Information card for entry 7715562

Structure parameters

• Common name: O2CB-084. Cr(dmpe)(N2)2.
• Formula: C12 H32 Cr N4 P4
• Calculated formula: C12 H32 Cr N4 P4
• Title of publication: Catalytic dinitrogen reduction to hydrazine and ammonia using Cr(N₂)₂(diphosphine)₂ complexes.
• Authors of publication: Beasley, Charles H.; Duletski, Olivia L.; Stankevich, Ksenia S.; Arulsamy, Navamoney; Mock, Michael T.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2024
• Journal volume: 53
• Journal issue: 15
• Pages of publication: 6496 - 6500
• a: 7.4075 ± 0.0014 Å
• b: 8.633 ± 0.0017 Å
• c: 8.9332 ± 0.0019 Å
• α: 104.558 ± 0.006°
• β: 105.008 ± 0.006°
• γ: 103.613 ± 0.007°
• Cell volume: 505.73 ± 0.18 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0523
• Residual factor for significantly intense reflections: 0.0378
• Weighted residual factors for significantly intense reflections: 0.072
• Weighted residual factors for all reflections included in the refinement: 0.0766
• Goodness-of-fit parameter for all reflections included in the refinement: 1.067
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No