Information card for entry 7715241

Structure parameters

• Formula: C40 H58 Cl4 Ga2 N4
• Calculated formula: C40 H58 Cl4 Ga2 N4
• SMILES: [Ga]1(Cl)(Cl)N(C(=CC(=[N]1c1c(cccc1C(C)C)C(C)C)C)C)[C@H]1[C@H](N2[Ga](Cl)(Cl)[N](=C(C=C2C)C)c2c(cccc2C(C)C)C(C)C)CCCC1
• Title of publication: Metal-metal cooperativity boosts Lewis basicity and reduction properties of the bis(gallanediyl) ^CyL₂Ga₂.
• Authors of publication: Helling, Christoph; Döhler, Lotta; Kysliak, Oleksandr; Görls, Helmar; Liebing, Phil; Wölper, Christoph; Kretschmer, Robert; Schulz, Stephan
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2024
• Journal volume: 53
• Journal issue: 11
• Pages of publication: 4922 - 4929
• a: 10.264 ± 0.0019 Å
• b: 18.797 ± 0.003 Å
• c: 22.81 ± 0.004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4400.8 ± 1.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0446
• Residual factor for significantly intense reflections: 0.0312
• Weighted residual factors for significantly intense reflections: 0.0629
• Weighted residual factors for all reflections included in the refinement: 0.068
• Goodness-of-fit parameter for all reflections included in the refinement: 1.057
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No