#------------------------------------------------------------------------------
#$Date: 2025-10-06 11:26:32 +0200 (Mon 06 de Oct de 2025) $
#$Revision: 302647 $
#$URL: svn://www.crystallography.net/cod/cif/7/71/92/7719259.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7719259
loop_
_publ_author_name
'Ryan, Aidan'
'Delattre, Hugo'
'Kociok-Köhn, Gabriele'
'Johnson, Andrew L.'
_publ_section_title
;
 Synthesis and characterization of Sn(II) complexes supported by amino
 bis-phenoxide ligands.
;
_journal_issue                   36
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13632
_journal_page_last               13641
_journal_paper_doi               10.1039/d5dt01442e
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C40 H50 N2 O4 Sn, 2(C7 H8)'
_chemical_formula_sum            'C54 H66 N2 O4 Sn'
_chemical_formula_weight         925.77
_chemical_properties_physical    Moisture-sensitive
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_method           SHELXL-2019/3
_audit_update_record
;
2025-06-19 deposited with the CCDC.	2025-08-06 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 110.0141(15)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.4186(2)
_cell_length_b                   21.9250(2)
_cell_length_c                   14.6746(2)
_cell_measurement_reflns_used    21616
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      71.4710
_cell_measurement_theta_min      3.1700
_cell_volume                     4661.20(11)
_computing_cell_refinement       'CrysAlisPro 1.171.42.56a (Rigaku OD, 2022)'
_computing_data_collection       'CrysAlisPro 1.171.42.56a (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.56a (Rigaku OD, 2022)'
_computing_molecular_graphics
'ORTEP3 for Windows - Farrugia, L. J. J. Appl. Crystallogr. 1997, 30, 565'
_computing_publication_material
;
 'WinGX publication routines, Farrugia, 
 L. J., J. Appl. Crystallogr., 1999, 32, 837-838
;
_computing_structure_refinement
;
 SHELXL-2019/2 (Sheldrick, 2019)
 Sheldrick GM (2008) Acta Crystallogr A64:112--122 and 
 C. B. Hübschle, G. M. Sheldrick and B. Dittrich
 ShelXle: a Qt graphical user interface for SHELXL
 J. Appl. Cryst., 44, (2011) 1281-1284.
;
_computing_structure_solution
; 
 SHELXT
 Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
;
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      150.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 8.1150
_diffrn_detector_type            EosS2
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, EosS2'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0379
_diffrn_reflns_av_unetI/netI     0.0301
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            32217
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         71.562
_diffrn_reflns_theta_min         3.050
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    4.725
_exptl_absorpt_correction_T_max  0.570
_exptl_absorpt_correction_T_min  0.059
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.43a (Rigaku Oxford Diffraction, 2019)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.319
_exptl_crystal_description       block
_exptl_crystal_F_000             1944
_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent'
_exptl_crystal_size_max          0.622
_exptl_crystal_size_mid          0.476
_exptl_crystal_size_min          0.286
_refine_diff_density_max         1.095
_refine_diff_density_min         -1.283
_refine_diff_density_rms         0.071
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     562
_refine_ls_number_reflns         8988
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0353
_refine_ls_R_factor_gt           0.0342
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0593P)²+1.6050P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0944
_refine_ls_wR_factor_ref         0.0955
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8634
_reflns_number_total             8988
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5dt01442e2.cif
_cod_data_source_block           s20alj24
_cod_depositor_comments
'Adding full bibliography for 7719254--7719260.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7719259
_shelx_shelxl_version_number     2019/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.157
_shelx_estimated_absorpt_t_max   0.345
_oxdiff_exptl_absorpt_empirical_full_min 0.754
_oxdiff_exptl_absorpt_empirical_full_max 1.318
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn 0.22983(2) 0.11115(2) 0.41738(2) 0.02485(7) Uani 1 1 d . . . . .
N1 N 0.26176(13) 0.17405(8) 0.54457(13) 0.0270(4) Uani 1 1 d . . . . .
N2 N 0.19978(13) 0.05128(8) 0.28643(13) 0.0266(4) Uani 1 1 d . . . . .
O1 O 0.34293(12) 0.06116(8) 0.48670(11) 0.0352(4) Uani 1 1 d . . . . .
O2 O 0.12041(11) 0.16370(7) 0.34273(11) 0.0306(3) Uani 1 1 d . . . . .
O3 O 0.30793(12) 0.16525(7) 0.36379(12) 0.0331(3) Uani 1 1 d . . . . .
O4 O 0.14676(13) 0.06022(7) 0.46683(12) 0.0343(4) Uani 1 1 d . . . . .
C1 C 0.21340(17) 0.15678(10) 0.61388(16) 0.0308(5) Uani 1 1 d . . . . .
H1A H 0.232509 0.114975 0.637894 0.037 Uiso 1 1 calc R U . . .
H1B H 0.146098 0.155918 0.578052 0.037 Uiso 1 1 calc R U . . .
C2 C 0.23190(19) 0.19905(12) 0.70064(18) 0.0393(5) Uani 1 1 d . . . . .
H2A H 0.217486 0.241117 0.677946 0.059 Uiso 1 1 calc R U . . .
H2B H 0.297054 0.196221 0.741525 0.059 Uiso 1 1 calc R U . . .
