#------------------------------------------------------------------------------
#$Date: 2025-10-06 11:41:27 +0200 (Mon 06 de Oct de 2025) $
#$Revision: 302673 $
#$URL: svn://www.crystallography.net/cod/cif/7/71/91/7719165.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7719165
loop_
_publ_author_name
'Kushik, ?'
'Rippke, Mirko'
'Drexler, Hans-Joachim'
'Dankert, Fabian'
'Hering-Junghans, Christian'
'Beweries, Torsten'
_publ_section_title
;
 Coordination and C-H activation of an amidobis(phosphaalkene) ligand at
 rhodium(I).
;
_journal_issue                   34
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12913
_journal_page_last               12918
_journal_paper_doi               10.1039/d5dt01734c
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C60 H82 Cl N P2 Rh2, C5 H12'
_chemical_formula_sum            'C65 H94 Cl N P2 Rh2'
_chemical_formula_weight         1192.62
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2025-05-14 deposited with the CCDC.	2025-07-24 downloaded from the CCDC.
;
_cell_angle_alpha                90.019(4)
_cell_angle_beta                 100.920(4)
_cell_angle_gamma                96.787(4)
_cell_formula_units_Z            2
_cell_length_a                   11.9255(12)
_cell_length_b                   15.6360(17)
_cell_length_c                   16.4992(17)
_cell_measurement_reflns_used    9889
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      66.58
_cell_measurement_theta_min      2.73
_cell_volume                     2998.9(5)
_computing_cell_refinement       'SAINT (Bruker, 2013)'
_computing_data_collection       'APEX2 (Bruker, 2014)'
_computing_data_reduction        'SAINT (Bruker, 2013)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 8.3333
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  multilayer
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0355
_diffrn_reflns_av_unetI/netI     0.0371
_diffrn_reflns_Laue_measured_fraction_full 0.981
_diffrn_reflns_Laue_measured_fraction_max 0.981
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            29886
_diffrn_reflns_point_group_measured_fraction_full 0.981
_diffrn_reflns_point_group_measured_fraction_max 0.981
_diffrn_reflns_theta_full        66.629
_diffrn_reflns_theta_max         66.629
_diffrn_reflns_theta_min         2.728
_diffrn_source                   microfocus
_exptl_absorpt_coefficient_mu    5.647
_exptl_absorpt_correction_T_max  0.7528
_exptl_absorpt_correction_T_min  0.6508
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2014)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.321
_exptl_crystal_description       prism
_exptl_crystal_F_000             1256
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.071
_exptl_crystal_size_min          0.053
_refine_diff_density_max         0.921
_refine_diff_density_min         -0.384
_refine_diff_density_rms         0.067
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     666
_refine_ls_number_reflns         10403
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0355
_refine_ls_R_factor_gt           0.0286
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0377P)²+1.0085P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0694
_refine_ls_wR_factor_ref         0.0729
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9052
_reflns_number_total             10403
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5dt01734c3.cif
_cod_data_source_block           AX2707abs_cmpd5
_cod_depositor_comments
'Adding full bibliography for 7719162--7719167.cif.'
_cod_database_code               7719165
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.602
_shelx_estimated_absorpt_t_max   0.754
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.34841(2) 0.30738(2) 0.22196(2) 0.01657(6) Uani 1 1 d . . . . .
Rh2 Rh 0.56960(2) 0.18150(2) 0.21564(2) 0.01964(6) Uani 1 1 d . . . . .
Cl1 Cl 0.49835(5) 0.30262(4) 0.14401(4) 0.02407(13) Uani 1 1 d . . . . .
P1 P 0.19800(5) 0.30637(4) 0.11051(4) 0.01823(12) Uani 1 1 d . . . . .
P2 P 0.46141(5) 0.22073(4) 0.30971(4) 0.01718(12) Uani 1 1 d . . . . .
N1 N 0.23854(17) 0.33454(13) 0.29117(13) 0.0194(4) Uani 1 1 d . . . . .
C1 C 0.0685(2) 0.32396(15) 0.13077(16) 0.0207(5) Uani 1 1 d . . . . .
H1 H 0.0085 0.3276 0.0844 0.025 Uiso 1 1 calc R U . . .
C2 C 0.0401(2) 0.33395(15) 0.21043(16) 0.0203(5) Uani 1 1 d . . . . .
C3 C -0.0722(2) 0.34599(16) 0.22022(16) 0.0225(5) Uani 1 1 d . . . . .
H3 H -0.1316 0.3412 0.1726 0.027 Uiso 1 1 calc R U . . .
C4 C -0.1006(2) 0.36454(17) 0.29578(17) 0.0249(5) Uani 1 1 d . . . . .
C5 C -0.0138(2) 0.37402(16) 0.36668(16) 0.0244(5) Uani 1 1 d . . . . .
H5 H -0.0319 0.3881 0.4183 0.029 Uiso 1 1 calc R U . . .
C6 C 0.0980(2) 0.36299(16) 0.36192(16) 0.0220(5) Uani 1 1 d . . . . .
C7 C 0.2073(2) 0.37289(16) 0.42006(16) 0.0219(5) Uani 1 1 d . . . . .
C8 C 0.2489(2) 0.39908(17) 0.50250(16) 0.0251(5) Uani 1 1 d . . . . .
H8 H 0.1973 0.4118 0.5370 0.030 Uiso 1 1 calc R U . . .
C9 C 0.3664(2) 0.40617(16) 0.53322(16) 0.0244(5) Uani 1 1 d . . . . .
C10 C 0.4435(2) 0.38667(16) 0.48297(16) 0.0231(5) Uani 1 1 d . . . . .
H10 H 0.5237 0.3933 0.5052 0.028 Uiso 1 1 calc R U . . .
C11 C 0.4049(2) 0.35774(15) 0.40131(15) 0.0201(5) Uani 1 1 d . . . . .
C12 C 0.4692(2) 0.33060(16) 0.33752(15) 0.0196(5) Uani 1 1 d . . . . .
H12 H 0.534(2) 0.3629(18) 0.3312(17) 0.017(7) Uiso 1 1 d . . . . .
