Information card for entry 7704520

Structure parameters

• Formula: C43 H45 Au2 Cl S2 Si3
• Calculated formula: C43 H45 Au2 Cl S2 Si3
• SMILES: C1(=[Au](Cl)[Au](C(S1)([Si](c1ccccc1)(c1ccccc1)C)[Si](c1ccccc1)(c1ccccc1)C)[S](C)C)[Si](c1ccccc1)(c1ccccc1)C
• Title of publication: (Thio)(silyl)carbene and (seleno)(silyl)carbene gold(i) complexes from the reaction of bis(methylene)-λ⁴-sulfane and bis(methylene)-λ⁴-selane with chloro(dimethylsulfide)gold(i).
• Authors of publication: Sugamata, Koh; Urao, Yukiko; Minoura, Mao
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 23
• Pages of publication: 7688 - 7691
• a: 10.5587 ± 0.0001 Å
• b: 12.7258 ± 0.0001 Å
• c: 16.3375 ± 0.0002 Å
• α: 96.606 ± 0.001°
• β: 107.201 ± 0.001°
• γ: 93.562 ± 0.001°
• Cell volume: 2072.41 ± 0.04 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0215
• Residual factor for significantly intense reflections: 0.0208
• Weighted residual factors for significantly intense reflections: 0.0558
• Weighted residual factors for all reflections included in the refinement: 0.0562
• Goodness-of-fit parameter for all reflections included in the refinement: 1.068
• Diffraction radiation wavelength: 0.4118 Å
• Diffraction radiation type: synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No