Information card for entry 7716443

Structure parameters

• Formula: C38 H40 B4 N24 O4 Sm2
• Calculated formula: C38 H40 B4 N24 O4 Sm2
• Title of publication: Activation and functionalisation of carbon dioxide by bis-tris(pyrazolyl)borate-supported divalent samarium and trivalent lanthanide silylamide complexes.
• Authors of publication: Chowdhury, Tajrian; Wilson, Claire; Farnaby, Joy H.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2024
• Journal volume: 53
• Journal issue: 28
• Pages of publication: 11884 - 11894
• a: 20.9732 ± 0.0006 Å
• b: 28.6287 ± 0.0008 Å
• c: 21.4608 ± 0.0006 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 12885.8 ± 0.6 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 43
• Hermann-Mauguin space group symbol: F d d 2
• Hall space group symbol: F 2 -2d
• Residual factor for all reflections: 0.0644
• Residual factor for significantly intense reflections: 0.0511
• Weighted residual factors for significantly intense reflections: 0.1389
• Weighted residual factors for all reflections included in the refinement: 0.1487
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.6889 Å
• Diffraction radiation type: synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No