C13 C 0.2876(2) 0.35383(16) 0.37299(15) 0.0207(5) Uani 1 1 d . . . . .
C14 C 0.1246(2) 0.34014(15) 0.28403(15) 0.0186(5) Uani 1 1 d . . . . .
C15 C -0.2231(2) 0.37460(19) 0.30115(18) 0.0301(6) Uani 1 1 d . . . . .
H15A H -0.2552 0.4111 0.2565 0.045 Uiso 1 1 calc R U . . .
H15B H -0.2249 0.4014 0.3545 0.045 Uiso 1 1 calc R U . . .
H15C H -0.2689 0.3178 0.2959 0.045 Uiso 1 1 calc R U . . .
C16 C 0.4133(3) 0.43221(19) 0.62265(17) 0.0317(6) Uani 1 1 d . . . . .
H16A H 0.3552 0.4590 0.6453 0.048 Uiso 1 1 calc R U . . .
H16B H 0.4828 0.4734 0.6263 0.048 Uiso 1 1 calc R U . . .
H16C H 0.4322 0.3811 0.6543 0.048 Uiso 1 1 calc R U . . .
C17 C 0.1745(2) 0.32023(16) -0.00275(15) 0.0190(5) Uani 1 1 d . . . . .
C18 C 0.1759(2) 0.40430(16) -0.03595(15) 0.0216(5) Uani 1 1 d . . . . .
C19 C 0.1162(2) 0.41282(16) -0.11617(16) 0.0227(5) Uani 1 1 d . . . . .
H19 H 0.1142 0.4690 -0.1379 0.027 Uiso 1 1 calc R U . . .
C20 C 0.0594(2) 0.34328(17) -0.16593(15) 0.0212(5) Uani 1 1 d . . . . .
C21 C 0.0724(2) 0.26197(16) -0.13553(15) 0.0222(5) Uani 1 1 d . . . . .
H21 H 0.0407 0.2135 -0.1706 0.027 Uiso 1 1 calc R U . . .
C22 C 0.1298(2) 0.24777(16) -0.05591(15) 0.0204(5) Uani 1 1 d . . . . .
C23 C 0.2410(2) 0.48949(17) 0.00701(17) 0.0262(6) Uani 1 1 d . . . . .
C24 C 0.3298(4) 0.4813(2) 0.0835(3) 0.0782(17) Uani 1 1 d . . . . .
H24A H 0.3683 0.5386 0.1026 0.117 Uiso 1 1 calc R U . . .
H24B H 0.3867 0.4454 0.0711 0.117 Uiso 1 1 calc R U . . .
H24C H 0.2924 0.4546 0.1268 0.117 Uiso 1 1 calc R U . . .
C25 C 0.1531(3) 0.5471(2) 0.0250(3) 0.0589(10) Uani 1 1 d . . . . .
H25A H 0.1122 0.5202 0.0665 0.088 Uiso 1 1 calc R U . . .
H25B H 0.0978 0.5544 -0.0259 0.088 Uiso 1 1 calc R U . . .
H25C H 0.1928 0.6034 0.0459 0.088 Uiso 1 1 calc R U . . .
C26 C 0.3080(3) 0.5369(2) -0.0539(2) 0.0519(9) Uani 1 1 d . . . . .
H26A H 0.3511 0.5902 -0.0277 0.078 Uiso 1 1 calc R U . . .
H26B H 0.2540 0.5507 -0.1034 0.078 Uiso 1 1 calc R U . . .
H26C H 0.3617 0.4999 -0.0696 0.078 Uiso 1 1 calc R U . . .
C27 C -0.0068(2) 0.35823(17) -0.25310(16) 0.0250(5) Uani 1 1 d . . . . .
C28 C -0.0941(2) 0.4224(2) -0.24942(18) 0.0343(6) Uani 1 1 d . . . . .
H28A H -0.1495 0.3989 -0.2158 0.051 Uiso 1 1 calc R U . . .
H28B H -0.1349 0.4321 -0.3054 0.051 Uiso 1 1 calc R U . . .
H28C H -0.0535 0.4772 -0.2247 0.051 Uiso 1 1 calc R U . . .
C29 C 0.0786(3) 0.3953(2) -0.30685(18) 0.0351(6) Uani 1 1 d . . . . .
H29A H 0.1206 0.4495 -0.2818 0.053 Uiso 1 1 calc R U . . .
H29B H 0.0364 0.4061 -0.3622 0.053 Uiso 1 1 calc R U . . .
H29C H 0.1331 0.3540 -0.3109 0.053 Uiso 1 1 calc R U . . .
C30 C -0.0728(2) 0.27481(19) -0.29461(17) 0.0318(6) Uani 1 1 d . . . . .
H30A H -0.0185 0.2339 -0.3006 0.048 Uiso 1 1 calc R U . . .
H30B H -0.1155 0.2874 -0.3492 0.048 Uiso 1 1 calc R U . . .
H30C H -0.1268 0.2497 -0.2606 0.048 Uiso 1 1 calc R U . . .
C31 C 0.1443(2) 0.15324(16) -0.03165(16) 0.0247(5) Uani 1 1 d . . . . .
C32 C 0.1120(3) 0.09115(18) -0.10695(18) 0.0358(7) Uani 1 1 d . . . . .
H32A H 0.1287 0.0332 -0.0899 0.054 Uiso 1 1 calc R U . . .
H32B H 0.1569 0.1109 -0.1488 0.054 Uiso 1 1 calc R U . . .
H32C H 0.0298 0.0897 -0.1301 0.054 Uiso 1 1 calc R U . . .
C33 C 0.2716(2) 0.14667(18) 0.00514(18) 0.0301(6) Uani 1 1 d . . . . .
H33A H 0.2956 0.1836 0.0549 0.045 Uiso 1 1 calc R U . . .
H33B H 0.3190 0.1654 -0.0355 0.045 Uiso 1 1 calc R U . . .
H33C H 0.2813 0.0868 0.0195 0.045 Uiso 1 1 calc R U . . .
