#------------------------------------------------------------------------------
#$Date: 2025-11-29 21:09:55 +0100 (Sat 29 de Nov de 2025) $
#$Revision: 303728 $
#$URL: svn://www.crystallography.net/cod/cif/7/71/89/7718914.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7718914
loop_
_publ_author_name
'Arikawa, Yasuhiro'
'Morinaga, Momo'
'Kubota, Miyu'
'Omoto, Kenichiro'
'Sakuda, Eri'
'Umakoshi, Keisuke'
_publ_section_title
;
 Visible-light-driven photocatalytic CO₂ reduction using
 ruthenium complexes having a CNC-type pincer ligand: comparison of
 substituent effect on a CNC ligand.
;
_journal_issue                   27
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10683
_journal_page_last               10690
_journal_paper_doi               10.1039/d5dt00900f
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C17 H19 Cl N7 Ru, F6 P, C2 H3 N'
_chemical_formula_sum            'C19 H22 Cl F6 N8 P Ru'
_chemical_formula_weight         643.92
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2025-03-06 deposited with the CCDC.	2025-06-17 downloaded from the CCDC.
;
_cell_angle_alpha                93.279(4)
_cell_angle_beta                 99.582(5)
_cell_angle_gamma                103.696(6)
_cell_formula_units_Z            2
_cell_length_a                   7.397(3)
_cell_length_b                   13.009(5)
_cell_length_c                   13.994(5)
_cell_measurement_reflns_used    3952
_cell_measurement_temperature    93
_cell_measurement_theta_max      27.50
_cell_measurement_theta_min      2.10
_cell_volume                     1283.5(9)
_computing_cell_refinement       'CrystalClear-SM Expert 2.0 r16'
_computing_data_collection       'CrystalClear-SM Expert 2.0 r16 (Rigaku, 2014)'
_computing_data_reduction        'CrystalClear-SM Expert 2.0 r16'
_computing_molecular_graphics    'CrystalStructure 4.3'
_computing_publication_material  'CrystalStructure 4.3 (Rigaku, 2019)'
_computing_structure_refinement  'SHELXL Version 2014/7 (Sheldrick, 2008)'
_computing_structure_solution    'Il Milione (Burla, et al., 2007)'
_diffrn_ambient_temperature      93
_diffrn_detector_area_resol_mean 7.111
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.960
_diffrn_measurement_device_type  'Rigaku Saturn724+'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0355
_diffrn_reflns_Laue_measured_fraction_full 0.981
_diffrn_reflns_Laue_measured_fraction_max 0.960
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            10646
_diffrn_reflns_point_group_measured_fraction_full 0.981
_diffrn_reflns_point_group_measured_fraction_max 0.960
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.483
_diffrn_reflns_theta_min         2.304
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.846
_exptl_absorpt_correction_T_max  0.975
_exptl_absorpt_correction_T_min  0.811
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.666
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       chip
_exptl_crystal_F_000             644.00
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: CH3CN/ether'
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.040
_exptl_crystal_size_min          0.030
_refine_diff_density_max         0.88
_refine_diff_density_min         -0.67
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     330
_refine_ls_number_reflns         5654
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0596
_refine_ls_R_factor_gt           0.0429
_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0356P)²+0.4069P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0804
_refine_ls_wR_factor_ref         0.0896
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4539
_reflns_number_total             5654
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            d5dt00900f2.cif
_cod_data_source_block           1900b
_cod_depositor_comments
'Adding full bibliography for 7718913--7718916.cif.'
_cod_database_code               7718914
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 -X,-Y,-Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.40622(4) 0.25361(2) 0.63898(2) 0.01586(9) Uani 1 1 d . . . . .
Cl1 Cl 0.68935(12) 0.26951(6) 0.56961(6) 0.01948(18) Uani 1 1 d . . . . .
P1 P 0.71130(14) 0.31391(8) 1.10502(7) 0.0267(2) Uani 1 1 d . . . . .