H2C H 0.193092 0.187044 0.738355 0.059 Uiso 1 1 calc R U . . .
C3 C 0.27220(17) 0.00312(10) 0.29941(16) 0.0305(5) Uani 1 1 d . . . . .
H3A H 0.275385 -0.022042 0.356478 0.037 Uiso 1 1 calc R U . . .
H3B H 0.332791 0.023373 0.313619 0.037 Uiso 1 1 calc R U . . .
C4 C 0.2562(2) -0.03874(12) 0.21268(19) 0.0417(6) Uani 1 1 d . . . . .
H4A H 0.246023 -0.014161 0.154157 0.062 Uiso 1 1 calc R U . . .
H4B H 0.201782 -0.064202 0.204546 0.062 Uiso 1 1 calc R U . . .
H4C H 0.310329 -0.064858 0.223381 0.062 Uiso 1 1 calc R U . . .
C11 C 0.38983(17) 0.06043(11) 0.58279(17) 0.0319(5) Uani 1 1 d . . . . .
C12 C 0.43007(19) 0.00524(12) 0.62545(19) 0.0383(5) Uani 1 1 d . . . . .
C13 C 0.48067(19) 0.00398(12) 0.72345(19) 0.0399(6) Uani 1 1 d . . . . .
H13 H 0.508333 -0.033297 0.751909 0.048 Uiso 1 1 calc R U . . .
C14 C 0.49250(18) 0.05565(13) 0.78201(18) 0.0389(5) Uani 1 1 d . . . . .
C15 C 0.45252(19) 0.10974(11) 0.73857(19) 0.0363(6) Uani 1 1 d . . . . .
H15 H 0.459597 0.145379 0.777258 0.044 Uiso 1 1 calc R U . . .
C16 C 0.40226(18) 0.11321(10) 0.63974(18) 0.0316(5) Uani 1 1 d . . . . .
C17 C 0.4172(2) -0.05109(12) 0.5629(2) 0.0518(7) Uani 1 1 d . . . . .
H17A H 0.351099 -0.058410 0.529867 0.078 Uiso 1 1 calc R U . . .
H17B H 0.444714 -0.086284 0.603740 0.078 Uiso 1 1 calc R U . . .
H17C H 0.447286 -0.045114 0.514649 0.078 Uiso 1 1 calc R U . . .
C18 C 0.5465(2) 0.05257(15) 0.88921(19) 0.0493(7) Uani 1 1 d . . . . .
H18A H 0.510032 0.031213 0.922383 0.074 Uiso 1 1 calc R U . . .
H18B H 0.560260 0.093994 0.915233 0.074 Uiso 1 1 calc R U . . .
H18C H 0.604396 0.030484 0.899634 0.074 Uiso 1 1 calc R U . . .
C19 C 0.36498(16) 0.17344(10) 0.59311(17) 0.0314(5) Uani 1 1 d . . . . .
H19A H 0.382661 0.205705 0.643311 0.038 Uiso 1 1 calc R U . . .
H19B H 0.394059 0.183317 0.544332 0.038 Uiso 1 1 calc R U . . .
C21 C 0.07989(16) 0.20653(10) 0.38037(16) 0.0280(4) Uani 1 1 d . . . . .
C22 C -0.01598(16) 0.21457(10) 0.33758(16) 0.0301(5) Uani 1 1 d . . . . .
C23 C -0.05864(17) 0.26020(11) 0.37278(17) 0.0330(5) Uani 1 1 d . . . . .
H23 H -0.123283 0.266118 0.343185 0.040 Uiso 1 1 calc R U . . .
C24 C -0.00972(17) 0.29740(11) 0.44988(17) 0.0338(5) Uani 1 1 d . . . . .
C25 C 0.08469(17) 0.28854(10) 0.49132(17) 0.0320(5) Uani 1 1 d . . . . .
H25 H 0.119072 0.313607 0.544140 0.038 Uiso 1 1 calc R U . . .
C26 C 0.13058(16) 0.24392(10) 0.45770(16) 0.0287(4) Uani 1 1 d . . . . .
C27 C -0.06888(18) 0.17449(12) 0.25448(19) 0.0386(5) Uani 1 1 d . . . . .
H27A H -0.041092 0.176623 0.203670 0.058 Uiso 1 1 calc R U . . .
H27B H -0.133125 0.188319 0.228301 0.058 Uiso 1 1 calc R U . . .
H27C H -0.067021 0.132294 0.277118 0.058 Uiso 1 1 calc R U . . .
C28 C -0.0589(2) 0.34494(13) 0.4886(2) 0.0447(6) Uani 1 1 d . . . . .
H28A H -0.095210 0.371431 0.435386 0.067 Uiso 1 1 calc R U . . .
H28B H -0.013416 0.369487 0.538037 0.067 Uiso 1 1 calc R U . . .
H28C H -0.100067 0.324764 0.517356 0.067 Uiso 1 1 calc R U . . .
C29 C 0.23365(16) 0.23689(10) 0.50298(17) 0.0294(4) Uani 1 1 d . . . . .
H29A H 0.257358 0.267491 0.555249 0.035 Uiso 1 1 calc R U . . .
H29B H 0.262353 0.245192 0.453345 0.035 Uiso 1 1 calc R U . . .
