Information card for entry 7714609

Structure parameters

• Formula: C136 H168 Cl2 Ga2 Ge2 N4
• Calculated formula: C112 H144 Cl2 Ga2 Ge2 N4
• SMILES: [Ge@@]1([Ge@@](c2c(cccc2c2c(cc(cc2C)C)C)c2c(cc(cc2C)C)C)(CC[Ga]2(Cl)[N](=C(C=C(N2c2c(cccc2C(C)C)C(C)C)C)C)c2c(cccc2C(C)C)C(C)C)CC1)(CC[Ga]1(Cl)N(C(=CC(=[N]1c1c(cccc1C(C)C)C(C)C)C)C)c1c(cccc1C(C)C)C(C)C)c1c(cccc1c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C.[Ge@]1([Ge@](c2c(cccc2c2c(cc(cc2C)C)C)c2c(cc(cc2C)C)C)(CC[Ga]2(Cl)[N](=C(C=C(N2c2c(cccc2C(C)C)C(C)C)C)C)c2c(cccc2C(C)C)C(C)C)CC1)(CC[Ga]1(Cl)N(C(=CC(=[N]1c1c(cccc1C(C)C)C(C)C)C)C)c1c(cccc1C(C)C)C(C)C)c1c(cccc1c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C
• Title of publication: Multiple ethylene activation by heteroleptic L(Cl)Ga-substituted germylenes.
• Authors of publication: Bücker, Anna; Wölper, Christoph; Siera, Hannah; Haberhauer, Gebhard; Schulz, Stephan
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2024
• Journal volume: 53
• Journal issue: 2
• Pages of publication: 640 - 646
• a: 14.0575 ± 0.0008 Å
• b: 20.597 ± 0.0012 Å
• c: 23.6061 ± 0.0014 Å
• α: 115.356 ± 0.002°
• β: 97.878 ± 0.002°
• γ: 94.81 ± 0.002°
• Cell volume: 6040.1 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.048
• Residual factor for significantly intense reflections: 0.0427
• Weighted residual factors for significantly intense reflections: 0.1114
• Weighted residual factors for all reflections included in the refinement: 0.117
• Goodness-of-fit parameter for all reflections included in the refinement: 1.011
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No