Eu1 C19 93.3(2) . 2_656 ?
O4 Eu1 O1 114.0(14) . 7_566 ?
O4 Eu1 O7 157.2(14) . 2_666 ?
O4 Eu1 O8 120.0(7) . 2_666 ?
O4 Eu1 O3 53.3(10) . . ?
O4 Eu1 O9 68.0(9) . 2_656 ?
O4 Eu1 C22 141.5(9) . 2_666 ?
O4 Eu1 C19 88.1(7) . 2_656 ?
O4 Eu1 O11 83.2(14) . . ?
O4A Eu1 O3 55.9(3) . . ?
O4A Eu1 C19 97.0(10) . 2_656 ?
O4A Eu1 O11 72.0(7) . . ?
C1 O1 Eu1 137.1(3) . 7_566 ?
C19 O10 Eu1 97.7(3) . 2_656 ?
C22 O7 Eu1 95.1(3) . 2_646 ?
C16 N3 H3 117.3 . . ?
C15 N3 H3 117.3 . . ?
C15 N3 C16 125.4(4) . . ?
C22 O8 Eu1 93.5(3) . 2_646 ?
C21 C23 H23 120.2 . . ?
C21 C23 C16 119.6(4) . . ?
C16 C23 H23 120.2 . . ?
C5 O3 Eu1 89.4(3) . . ?
C23 C21 C20 119.8(4) . . ?
C23 C21 C22 117.8(4) . . ?
C20 C21 C22 122.3(4) . . ?
C19 O9 Eu1 90.3(3) . 2_656 ?
C23 C16 N3 122.1(4) . . ?
C17 C16 N3 117.1(4) . . ?
C17 C16 C23 120.6(4) . . ?
C10 N1 C14 121.7(4) . . ?
C21 C20 H20 119.7 . . ?
C21 C20 C18 120.5(4) . . ?
C18 C20 H20 119.7 . . ?
C16 C17 H17 120.2 . . ?
C18 C17 C16 119.6(4) . . ?
C18 C17 H17 120.2 . . ?
C7 N2 H2 116.8 . . ?
C9 N2 H2 116.8 . . ?
C9 N2 C7 126.5(4) . . ?
O3 C5 C4 117.5(5) . . ?
O3 C5 O4 121.9(15) . . ?
O3 C5 O4A 122.5(7) . . ?
O4 C5 C4 116.3(14) . . ?
O4A C5 C4 119.6(6) . . ?
C20 C18 C19 122.6(4) . . ?
C17 C18 C20 119.8(4) . . ?
C17 C18 C19 117.5(4) . . ?
C3 C4 C5 120.4(4) . . ?
C6 C4 C5 115.3(4) . . ?
C6 C4 C3 124.3(4) . . ?
C4 C3 H3A 120.9 . . ?
C2 C3 C4 118.2(4) . . ?
C2 C3 H3A 120.9 . . ?
O7 C22 Eu1 58.5(2) . 2_646 ?
O7 C22 C21 120.9(4) . . ?
O8 C22 Eu1 60.4(3) . 2_646 ?
O8 C22 O7 118.7(4) . . ?
O8 C22 C21 120.4(4) . . ?
C21 C22 Eu1 175.3(4) . 2_646 ?
C2 C8 H8 118.0 . . ?
C2 C8 C7 124.0(4) . . ?
C7 C8 H8 118.0 . . ?
C3 C2 C8 117.7(4) . . ?
C3 C2 C1 119.9(4) . . ?
C8 C2 C1 122.4(4) . . ?
C4 C6 H6 121.5 . . ?
C7 C6 C4 117.1(4) . . ?
C7 C6 H6 121.5 . . ?
C8 C7 N2 127.4(4) . . ?
C6 C7 N2 113.9(4) . . ?
C6 C7 C8 118.7(4) . . ?
O10 C19 Eu1 56.2(2) . 2_656 ?
O10 C19 C18 119.9(4) . . ?
O9 C19 Eu1 64.0(3) . 2_656 ?
O9 C19 O10 119.9(4) . . ?
O9 C19 C18 120.2(4) . . ?
C18 C19 Eu1 172.0(4) . 2_656 ?
C10 C11 H11 121.3 . . ?
C10 C11 C12 117.4(5) . . ?
C12 C11 H11 121.3 . . ?
O1 C1 C2 121.7(4) . . ?
O2 C1 O1 120.1(5) . . ?
O2 C1 C2 118.2(5) . . ?
N1 C10 C9 121.7(4) . . ?