C41 C 0.33556(16) 0.15478(10) 0.28802(16) 0.0295(5) Uani 1 1 d . . . . .
C42 C 0.41841(17) 0.18208(11) 0.28943(18) 0.0336(5) Uani 1 1 d . . . . .
C43 C 0.44731(17) 0.17413(11) 0.2104(2) 0.0372(5) Uani 1 1 d . . . . .
H43 H 0.502962 0.193102 0.211195 0.045 Uiso 1 1 calc R U . . .
C44 C 0.39774(18) 0.13939(12) 0.13005(19) 0.0375(5) Uani 1 1 d . . . . .
C45 C 0.31657(19) 0.11224(10) 0.13021(19) 0.0329(5) Uani 1 1 d . . . . .
H45 H 0.282075 0.087904 0.076461 0.040 Uiso 1 1 calc R U . . .
C46 C 0.28439(17) 0.11988(10) 0.20768(17) 0.0298(5) Uani 1 1 d . . . . .
C47 C 0.47284(19) 0.21930(13) 0.3758(2) 0.0431(6) Uani 1 1 d . . . . .
H47A H 0.432436 0.249737 0.389579 0.065 Uiso 1 1 calc R U . . .
H47B H 0.523415 0.239979 0.362187 0.065 Uiso 1 1 calc R U . . .
H47C H 0.498253 0.192498 0.432152 0.065 Uiso 1 1 calc R U . . .
C48 C 0.4308(2) 0.13218(16) 0.0455(2) 0.0516(7) Uani 1 1 d . . . . .
H48A H 0.398085 0.161048 -0.005721 0.077 Uiso 1 1 calc R U . . .
H48B H 0.418735 0.090443 0.020393 0.077 Uiso 1 1 calc R U . . .
H48C H 0.497294 0.140332 0.066586 0.077 Uiso 1 1 calc R U . . .
C49 C 0.19284(16) 0.09278(10) 0.20258(16) 0.0291(4) Uani 1 1 d . . . . .
H49A H 0.149309 0.126271 0.201088 0.035 Uiso 1 1 calc R U . . .
H49B H 0.167177 0.069501 0.141389 0.035 Uiso 1 1 calc R U . . .
C31 C 0.12204(16) 0.00178(10) 0.44174(17) 0.0297(5) Uani 1 1 d . . . . .
C32 C 0.11179(17) -0.03702(11) 0.51308(17) 0.0322(5) Uani 1 1 d . . . . .
C33 C 0.08199(18) -0.09665(11) 0.48721(18) 0.0355(5) Uani 1 1 d . . . . .
H33 H 0.073338 -0.122790 0.535019 0.043 Uiso 1 1 calc R U . . .
C34 C 0.06446(19) -0.11929(11) 0.39418(19) 0.0349(5) Uani 1 1 d . . . . .
C35 C 0.07550(17) -0.07978(11) 0.32491(17) 0.0333(5) Uani 1 1 d . . . . .
H35 H 0.064234 -0.094267 0.260872 0.040 Uiso 1 1 calc R U . . .
C36 C 0.10284(16) -0.01914(10) 0.34733(16) 0.0291(4) Uani 1 1 d . . . . .
C37 C 0.1320(2) -0.01318(12) 0.61432(18) 0.0402(6) Uani 1 1 d . . . . .
H37A H 0.197265 -0.001875 0.642014 0.060 Uiso 1 1 calc R U . . .
H37B H 0.118181 -0.044866 0.654455 0.060 Uiso 1 1 calc R U . . .
H37C H 0.093572 0.022746 0.612469 0.060 Uiso 1 1 calc R U . . .
C38 C 0.0347(2) -0.18451(12) 0.3688(2) 0.0461(6) Uani 1 1 d . . . . .
H38A H 0.089284 -0.210174 0.379218 0.069 Uiso 1 1 calc R U . . .
H38B H -0.005144 -0.186873 0.300648 0.069 Uiso 1 1 calc R U . . .
H38C H 0.000633 -0.198832 0.410155 0.069 Uiso 1 1 calc R U . . .
C39 C 0.10586(16) 0.02394(10) 0.26888(16) 0.0288(4) Uani 1 1 d . . . . .
H39A H 0.061058 0.057290 0.263372 0.035 Uiso 1 1 calc R U . . .
H39B H 0.086329 0.001803 0.206308 0.035 Uiso 1 1 calc R U . . .
C1S C 0.2423(2) 0.51056(16) 0.3762(2) 0.0539(7) Uani 1 1 d . . . . .
C2S C 0.1864(2) 0.53659(15) 0.4212(2) 0.0548(7) Uani 1 1 d . . . . .
H2S H 0.194442 0.578420 0.438987 0.066 Uiso 1 1 calc R U . . .
C3S C 0.1192(2) 0.50341(15) 0.4409(2) 0.0562(8) Uani 1 1 d . . . . .
H3S H 0.081510 0.522318 0.472170 0.067 Uiso 1 1 calc R U . . .
C4S C 0.1067(3) 0.44312(15) 0.4155(2) 0.0570(8) Uani 1 1 d . . . . .
H4S H 0.059988 0.420198 0.428535 0.068 Uiso 1 1 calc R U . . .
