Information card for entry 7719118

Structure parameters

• Formula: C104 H88 B2 Cl4 Cu2 F8 Fe3 P6
• Calculated formula: C102 H84 B2 Cu2 F8 Fe3 P6
• Title of publication: Homoleptic copper(I)-bisphosphine complexes as photoredox catalysts.
• Authors of publication: Saha, Priya; Tomita, Ryunosuke; Tsuneda, Takao; Jiang, Pingyu; Taketsugu, Tetsuya; Jin, Mingoo; Huang, Dennis Chung-Yang
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2025
• Journal volume: 54
• Journal issue: 30
• Pages of publication: 11725 - 11731
• a: 32.6587 ± 0.0013 Å
• b: 14.7541 ± 0.0002 Å
• c: 25.9909 ± 0.001 Å
• α: 90°
• β: 128.902 ± 0.006°
• γ: 90°
• Cell volume: 9746.2 ± 1 ų
• Cell temperature: 153 K
• Ambient diffraction temperature: 153 K
• Number of distinct elements: 8
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0334
• Residual factor for significantly intense reflections: 0.0308
• Weighted residual factors for significantly intense reflections: 0.0782
• Weighted residual factors for all reflections included in the refinement: 0.0798
• Goodness-of-fit parameter for all reflections included in the refinement: 1.006
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No