Information card for entry 7711431

Structure parameters

• Formula: C31 H44 F3 Ir N3 O7 S Si
• Calculated formula: C31 H44 F3 Ir N3 O7 S Si
• Title of publication: Heterolytic cleavage of a Si-H bond by a metal-ligand cooperation of a cationic iridium amido complex and hydrosilylation of aldehydes.
• Authors of publication: Iizuka, Kosuke; Nakajima, Yumiko; Sato, Kazuhiko
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2022
• Journal volume: 51
• Journal issue: 34
• Pages of publication: 12781 - 12785
• a: 11.3688 ± 0.0003 Å
• b: 11.7329 ± 0.0003 Å
• c: 15.0057 ± 0.0003 Å
• α: 104.111 ± 0.002°
• β: 91.708 ± 0.002°
• γ: 113.962 ± 0.002°
• Cell volume: 1755.06 ± 0.08 ų
• Cell temperature: 100 ± 1 K
• Ambient diffraction temperature: 100 ± 1 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0641
• Residual factor for significantly intense reflections: 0.047
• Weighted residual factors for significantly intense reflections: 0.1043
• Weighted residual factors for all reflections included in the refinement: 0.1102
• Goodness-of-fit parameter for all reflections included in the refinement: 1.026
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No