C5S C 0.1619(3) 0.41586(16) 0.3710(2) 0.0619(9) Uani 1 1 d . . . . .
H5S H 0.153589 0.374001 0.353412 0.074 Uiso 1 1 calc R U . . .
C6S C 0.2294(3) 0.44933(16) 0.3518(2) 0.0607(9) Uani 1 1 d . . . . .
H6S H 0.267559 0.430146 0.321468 0.073 Uiso 1 1 calc R U . . .
C7S C 0.3146(3) 0.5470(2) 0.3540(3) 0.0791(12) Uani 1 1 d . . . . .
H7SA H 0.288507 0.564321 0.288747 0.119 Uiso 1 1 calc R U . . .
H7SB H 0.366786 0.520523 0.357376 0.119 Uiso 1 1 calc R U . . .
H7SC H 0.335814 0.580042 0.401467 0.119 Uiso 1 1 calc R U . . .
C8S C 0.6726(2) 0.27250(16) 0.2612(3) 0.0589(8) Uani 1 1 d . . . . .
C13S C 0.6902(2) 0.21008(18) 0.2628(3) 0.0697(10) Uani 1 1 d . . . . .
H13S H 0.682482 0.189289 0.203775 0.084 Uiso 1 1 calc R U . . .
C12S C 0.7183(3) 0.17839(18) 0.3480(4) 0.0745(11) Uani 1 1 d . . . . .
H12S H 0.729174 0.135793 0.346998 0.089 Uiso 1 1 calc R U . . .
C11S C 0.7311(2) 0.2066(2) 0.4347(3) 0.0704(10) Uani 1 1 d . . . . .
H11S H 0.750871 0.183996 0.493475 0.084 Uiso 1 1 calc R U . . .
C10S C 0.7148(2) 0.26847(18) 0.4356(3) 0.0658(9) Uani 1 1 d . . . . .
H10S H 0.723669 0.288805 0.495319 0.079 Uiso 1 1 calc R U . . .
C9S C 0.6853(2) 0.30120(15) 0.3485(3) 0.0573(8) Uani 1 1 d . . . . .
H9S H 0.673954 0.343733 0.349446 0.069 Uiso 1 1 calc R U . . .
C14S C 0.6424(3) 0.3073(2) 0.1676(3) 0.0817(12) Uani 1 1 d . . . . .
H14A H 0.696441 0.325751 0.157642 0.123 Uiso 1 1 calc R U . . .
H14B H 0.599150 0.339479 0.170055 0.123 Uiso 1 1 calc R U . . .
H14C H 0.612055 0.279521 0.113821 0.123 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn 0.0259 5.4591 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-1 11 6 0.1713
10 0 0 0.2824
9 -6 -4 0.2748
-2 9 -6 0.1007
1 7 7 0.1823
-2 -3 -8 0.1652
2 -12 4 0.2022
2 -6 7 0.1623
2 3 8 0.1604
-8 8 3 0.2559
-7 -5 -3 0.2074
-8 -7 0 0.2292
-7 7 7 0.2454
9 -4 -6 0.2502
-8 -8 3 0.2551
-5 6 8 0.2243
-5 -9 7 0.2355
-3 4 9 0.1900
3 -2 -9 0.1587
9 -2 -6 0.2363
8 8 0 0.3368
1 -1 -9 0.1136
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Sn1 O1 93.65(7) . . ?
O4 Sn1 O2 89.74(7) . . ?
O1 Sn1 O2 176.49(7) . . ?
O4 Sn1 O3 177.04(7) . . ?
O1 Sn1 O3 89.31(7) . . ?
O2 Sn1 O3 87.30(7) . . ?
O4 Sn1 N1 91.53(6) . . ?
O1 Sn1 N1 90.51(7) . . ?
O2 Sn1 N1 90.30(6) . . ?
O3 Sn1 N1 88.43(7) . . ?
O4 Sn1 N2 90.79(6) . . ?
O1 Sn1 N2 90.20(7) . . ?
O2 Sn1 N2 88.85(6) . . ?
O3 Sn1 N2 89.21(6) . . ?
N1 Sn1 N2 177.53(6) . . ?
C1 N1 C19 111.54(18) . . ?
C1 N1 C29 111.34(17) . . ?
C19 N1 C29 108.09(17) . . ?
C1 N1 Sn1 113.05(13) . . ?
C19 N1 Sn1 106.53(13) . . ?
C29 N1 Sn1 105.95(13) . . ?
C3 N2 C49 111.76(17) . . ?
C3 N2 C39 111.83(17) . . ?
C49 N2 C39 107.81(17) . . ?
C3 N2 Sn1 112.14(13) . . ?
C49 N2 Sn1 106.44(13) . . ?
C39 N2 Sn1 106.53(12) . . ?
C11 O1 Sn1 126.64(14) . . ?
C21 O2 Sn1 126.29(14) . . ?
C41 O3 Sn1 128.35(14) . . ?
C31 O4 Sn1 125.64(14) . . ?
N1 C1 C2 114.78(19) . . ?
N1 C1 H1A 108.6 . . ?
C2 C1 H1A 108.6 . . ?
N1 C1 H1B 108.6 . . ?
C2 C1 H1B 108.6 . . ?
H1A C1 H1B 107.5 . . ?
