#------------------------------------------------------------------------------
#$Date: 2025-10-06 11:34:54 +0200 (Mon 06 de Oct de 2025) $
#$Revision: 302661 $
#$URL: svn://www.crystallography.net/cod/cif/7/71/92/7719249.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7719249
loop_
_publ_author_name
'Jornet-Mollá, Verónica'
'Gómez-García, Carlos J'
'Dolz-Lozano, Miquel J'
'Giménez-Saiz, Carlos'
'Romero, Francisco M.'
_publ_section_title
;
 Synthesis, structure and slow magnetic relaxation of lanthanoid
 coordination polymers based on ethynyl-bridged picolinate ligands.
;
_journal_issue                   35
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13143
_journal_page_last               13154
_journal_paper_doi               10.1039/d5dt01330e
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C30 H18 Dy N2 O10, C2 H8 N'
_chemical_formula_sum            'C32 H26 Dy N3 O10'
_chemical_formula_weight         775.06
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-I 2ya'
_space_group_name_H-M_alt        'I 1 2/a 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     difmap
_atom_sites_solution_secondary   geom
_audit_creation_method           SHELXL-2019/3
_audit_update_record
;
2024-10-21 deposited with the CCDC.	2025-08-01 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 98.3972(8)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.93791(9)
_cell_length_b                   10.73099(12)
_cell_length_c                   24.5071(3)
_cell_measurement_reflns_used    39058
_cell_measurement_temperature    119.95(10)
_cell_measurement_theta_max      27.5680
_cell_measurement_theta_min      3.9040
_cell_volume                     3105.84(6)
_computing_cell_refinement       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_structure_refinement  'SHELXL-2019/2 (Sheldrick, 2019)'
_computing_structure_solution    'SHELXL-2018/3 (Sheldrick, 2018)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      119.95(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.0267
_diffrn_detector_type            Sapphire3
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.956
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -51.00  54.00   0.75    8.00    --  -17.76  77.00   0.00  140
  2  ω    -51.00  54.00   0.75    8.00    --  -17.76  77.00 -90.00  140
  3  ω    -41.00  52.00   0.75    8.00    --  -17.76  57.00 120.00  124
  4  ω     -5.00  88.00   0.75    8.00    --   18.62  57.00 -90.00  124
  5  ω     -5.00  88.00   0.75    8.00    --   18.62  57.00   0.00  124
  6  ω     -5.00  88.00   0.75    8.00    --   18.62  57.00  60.00  124
  7  ω    -20.00  62.50   0.75    8.00    --   18.62 -99.00-150.00  110
  8  ω    -14.00  91.00   0.75    8.00    --   18.62  77.00 150.00  140
  9  ω    -20.00  26.50   0.75    8.00    --  -17.76 -99.00-180.00   62
 10  ω    -49.00  56.00   0.75    8.00    --  -17.76  38.00 -90.00  140
 11  ω    -49.00  56.00   0.75    8.00    --  -17.76  38.00 -30.00  140
 12  ω    -90.00  15.00   0.75    8.00    --  -17.76 -77.00 -90.00  140
 13  ω    -20.00  62.50   0.75    8.00    --   18.62 -99.00 -60.00  110
 14  ω    -20.00  62.50   0.75    8.00    --   18.62 -99.00  90.00  110
 15  ω    -56.00  94.00   0.75    8.00    --   18.62   0.00-150.00  200
 16  ω    -56.00  94.00   0.75    8.00    --   18.62   0.00-120.00  200
 17  ω    -56.00  94.00   0.75    8.00    --   18.62   0.00 -90.00  200
 18  ω    -56.00  94.00   0.75    8.00    --   18.62   0.00 -60.00  200
 19  ω    -56.00  60.25   0.75    8.00    --   18.62   0.00 -30.00  155
 20  ω    -56.00  94.00   0.75    8.00    --   18.62   0.00-180.00  200