C34 C 0.0678(2) 0.11925(17) 0.02899(18) 0.0298(6) Uani 1 1 d . . . . .
H34A H 0.0784 0.0590 0.0410 0.045 Uiso 1 1 calc R U . . .
H34B H -0.0129 0.1230 0.0045 0.045 Uiso 1 1 calc R U . . .
H34C H 0.0890 0.1539 0.0803 0.045 Uiso 1 1 calc R U . . .
C35 C 0.39457(19) 0.15936(15) 0.38758(14) 0.0175(5) Uani 1 1 d . . . . .
C36 C 0.4462(2) 0.17517(16) 0.47303(15) 0.0204(5) Uani 1 1 d . . . . .
C37 C 0.3740(2) 0.16692(16) 0.53022(15) 0.0225(5) Uani 1 1 d . . . . .
H37 H 0.4061 0.1813 0.5864 0.027 Uiso 1 1 calc R U . . .
C38 C 0.2569(2) 0.13861(16) 0.50908(16) 0.0222(5) Uani 1 1 d . . . . .
C39 C 0.2167(2) 0.10776(16) 0.42958(16) 0.0223(5) Uani 1 1 d . . . . .
H39 H 0.1402 0.0797 0.4162 0.027 Uiso 1 1 calc R U . . .
C40 C 0.2815(2) 0.11517(16) 0.36740(15) 0.0195(5) Uani 1 1 d . . . . .
C41 C 0.5782(2) 0.18535(17) 0.50859(15) 0.0238(5) Uani 1 1 d . . . . .
C42 C 0.6573(2) 0.25063(17) 0.46917(16) 0.0252(5) Uani 1 1 d . . . . .
H42A H 0.6378 0.3089 0.4770 0.038 Uiso 1 1 calc R U . . .
H42B H 0.6468 0.2372 0.4100 0.038 Uiso 1 1 calc R U . . .
H42C H 0.7375 0.2474 0.4953 0.038 Uiso 1 1 calc R U . . .
C43 C 0.6157(2) 0.09497(18) 0.49926(18) 0.0291(6) Uani 1 1 d . . . . .
H43A H 0.5991 0.0774 0.4408 0.044 Uiso 1 1 calc R U . . .
H43B H 0.5734 0.0534 0.5303 0.044 Uiso 1 1 calc R U . . .
H43C H 0.6985 0.0969 0.5208 0.044 Uiso 1 1 calc R U . . .
C44 C 0.6052(2) 0.2091(2) 0.60163(17) 0.0344(7) Uani 1 1 d . . . . .
H44A H 0.6888 0.2171 0.6211 0.052 Uiso 1 1 calc R U . . .
H44B H 0.5705 0.1626 0.6321 0.052 Uiso 1 1 calc R U . . .
H44C H 0.5736 0.2626 0.6108 0.052 Uiso 1 1 calc R U . . .
C45 C 0.1757(2) 0.13551(18) 0.57106(16) 0.0266(6) Uani 1 1 d . . . . .
C46 C 0.2319(3) 0.1830(2) 0.65227(18) 0.0385(7) Uani 1 1 d . . . . .
H46A H 0.2964 0.1536 0.6798 0.058 Uiso 1 1 calc R U . . .
H46B H 0.1751 0.1833 0.6881 0.058 Uiso 1 1 calc R U . . .
H46C H 0.2601 0.2424 0.6410 0.058 Uiso 1 1 calc R U . . .
C47 C 0.1398(3) 0.0413(2) 0.5889(2) 0.0377(7) Uani 1 1 d . . . . .
H47A H 0.2081 0.0144 0.6136 0.057 Uiso 1 1 calc R U . . .
H47B H 0.1023 0.0106 0.5373 0.057 Uiso 1 1 calc R U . . .
H47C H 0.0861 0.0384 0.6273 0.057 Uiso 1 1 calc R U . . .
C48 C 0.0684(2) 0.1784(2) 0.53345(18) 0.0322(6) Uani 1 1 d . . . . .
H48A H 0.0143 0.1737 0.5716 0.048 Uiso 1 1 calc R U . . .
H48B H 0.0315 0.1494 0.4808 0.048 Uiso 1 1 calc R U . . .
H48C H 0.0912 0.2393 0.5241 0.048 Uiso 1 1 calc R U . . .
C49 C 0.2201(2) 0.06870(16) 0.28526(15) 0.0204(5) Uani 1 1 d . . . . .
C50 C 0.1080(2) 0.10662(18) 0.25117(16) 0.0266(6) Uani 1 1 d . . . . .
H50A H 0.1262 0.1656 0.2334 0.040 Uiso 1 1 calc R U . . .
H50B H 0.0619 0.1072 0.2944 0.040 Uiso 1 1 calc R U . . .
H50C H 0.0644 0.0712 0.2040 0.040 Uiso 1 1 calc R U . . .
C51 C 0.1904(2) -0.02701(17) 0.30477(17) 0.0290(6) Uani 1 1 d . . . . .
H51A H 0.1493 -0.0583 0.2544 0.044 Uiso 1 1 calc R U . . .
H51B H 0.1417 -0.0313 0.3466 0.044 Uiso 1 1 calc R U . . .
H51C H 0.2615 -0.0521 0.3257 0.044 Uiso 1 1 calc R U . . .
C52 C 0.2908(2) 0.06860(18) 0.21712(16) 0.0257(5) Uani 1 1 d . . . . .
H52A H 0.2488 0.0306 0.1714 0.039 Uiso 1 1 calc R U . . .
H52B H 0.3648 0.0479 0.2391 0.039 Uiso 1 1 calc R U . . .
H52C H 0.3044 0.1273 0.1972 0.039 Uiso 1 1 calc R U . . .
C53 C 0.6010(2) 0.05820(16) 0.26259(16) 0.0240(5) Uani 1 1 d . . . . .
H53 H 0.5563 0.0382 0.3060 0.029 Uiso 1 1 calc R U . . .
C54 C 0.6973(2) 0.11932(17) 0.29089(17) 0.0252(5) Uani 1 1 d . . . . .