C11 C10 N1 120.3(5) . . ?
C11 C10 C9 118.0(4) . . ?
N3 C15 C14 110.6(4) . . ?
O6 C15 N3 124.2(5) . . ?
O6 C15 C14 125.2(4) . . ?
O5 C9 N2 122.2(5) . . ?
O5 C9 C10 124.1(4) . . ?
N2 C9 C10 113.7(4) . . ?
N1 C14 C15 121.4(4) . . ?
C13 C14 N1 122.0(5) . . ?
C13 C14 C15 116.6(4) . . ?
C11 C12 H12 118.5 . . ?
C13 C12 C11 123.1(5) . . ?
C13 C12 H12 118.5 . . ?
C14 C13 C12 115.6(5) . . ?
C14 C13 H13 122.2 . . ?
C12 C13 H13 122.2 . . ?
C5 O4 Eu1 91.5(13) . . ?
C5 O4A Eu1 91.1(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.371(3) 7_566 ?
Eu1 O10 2.369(4) 2_656 ?
Eu1 O7 2.393(3) 2_666 ?
Eu1 O8 2.437(4) 2_666 ?
Eu1 O3 2.419(4) . ?
Eu1 O9 2.539(4) 2_656 ?
Eu1 C22 2.796(5) 2_666 ?
Eu1 C19 2.825(5) 2_656 ?
Eu1 O11 2.439(6) . ?
Eu1 O4 2.37(3) . ?
Eu1 O4A 2.332(11) . ?
O1 C1 1.277(6) . ?
O10 C19 1.256(6) . ?
O7 C22 1.248(6) . ?
N3 H3 0.8600 . ?
N3 C16 1.397(6) . ?
N3 C15 1.304(6) . ?
O8 C22 1.230(6) . ?
O5 C9 1.239(6) . ?
O2 C1 1.184(6) . ?
C23 H23 0.9300 . ?
C23 C21 1.370(6) . ?
C23 C16 1.383(6) . ?
O3 C5 1.227(6) . ?
C21 C20 1.374(6) . ?
C21 C22 1.478(6) . ?
O6 C15 1.239(6) . ?
O9 C19 1.227(6) . ?
C16 C17 1.383(6) . ?
N1 C10 1.347(6) . ?
N1 C14 1.352(6) . ?
C20 H20 0.9300 . ?
C20 C18 1.388(6) . ?
C17 H17 0.9300 . ?
C17 C18 1.362(7) . ?
N2 H2 0.8600 . ?
N2 C7 1.425(6) . ?
N2 C9 1.281(6) . ?
C5 C4 1.434(6) . ?
C5 O4 1.23(3) . ?
C5 O4A 1.316(12) . ?
C18 C19 1.495(6) . ?
C4 C3 1.423(7) . ?
C4 C6 1.393(7) . ?
C3 H3A 0.9300 . ?
C3 C2 1.332(7) . ?
C8 H8 0.9300 . ?
C8 C2 1.387(7) . ?
C8 C7 1.422(7) . ?
C2 C1 1.542(7) . ?
C6 H6 0.9300 . ?
C6 C7 1.332(6) . ?
C11 H11 0.9300 . ?
C11 C10 1.342(7) . ?
C11 C12 1.400(8) . ?
C10 C9 1.517(7) . ?
C15 C14 1.517(7) . ?
C14 C13 1.348(7) . ?
C12 H12 0.9300 . ?
C12 C13 1.386(8) . ?
C13 H13 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1 C1 O2 63.9(8) 7_566 . . . ?
Eu1 O1 C1 C2 -114.6(5) 7_566 . . . ?
Eu1 O10 C19 O9 -5.6(6) 2_656 . . . ?
Eu1 O10 C19 C18 171.8(4) 2_656 . . . ?
Eu1 O7 C22 O8 4.9(5) 2_646 . . . ?
Eu1 O7 C22 C21 -174.6(4) 2_646 . . . ?
Eu1 O8 C22 O7 -4.8(5) 2_646 . . . ?
Eu1 O8 C22 C21 174.7(4) 2_646 . . . ?
Eu1 O3 C5 C4 176.2(5) . . . . ?
Eu1 O3 C5 O4 20(3) . . . . ?
Eu1 O3 C5 O4A -11(2) . . . . ?
Eu1 O9 C19 O10 5.2(5) 2_656 . . . ?
Eu1 O9 C19 C18 -172.2(4) 2_656 . . . ?
N3 C16 C17 C18 174.7(5) . . . . ?
