Information card for entry 7715930

Structure parameters

• Formula: C48 H57 Au O2 P Rh3
• Calculated formula: C48 H57 Au O2 P Rh3
• SMILES: [Au]([P](c1ccccc1)(c1ccccc1)c1ccccc1)[O]12[Rh]34567([Rh]89%10%111([Rh]1%12%1323([O]48)[CH]2=[CH]1CC[CH]%12=[CH]%13CC2)[CH]1=[CH]9CC[CH]%10=[CH]%11CC1)[CH]1=[CH]5CC[CH]6=[CH]7CC1.c1ccccc1
• Title of publication: Effect of distal metal species on lewis basicity of a μ₃-oxo ligand in a doubly oxo-bridged (μ₃-O)[Rh(cod)]₃(μ₄-O)M core.
• Authors of publication: Tsurugi, Hayato; Mori, Hiroki; Mori, Haruna; Nakamoto, Masami; Tanaka, Shinji; Mashima, Kazushi
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2024
• Journal volume: 53
• Journal issue: 20
• Pages of publication: 8546 - 8549
• a: 9.4939 ± 0.0005 Å
• b: 23.9667 ± 0.0015 Å
• c: 18.8664 ± 0.0011 Å
• α: 90°
• β: 97.2108 ± 0.0013°
• γ: 90°
• Cell volume: 4258.9 ± 0.4 ų
• Cell temperature: 113 K
• Ambient diffraction temperature: 113 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.016
• Residual factor for significantly intense reflections: 0.0145
• Weighted residual factors for significantly intense reflections: 0.0347
• Weighted residual factors for all reflections included in the refinement: 0.035
• Goodness-of-fit parameter for all reflections included in the refinement: 1.067
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No