#------------------------------------------------------------------------------
#$Date: 2025-11-29 22:02:34 +0100 (Sat 29 de Nov de 2025) $
#$Revision: 303813 $
#$URL: svn://www.crystallography.net/cod/cif/7/71/93/7719378.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7719378
loop_
_publ_author_name
'Chlebík, Richard'
'Kertész, Erik'
'Erben, Milan'
'Růžička, Aleš'
'Jambor, Roman'
'Benkő, Zoltán'
'Dostál, Libor'
_publ_section_title
;
 Remarkable coordination variability of the P,C,P-pincer ligand in
 organotin(IV) compounds - a promising outlook for other p-block elements.
;
_journal_issue                   40
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15093
_journal_page_last               15106
_journal_paper_doi               10.1039/d5dt01873k
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety
'C68 H132 Ag2 O4 P4 Sn2, 2(C F3 O3 S), 2(C H2 Cl2)'
_chemical_formula_sum            'C72 H136 Ag2 Cl4 F6 O10 P4 S2 Sn2'
_chemical_formula_weight         2058.72
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           'APEX4 v2022.10-0'
_audit_update_record
;
2025-07-02 deposited with the CCDC.	2025-09-05 downloaded from the CCDC.
;
_cell_angle_alpha                99.0350(10)
_cell_angle_beta                 100.6990(10)
_cell_angle_gamma                116.6860(10)
_cell_formula_units_Z            1
_cell_length_a                   13.2916(5)
_cell_length_b                   13.6331(5)
_cell_length_c                   15.1787(6)
_cell_measurement_reflns_used    96922
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      28
_cell_measurement_theta_min      1
_cell_volume                     2322.47(16)
_computing_cell_refinement       'APEX4 v2022.10-0 (Bruker AXS)'
_computing_data_collection       'Bruker Instrument Service vV6.2.3'
_computing_data_reduction        'SAINT V8.37A (Bruker AXS Inc., 2015)'
_computing_molecular_graphics    'Platon (Spek, 2009)'
_computing_publication_material  'Platon (Spek, 2009)'
_computing_structure_refinement  'SHELXL-2019/1 (Sheldrick, 2019)'
_computing_structure_solution    'XT, VERSION 2014/5'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 10.4167
_diffrn_measured_fraction_theta_full 0.965
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Bruker D8 - Venture'
_diffrn_measurement_method       'φ and ω scans to fill the Ewald sphere'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0306
_diffrn_reflns_av_unetI/netI     0.0191
_diffrn_reflns_Laue_measured_fraction_full 0.965
_diffrn_reflns_Laue_measured_fraction_max 0.974
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            96816
_diffrn_reflns_point_group_measured_fraction_full 0.965
_diffrn_reflns_point_group_measured_fraction_max 0.974
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.289
_diffrn_reflns_theta_min         2.590
_diffrn_source                   'sealed X-ray tube'
_exptl_absorpt_coefficient_mu    1.236
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6115
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 - Bruker AXS area detector
scaling and absorption correction
Reference: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D.,
 J. Appl. Cryst. 48 (2015) 3-10.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.472
_exptl_crystal_description       block
_exptl_crystal_F_000             1056
_exptl_crystal_size_max          0.391
_exptl_crystal_size_mid          0.342
_exptl_crystal_size_min          0.262
_refine_diff_density_max         0.761
_refine_diff_density_min         -0.581
_refine_diff_density_rms         0.052
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.089
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     507
_refine_ls_number_reflns         11252
_refine_ls_number_restraints     367
_refine_ls_restrained_S_all      1.083
_refine_ls_R_factor_all          0.0212
_refine_ls_R_factor_gt           0.0198
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0092P)²+1.5979P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0459
_refine_ls_wR_factor_ref         0.0473
_reflns_Friedel_coverage         0.000
_reflns_number_gt                10705
_reflns_number_total             11252
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5dt01873k2.cif
_cod_data_source_block           4AgOTf
_cod_depositor_comments
'Adding full bibliography for 7719373--7719382.cif.'