;
_diffrn_measurement_device_type  'four-circle diffractometer'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0018853000
_diffrn_orient_matrix_UB_12      -0.0646052000
_diffrn_orient_matrix_UB_13      0.0061733000
_diffrn_orient_matrix_UB_21      0.0446943000
_diffrn_orient_matrix_UB_22      0.0107633000
_diffrn_orient_matrix_UB_23      0.0219384000
_diffrn_orient_matrix_UB_31      -0.0400531000
_diffrn_orient_matrix_UB_32      0.0089283000
_diffrn_orient_matrix_UB_33      0.0183553000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0364
_diffrn_reflns_av_unetI/netI     0.0161
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.956
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            58070
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.956
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.776
_diffrn_reflns_theta_min         3.202
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    2.469
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.446
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.658
_exptl_crystal_description       spearhead
_exptl_crystal_F_000             1540
_exptl_crystal_preparation       'Magnetic properties'
_exptl_crystal_recrystallization_method 'Solvothermal (DMF/H2O)'
_exptl_crystal_size_max          0.336
_exptl_crystal_size_mid          0.154
_exptl_crystal_size_min          0.085
_refine_diff_density_max         0.852
_refine_diff_density_min         -0.368
_refine_diff_density_rms         0.072
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.119
_refine_ls_hydrogen_treatment    hetero
_refine_ls_matrix_type           full
_refine_ls_number_parameters     218
_refine_ls_number_reflns         3495
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.119
_refine_ls_R_factor_all          0.0184
_refine_ls_R_factor_gt           0.0159
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0165P)²+4.4712P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0371
_refine_ls_wR_factor_ref         0.0391
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3315
_reflns_number_total             3495
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5dt01330e2.cif
_cod_data_source_block           picCOODy-c4
_cod_depositor_comments
'Adding full bibliography for 7719245--7719249.cif.'
_cod_original_sg_symbol_H-M      'I 2/a'
_cod_database_code               7719249
_shelx_shelxl_version_number     2019/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.491
_shelx_estimated_absorpt_t_max   0.818
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.750000 0.56207(2) 0.000000 0.01316(4) Uani 1 2 d S T P . .
O1 O 0.68338(11) 0.48450(12) 0.07760(5) 0.0200(3) Uani 1 1 d . . . . .
O2 O 0.79192(11) 0.33420(13) 0.12051(6) 0.0257(3) Uani 1 1 d . . . . .
O3 O 0.07365(10) 0.16793(11) 0.49524(5) 0.0173(2) Uani 1 1 d . . . . .
O4 O -0.05514(11) 0.30564(13) 0.45699(6) 0.0266(3) Uani 1 1 d . . . . .
O1W O 0.87831(11) 0.40812(13) 0.03504(6) 0.0210(3) Uani 1 1 d . . . . .
H1WA H 0.938(2) 0.387(2) 0.0266(10) 0.032 Uiso 1 1 d . U . . .
H1WB H 0.864(2) 0.380(2) 0.0634(11) 0.032 Uiso 1 1 d . U . . .
N1 N 0.21432(12) 0.22858(14) 0.42549(6) 0.0187(3) Uani 1 1 d . . . . .
C1 C 0.70695(15) 0.40378(18) 0.11510(7) 0.0191(4) Uani 1 1 d . . . . .
C2 C 0.62721(15) 0.39382(18) 0.15716(7) 0.0195(4) Uani 1 1 d . . . . .
C3 C 0.64704(16) 0.3068(2) 0.19927(8) 0.0277(4) Uani 1 1 d . . . . .
H3 H 0.710549 0.252857 0.201131 0.033 Uiso 1 1 calc R U . . .
C4 C 0.57520(17) 0.2978(2) 0.23867(8) 0.0305(5) Uani 1 1 d . . . . .
H4 H 0.590413 0.238903 0.267735 0.037 Uiso 1 1 calc R U . . .
