Information card for entry 7714174

Structure parameters

• Formula: C23.5 H31 B Cl2 P Rh
• Calculated formula: C23.5 H31 B Cl2 P Rh
• SMILES: [Rh]1234([Cl][B](C[P]1(c1ccccc1)c1ccccc1)(C)C)[CH]1=[CH]2CC[CH]3=[CH]4CC1.ClCCl
• Title of publication: A comparison of the coordination behaviour of R₂PCH₂BMe₂ (R = Me <i>vs.</i> Ph) ambiphilic ligands with late transition metals.
• Authors of publication: Paskaruk, Katia M.; Emslie, David J. H.; Britten, James F.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2023
• a: 11.1915 ± 0.0016 Å
• b: 11.7307 ± 0.0017 Å
• c: 19.199 ± 0.003 Å
• α: 100.853 ± 0.003°
• β: 92.045 ± 0.003°
• γ: 101.711 ± 0.002°
• Cell volume: 2416.7 ± 0.6 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0624
• Residual factor for significantly intense reflections: 0.04
• Weighted residual factors for significantly intense reflections: 0.0832
• Weighted residual factors for all reflections included in the refinement: 0.0899
• Goodness-of-fit parameter for all reflections included in the refinement: 1.045
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No