_cod_original_cell_volume        2322.47(15)
_cod_database_code               7719378
_shelx_shelxl_version_number     2019/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_exptl_absorpt_special_details
;
The ratio of minimum to maximum
apparent transmission was 0.820
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn 0.77355(2) 1.13647(2) 0.35858(2) 0.01693(3) Uani 1 1 d . . . . .
Ag1 Ag 0.34730(2) 0.73368(2) 0.00995(2) 0.01863(3) Uani 1 1 d . . . . .
Cl1 Cl 0.11082(4) -0.17305(5) 0.13324(3) 0.04495(10) Uani 1 1 d . . . . .
F1 F 0.3053(19) 0.3606(15) 0.2919(14) 0.058(3) Uani 0.38(3) 1 d . . P A 1
F2 F 0.1970(18) 0.1913(11) 0.2630(8) 0.079(3) Uani 0.38(3) 1 d . . P A 1
F3 F 0.3769(19) 0.2394(18) 0.2692(9) 0.076(3) Uani 0.38(3) 1 d . . P A 1
Cl2 Cl -0.03239(10) -0.08800(19) 0.19028(13) 0.0751(6) Uani 0.726(4) 1 d . . P B
1
F1A F 0.3393(12) 0.3692(10) 0.2930(9) 0.0638(19) Uani 0.62(3) 1 d . . P A 2
F2A F 0.3300(14) 0.2081(10) 0.2681(6) 0.080(2) Uani 0.62(3) 1 d . . P A 2
F3A F 0.1648(9) 0.2052(7) 0.2465(9) 0.087(2) Uani 0.62(3) 1 d . . P A 2
Cl2A Cl -0.0196(3) -0.0425(4) 0.1669(4) 0.0751(6) Uani 0.274(4) 1 d . . P B 2
S1 S 0.26316(3) 0.25676(3) 0.11665(3) 0.02872(8) Uani 1 1 d . . . . .
P1 P 0.46369(3) 0.77105(3) 0.16543(2) 0.01526(6) Uani 1 1 d . . . . .
P2 P 0.78662(3) 1.35112(3) 0.14479(2) 0.01484(6) Uani 1 1 d . . . . .
O2 O 0.73888(8) 1.28608(7) 0.22275(6) 0.01646(17) Uani 1 1 d . . . . .
O3 O 0.38069(12) 0.32909(13) 0.11635(10) 0.0472(3) Uani 1 1 d . . . . .
O4 O 0.18356(12) 0.30006(12) 0.09619(11) 0.0499(4) Uani 1 1 d . . . . .
O5 O 0.21517(13) 0.13764(11) 0.07112(10) 0.0427(3) Uani 1 1 d . . . . .
C1 C 0.63350(10) 1.09665(10) 0.23506(8) 0.0148(2) Uani 1 1 d . . . . .
C2 C 0.52831(11) 0.99273(10) 0.20275(8) 0.0148(2) Uani 1 1 d . . . . .
C13 C 0.32623(16) 0.56241(13) 0.19262(14) 0.0379(4) Uani 1 1 d . . . . .
H13A H 0.267081 0.518314 0.221626 0.057 Uiso 1 1 calc R U . . .
H13B H 0.389502 0.543256 0.202297 0.057 Uiso 1 1 calc R U . . .
H13C H 0.289494 0.543932 0.125638 0.057 Uiso 1 1 calc R U . . .
C14 C 0.44494(16) 0.72519(17) 0.33955(12) 0.0405(4) Uani 1 1 d . . . . .
H14A H 0.391192 0.685757 0.374250 0.061 Uiso 1 1 calc R U . . .
H14B H 0.479800 0.807869 0.364518 0.061 Uiso 1 1 calc R U . . .
H14C H 0.507454 0.704948 0.345884 0.061 Uiso 1 1 calc R U . . .