F1 F 0.8370(3) 0.32288(18) 1.02142(15) 0.0337(5) Uani 1 1 d . . . . .
F2 F 0.5375(3) 0.33114(19) 1.02810(16) 0.0397(6) Uani 1 1 d . . . . .
F3 F 0.6381(3) 0.18873(17) 1.07664(15) 0.0350(6) Uani 1 1 d . . . . .
F4 F 0.7848(4) 0.43919(19) 1.13322(18) 0.0530(7) Uani 1 1 d . . . . .
F5 F 0.8849(3) 0.2948(2) 1.18085(16) 0.0500(7) Uani 1 1 d . . . . .
F6 F 0.5862(3) 0.30469(18) 1.18875(16) 0.0391(6) Uani 1 1 d . . . . .
N1 N 0.2699(4) 0.1526(2) 0.52210(19) 0.0150(6) Uani 1 1 d . . . . .
N2 N 0.2032(4) 0.2986(2) 0.45858(19) 0.0174(6) Uani 1 1 d . . . . .
N3 N 0.2874(4) 0.4530(2) 0.53846(19) 0.0179(6) Uani 1 1 d . . . . .
N4 N 0.3647(4) 0.0269(2) 0.60920(19) 0.0161(6) Uani 1 1 d . . . . .
N5 N 0.4757(4) 0.0551(2) 0.7621(2) 0.0193(6) Uani 1 1 d . . . . .
N6 N 0.1843(4) 0.2490(2) 0.70634(19) 0.0186(6) Uani 1 1 d . . . . .
N7 N 0.5542(4) 0.3640(2) 0.7525(2) 0.0190(6) Uani 1 1 d . . . . .
N8 N 0.0339(7) 0.0182(4) 0.8778(3) 0.0645(13) Uani 1 1 d . . . . .
C1 C 0.3066(5) 0.3531(3) 0.5459(2) 0.0175(7) Uani 1 1 d . . . . .
C2 C 0.4317(5) 0.1081(3) 0.6857(2) 0.0178(7) Uani 1 1 d . . . . .
C3 C 0.1231(5) 0.3649(3) 0.3989(2) 0.0206(8) Uani 1 1 d . . . . .
H3 H 0.0470 0.3458 0.3358 0.025 Uiso 1 1 calc R U . . .
C4 C 0.1761(5) 0.4611(3) 0.4494(2) 0.0215(8) Uani 1 1 d . . . . .
H4 H 0.1438 0.5237 0.4284 0.026 Uiso 1 1 calc R U . . .
C5 C 0.3721(5) -0.0728(3) 0.6407(2) 0.0198(7) Uani 1 1 d . . . . .
H5 H 0.3349 -0.1394 0.6022 0.024 Uiso 1 1 calc R U . . .
C6 C 0.4419(5) -0.0544(3) 0.7360(2) 0.0215(8) Uani 1 1 d . . . . .
H6 H 0.4648 -0.1061 0.7785 0.026 Uiso 1 1 calc R U . . .
C7 C 0.1864(4) 0.1893(3) 0.4427(2) 0.0152(7) Uani 1 1 d . . . . .
C8 C 0.0990(5) 0.1234(3) 0.3590(2) 0.0190(7) Uani 1 1 d . . . . .
H8 H 0.0395 0.1501 0.3037 0.023 Uiso 1 1 calc R U . . .
C9 C 0.1006(5) 0.0173(3) 0.3579(2) 0.0200(7) Uani 1 1 d . . . . .
H9 H 0.0402 -0.0299 0.3011 0.024 Uiso 1 1 calc R U . . .
C10 C 0.1896(5) -0.0214(3) 0.4388(2) 0.0188(7) Uani 1 1 d . . . . .
H10 H 0.1922 -0.0941 0.4382 0.023 Uiso 1 1 calc R U . . .
C11 C 0.2733(4) 0.0495(3) 0.5192(2) 0.0160(7) Uani 1 1 d . . . . .