C1 C2 H2A 109.5 . . ?
C1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
C1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
N2 C3 C4 114.7(2) . . ?
N2 C3 H3A 108.6 . . ?
C4 C3 H3A 108.6 . . ?
N2 C3 H3B 108.6 . . ?
C4 C3 H3B 108.6 . . ?
H3A C3 H3B 107.6 . . ?
C3 C4 H4A 109.5 . . ?
C3 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C3 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
O1 C11 C16 122.0(2) . . ?
O1 C11 C12 118.3(2) . . ?
C16 C11 C12 119.7(2) . . ?
C13 C12 C11 119.1(2) . . ?
C13 C12 C17 121.7(2) . . ?
C11 C12 C17 119.2(2) . . ?
C12 C13 C14 122.2(2) . . ?
C12 C13 H13 118.9 . . ?
C14 C13 H13 118.9 . . ?
C15 C14 C13 117.8(2) . . ?
C15 C14 C18 121.2(3) . . ?
C13 C14 C18 121.0(2) . . ?
C14 C15 C16 121.8(2) . . ?
C14 C15 H15 119.1 . . ?
C16 C15 H15 119.1 . . ?
C15 C16 C11 119.3(2) . . ?
C15 C16 C19 120.7(2) . . ?
C11 C16 C19 120.0(2) . . ?
C12 C17 H17A 109.5 . . ?
C12 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C12 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C14 C18 H18A 109.5 . . ?
C14 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C14 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N1 C19 C16 113.57(19) . . ?
N1 C19 H19A 108.9 . . ?
C16 C19 H19A 108.9 . . ?
N1 C19 H19B 108.9 . . ?
C16 C19 H19B 108.9 . . ?
H19A C19 H19B 107.7 . . ?
O2 C21 C26 122.1(2) . . ?
O2 C21 C22 118.0(2) . . ?
C26 C21 C22 119.9(2) . . ?
C23 C22 C21 118.9(2) . . ?
C23 C22 C27 122.0(2) . . ?
C21 C22 C27 119.1(2) . . ?
C24 C23 C22 122.1(2) . . ?
C24 C23 H23 119.0 . . ?
C22 C23 H23 119.0 . . ?
C25 C24 C23 118.1(2) . . ?
C25 C24 C28 121.3(2) . . ?
C23 C24 C28 120.6(2) . . ?
C24 C25 C26 121.8(2) . . ?
C24 C25 H25 119.1 . . ?
C26 C25 H25 119.1 . . ?
C25 C26 C21 119.2(2) . . ?
C25 C26 C29 120.2(2) . . ?
C21 C26 C29 120.6(2) . . ?
C22 C27 H27A 109.5 . . ?
C22 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C22 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C24 C28 H28A 109.5 . . ?
C24 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C24 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C26 C29 N1 112.67(18) . . ?
C26 C29 H29A 109.1 . . ?
N1 C29 H29A 109.1 . . ?
C26 C29 H29B 109.1 . . ?
N1 C29 H29B 109.1 . . ?
H29A C29 H29B 107.8 . . ?
O3 C41 C46 123.0(2) . . ?
O3 C41 C42 117.4(2) . . ?
C46 C41 C42 119.5(2) . . ?
C43 C42 C41 119.0(2) . . ?
C43 C42 C47 121.8(2) . . ?
C41 C42 C47 119.2(2) . . ?
C42 C43 C44 122.4(2) . . ?
C42 C43 H43 118.8 . . ?
C44 C43 H43 118.8 . . ?
C45 C44 C43 117.9(2) . . ?
C45 C44 C48 121.2(3) . . ?
C43 C44 C48 120.9(2) . . ?
C44 C45 C46 121.5(2) . . ?
C44 C45 H45 119.3 . . ?
C46 C45 H45 119.3 . . ?
C45 C46 C41 119.7(2) . . ?
C45 C46 C49 119.9(2) . . ?
C41 C46 C49 120.3(2) . . ?
C42 C47 H47A 109.5 . . ?
C42 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C42 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C44 C48 H48A 109.5 . . ?
C44 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C44 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
N2 C49 C46 113.20(19) . . ?
N2 C49 H49A 108.9 . . ?
C46 C49 H49A 108.9 . . ?
N2 C49 H49B 108.9 . . ?
C46 C49 H49B 108.9 . . ?
H49A C49 H49B 107.8 . . ?
O4 C31 C36 121.9(2) . . ?
O4 C31 C32 117.8(2) . . ?
C36 C31 C32 120.3(2) . . ?
C33 C32 C31 118.5(2) . . ?
C33 C32 C37 122.2(2) . . ?
C31 C32 C37 119.3(2) . . ?
C34 C33 C32 122.5(2) . . ?
C34 C33 H33 118.7 . . ?
C32 C33 H33 118.7 . . ?
C33 C34 C35 117.7(2) . . ?
C33 C34 C38 121.4(2) . . ?
C35 C34 C38 120.9(2) . . ?
C34 C35 C36 121.5(2) . . ?
C34 C35 H35 119.2 . . ?
C36 C35 H35 119.2 . . ?
C31 C36 C35 119.4(2) . . ?
C31 C36 C39 120.3(2) . . ?
C35 C36 C39 120.2(2) . . ?
C32 C37 H37A 109.5 . . ?
