Information card for entry 7711313

Structure parameters

• Formula: C24 H104 B32 Cu6 N24 O104 V12
• Calculated formula: C24 H104 B32 Cu6 N24 O104 V12
• Title of publication: A highly efficient heterogeneous catalyst for selective oxidation of sulfides derived from an open-framework copper borovanadate containing a unique crown-shaped anion
• Authors of publication: Feng, Yuquan; Zhong, Zhiguo; Meng, Zhaohui; Ma, Keshuan; Wang, Hongwei; Feng, Xun; Wang, Suhong; Yue, Zilong; Zeng, Zhaoge; Zhang, Shuhan
• Journal of publication: Dalton Transactions
• Year of publication: 2022
• a: 19.183 ± 0.002 Å
• b: 19.183 ± 0.002 Å
• c: 19.669 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 7237.9 ± 1.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 87
• Hermann-Mauguin space group symbol: I 4/m
• Hall space group symbol: -I 4
• Residual factor for all reflections: 0.1364
• Residual factor for significantly intense reflections: 0.1098
• Weighted residual factors for significantly intense reflections: 0.2372
• Weighted residual factors for all reflections included in the refinement: 0.2467
• Goodness-of-fit parameter for all reflections included in the refinement: 1.082
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No