H54 H 0.7081 0.1348 0.3509 0.030 Uiso 1 1 calc R U . . .
C55 C 0.8079(2) 0.12985(19) 0.25781(19) 0.0325(6) Uani 1 1 d . . . . .
H55A H 0.8533 0.0826 0.2784 0.039 Uiso 1 1 calc R U . . .
H55B H 0.8534 0.1848 0.2798 0.039 Uiso 1 1 calc R U . . .
C56 C 0.7898(2) 0.1295(2) 0.1636(2) 0.0370(7) Uani 1 1 d . . . . .
H56A H 0.8570 0.1631 0.1468 0.044 Uiso 1 1 calc R U . . .
H56B H 0.7852 0.0696 0.1428 0.044 Uiso 1 1 calc R U . . .
C57 C 0.6823(2) 0.16703(19) 0.12479(17) 0.0310(6) Uani 1 1 d . . . . .
H57 H 0.6956 0.2191 0.0911 0.037 Uiso 1 1 calc R U . . .
C58 C 0.5762(2) 0.11777(19) 0.09933(16) 0.0309(6) Uani 1 1 d . . . . .
H58 H 0.5271 0.1407 0.0501 0.037 Uiso 1 1 calc R U . . .
C59 C 0.5511(3) 0.0221(2) 0.10896(19) 0.0372(7) Uani 1 1 d . . . . .
H59A H 0.5845 -0.0081 0.0681 0.045 Uiso 1 1 calc R U . . .
H59B H 0.4668 0.0057 0.0965 0.045 Uiso 1 1 calc R U . . .
C60 C 0.5989(3) -0.00849(18) 0.19558(19) 0.0330(6) Uani 1 1 d . . . . .
H60A H 0.5512 -0.0618 0.2067 0.040 Uiso 1 1 calc R U . . .
H60B H 0.6781 -0.0226 0.1973 0.040 Uiso 1 1 calc R U . . .
C61 C 0.7610(3) 0.1675(3) 0.9152(3) 0.0650(11) Uani 1 1 d . . . . .
H61A H 0.7927 0.2098 0.9599 0.097 Uiso 1 1 calc R U . . .
H61B H 0.8236 0.1502 0.8904 0.097 Uiso 1 1 calc R U . . .
H61C H 0.7216 0.1168 0.9374 0.097 Uiso 1 1 calc R U . . .
C62 C 0.6777(3) 0.2064(3) 0.8511(2) 0.0553(9) Uani 1 1 d . . . . .
H62A H 0.6466 0.1627 0.8066 0.066 Uiso 1 1 calc R U . . .
H62B H 0.7202 0.2548 0.8266 0.066 Uiso 1 1 calc R U . . .
C63 C 0.5782(3) 0.2393(2) 0.8800(2) 0.0418(7) Uani 1 1 d . . . . .
H63A H 0.5312 0.1900 0.8995 0.050 Uiso 1 1 calc R U . . .
H63B H 0.6089 0.2791 0.9278 0.050 Uiso 1 1 calc R U . . .
C64 C 0.5015(3) 0.2852(3) 0.8163(2) 0.0518(9) Uani 1 1 d . . . . .
H64A H 0.4727 0.2460 0.7678 0.062 Uiso 1 1 calc R U . . .
H64B H 0.5481 0.3356 0.7980 0.062 Uiso 1 1 calc R U . . .
C65 C 0.4002(3) 0.3159(3) 0.8445(3) 0.0605(10) Uani 1 1 d . . . . .
H65A H 0.3473 0.2661 0.8551 0.091 Uiso 1 1 calc R U . . .
H65B H 0.3602 0.3507 0.8015 0.091 Uiso 1 1 calc R U . . .
H65C H 0.4269 0.3508 0.8953 0.091 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Rh1 C12 82.08(9) . . ?
N1 Rh1 P1 86.69(6) . . ?
C12 Rh1 P1 166.76(7) . . ?
N1 Rh1 P2 101.23(6) . . ?
C12 Rh1 P2 46.05(7) . . ?
P1 Rh1 P2 144.36(2) . . ?
N1 Rh1 Cl1 168.90(6) . . ?
C12 Rh1 Cl1 92.89(7) . . ?
P1 Rh1 Cl1 96.91(2) . . ?
P2 Rh1 Cl1 81.95(2) . . ?
C54 Rh2 C53 38.90(10) . . ?
C54 Rh2 C58 97.14(11) . . ?
C53 Rh2 C58 81.95(11) . . ?
C54 Rh2 C57 81.19(11) . . ?
C53 Rh2 C57 89.97(10) . . ?
C58 Rh2 C57 36.86(11) . . ?
C54 Rh2 P2 102.24(8) . . ?
C53 Rh2 P2 98.21(7) . . ?
C58 Rh2 P2 148.95(8) . . ?
C57 Rh2 P2 170.57(8) . . ?
C54 Rh2 Cl1 153.41(8) . . ?
C53 Rh2 Cl1 167.36(7) . . ?
C58 Rh2 Cl1 91.03(8) . . ?
C57 Rh2 Cl1 90.67(7) . . ?
P2 Rh2 Cl1 82.39(2) . . ?
Rh2 Cl1 Rh1 93.54(2) . . ?
C1 P1 C17 101.26(11) . . ?
C1 P1 Rh1 117.09(9) . . ?
C17 P1 Rh1 139.32(8) . . ?
C12 P2 C35 106.29(11) . . ?
C12 P2 Rh2 118.95(9) . . ?
C35 P2 Rh2 132.39(8) . . ?
C12 P2 Rh1 61.90(8) . . ?
C35 P2 Rh1 117.69(7) . . ?
Rh2 P2 Rh1 97.09(2) . . ?
C14 N1 C13 106.26(19) . . ?
C14 N1 Rh1 139.34(17) . . ?
C13 N1 Rh1 114.40(15) . . ?
C2 C1 P1 126.77(19) . . ?
C2 C1 H1 116.6 . . ?
P1 C1 H1 116.6 . . ?
C3 C2 C14 115.6(2) . . ?
C3 C2 C1 122.0(2) . . ?