C32 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C32 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C34 C38 H38A 109.5 . . ?
C34 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C34 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C36 C39 N2 113.54(18) . . ?
C36 C39 H39A 108.9 . . ?
N2 C39 H39A 108.9 . . ?
C36 C39 H39B 108.9 . . ?
N2 C39 H39B 108.9 . . ?
H39A C39 H39B 107.7 . . ?
C2S C1S C6S 117.8(3) . . ?
C2S C1S C7S 121.2(3) . . ?
C6S C1S C7S 120.9(4) . . ?
C1S C2S C3S 121.5(3) . . ?
C1S C2S H2S 119.3 . . ?
C3S C2S H2S 119.3 . . ?
C4S C3S C2S 119.9(3) . . ?
C4S C3S H3S 120.0 . . ?
C2S C3S H3S 120.0 . . ?
C3S C4S C5S 119.8(3) . . ?
C3S C4S H4S 120.1 . . ?
C5S C4S H4S 120.1 . . ?
C4S C5S C6S 119.9(3) . . ?
C4S C5S H5S 120.0 . . ?
C6S C5S H5S 120.0 . . ?
C5S C6S C1S 121.0(3) . . ?
C5S C6S H6S 119.5 . . ?
C1S C6S H6S 119.5 . . ?
C1S C7S H7SA 109.5 . . ?
C1S C7S H7SB 109.5 . . ?
H7SA C7S H7SB 109.5 . . ?
C1S C7S H7SC 109.5 . . ?
H7SA C7S H7SC 109.5 . . ?
H7SB C7S H7SC 109.5 . . ?
C9S C8S C13S 117.8(4) . . ?
C9S C8S C14S 121.3(3) . . ?
C13S C8S C14S 120.9(4) . . ?
C12S C13S C8S 121.0(4) . . ?
C12S C13S H13S 119.5 . . ?
C8S C13S H13S 119.5 . . ?
C13S C12S C11S 121.4(4) . . ?
C13S C12S H12S 119.3 . . ?
C11S C12S H12S 119.3 . . ?
C12S C11S C10S 119.0(4) . . ?
C12S C11S H11S 120.5 . . ?
C10S C11S H11S 120.5 . . ?
C11S C10S C9S 119.9(4) . . ?
C11S C10S H10S 120.1 . . ?
C9S C10S H10S 120.1 . . ?
C8S C9S C10S 120.9(3) . . ?
C8S C9S H9S 119.6 . . ?
C10S C9S H9S 119.6 . . ?
C8S C14S H14A 109.5 . . ?
C8S C14S H14B 109.5 . . ?
H14A C14S H14B 109.5 . . ?
C8S C14S H14C 109.5 . . ?
H14A C14S H14C 109.5 . . ?
H14B C14S H14C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sn1 O4 2.0126(16) . ?
Sn1 O1 2.0157(16) . ?
Sn1 O2 2.0269(16) . ?
Sn1 O3 2.0306(16) . ?
Sn1 N1 2.2359(18) . ?
Sn1 N2 2.2407(18) . ?
N1 C1 1.501(3) . ?
N1 C19 1.505(3) . ?
N1 C29 1.509(3) . ?
N2 C3 1.501(3) . ?
N2 C49 1.504(3) . ?
N2 C39 1.506(3) . ?
O1 C11 1.347(3) . ?
O2 C21 1.347(3) . ?
O3 C41 1.340(3) . ?
O4 C31 1.352(3) . ?
C1 C2 1.521(3) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 C4 1.519(3) . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C11 C16 1.402(3) . ?
C11 C12 1.405(3) . ?
C12 C13 1.382(4) . ?
C12 C17 1.510(4) . ?
C13 C14 1.396(4) . ?
C13 H13 0.9500 . ?
C14 C15 1.387(4) . ?
C14 C18 1.509(4) . ?
C15 C16 1.393(4) . ?
C15 H15 0.9500 . ?
C16 C19 1.508(3) . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C21 C26 1.401(3) . ?
C21 C22 1.405(3) . ?
C22 C23 1.390(3) . ?
C22 C27 1.498(3) . ?
C23 C24 1.389(3) . ?
C23 H23 0.9500 . ?
C24 C25 1.386(3) . ?
C24 C28 1.509(3) . ?
C25 C26 1.393(3) . ?
C25 H25 0.9500 . ?
C26 C29 1.506(3) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C41 C46 1.400(3) . ?
C41 C42 1.405(3) . ?
C42 C43 1.388(4) . ?
C42 C47 1.500(4) . ?
C43 C44 1.392(4) . ?
C43 H43 0.9500 . ?
C44 C45 1.387(4) . ?
C44 C48 1.503(3) . ?
C45 C46 1.397(3) . ?
C45 H45 0.9500 . ?
C46 C49 1.510(3) . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C49 H49A 0.9900 . ?
C49 H49B 0.9900 . ?
C31 C36 1.392(3) . ?
C31 C32 1.399(3) . ?
C32 C33 1.395(3) . ?
C32 C37 1.504(3) . ?
C33 C34 1.389(4) . ?
C33 H33 0.9500 . ?
C34 C35 1.390(3) . ?
C34 C38 1.509(3) . ?
C35 C36 1.400(3) . ?
