Information card for entry 7705989

Structure parameters

• Formula: C32 H57 N2 P2 Rh Si4
• Calculated formula: C32 H57 N2 P2 Rh Si4
• SMILES: [Rh]123([P@]4(C[Si](N[Si](C)(C)C[P@]1(c1ccccc1)C[Si](N2[Si](C4)(C)C)(C)C)(C)C)c1ccccc1)[CH]1=[CH]3CCCCCC1
• Title of publication: Forays into rhodium macrocyclic chemistry stabilized by a P₂N₂ donor set. Activation of dihydrogen and benzene.
• Authors of publication: Yeo, Alyssa; Sanz, Corey A.; Fryzuk, Michael D.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2021
• Journal volume: 50
• Journal issue: 3
• Pages of publication: 899 - 907
• a: 12.0577 ± 0.0008 Å
• b: 16.8079 ± 0.0012 Å
• c: 18.6727 ± 0.0014 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3784.3 ± 0.5 ų
• Cell temperature: 90 K
• Ambient diffraction temperature: 90 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0329
• Residual factor for significantly intense reflections: 0.0281
• Weighted residual factors for significantly intense reflections: 0.0575
• Weighted residual factors for all reflections included in the refinement: 0.059
• Goodness-of-fit parameter for all reflections included in the refinement: 1.067
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No