C14 C2 C1 122.2(2) . . ?
C4 C3 C2 123.7(2) . . ?
C4 C3 H3 118.2 . . ?
C2 C3 H3 118.2 . . ?
C3 C4 C5 119.1(2) . . ?
C3 C4 C15 120.3(2) . . ?
C5 C4 C15 120.5(2) . . ?
C6 C5 C4 120.4(2) . . ?
C6 C5 H5 119.8 . . ?
C4 C5 H5 119.8 . . ?
C5 C6 C14 119.5(2) . . ?
C5 C6 C7 134.7(2) . . ?
C14 C6 C7 105.7(2) . . ?
C13 C7 C8 117.6(2) . . ?
C13 C7 C6 104.3(2) . . ?
C8 C7 C6 138.0(2) . . ?
C9 C8 C7 119.1(2) . . ?
C9 C8 H8 120.4 . . ?
C7 C8 H8 120.4 . . ?
C8 C9 C10 121.0(2) . . ?
C8 C9 C16 120.2(2) . . ?
C10 C9 C16 118.8(2) . . ?
C11 C10 C9 121.5(2) . . ?
C11 C10 H10 119.2 . . ?
C9 C10 H10 119.2 . . ?
C13 C11 C10 115.3(2) . . ?
C13 C11 C12 113.6(2) . . ?
C10 C11 C12 131.1(2) . . ?
C11 C12 P2 120.31(18) . . ?
C11 C12 Rh1 108.01(16) . . ?
P2 C12 Rh1 72.05(9) . . ?
C11 C12 H12 119.0(18) . . ?
P2 C12 H12 114.7(18) . . ?
Rh1 C12 H12 112.1(17) . . ?
C11 C13 N1 121.7(2) . . ?
C11 C13 C7 125.5(2) . . ?
N1 C13 C7 112.8(2) . . ?
N1 C14 C2 127.3(2) . . ?
N1 C14 C6 110.9(2) . . ?
C2 C14 C6 121.5(2) . . ?
C4 C15 H15A 109.5 . . ?
C4 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C4 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C9 C16 H16A 109.5 . . ?
C9 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C9 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C22 C17 C18 119.1(2) . . ?
C22 C17 P1 119.18(18) . . ?
C18 C17 P1 120.14(18) . . ?
C19 C18 C17 117.9(2) . . ?
C19 C18 C23 115.2(2) . . ?
C17 C18 C23 126.9(2) . . ?
C20 C19 C18 123.3(2) . . ?
C20 C19 H19 118.4 . . ?
C18 C19 H19 118.4 . . ?
C21 C20 C19 117.0(2) . . ?
C21 C20 C27 122.7(2) . . ?
C19 C20 C27 120.1(2) . . ?
C20 C21 C22 123.1(2) . . ?
C20 C21 H21 118.4 . . ?
C22 C21 H21 118.4 . . ?
C21 C22 C17 118.4(2) . . ?
C21 C22 C31 117.6(2) . . ?
C17 C22 C31 123.9(2) . . ?
C24 C23 C25 110.1(3) . . ?
C24 C23 C26 104.7(3) . . ?
C25 C23 C26 107.5(3) . . ?
C24 C23 C18 117.0(2) . . ?
C25 C23 C18 109.0(2) . . ?
C26 C23 C18 108.0(2) . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C23 C25 H25A 109.5 . . ?
C23 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C23 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C23 C26 H26A 109.5 . . ?
C23 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C23 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C30 C27 C20 112.1(2) . . ?
C30 C27 C29 108.3(2) . . ?
C20 C27 C29 109.3(2) . . ?
C30 C27 C28 107.9(2) . . ?
C20 C27 C28 110.2(2) . . ?
C29 C27 C28 108.9(2) . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C27 C30 H30A 109.5 . . ?
C27 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C27 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C34 C31 C32 105.9(2) . . ?
C34 C31 C33 110.4(2) . . ?
C32 C31 C33 106.4(2) . . ?
C34 C31 C22 112.7(2) . . ?
C32 C31 C22 112.0(2) . . ?
C33 C31 C22 109.3(2) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C31 C34 H34A 109.5 . . ?
C31 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C31 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C40 C35 C36 118.8(2) . . ?
C40 C35 P2 121.48(18) . . ?
C36 C35 P2 117.86(18) . . ?
C37 C36 C35 117.6(2) . . ?
C37 C36 C41 116.5(2) . . ?
C35 C36 C41 125.1(2) . . ?
C36 C37 C38 123.1(2) . . ?
C36 C37 H37 118.4 . . ?
C38 C37 H37 118.4 . . ?
C39 C38 C37 116.6(2) . . ?
C39 C38 C45 120.2(2) . . ?
C37 C38 C45 123.1(2) . . ?
C38 C39 C40 123.9(2) . . ?
C38 C39 H39 118.0 . . ?
C40 C39 H39 118.0 . . ?
C39 C40 C35 117.5(2) . . ?
C39 C40 C49 113.8(2) . . ?
C35 C40 C49 128.6(2) . . ?
C42 C41 C44 105.4(2) . . ?
C42 C41 C43 108.0(2) . . ?
C44 C41 C43 107.1(2) . . ?
C42 C41 C36 118.6(2) . . ?
C44 C41 C36 111.9(2) . . ?
C43 C41 C36 105.4(2) . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C41 C44 H44A 109.5 . . ?
C41 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C41 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C46 C45 C47 108.9(2) . . ?
C46 C45 C38 112.4(2) . . ?
C47 C45 C38 108.7(2) . . ?
C46 C45 C48 108.0(2) . . ?
C47 C45 C48 109.6(2) . . ?
C38 C45 C48 109.2(2) . . ?
C45 C46 H46A 109.5 . . ?
C45 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C45 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C45 C47 H47A 109.5 . . ?
C45 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C45 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C45 C48 H48A 109.5 . . ?
C45 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C45 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C52 C49 C50 108.6(2) . . ?
C52 C49 C51 105.6(2) . . ?
C50 C49 C51 108.8(2) . . ?
C52 C49 C40 116.0(2) . . ?