C5 C 0.48069(16) 0.37502(19) 0.23574(8) 0.0233(4) Uani 1 1 d . . . . .
C6 C 0.45999(16) 0.46160(19) 0.19313(8) 0.0241(4) Uani 1 1 d . . . . .
H6 H 0.395642 0.514505 0.190658 0.029 Uiso 1 1 calc R U . . .
C7 C 0.53313(16) 0.47063(19) 0.15437(8) 0.0229(4) Uani 1 1 d . . . . .
H7 H 0.518707 0.530166 0.125509 0.027 Uiso 1 1 calc R U . . .
C8 C 0.03587(14) 0.24991(16) 0.45965(7) 0.0174(3) Uani 1 1 d . . . . .
C9 C 0.11097(14) 0.28110(17) 0.41709(7) 0.0176(3) Uani 1 1 d . . . . .
C10 C 0.07583(15) 0.35915(18) 0.37287(8) 0.0234(4) Uani 1 1 d . . . . .
H10 H 0.002349 0.395146 0.368286 0.028 Uiso 1 1 calc R U . . .
C11 C 0.14900(17) 0.3838(2) 0.33562(8) 0.0270(4) Uani 1 1 d . . . . .
H11 H 0.126260 0.436065 0.304696 0.032 Uiso 1 1 calc R U . . .
C12 C 0.25708(16) 0.33090(19) 0.34397(8) 0.0240(4) Uani 1 1 d . . . . .
C13 C 0.28560(15) 0.25404(18) 0.38977(8) 0.0222(4) Uani 1 1 d . . . . .
H13 H 0.359119 0.218155 0.395833 0.027 Uiso 1 1 calc R U . . .
C14 C 0.33697(17) 0.3514(2) 0.30667(8) 0.0270(4) Uani 1 1 d . . . . .
C15 C 0.40336(16) 0.3634(2) 0.27509(8) 0.0265(4) Uani 1 1 d . . . . .
N2 N -0.250000 0.3419(2) 0.500000 0.0260(5) Uani 1 2 d S T P . .
H2N H -0.197(2) 0.293(2) 0.4890(10) 0.039 Uiso 1 1 d . U . . .
C16 C -0.3022(2) 0.4183(2) 0.45312(11) 0.0378(5) Uani 1 1 d . . . . .
H16A H -0.335688 0.363705 0.423050 0.057 Uiso 1 1 calc R U . . .
H16B H -0.361351 0.471031 0.464844 0.057 Uiso 1 1 calc R U . . .
H16C H -0.244275 0.471025 0.440293 0.057 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 O1 137.96(6) . 2_655 ?
O1 Dy1 O1W 76.24(5) . 2_655 ?
O1 Dy1 O1W 74.29(5) 2_655 2_655 ?
O1 Dy1 O1W 74.29(5) . . ?
O1 Dy1 O1W 76.24(5) 2_655 . ?
O1W Dy1 O1W 89.69(7) 2_655 . ?
O1 Dy1 O3 122.52(4) . 4 ?
O1 Dy1 O3 78.74(4) 2_655 4 ?
O1W Dy1 O3 152.34(5) 2_655 4 ?
O1W Dy1 O3 77.94(4) . 4 ?
O1 Dy1 O3 78.74(4) . 3_554 ?
O1 Dy1 O3 122.52(4) 2_655 3_554 ?
O1W Dy1 O3 77.94(4) 2_655 3_554 ?
O1W Dy1 O3 152.34(5) . 3_554 ?
O3 Dy1 O3 122.98(6) 4 3_554 ?
O1 Dy1 N1 72.86(5) . 4 ?
O1 Dy1 N1 142.96(5) 2_655 4 ?
O1W Dy1 N1 142.57(5) 2_655 4 ?
O1W Dy1 N1 101.60(5) . 4 ?
O3 Dy1 N1 64.89(4) 4 4 ?
O3 Dy1 N1 75.78(4) 3_554 4 ?
