Group 3 dialkyl complexes of a rigid monoanionic NNN-donor pincer ligand: synthesis, structures, unexpected reactivity with CPh<sub>3</sub><sup>+</sup>, and hydroamination catalysis.
Authors of publication
Vasanthakumar, Aathith; Gray, Novan A. G.; Franko, Christopher J.; Murphy, Maia C.; Emslie, David J. H.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2023
a
14.651 ± 0.006 Å
b
16.119 ± 0.008 Å
c
25.584 ± 0.01 Å
α
94.046 ± 0.011°
β
93.705 ± 0.009°
γ
110.899 ± 0.01°
Cell volume
5604 ± 4 Å3
Cell temperature
100 K
Ambient diffraction temperature
100 K
Number of distinct elements
5
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0961
Residual factor for significantly intense reflections
0.0588
Weighted residual factors for significantly intense reflections
0.1385
Weighted residual factors for all reflections included in the refinement
0.156
Goodness-of-fit parameter for all reflections included in the refinement
