Information card for entry 7708167

Structure parameters

• Formula: C44 H90 P2 Pt
• Calculated formula: C44 H90 P2 Pt
• Title of publication: Platinum(ii) alkyl complexes of chelating dibridgehead diphosphines P((CH2)n)3P (n = 14, 18, 22); facile cis/trans isomerizations interconverting gyroscope and parachute like adducts
• Authors of publication: Zhu, Yun; Ehnbom, Andreas; Fiedler, Tobias; Shu, Yi; Bhuvanesh, Nattamai; Hall, Michael B.; Gladysz, John A.
• Journal of publication: Dalton Transactions
• Year of publication: 2021
• a: 10.3514 ± 0.0004 Å
• b: 15.4895 ± 0.0006 Å
• c: 28.4607 ± 0.0012 Å
• α: 90°
• β: 95.767 ± 0.001°
• γ: 90°
• Cell volume: 4540.2 ± 0.3 ų
• Cell temperature: 110 K
• Ambient diffraction temperature: 110 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0378
• Residual factor for significantly intense reflections: 0.0331
• Weighted residual factors for significantly intense reflections: 0.0695
• Weighted residual factors for all reflections included in the refinement: 0.0732
• Goodness-of-fit parameter for all reflections included in the refinement: 1.073
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No