Information card for entry 7709318

Structure parameters

• Chemical name: tBu-PBP-Pt-SH
• Formula: C24 H45 B N2 P2 Pt S
• Calculated formula: C24 H45 B N2 P2 Pt S
• SMILES: [Pt]12([P](C(C)(C)C)(C(C)(C)C)CN3B2N(C[P]1(C(C)(C)C)C(C)(C)C)c1c3cccc1)S
• Title of publication: Platinum thiolate complexes supported by PBP and POCOP pincer ligands as efficient catalysts for the hydrosilylation of carbonyl compounds
• Authors of publication: Xue, Man-Man; Chang, Jiarui; Zhang, Jie; Chen, Xuenian
• Journal of publication: Dalton Transactions
• Year of publication: 2022
• a: 12.0127 ± 0.0001 Å
• b: 14.4319 ± 0.0002 Å
• c: 32.144 ± 0.0005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5572.68 ± 0.13 ų
• Cell temperature: 150 ± 0.3 K
• Ambient diffraction temperature: 150 ± 0.3 K
• Number of distinct elements: 7
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0597
• Residual factor for significantly intense reflections: 0.0416
• Weighted residual factors for significantly intense reflections: 0.108
• Weighted residual factors for all reflections included in the refinement: 0.1174
• Goodness-of-fit parameter for all reflections included in the refinement: 1.088
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No