C12 C 0.3640(5) 0.5403(3) 0.6160(2) 0.0225(8) Uani 1 1 d . . . . .
H12A H 0.3595 0.6079 0.5894 0.027 Uiso 1 1 calc R U . . .
H12B H 0.4956 0.5413 0.6430 0.027 Uiso 1 1 calc R U . . .
H12C H 0.2884 0.5301 0.6675 0.027 Uiso 1 1 calc R U . . .
C13 C 0.5334(5) 0.1033(3) 0.8628(2) 0.0267(8) Uani 1 1 d . . . . .
H13A H 0.5448 0.1800 0.8644 0.032 Uiso 1 1 calc R U . . .
H13B H 0.6558 0.0906 0.8908 0.032 Uiso 1 1 calc R U . . .
H13C H 0.4382 0.0715 0.9007 0.032 Uiso 1 1 calc R U . . .
C14 C 0.0782(5) 0.2571(3) 0.7532(3) 0.0225(8) Uani 1 1 d . . . . .
C15 C -0.0553(6) 0.2691(4) 0.8152(3) 0.0395(11) Uani 1 1 d . . . . .
H15A H -0.1816 0.2585 0.7752 0.047 Uiso 1 1 calc R U . . .
H15B H -0.0160 0.3407 0.8498 0.047 Uiso 1 1 calc R U . . .
H15C H -0.0588 0.2163 0.8624 0.047 Uiso 1 1 calc R U . . .
C16 C 0.6280(5) 0.4294(3) 0.8136(2) 0.0192(7) Uani 1 1 d . . . . .
C17 C 0.7226(5) 0.5165(3) 0.8892(3) 0.0279(9) Uani 1 1 d . . . . .
H17A H 0.8472 0.5511 0.8756 0.034 Uiso 1 1 calc R U . . .
H17B H 0.7381 0.4884 0.9527 0.034 Uiso 1 1 calc R U . . .
H17C H 0.6460 0.5684 0.8900 0.034 Uiso 1 1 calc R U . . .
C18 C -0.0493(7) -0.0652(4) 0.8943(3) 0.0436(11) Uani 1 1 d . . . . .
C19 C -0.1545(6) -0.1667(3) 0.9157(3) 0.0432(11) Uani 1 1 d . . . . .
H19A H -0.0687 -0.2132 0.9299 0.052 Uiso 1 1 calc R U . . .
H19B H -0.2535 -0.1994 0.8594 0.052 Uiso 1 1 calc R U . . .
H19C H -0.2127 -0.1566 0.9724 0.052 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Cl Cl 0.1484 0.1585
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
F F 0.0171 0.0103
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
P P 0.1023 0.0942
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Ru Ru -1.2594 0.8363
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ru1 N6 97.93(11) . . ?
N1 Ru1 N7 176.09(12) . . ?
N6 Ru1 N7 84.77(11) . . ?
N1 Ru1 C1 77.99(12) . . ?
N6 Ru1 C1 88.86(12) . . ?
N7 Ru1 C1 99.29(12) . . ?
N1 Ru1 C2 77.95(12) . . ?
N6 Ru1 C2 90.78(12) . . ?
N7 Ru1 C2 104.92(12) . . ?
C1 Ru1 C2 155.66(13) . . ?
N1 Ru1 Cl1 86.94(8) . . ?
N6 Ru1 Cl1 175.14(8) . . ?
N7 Ru1 Cl1 90.38(8) . . ?
C1 Ru1 Cl1 92.25(10) . . ?
C2 Ru1 Cl1 90.16(10) . . ?
F3 P1 F4 179.87(16) . . ?
F3 P1 F2 89.67(13) . . ?
F4 P1 F2 90.32(14) . . ?
F3 P1 F5 89.44(14) . . ?
F4 P1 F5 90.57(15) . . ?
F2 P1 F5 179.00(15) . . ?
F3 P1 F6 89.78(13) . . ?
F4 P1 F6 90.35(13) . . ?
F2 P1 F6 90.53(13) . . ?
