Information card for entry 7704638

Structure parameters

• Common name: Os(^Ph^ap)~2~Cl~2~ . CDCl~3~
• Chemical name: Cis-bis-(2-(phenylimido)-4,6-di-tert-butylphenoxo)dichloroosmium(VI) chloroform solvate
• Formula: C41 H50 Cl5 D N2 O2 Os
• Calculated formula: C41 H50 Cl5 D N2 O2 Os
• Title of publication: High-valent osmium iminoxolene complexes.
• Authors of publication: Gianino, Jacqueline; Erickson, Alexander N.; Markovitz, Sean J.; Brown, Seth N.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 25
• Pages of publication: 8504 - 8515
• a: 16.8082 ± 0.0007 Å
• b: 40.829 ± 0.002 Å
• c: 12.5096 ± 0.0007 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 8584.9 ± 0.7 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 7
• Space group number: 43
• Hermann-Mauguin space group symbol: F d d 2
• Hall space group symbol: F 2 -2d
• Residual factor for all reflections: 0.0156
• Residual factor for significantly intense reflections: 0.014
• Weighted residual factors for significantly intense reflections: 0.0322
• Weighted residual factors for all reflections included in the refinement: 0.0327
• Goodness-of-fit parameter for all reflections included in the refinement: 1.047
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No