O1 Dy1 N1 142.96(5) . 3_554 ?
O1 Dy1 N1 72.86(5) 2_655 3_554 ?
O1W Dy1 N1 101.60(5) 2_655 3_554 ?
O1W Dy1 N1 142.57(5) . 3_554 ?
O3 Dy1 N1 75.78(4) 4 3_554 ?
O3 Dy1 N1 64.89(4) 3_554 3_554 ?
N1 Dy1 N1 90.85(7) 4 3_554 ?
C1 O1 Dy1 140.80(12) . . ?
C8 O3 Dy1 125.82(10) . 3_445 ?
Dy1 O1W H1WA 131.8(18) . . ?
Dy1 O1W H1WB 112.6(18) . . ?
H1WA O1W H1WB 115(2) . . ?
C13 N1 C9 118.18(16) . . ?
C13 N1 Dy1 123.92(12) . 3_445 ?
C9 N1 Dy1 117.23(11) . 3_445 ?
O2 C1 O1 125.23(16) . . ?
O2 C1 C2 117.98(16) . . ?
O1 C1 C2 116.77(16) . . ?
C3 C2 C7 119.09(17) . . ?
C3 C2 C1 120.08(17) . . ?
C7 C2 C1 120.83(16) . . ?
C4 C3 C2 120.68(18) . . ?
C4 C3 H3 119.7 . . ?
C2 C3 H3 119.7 . . ?
C3 C4 C5 120.12(18) . . ?
C3 C4 H4 119.9 . . ?
C5 C4 H4 119.9 . . ?
C6 C5 C4 119.27(17) . . ?
C6 C5 C15 120.08(18) . . ?
C4 C5 C15 120.62(18) . . ?
C7 C6 C5 120.04(18) . . ?
C7 C6 H6 120.0 . . ?
C5 C6 H6 120.0 . . ?
C6 C7 C2 120.79(18) . . ?
C6 C7 H7 119.6 . . ?
C2 C7 H7 119.6 . . ?
O4 C8 O3 126.29(16) . . ?
O4 C8 C9 117.63(16) . . ?
O3 C8 C9 116.08(15) . . ?
N1 C9 C10 122.64(16) . . ?
N1 C9 C8 115.20(15) . . ?
C10 C9 C8 122.15(16) . . ?
C11 C10 C9 119.04(17) . . ?
C11 C10 H10 120.5 . . ?
C9 C10 H10 120.5 . . ?
C10 C11 C12 119.09(18) . . ?
C10 C11 H11 120.5 . . ?
C12 C11 H11 120.5 . . ?
C13 C12 C11 118.03(17) . . ?
C13 C12 C14 119.85(17) . . ?
C11 C12 C14 122.11(18) . . ?
N1 C13 C12 123.00(17) . . ?
N1 C13 H13 118.5 . . ?
C12 C13 H13 118.5 . . ?
C15 C14 C12 177.3(2) . . ?
C14 C15 C5 178.0(2) . . ?
C16 N2 C16 112.4(2) 2_456 . ?
C16 N2 H2N 108.9(16) 2_456 . ?
C16 N2 H2N 109.2(16) . . ?
C16 N2 H2N 109.2(16) 2_456 2_456 ?
C16 N2 H2N 108.9(16) . 2_456 ?
H2N N2 H2N 108(3) . 2_456 ?
N2 C16 H16A 109.5 . . ?
N2 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
N2 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.3204(12) . ?
Dy1 O1 2.3204(12) 2_655 ?
Dy1 O1W 2.3299(13) 2_655 ?
Dy1 O1W 2.3299(13) . ?
Dy1 O3 2.3801(12) 4 ?
Dy1 O3 2.3801(12) 3_554 ?
Dy1 N1 2.5460(15) 4 ?
Dy1 N1 2.5460(15) 3_554 ?
O1 C1 1.264(2) . ?
O2 C1 1.251(2) . ?
O3 C8 1.274(2) . ?