F5 P1 F6 89.91(14) . . ?
F3 P1 F1 90.13(13) . . ?
F4 P1 F1 89.73(14) . . ?
F2 P1 F1 89.66(12) . . ?
F5 P1 F1 89.89(13) . . ?
F6 P1 F1 179.79(14) . . ?
C11 N1 C7 119.5(3) . . ?
C11 N1 Ru1 120.4(2) . . ?
C7 N1 Ru1 119.9(2) . . ?
C1 N2 C3 111.8(3) . . ?
C1 N2 C7 118.8(3) . . ?
C3 N2 C7 129.3(3) . . ?
C1 N3 C4 111.4(3) . . ?
C1 N3 C12 124.2(3) . . ?
C4 N3 C12 124.3(3) . . ?
C2 N4 C5 111.7(3) . . ?
C2 N4 C11 119.0(3) . . ?
C5 N4 C11 128.3(3) . . ?
C2 N5 C6 112.4(3) . . ?
C2 N5 C13 124.1(3) . . ?
C6 N5 C13 123.1(3) . . ?
C14 N6 Ru1 170.2(3) . . ?
C16 N7 Ru1 175.3(3) . . ?
N3 C1 N2 103.3(3) . . ?
N3 C1 Ru1 144.3(2) . . ?
N2 C1 Ru1 112.1(2) . . ?
N5 C2 N4 102.5(3) . . ?
N5 C2 Ru1 146.2(2) . . ?
N4 C2 Ru1 111.0(2) . . ?
C4 C3 N2 105.5(3) . . ?
C4 C3 H3 127.2 . . ?
N2 C3 H3 127.2 . . ?
C3 C4 N3 107.9(3) . . ?
C3 C4 H4 126.0 . . ?
N3 C4 H4 126.0 . . ?
C6 C5 N4 105.7(3) . . ?
C6 C5 H5 127.2 . . ?
N4 C5 H5 127.2 . . ?
C5 C6 N5 107.7(3) . . ?
C5 C6 H6 126.2 . . ?
N5 C6 H6 126.2 . . ?
N1 C7 C8 121.8(3) . . ?
N1 C7 N2 111.1(3) . . ?
C8 C7 N2 127.1(3) . . ?
C7 C8 C9 117.9(3) . . ?
C7 C8 H8 121.0 . . ?
C9 C8 H8 121.0 . . ?
C8 C9 C10 120.9(3) . . ?
C8 C9 H9 119.5 . . ?
C10 C9 H9 119.5 . . ?
C11 C10 C9 117.4(3) . . ?
C11 C10 H10 121.3 . . ?
C9 C10 H10 121.3 . . ?
N1 C11 C10 122.4(3) . . ?
N1 C11 N4 110.8(3) . . ?
C10 C11 N4 126.8(3) . . ?
N3 C12 H12A 109.5 . . ?
N3 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
N3 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
N5 C13 H13A 109.5 . . ?
N5 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
N5 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
N6 C14 C15 178.8(4) . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
N7 C16 C17 177.7(4) . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
N8 C18 C19 178.8(6) . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 N1 1.999(3) . ?
Ru1 N6 2.016(3) . ?
Ru1 N7 2.049(3) . ?
Ru1 C1 2.059(3) . ?
Ru1 C2 2.077(3) . ?
Ru1 Cl1 2.4220(12) . ?
P1 F3 1.594(2) . ?
P1 F4 1.595(3) . ?
P1 F2 1.602(2) . ?
P1 F5 1.602(2) . ?
P1 F6 1.602(2) . ?
P1 F1 1.604(2) . ?
N1 C11 1.346(4) . ?
N1 C7 1.347(4) . ?
N2 C1 1.383(4) . ?
N2 C3 1.397(4) . ?
N2 C7 1.400(4) . ?
N3 C1 1.349(4) . ?
N3 C4 1.399(4) . ?
N3 C12 1.462(4) . ?
N4 C2 1.398(4) . ?
