Information card for entry 7702336

Structure parameters

• Chemical name: {[1,1`-Bis(diphenylphosphino)ferrocene]bis(pyrrazol-1-yl)platinum(II)- cadmium(II) iodide} dichloromethane solvate
• Formula: C40.45 H34.9 Cd Cl0.9 Fe I2 N4 P2 Pt
• Calculated formula: C40.452 H34.904 Cd Cl0.904 Fe I2 N4 P2 Pt
• Title of publication: Heteropolymetallic compounds containing 1,1′-bis(diphenylphosphino)ferrocene (DPPF ) and pyrazolate ligands: synthesis, spectroscopic characterization and reactivity. Crystal and molecular structure of [(DPPF )Pt(az)2] [azH = pyrazole (pzH) or 3,5-dimethylpyrazole] and [(DPPF )Pt(μ-pz)2CdI2]
• Authors of publication: Pettinari, Claudio; Marchetti, Fabio; Cingolani, Augusto; Troyanov, Sergei I.; Drozdov, Andrei
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1998
• Journal issue: 19
• Pages of publication: 3335
• a: 35.376 ± 0.01 Å
• b: 13.522 ± 0.007 Å
• c: 19.749 ± 0.008 Å
• α: 90°
• β: 116.22 ± 0.03°
• γ: 90°
• Cell volume: 8475 ± 6 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 9
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0781
• Residual factor for significantly intense reflections: 0.0516
• Weighted residual factors for all reflections: 0.1062
• Weighted residual factors for significantly intense reflections: 0.0968
• Goodness-of-fit parameter for all reflections: 1.106
• Goodness-of-fit parameter for significantly intense reflections: 1.136
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No