Information card for entry 7718981

Structure parameters

• Chemical name: (triphenylphosphine)-[7-{[t-butyl(dimethyl)silyl]oxy}-5-oxido-2-(4-{[t-butyl(dimethyl)silyl]oxy}phenyl)-4H-1-benzopyran-4-onato]-dichlorido-oxido-rhenium(V) acetone solvate 2:1
• Formula: C46.5 H55 Cl2 O6.5 P Re Si2
• Calculated formula: C45 H52 Cl2 O6 P Re Si2
• Title of publication: Oxidorhenium(V) complexes of apigenin: a rare example of catalysis with <i>O</i>,<i>O</i>-bidentate ligands obtained from a naturally renewable resource.
• Authors of publication: Milovanović, Milan R; Nikolić, Stefan R; Dupé, Antoine; Schachner, Jörg A; Mihajlović, Ljiljana E
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2025
• Journal volume: 54
• Journal issue: 28
• Pages of publication: 11047 - 11055
• a: 10.5286 ± 0.0001 Å
• b: 13.1593 ± 0.0001 Å
• c: 19.4627 ± 0.0001 Å
• α: 74.206 ± 0.001°
• β: 79.446 ± 0.001°
• γ: 66.519 ± 0.001°
• Cell volume: 2371.33 ± 0.04 ų
• Cell temperature: 99.99 ± 0.1 K
• Ambient diffraction temperature: 99.99 ± 0.1 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0264
• Residual factor for significantly intense reflections: 0.0253
• Weighted residual factors for significantly intense reflections: 0.0608
• Weighted residual factors for all reflections included in the refinement: 0.0614
• Goodness-of-fit parameter for all reflections included in the refinement: 1.046
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No