C50 C49 C40 110.3(2) . . ?
C51 C49 C40 107.1(2) . . ?
C49 C50 H50A 109.5 . . ?
C49 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C49 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C49 C51 H51A 109.5 . . ?
C49 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C49 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C49 C52 H52A 109.5 . . ?
C49 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C49 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C54 C53 C60 122.7(2) . . ?
C54 C53 Rh2 69.84(14) . . ?
C60 C53 Rh2 113.17(18) . . ?
C54 C53 H53 114.4 . . ?
C60 C53 H53 114.4 . . ?
Rh2 C53 H53 114.4 . . ?
C53 C54 C55 125.8(3) . . ?
C53 C54 Rh2 71.26(14) . . ?
C55 C54 Rh2 110.96(18) . . ?
C53 C54 H54 113.7 . . ?
C55 C54 H54 113.7 . . ?
Rh2 C54 H54 113.7 . . ?
C54 C55 C56 113.9(2) . . ?
C54 C55 H55A 108.8 . . ?
C56 C55 H55A 108.8 . . ?
C54 C55 H55B 108.8 . . ?
C56 C55 H55B 108.8 . . ?
H55A C55 H55B 107.7 . . ?
C57 C56 C55 112.5(2) . . ?
C57 C56 H56A 109.1 . . ?
C55 C56 H56A 109.1 . . ?
C57 C56 H56B 109.1 . . ?
C55 C56 H56B 109.1 . . ?
H56A C56 H56B 107.8 . . ?
C58 C57 C56 123.5(3) . . ?
C58 C57 Rh2 69.95(14) . . ?
C56 C57 Rh2 111.48(19) . . ?
C58 C57 H57 114.6 . . ?
C56 C57 H57 114.6 . . ?
Rh2 C57 H57 114.6 . . ?
C57 C58 C59 125.8(3) . . ?
C57 C58 Rh2 73.19(16) . . ?
C59 C58 Rh2 108.27(18) . . ?
C57 C58 H58 113.9 . . ?
C59 C58 H58 113.9 . . ?
Rh2 C58 H58 113.9 . . ?
C58 C59 C60 113.5(2) . . ?
C58 C59 H59A 108.9 . . ?
C60 C59 H59A 108.9 . . ?
C58 C59 H59B 108.9 . . ?
C60 C59 H59B 108.9 . . ?
H59A C59 H59B 107.7 . . ?
C53 C60 C59 112.8(2) . . ?
C53 C60 H60A 109.0 . . ?
C59 C60 H60A 109.0 . . ?
C53 C60 H60B 109.0 . . ?
C59 C60 H60B 109.0 . . ?
H60A C60 H60B 107.8 . . ?
C62 C61 H61A 109.5 . . ?
C62 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C62 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C61 C62 C63 116.1(3) . . ?
C61 C62 H62A 108.3 . . ?
C63 C62 H62A 108.3 . . ?
C61 C62 H62B 108.3 . . ?
C63 C62 H62B 108.3 . . ?
H62A C62 H62B 107.4 . . ?
C64 C63 C62 115.1(3) . . ?
C64 C63 H63A 108.5 . . ?
C62 C63 H63A 108.5 . . ?
C64 C63 H63B 108.5 . . ?
C62 C63 H63B 108.5 . . ?
H63A C63 H63B 107.5 . . ?
C63 C64 C65 115.1(3) . . ?
C63 C64 H64A 108.5 . . ?
C65 C64 H64A 108.5 . . ?
C63 C64 H64B 108.5 . . ?
C65 C64 H64B 108.5 . . ?
H64A C64 H64B 107.5 . . ?
C64 C65 H65A 109.5 . . ?
C64 C65 H65B 109.5 . . ?
H65A C65 H65B 109.5 . . ?
C64 C65 H65C 109.5 . . ?
H65A C65 H65C 109.5 . . ?
H65B C65 H65C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 N1 1.975(2) . ?
Rh1 C12 2.163(2) . ?
Rh1 P1 2.3114(6) . ?
Rh1 P2 2.3327(6) . ?
Rh1 Cl1 2.3999(6) . ?
Rh2 C54 2.107(2) . ?
Rh2 C53 2.126(2) . ?
Rh2 C58 2.181(3) . ?
Rh2 C57 2.222(2) . ?
Rh2 P2 2.3228(6) . ?
Rh2 Cl1 2.3890(6) . ?
P1 C1 1.694(2) . ?
P1 C17 1.853(2) . ?
P2 C12 1.765(3) . ?
P2 C35 1.848(2) . ?
N1 C14 1.354(3) . ?
N1 C13 1.384(3) . ?
C1 C2 1.431(4) . ?
C1 H1 0.9500 . ?
C2 C3 1.412(3) . ?
C2 C14 1.419(3) . ?
C3 C4 1.392(4) . ?
C3 H3 0.9500 . ?
C4 C5 1.403(4) . ?
C4 C15 1.506(4) . ?
C5 C6 1.381(4) . ?
C5 H5 0.9500 . ?
C6 C14 1.436(3) . ?
C6 C7 1.456(4) . ?
C7 C13 1.399(3) . ?
C7 C8 1.400(4) . ?
C8 C9 1.389(4) . ?
C8 H8 0.9500 . ?
C9 C10 1.407(4) . ?
C9 C16 1.513(4) . ?
C10 C11 1.395(4) . ?
C10 H10 0.9500 . ?
C11 C13 1.383(4) . ?
C11 C12 1.503(3) . ?
C12 H12 0.90(3) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C22 1.420(3) . ?
C17 C18 1.424(3) . ?
C18 C19 1.394(4) . ?
C18 C23 1.557(3) . ?
C19 C20 1.389(4) . ?
C19 H19 0.9500 . ?
C20 C21 1.382(4) . ?
C20 C27 1.536(3) . ?
C21 C22 1.392(4) . ?
C21 H21 0.9500 . ?
C22 C31 1.552(3) . ?
C23 C24 1.503(4) . ?
C23 C25 1.529(4) . ?
C23 C26 1.538(4) . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 C30 1.531(4) . ?