N4 C5 1.403(4) . ?
N4 C11 1.408(4) . ?
N5 C2 1.341(4) . ?
N5 C6 1.402(4) . ?
N5 C13 1.461(4) . ?
N6 C14 1.122(4) . ?
N7 C16 1.138(4) . ?
N8 C18 1.170(6) . ?
C3 C4 1.338(4) . ?
C3 H3 0.9500 . ?
C4 H4 0.9500 . ?
C5 C6 1.333(5) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.376(4) . ?
C8 C9 1.383(5) . ?
C8 H8 0.9500 . ?
C9 C10 1.394(4) . ?
C9 H9 0.9500 . ?
C10 C11 1.372(4) . ?
C10 H10 0.9500 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 C15 1.448(5) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C17 1.461(4) . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 C19 1.441(6) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C4 N3 C1 N2 -0.1(4) . . . . ?
C12 N3 C1 N2 176.5(3) . . . . ?
C4 N3 C1 Ru1 -172.1(3) . . . . ?
C12 N3 C1 Ru1 4.6(6) . . . . ?
C3 N2 C1 N3 0.2(4) . . . . ?
C7 N2 C1 N3 -177.7(3) . . . . ?
C3 N2 C1 Ru1 175.2(2) . . . . ?
C7 N2 C1 Ru1 -2.7(4) . . . . ?
C6 N5 C2 N4 1.0(4) . . . . ?
C13 N5 C2 N4 -173.0(3) . . . . ?
C6 N5 C2 Ru1 174.6(4) . . . . ?
C13 N5 C2 Ru1 0.6(6) . . . . ?
C5 N4 C2 N5 -0.8(4) . . . . ?
C11 N4 C2 N5 168.9(3) . . . . ?
C5 N4 C2 Ru1 -177.0(2) . . . . ?
C11 N4 C2 Ru1 -7.3(4) . . . . ?
C1 N2 C3 C4 -0.3(4) . . . . ?
C7 N2 C3 C4 177.4(3) . . . . ?
N2 C3 C4 N3 0.2(4) . . . . ?
C1 N3 C4 C3 0.0(4) . . . . ?
C12 N3 C4 C3 -176.7(3) . . . . ?
C2 N4 C5 C6 0.3(4) . . . . ?
C11 N4 C5 C6 -168.2(3) . . . . ?
N4 C5 C6 N5 0.3(4) . . . . ?
C2 N5 C6 C5 -0.8(4) . . . . ?
C13 N5 C6 C5 173.2(3) . . . . ?
C11 N1 C7 C8 1.9(5) . . . . ?
Ru1 N1 C7 C8 176.8(3) . . . . ?
C11 N1 C7 N2 -177.9(3) . . . . ?
Ru1 N1 C7 N2 -3.0(4) . . . . ?
C1 N2 C7 N1 3.7(4) . . . . ?
C3 N2 C7 N1 -173.8(3) . . . . ?
C1 N2 C7 C8 -176.1(3) . . . . ?
C3 N2 C7 C8 6.4(6) . . . . ?
N1 C7 C8 C9 -0.7(5) . . . . ?
N2 C7 C8 C9 179.1(3) . . . . ?
C7 C8 C9 C10 -0.6(5) . . . . ?
C8 C9 C10 C11 0.6(5) . . . . ?
C7 N1 C11 C10 -1.9(5) . . . . ?
Ru1 N1 C11 C10 -176.7(3) . . . . ?
C7 N1 C11 N4 -179.4(3) . . . . ?
Ru1 N1 C11 N4 5.7(4) . . . . ?
C9 C10 C11 N1 0.6(5) . . . . ?
C9 C10 C11 N4 177.8(3) . . . . ?
C2 N4 C11 N1 1.5(4) . . . . ?
C5 N4 C11 N1 169.3(3) . . . . ?
C2 N4 C11 C10 -175.9(3) . . . . ?
C5 N4 C11 C10 -8.1(6) . . . . ?