N3 C15 C14 N1 -5.9(7) . . . . ?
N3 C15 C14 C13 173.6(5) . . . . ?
C23 C21 C20 C18 0.3(8) . . . . ?
C23 C21 C22 O7 7.6(7) . . . . ?
C23 C21 C22 O8 -171.9(5) . . . . ?
C23 C16 C17 C18 -0.7(8) . . . . ?
O3 C5 C4 C3 3.7(8) . . . . ?
O3 C5 C4 C6 -174.3(6) . . . . ?
O3 C5 O4 Eu1 -21(3) . . . . ?
O3 C5 O4A Eu1 11(3) . . . . ?
C21 C23 C16 N3 -174.5(5) . . . . ?
C21 C23 C16 C17 0.8(8) . . . . ?
C21 C20 C18 C17 -0.3(8) . . . . ?
C21 C20 C18 C19 177.5(5) . . . . ?
O6 C15 C14 N1 174.1(5) . . . . ?
O6 C15 C14 C13 -6.4(8) . . . . ?
C16 N3 C15 O6 -1.0(9) . . . . ?
C16 N3 C15 C14 179.0(5) . . . . ?
C16 C23 C21 C20 -0.5(7) . . . . ?
C16 C23 C21 C22 175.5(5) . . . . ?
C16 C17 C18 C20 0.5(8) . . . . ?
C16 C17 C18 C19 -177.5(5) . . . . ?
N1 C10 C9 O5 176.5(5) . . . . ?
N1 C10 C9 N2 -5.5(8) . . . . ?
N1 C14 C13 C12 0.9(9) . . . . ?
C20 C21 C22 O7 -176.5(5) . . . . ?
C20 C21 C22 O8 4.1(8) . . . . ?
C20 C18 C19 O10 -176.7(5) . . . . ?
C20 C18 C19 O9 0.8(8) . . . . ?
C17 C18 C19 O10 1.2(8) . . . . ?
C17 C18 C19 O9 178.6(5) . . . . ?
C5 C4 C3 C2 -179.2(5) . . . . ?
C5 C4 C6 C7 178.1(5) . . . . ?
C4 C5 O4 Eu1 -176.9(5) . . . . ?
C4 C5 O4A Eu1 -175.9(5) . . . . ?
C4 C3 C2 C8 0.8(7) . . . . ?
C4 C3 C2 C1 179.2(5) . . . . ?
C4 C6 C7 N2 -177.3(5) . . . . ?
C4 C6 C7 C8 1.5(8) . . . . ?
C3 C4 C6 C7 0.1(8) . . . . ?
C3 C2 C1 O1 6.3(8) . . . . ?
C3 C2 C1 O2 -172.3(5) . . . . ?
C22 C21 C20 C18 -175.6(5) . . . . ?
C8 C2 C1 O1 -175.4(5) . . . . ?
C8 C2 C1 O2 6.0(8) . . . . ?
C2 C8 C7 N2 176.5(5) . . . . ?
C2 C8 C7 C6 -2.1(8) . . . . ?
C6 C4 C3 C2 -1.4(8) . . . . ?
C7 N2 C9 O5 3.1(9) . . . . ?
C7 N2 C9 C10 -174.9(5) . . . . ?
C7 C8 C2 C3 0.9(8) . . . . ?
C7 C8 C2 C1 -177.4(5) . . . . ?
C11 C10 C9 O5 -4.6(9) . . . . ?
C11 C10 C9 N2 173.3(5) . . . . ?
C11 C12 C13 C14 -1.0(10) . . . . ?
C10 N1 C14 C15 179.3(5) . . . . ?
C10 N1 C14 C13 -0.2(8) . . . . ?
C10 C11 C12 C13 0.3(10) . . . . ?
C15 N3 C16 C23 -38.3(8) . . . . ?
C15 N3 C16 C17 146.3(5) . . . . ?
C15 C14 C13 C12 -178.5(5) . . . . ?
C9 N2 C7 C8 0.5(9) . . . . ?
C9 N2 C7 C6 179.2(5) . . . . ?
C14 N1 C10 C11 -0.6(8) . . . . ?
C14 N1 C10 C9 178.1(5) . . . . ?
C12 C11 C10 N1 0.6(9) . . . . ?
C12 C11 C10 C9 -178.3(5) . . . . ?
O4 C5 C4 C3 161(3) . . . . ?
O4 C5 C4 C6 -17(3) . . . . ?
O4A C5 C4 C3 -170(2) . . . . ?
O4A C5 C4 C6 12(2) . . . . ?