C35 H35 0.9500 . ?
C36 C39 1.502(3) . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C1S C2S 1.376(5) . ?
C1S C6S 1.386(5) . ?
C1S C7S 1.494(5) . ?
C2S C3S 1.376(5) . ?
C2S H2S 0.9500 . ?
C3S C4S 1.369(5) . ?
C3S H3S 0.9500 . ?
C4S C5S 1.374(5) . ?
C4S H4S 0.9500 . ?
C5S C6S 1.378(5) . ?
C5S H5S 0.9500 . ?
C6S H6S 0.9500 . ?
C7S H7SA 0.9800 . ?
C7S H7SB 0.9800 . ?
C7S H7SC 0.9800 . ?
C8S C9S 1.379(5) . ?
C8S C13S 1.394(5) . ?
C8S C14S 1.500(6) . ?
C13S C12S 1.364(6) . ?
C13S H13S 0.9500 . ?
C12S C11S 1.368(6) . ?
C12S H12S 0.9500 . ?
C11S C10S 1.380(6) . ?
C11S H11S 0.9500 . ?
C10S C9S 1.400(5) . ?
C10S H10S 0.9500 . ?
C9S H9S 0.9500 . ?
C14S H14A 0.9800 . ?
C14S H14B 0.9800 . ?
C14S H14C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C19 N1 C1 C2 61.0(2) . . . . ?
C29 N1 C1 C2 -59.9(3) . . . . ?
Sn1 N1 C1 C2 -178.99(17) . . . . ?
C49 N2 C3 C4 -60.1(3) . . . . ?
C39 N2 C3 C4 60.9(2) . . . . ?
Sn1 N2 C3 C4 -179.54(17) . . . . ?
Sn1 O1 C11 C16 -36.7(3) . . . . ?
Sn1 O1 C11 C12 145.74(19) . . . . ?
O1 C11 C12 C13 178.2(2) . . . . ?
C16 C11 C12 C13 0.6(4) . . . . ?
O1 C11 C12 C17 -1.6(4) . . . . ?
C16 C11 C12 C17 -179.2(3) . . . . ?
C11 C12 C13 C14 0.7(4) . . . . ?
C17 C12 C13 C14 -179.5(3) . . . . ?
C12 C13 C14 C15 -0.9(4) . . . . ?
C12 C13 C14 C18 178.8(3) . . . . ?
C13 C14 C15 C16 -0.2(4) . . . . ?
C18 C14 C15 C16 -179.8(3) . . . . ?
C14 C15 C16 C11 1.5(4) . . . . ?
C14 C15 C16 C19 -175.8(2) . . . . ?
O1 C11 C16 C15 -179.1(2) . . . . ?
C12 C11 C16 C15 -1.6(4) . . . . ?
O1 C11 C16 C19 -1.8(4) . . . . ?
C12 C11 C16 C19 175.7(2) . . . . ?
C1 N1 C19 C16 56.2(2) . . . . ?
C29 N1 C19 C16 178.88(19) . . . . ?
Sn1 N1 C19 C16 -67.6(2) . . . . ?
C15 C16 C19 N1 -121.4(3) . . . . ?
C11 C16 C19 N1 61.3(3) . . . . ?
Sn1 O2 C21 C26 36.3(3) . . . . ?
Sn1 O2 C21 C22 -145.81(16) . . . . ?
O2 C21 C22 C23 -177.43(19) . . . . ?
C26 C21 C22 C23 0.5(3) . . . . ?
O2 C21 C22 C27 1.6(3) . . . . ?
C26 C21 C22 C27 179.5(2) . . . . ?
C21 C22 C23 C24 -1.0(3) . . . . ?
C27 C22 C23 C24 180.0(2) . . . . ?
C22 C23 C24 C25 0.8(3) . . . . ?
C22 C23 C24 C28 -177.7(2) . . . . ?
C23 C24 C25 C26 0.1(3) . . . . ?
C28 C24 C25 C26 178.5(2) . . . . ?
C24 C25 C26 C21 -0.6(3) . . . . ?
C24 C25 C26 C29 178.3(2) . . . . ?
O2 C21 C26 C25 178.1(2) . . . . ?
C22 C21 C26 C25 0.3(3) . . . . ?
O2 C21 C26 C29 -0.8(3) . . . . ?
C22 C21 C26 C29 -178.6(2) . . . . ?
C25 C26 C29 N1 121.3(2) . . . . ?
C21 C26 C29 N1 -59.8(3) . . . . ?
C1 N1 C29 C26 -53.7(2) . . . . ?
C19 N1 C29 C26 -176.49(18) . . . . ?
Sn1 N1 C29 C26 69.64(19) . . . . ?
Sn1 O3 C41 C46 30.1(3) . . . . ?
Sn1 O3 C41 C42 -151.95(17) . . . . ?
O3 C41 C42 C43 -177.5(2) . . . . ?
C46 C41 C42 C43 0.5(3) . . . . ?
O3 C41 C42 C47 2.1(3) . . . . ?
C46 C41 C42 C47 -179.9(2) . . . . ?
C41 C42 C43 C44 -0.8(4) . . . . ?
C47 C42 C43 C44 179.6(2) . . . . ?
C42 C43 C44 C45 0.2(4) . . . . ?