O4 C8 1.234(2) . ?
O1W H1WA 0.81(3) . ?
O1W H1WB 0.80(3) . ?
N1 C13 1.335(2) . ?
N1 C9 1.345(2) . ?
C1 C2 1.506(2) . ?
C2 C3 1.386(3) . ?
C2 C7 1.387(3) . ?
C3 C4 1.385(3) . ?
C3 H3 0.9500 . ?
C4 C5 1.393(3) . ?
C4 H4 0.9500 . ?
C5 C6 1.393(3) . ?
C5 C15 1.435(3) . ?
C6 C7 1.384(3) . ?
C6 H6 0.9500 . ?
C7 H7 0.9500 . ?
C8 C9 1.509(2) . ?
C9 C10 1.385(3) . ?
C10 C11 1.378(3) . ?
C10 H10 0.9500 . ?
C11 C12 1.397(3) . ?
C11 H11 0.9500 . ?
C12 C13 1.394(3) . ?
C12 C14 1.431(3) . ?
C13 H13 0.9500 . ?
C14 C15 1.193(3) . ?
N2 C16 1.473(3) 2_456 ?
N2 C16 1.473(3) . ?
N2 H2N 0.90(2) . ?
N2 H2N 0.90(2) 2_456 ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
O1W H1WA O3 0.81(3) 1.98(3) 2.7783(18) 172(2) 8_654 yes
O1W H1WB O2 0.80(3) 1.82(3) 2.5907(19) 163(2) . yes
N2 H2N O4 0.90(2) 1.97(2) 2.7184(13) 140(2) . yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O1 C1 O2 2.1(3) . . . . ?
Dy1 O1 C1 C2 -179.46(12) . . . . ?
O2 C1 C2 C3 -2.0(3) . . . . ?
O1 C1 C2 C3 179.52(18) . . . . ?
O2 C1 C2 C7 178.25(18) . . . . ?
O1 C1 C2 C7 -0.3(3) . . . . ?
C7 C2 C3 C4 -1.1(3) . . . . ?
C1 C2 C3 C4 179.12(19) . . . . ?
C2 C3 C4 C5 1.2(3) . . . . ?
C3 C4 C5 C6 -0.5(3) . . . . ?
C3 C4 C5 C15 177.6(2) . . . . ?
C4 C5 C6 C7 -0.2(3) . . . . ?
C15 C5 C6 C7 -178.38(19) . . . . ?
C5 C6 C7 C2 0.3(3) . . . . ?
C3 C2 C7 C6 0.4(3) . . . . ?
C1 C2 C7 C6 -179.85(18) . . . . ?
Dy1 O3 C8 O4 -179.67(14) 3_445 . . . ?
Dy1 O3 C8 C9 0.1(2) 3_445 . . . ?
C13 N1 C9 C10 0.5(3) . . . . ?
Dy1 N1 C9 C10 -170.49(14) 3_445 . . . ?
C13 N1 C9 C8 -178.95(16) . . . . ?
Dy1 N1 C9 C8 10.0(2) 3_445 . . . ?
O4 C8 C9 N1 172.75(16) . . . . ?
O3 C8 C9 N1 -7.0(2) . . . . ?
O4 C8 C9 C10 -6.7(3) . . . . ?
O3 C8 C9 C10 173.49(17) . . . . ?
N1 C9 C10 C11 0.4(3) . . . . ?
C8 C9 C10 C11 179.85(18) . . . . ?
C9 C10 C11 C12 -0.9(3) . . . . ?
C10 C11 C12 C13 0.6(3) . . . . ?
C10 C11 C12 C14 179.3(2) . . . . ?
C9 N1 C13 C12 -0.9(3) . . . . ?
Dy1 N1 C13 C12 169.45(15) 3_445 . . . ?
C11 C12 C13 N1 0.4(3) . . . . ?
C14 C12 C13 N1 -178.38(19) . . . . ?
