Information card for entry 7715302

Structure parameters

• Formula: C40 H40 O8 P2 Rh2
• Calculated formula: C40 H40 O8 P2 Rh2
• SMILES: [Rh]12345([Rh]6789([P](OC)(OC)OC)([c]%10%113[c]2([cH]1[c]5([c]49%11[c]8([cH]7[c]6%10c1ccccc1)c1ccccc1)c1ccccc1)c1ccccc1)C#[O])([P](OC)(OC)OC)C#[O]
• Title of publication: Twinned <i>versus</i> linked organometallics - bimetallic "half-baguette" pentalenide complexes of Rh(I).
• Authors of publication: Sanderson, Hugh J.; Kociok-Köhn, Gabriele; McMullin, Claire L.; Hintermair, Ulrich
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2024
• Journal volume: 53
• Journal issue: 13
• Pages of publication: 5881 - 5899
• a: 9.8739 ± 0.00005 Å
• b: 21.78333 ± 0.00008 Å
• c: 17.76504 ± 0.00007 Å
• α: 90°
• β: 102.682 ± 0.0005°
• γ: 90°
• Cell volume: 3727.8 ± 0.03 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 0.1 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0202
• Residual factor for significantly intense reflections: 0.0201
• Weighted residual factors for significantly intense reflections: 0.0492
• Weighted residual factors for all reflections included in the refinement: 0.0493
• Goodness-of-fit parameter for all reflections included in the refinement: 1.127
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No