Information card for entry 7714122

Structure parameters

• Formula: C24 H66 Ge Mn2 P8
• Calculated formula: C24 H66 Ge Mn2 P8
• SMILES: [Ge](=[MnH]12([P](CC[P]1(C)C)(C)C)[P](CC[P]2(C)C)(C)C)=[MnH]12([P](C)(CC[P]1(C)C)C)[P](C)(C)CC[P]2(C)C
• Title of publication: Reactions of [(dmpe)₂MnH(C₂H₄)] with hydrogermanes to form germylene, germyl, hydrogermane, and germanide complexes.
• Authors of publication: Price, Jeffrey S.; Vargas-Baca, Ignacio; Emslie, David J. H.; Britten, James F.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2023
• a: 17.673 ± 0.002 Å
• b: 17.979 ± 0.007 Å
• c: 11.97 ± 0.003 Å
• α: 90°
• β: 101.283 ± 0.018°
• γ: 90°
• Cell volume: 3729.9 ± 1.8 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0397
• Residual factor for significantly intense reflections: 0.0321
• Weighted residual factors for significantly intense reflections: 0.0732
• Weighted residual factors for all reflections included in the refinement: 0.0751
• Goodness-of-fit parameter for all reflections included in the refinement: 1.185
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No