Information card for entry 7705851

Structure parameters

• Formula: C137 H150 B2 F48 N2 P4 Rh2
• Calculated formula: C137 H150 B2 F48 N2 P4 Rh2
• Title of publication: Reactions of Rh(PNP) pincer complexes with terminal alkynes: homocoupling through a ring or not at all.
• Authors of publication: Hood, Thomas M.; Chaplin, Adrian B.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2020
• Journal volume: 49
• Journal issue: 46
• Pages of publication: 16649 - 16652
• a: 15.3009 ± 0.0004 Å
• b: 15.9126 ± 0.0003 Å
• c: 16.7557 ± 0.0004 Å
• α: 114.303 ± 0.002°
• β: 91.265 ± 0.0019°
• γ: 97.977 ± 0.0018°
• Cell volume: 3667.92 ± 0.16 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0798
• Residual factor for significantly intense reflections: 0.0613
• Weighted residual factors for significantly intense reflections: 0.1628
• Weighted residual factors for all reflections included in the refinement: 0.1781
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No