C27 C29 1.537(4) . ?
C27 C28 1.538(4) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C34 1.532(4) . ?
C31 C32 1.537(4) . ?
C31 C33 1.541(4) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 C40 1.420(3) . ?
C35 C36 1.436(3) . ?
C36 C37 1.389(3) . ?
C36 C41 1.562(3) . ?
C37 C38 1.392(4) . ?
C37 H37 0.9500 . ?
C38 C39 1.375(4) . ?
C38 C45 1.533(3) . ?
C39 C40 1.394(3) . ?
C39 H39 0.9500 . ?
C40 C49 1.549(3) . ?
C41 C42 1.536(3) . ?
C41 C44 1.543(4) . ?
C41 C43 1.548(4) . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C45 C46 1.528(4) . ?
C45 C47 1.530(4) . ?
C45 C48 1.541(4) . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C49 C52 1.528(3) . ?
C49 C50 1.535(3) . ?
C49 C51 1.545(3) . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 C54 1.410(4) . ?
C53 C60 1.514(4) . ?
C53 H53 1.0000 . ?
C54 C55 1.511(4) . ?
C54 H54 1.0000 . ?
C55 C56 1.528(4) . ?
C55 H55A 0.9900 . ?
C55 H55B 0.9900 . ?
C56 C57 1.505(4) . ?
C56 H56A 0.9900 . ?
C56 H56B 0.9900 . ?
C57 C58 1.392(4) . ?
C57 H57 1.0000 . ?
C58 C59 1.505(4) . ?
C58 H58 1.0000 . ?
C59 C60 1.534(4) . ?
C59 H59A 0.9900 . ?
C59 H59B 0.9900 . ?
C60 H60A 0.9900 . ?
C60 H60B 0.9900 . ?
C61 C62 1.491(5) . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C62 C63 1.502(5) . ?
C62 H62A 0.9900 . ?
C62 H62B 0.9900 . ?
C63 C64 1.500(5) . ?
C63 H63A 0.9900 . ?
C63 H63B 0.9900 . ?
C64 C65 1.501(5) . ?
C64 H64A 0.9900 . ?
C64 H64B 0.9900 . ?
C65 H65A 0.9800 . ?
C65 H65B 0.9800 . ?
C65 H65C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C17 P1 C1 C2 -170.4(2) . . . . ?
Rh1 P1 C1 C2 -4.4(3) . . . . ?
P1 C1 C2 C3 -178.15(19) . . . . ?
P1 C1 C2 C14 7.6(4) . . . . ?
C14 C2 C3 C4 1.3(4) . . . . ?
C1 C2 C3 C4 -173.3(2) . . . . ?
C2 C3 C4 C5 1.5(4) . . . . ?
C2 C3 C4 C15 -178.7(2) . . . . ?
C3 C4 C5 C6 -1.6(4) . . . . ?
C15 C4 C5 C6 178.6(2) . . . . ?
C4 C5 C6 C14 -1.2(4) . . . . ?
C4 C5 C6 C7 175.5(3) . . . . ?
C5 C6 C7 C13 -178.0(3) . . . . ?
C14 C6 C7 C13 -1.1(3) . . . . ?
C5 C6 C7 C8 -2.3(6) . . . . ?
C14 C6 C7 C8 174.6(3) . . . . ?
C13 C7 C8 C9 0.9(4) . . . . ?
C6 C7 C8 C9 -174.3(3) . . . . ?
C7 C8 C9 C10 -0.6(4) . . . . ?
C7 C8 C9 C16 -178.5(2) . . . . ?
C8 C9 C10 C11 -1.5(4) . . . . ?
C16 C9 C10 C11 176.4(2) . . . . ?
C9 C10 C11 C13 2.9(4) . . . . ?
C9 C10 C11 C12 -177.8(2) . . . . ?
C13 C11 C12 P2 -74.1(3) . . . . ?
C10 C11 C12 P2 106.6(3) . . . . ?
C13 C11 C12 Rh1 5.2(3) . . . . ?
C10 C11 C12 Rh1 -174.1(2) . . . . ?
C35 P2 C12 C11 -12.3(2) . . . . ?
Rh2 P2 C12 C11 -176.99(15) . . . . ?
Rh1 P2 C12 C11 100.8(2) . . . . ?
C35 P2 C12 Rh1 -113.13(9) . . . . ?
Rh2 P2 C12 Rh1 82.22(7) . . . . ?
C10 C11 C13 N1 173.5(2) . . . . ?
C12 C11 C13 N1 -5.8(3) . . . . ?
C10 C11 C13 C7 -2.7(4) . . . . ?
C12 C11 C13 C7 177.9(2) . . . . ?
C14 N1 C13 C11 -177.2(2) . . . . ?
Rh1 N1 C13 C11 3.2(3) . . . . ?
C14 N1 C13 C7 -0.5(3) . . . . ?
Rh1 N1 C13 C7 179.87(17) . . . . ?
C8 C7 C13 C11 0.8(4) . . . . ?
C6 C7 C13 C11 177.5(2) . . . . ?
C8 C7 C13 N1 -175.7(2) . . . . ?
C6 C7 C13 N1 1.0(3) . . . . ?
C13 N1 C14 C2 173.6(2) . . . . ?
Rh1 N1 C14 C2 -7.0(4) . . . . ?
C13 N1 C14 C6 -0.2(3) . . . . ?
Rh1 N1 C14 C6 179.24(19) . . . . ?
C3 C2 C14 N1 -177.3(2) . . . . ?
C1 C2 C14 N1 -2.7(4) . . . . ?
C3 C2 C14 C6 -4.1(3) . . . . ?
C1 C2 C14 C6 170.5(2) . . . . ?
C5 C6 C14 N1 178.3(2) . . . . ?
C7 C6 C14 N1 0.8(3) . . . . ?
C5 C6 C14 C2 4.1(4) . . . . ?
C7 C6 C14 C2 -173.4(2) . . . . ?
C1 P1 C17 C22 -89.0(2) . . . . ?
Rh1 P1 C17 C22 110.32(18) . . . . ?
