Information card for entry 7716160

Structure parameters

• Chemical name: DB-636
• Formula: C32 H32 B N2 O6 P W
• Calculated formula: C32 H32 B N2 O6 P W
• SMILES: [W]([PH](C(c1ccccc1)(c1ccccc1)c1ccccc1)[BH2][n]1cn(cc1)C)(C#[O])(C#[O])(C#[O])(C#[O])C#[O].O1CCCC1
• Title of publication: A metal and a metalloid Lewis acid bridged by a μ₂-phosphinidene.
• Authors of publication: Biskup, David; Schnakenburg, Gregor; Espinosa Ferao, Arturo; Streubel, Rainer
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2024
• Journal volume: 53
• Journal issue: 23
• Pages of publication: 9670 - 9674
• a: 9.536 ± 0.0006 Å
• b: 12.7052 ± 0.0008 Å
• c: 13.018 ± 0.0007 Å
• α: 86.357 ± 0.002°
• β: 80.306 ± 0.002°
• γ: 85.98 ± 0.002°
• Cell volume: 1548.72 ± 0.16 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0159
• Residual factor for significantly intense reflections: 0.0154
• Weighted residual factors for significantly intense reflections: 0.0359
• Weighted residual factors for all reflections included in the refinement: 0.0361
• Goodness-of-fit parameter for all reflections included in the refinement: 1.05
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No