Information card for entry 7714177

Structure parameters

• Formula: C45 H54 B3 Cl P3 Rh
• Calculated formula: C45 H54 B3 Cl P3 Rh
• SMILES: [Rh]12([Cl]([B](C[P]1(c1ccccc1)c1ccccc1)(C)C)[B](C[P]2(c1ccccc1)c1ccccc1)(C)C)[P](c1ccccc1)(c1ccccc1)CB(C)C
• Title of publication: A comparison of the coordination behaviour of R₂PCH₂BMe₂ (R = Me <i>vs.</i> Ph) ambiphilic ligands with late transition metals.
• Authors of publication: Paskaruk, Katia M.; Emslie, David J. H.; Britten, James F.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2023
• a: 9.9012 ± 0.0018 Å
• b: 22.77 ± 0.006 Å
• c: 19.527 ± 0.005 Å
• α: 90°
• β: 102.48 ± 0.04°
• γ: 90°
• Cell volume: 4298.3 ± 1.9 ų
• Cell temperature: 100 ± 0.1 K
• Ambient diffraction temperature: 100 ± 0.1 K
• Number of distinct elements: 6
• Space group number: 7
• Hermann-Mauguin space group symbol: P 1 c 1
• Hall space group symbol: P -2yc
• Residual factor for all reflections: 0.0382
• Residual factor for significantly intense reflections: 0.0339
• Weighted residual factors for significantly intense reflections: 0.0795
• Weighted residual factors for all reflections included in the refinement: 0.081
• Goodness-of-fit parameter for all reflections included in the refinement: 1.024
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No