C42 C43 C44 C48 179.6(2) . . . . ?
C43 C44 C45 C46 0.8(4) . . . . ?
C48 C44 C45 C46 -178.6(2) . . . . ?
C44 C45 C46 C41 -1.1(3) . . . . ?
C44 C45 C46 C49 176.3(2) . . . . ?
O3 C41 C46 C45 178.4(2) . . . . ?
C42 C41 C46 C45 0.5(3) . . . . ?
O3 C41 C46 C49 1.0(3) . . . . ?
C42 C41 C46 C49 -176.9(2) . . . . ?
C3 N2 C49 C46 -52.6(2) . . . . ?
C39 N2 C49 C46 -175.93(18) . . . . ?
Sn1 N2 C49 C46 70.1(2) . . . . ?
C45 C46 C49 N2 124.5(2) . . . . ?
C41 C46 C49 N2 -58.2(3) . . . . ?
Sn1 O4 C31 C36 -38.7(3) . . . . ?
Sn1 O4 C31 C32 144.36(18) . . . . ?
O4 C31 C32 C33 176.9(2) . . . . ?
C36 C31 C32 C33 -0.1(4) . . . . ?
O4 C31 C32 C37 -2.3(4) . . . . ?
C36 C31 C32 C37 -179.3(2) . . . . ?
C31 C32 C33 C34 1.7(4) . . . . ?
C37 C32 C33 C34 -179.1(3) . . . . ?
C32 C33 C34 C35 -1.5(4) . . . . ?
C32 C33 C34 C38 178.4(3) . . . . ?
C33 C34 C35 C36 -0.3(4) . . . . ?
C38 C34 C35 C36 179.8(3) . . . . ?
O4 C31 C36 C35 -178.5(2) . . . . ?
C32 C31 C36 C35 -1.6(4) . . . . ?
O4 C31 C36 C39 -2.2(4) . . . . ?
C32 C31 C36 C39 174.7(2) . . . . ?
C34 C35 C36 C31 1.9(4) . . . . ?
C34 C35 C36 C39 -174.4(2) . . . . ?
C31 C36 C39 N2 62.4(3) . . . . ?
C35 C36 C39 N2 -121.3(2) . . . . ?
C3 N2 C39 C36 56.4(2) . . . . ?
C49 N2 C39 C36 179.62(18) . . . . ?
Sn1 N2 C39 C36 -66.47(19) . . . . ?
C6S C1S C2S C3S -0.5(5) . . . . ?
C7S C1S C2S C3S 179.4(3) . . . . ?
C1S C2S C3S C4S -0.2(5) . . . . ?
C2S C3S C4S C5S 0.5(5) . . . . ?
C3S C4S C5S C6S -0.2(5) . . . . ?
C4S C5S C6S C1S -0.4(5) . . . . ?
C2S C1S C6S C5S 0.8(5) . . . . ?
C7S C1S C6S C5S -179.1(3) . . . . ?
C9S C8S C13S C12S 0.6(5) . . . . ?
C14S C8S C13S C12S 179.5(4) . . . . ?
C8S C13S C12S C11S -0.7(6) . . . . ?
C13S C12S C11S C10S 0.2(6) . . . . ?
C12S C11S C10S C9S 0.3(5) . . . . ?
C13S C8S C9S C10S -0.1(5) . . . . ?
C14S C8S C9S C10S -179.0(3) . . . . ?
C11S C10S C9S C8S -0.3(5) . . . . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-0.7246 11.2260 5.7060 0.0347 0.1493 0.9882
9.5446 0.2439 -0.4381 -0.2240 -0.9342 0.2777
9.0331 -6.0377 -3.5771 -0.2218 -0.9278 -0.2998
-1.9009 8.8041 -6.2060 0.9828 0.1828 -0.0261
1.4372 6.6954 7.3278 -0.3699 -0.0699 0.9265
-1.7880 -2.8716 -8.0390 0.6127 0.1149 -0.7819
1.6203 -11.5617 4.4890 -0.9511 -0.1766 -0.2533
2.0154 -6.1857 7.2015 -0.9540 -0.1777 0.2415
1.7607 3.2483 7.9994 -0.5916 -0.1110 0.7986
-8.1395 8.1750 3.4827 0.3004 0.8484 0.4360
-7.4822 -4.5740 -2.7588 0.2453 0.6964 -0.6745
-8.4048 -6.5085 0.1355 -0.0639 0.7964 -0.6014
-6.9368 7.2946 6.8001 -0.0585 0.7474 0.6618
9.1102 -3.7194 -5.8361 0.0742 -0.9399 -0.3333
-8.1744 -8.0951 3.4795 -0.4290 0.7879 -0.4418
-4.9844 6.0859 8.3801 -0.3042 0.5615 0.7695
-5.2091 -9.1735 6.7069 -0.8394 0.5134 -0.1785
-2.5154 4.2416 9.0654 -0.5165 0.3171 0.7954
3.2290 -2.1435 -9.4188 0.6207 -0.3808 -0.6854
9.1738 -2.2469 -6.2693 0.1757 -0.9430 -0.2828
7.8523 7.8808 -0.0769 0.1363 -0.7367 0.6623
1.0882 -1.3176 -9.2160 0.7015 -0.1671 -0.6928
