Information card for entry 7718180

Structure parameters

• Formula: C20 H17 Cl2 Co N5
• Calculated formula: C20 H17 Cl2 Co N5
• Title of publication: A well-defined phosphine-free metal-ligand cooperative route for <i>N</i>-alkylation of aromatic amines <i>via</i> activation of renewable alcohols catalyzed by NNN pincer cobalt(II) complexes.
• Authors of publication: Saini, Rahul; Kukreti, Prashant; Chauhan, Rahul; Panwar, Abhishek; Ghosh, Kaushik
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2025
• Journal volume: 54
• Journal issue: 14
• Pages of publication: 5838 - 5848
• a: 14.7263 ± 0.0006 Å
• b: 13.7199 ± 0.0006 Å
• c: 11.4426 ± 0.0005 Å
• α: 90°
• β: 109.199 ± 0.002°
• γ: 90°
• Cell volume: 2183.32 ± 0.16 ų
• Cell temperature: 102 ± 2 K
• Ambient diffraction temperature: 102 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0663
• Residual factor for significantly intense reflections: 0.0406
• Weighted residual factors for significantly intense reflections: 0.0847
• Weighted residual factors for all reflections included in the refinement: 0.0962
• Goodness-of-fit parameter for all reflections included in the refinement: 1.015
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No