C15 C 0.92134(11) 1.34035(11) 0.14797(9) 0.0191(2) Uani 1 1 d . . . . .
C16 C 0.87495(13) 1.21182(12) 0.10780(10) 0.0238(3) Uani 1 1 d . . . . .
H16A H 0.941277 1.198695 0.105762 0.036 Uiso 1 1 calc R U . . .
H16B H 0.821813 1.185622 0.044622 0.036 Uiso 1 1 calc R U . . .
H16C H 0.832258 1.169450 0.147492 0.036 Uiso 1 1 calc R U . . .
C17 C 1.00779(12) 1.38118(13) 0.24539(10) 0.0257(3) Uani 1 1 d . . . . .
H17A H 1.067381 1.358146 0.242386 0.039 Uiso 1 1 calc R U . . .
H17B H 0.964962 1.346953 0.288294 0.039 Uiso 1 1 calc R U . . .
H17C H 1.046255 1.464531 0.267730 0.039 Uiso 1 1 calc R U . . .
C18 C 0.98308(13) 1.40584(14) 0.08311(11) 0.0272(3) Uani 1 1 d . . . . .
H18A H 1.045055 1.388290 0.074453 0.041 Uiso 1 1 calc R U . . .
H18B H 1.017978 1.488016 0.110891 0.041 Uiso 1 1 calc R U . . .
H18C H 0.925601 1.383002 0.022589 0.041 Uiso 1 1 calc R U . . .
C19 C 0.81250(12) 1.49714(11) 0.19309(10) 0.0224(3) Uani 1 1 d . . . . .
C20 C 0.91405(16) 1.56663(15) 0.28276(13) 0.0408(4) Uani 1 1 d . . . . .
H20A H 0.914281 1.637361 0.308401 0.061 Uiso 1 1 calc R U . . .
H20B H 0.988744 1.585154 0.269077 0.061 Uiso 1 1 calc R U . . .
H20C H 0.904231 1.521924 0.328287 0.061 Uiso 1 1 calc R U . . .
C21 C 0.83295(18) 1.56090(14) 0.11739(14) 0.0393(4) Uani 1 1 d . . . . .
H21A H 0.840593 1.636041 0.139939 0.059 Uiso 1 1 calc R U . . .
H21B H 0.766093 1.516816 0.060965 0.059 Uiso 1 1 calc R U . . .
H21C H 0.905182 1.570447 0.103044 0.059 Uiso 1 1 calc R U . . .
C22 C 0.69741(14) 1.48123(13) 0.21225(12) 0.0301(3) Uani 1 1 d . . . . .
H22A H 0.704090 1.556100 0.233935 0.045 Uiso 1 1 calc R U . . .
H22B H 0.682522 1.440462 0.260232 0.045 Uiso 1 1 calc R U . . .
H22C H 0.632178 1.436966 0.154795 0.045 Uiso 1 1 calc R U . . .
C23 C 0.70016(13) 1.02700(12) 0.44446(9) 0.0237(3) Uani 1 1 d . . . . .
H23A H 0.617046 1.007926 0.435026 0.028 Uiso 1 1 calc R U . . .
H23B H 0.700936 0.954875 0.423507 0.028 Uiso 1 1 calc R U . . .
C24 C 0.76515(16) 1.07902(17) 0.54837(11) 0.0376(4) Uani 1 1 d . . . . .
H24A H 0.754857 1.144993 0.571508 0.045 Uiso 1 1 calc R U . . .
H24B H 0.850261 1.107780 0.557237 0.045 Uiso 1 1 calc R U . . .
C25 C 0.72235(17) 0.99445(19) 0.60647(12) 0.0414(4) Uani 1 1 d . . . . .
H25A H 0.732184 0.928325 0.582847 0.050 Uiso 1 1 calc R U . . .
H25B H 0.772735 1.031852 0.671813 0.050 Uiso 1 1 calc R U . . .
C26 C 0.59620(17) 0.95165(17) 0.60513(13) 0.0403(4) Uani 1 1 d . . . . .