C1 P1 C17 C18 76.8(2) . . . . ?
Rh1 P1 C17 C18 -83.9(2) . . . . ?
C22 C17 C18 C19 10.3(3) . . . . ?
P1 C17 C18 C19 -155.44(19) . . . . ?
C22 C17 C18 C23 -167.6(2) . . . . ?
P1 C17 C18 C23 26.6(3) . . . . ?
C17 C18 C19 C20 -2.5(4) . . . . ?
C23 C18 C19 C20 175.7(2) . . . . ?
C18 C19 C20 C21 -5.7(4) . . . . ?
C18 C19 C20 C27 178.7(2) . . . . ?
C19 C20 C21 C22 6.1(4) . . . . ?
C27 C20 C21 C22 -178.3(2) . . . . ?
C20 C21 C22 C17 1.6(4) . . . . ?
C20 C21 C22 C31 -176.4(2) . . . . ?
C18 C17 C22 C21 -10.0(3) . . . . ?
P1 C17 C22 C21 155.95(18) . . . . ?
C18 C17 C22 C31 167.9(2) . . . . ?
P1 C17 C22 C31 -26.2(3) . . . . ?
C19 C18 C23 C24 -164.8(3) . . . . ?
C17 C18 C23 C24 13.2(4) . . . . ?
C19 C18 C23 C25 69.5(3) . . . . ?
C17 C18 C23 C25 -112.5(3) . . . . ?
C19 C18 C23 C26 -47.0(3) . . . . ?
C17 C18 C23 C26 131.0(3) . . . . ?
C21 C20 C27 C30 10.2(3) . . . . ?
C19 C20 C27 C30 -174.4(2) . . . . ?
C21 C20 C27 C29 -109.9(3) . . . . ?
C19 C20 C27 C29 65.5(3) . . . . ?
C21 C20 C27 C28 130.4(3) . . . . ?
C19 C20 C27 C28 -54.2(3) . . . . ?
C21 C22 C31 C34 -108.2(3) . . . . ?
C17 C22 C31 C34 73.9(3) . . . . ?
C21 C22 C31 C32 11.1(3) . . . . ?
C17 C22 C31 C32 -166.8(2) . . . . ?
C21 C22 C31 C33 128.7(2) . . . . ?
C17 C22 C31 C33 -49.2(3) . . . . ?
C12 P2 C35 C40 109.8(2) . . . . ?
Rh2 P2 C35 C40 -88.5(2) . . . . ?
Rh1 P2 C35 C40 43.4(2) . . . . ?
C12 P2 C35 C36 -54.3(2) . . . . ?
Rh2 P2 C35 C36 107.40(18) . . . . ?
Rh1 P2 C35 C36 -120.69(16) . . . . ?
C40 C35 C36 C37 -16.3(3) . . . . ?
P2 C35 C36 C37 148.2(2) . . . . ?
C40 C35 C36 C41 152.6(2) . . . . ?
P2 C35 C36 C41 -42.9(3) . . . . ?
C35 C36 C37 C38 4.5(4) . . . . ?
C41 C36 C37 C38 -165.3(2) . . . . ?
C36 C37 C38 C39 8.3(4) . . . . ?
C36 C37 C38 C45 -175.6(2) . . . . ?
C37 C38 C39 C40 -9.9(4) . . . . ?
C45 C38 C39 C40 173.9(2) . . . . ?
C38 C39 C40 C35 -1.7(4) . . . . ?
C38 C39 C40 C49 175.3(2) . . . . ?
C36 C35 C40 C39 15.0(3) . . . . ?
P2 C35 C40 C39 -149.0(2) . . . . ?
C36 C35 C40 C49 -161.5(2) . . . . ?
P2 C35 C40 C49 34.5(3) . . . . ?
C37 C36 C41 C42 -138.6(2) . . . . ?
C35 C36 C41 C42 52.4(4) . . . . ?
C37 C36 C41 C44 -15.6(3) . . . . ?
C35 C36 C41 C44 175.4(2) . . . . ?
C37 C36 C41 C43 100.4(3) . . . . ?
C35 C36 C41 C43 -68.6(3) . . . . ?
C39 C38 C45 C46 -172.6(3) . . . . ?
C37 C38 C45 C46 11.4(4) . . . . ?
C39 C38 C45 C47 66.7(3) . . . . ?
C37 C38 C45 C47 -109.3(3) . . . . ?
C39 C38 C45 C48 -52.9(3) . . . . ?
C37 C38 C45 C48 131.2(3) . . . . ?
C39 C40 C49 C52 -175.3(2) . . . . ?
C35 C40 C49 C52 1.3(4) . . . . ?
C39 C40 C49 C50 60.6(3) . . . . ?
C35 C40 C49 C50 -122.8(3) . . . . ?
C39 C40 C49 C51 -57.6(3) . . . . ?
C35 C40 C49 C51 119.0(3) . . . . ?
C60 C53 C54 C55 2.5(4) . . . . ?
Rh2 C53 C54 C55 -102.8(3) . . . . ?
C60 C53 C54 Rh2 105.2(2) . . . . ?
C53 C54 C55 C56 46.2(4) . . . . ?
Rh2 C54 C55 C56 -35.3(3) . . . . ?
C54 C55 C56 C57 31.7(4) . . . . ?
C55 C56 C57 C58 -92.5(3) . . . . ?
C55 C56 C57 Rh2 -12.9(3) . . . . ?
C56 C57 C58 C59 2.4(4) . . . . ?
Rh2 C57 C58 C59 -100.7(3) . . . . ?
C56 C57 C58 Rh2 103.1(3) . . . . ?
C57 C58 C59 C60 47.0(4) . . . . ?
Rh2 C58 C59 C60 -35.2(3) . . . . ?
C54 C53 C60 C59 -91.8(3) . . . . ?
Rh2 C53 C60 C59 -11.6(3) . . . . ?
C58 C59 C60 C53 31.6(3) . . . . ?
C61 C62 C63 C64 174.8(4) . . . . ?
C62 C63 C64 C65 178.3(3) . . . . ?