H26A H 0.577581 0.904558 0.648624 0.061 Uiso 1 1 calc R U . . .
H26B H 0.544733 0.905795 0.542041 0.061 Uiso 1 1 calc R U . . .
H26C H 0.583992 1.016690 0.623848 0.061 Uiso 1 1 calc R U . . .
C27 C 0.90779(12) 1.10466(13) 0.32212(10) 0.0250(3) Uani 1 1 d . . . . .
H27A H 0.869170 1.028509 0.276830 0.030 Uiso 1 1 calc R U . . .
H27B H 0.950927 1.161957 0.290820 0.030 Uiso 1 1 calc R U . . .
C28 C 0.99616(14) 1.10886(14) 0.40466(11) 0.0285(3) Uani 1 1 d . . . . .
H28A H 0.952921 1.058818 0.440849 0.034 Uiso 1 1 calc R U . . .
H28B H 1.044168 1.078630 0.381047 0.034 Uiso 1 1 calc R U . . .
C29 C 1.07742(15) 1.22872(16) 0.46886(12) 0.0363(4) Uani 1 1 d . . . . .
H29A H 1.118720 1.279284 0.432202 0.044 Uiso 1 1 calc R U . . .
H29B H 1.029552 1.257969 0.494020 0.044 Uiso 1 1 calc R U . . .
C30 C 1.1680(2) 1.2338(2) 0.54949(15) 0.0579(6) Uani 1 1 d . . . . .
H30A H 1.217834 1.312693 0.588409 0.087 Uiso 1 1 calc R U . . .
H30B H 1.216978 1.206557 0.525128 0.087 Uiso 1 1 calc R U . . .
H30C H 1.127793 1.185293 0.586991 0.087 Uiso 1 1 calc R U . . .
C31 C 0.82502(13) 1.30670(12) 0.43774(10) 0.0246(3) Uani 1 1 d . . . . .
H31A H 0.870276 1.320988 0.502462 0.030 Uiso 1 1 calc R U . . .
H31B H 0.877091 1.363164 0.410010 0.030 Uiso 1 1 calc R U . . .
C32 C 0.71928(14) 1.32333(13) 0.43951(10) 0.0270(3) Uani 1 1 d . . . . .
H32A H 0.674436 1.308611 0.374544 0.032 Uiso 1 1 calc R U . . .
H32B H 0.667171 1.265831 0.466476 0.032 Uiso 1 1 calc R U . . .
C33 C 0.74993(18) 1.44139(15) 0.49466(13) 0.0412(4) Uani 1 1 d . . . . .
H33A H 0.784567 1.452178 0.561439 0.049 Uiso 1 1 calc R U . . .
H33B H 0.810218 1.499710 0.473547 0.049 Uiso 1 1 calc R U . . .
C34 C 0.6445(2) 1.46011(19) 0.48424(16) 0.0508(5) Uani 1 1 d . . . . .
H34A H 0.668140 1.534603 0.525269 0.076 Uiso 1 1 calc R U . . .
H34B H 0.582450 1.399861 0.501314 0.076 Uiso 1 1 calc R U . . .
H34C H 0.615009 1.457948 0.419410 0.076 Uiso 1 1 calc R U . . .
C35 C 0.2792(2) 0.2607(2) 0.23880(16) 0.0536(5) Uani 1 1 d . . . . .
C36 C 0.03032(17) -0.10625(18) 0.09718(17) 0.0491(5) Uani 1 1 d . . . . .
H36A H -0.032353 -0.154581 0.037902 0.059 Uiso 1 1 calc R U . B 1
H36B H 0.082472 -0.031512 0.088316 0.059 Uiso 1 1 calc R U . B 1
O1 O 0.52782(8) 0.90121(7) 0.23427(6) 0.01690(17) Uani 1 1 d . . . . .
C3 C 0.42541(11) 0.97813(11) 0.14518(9) 0.0176(2) Uani 1 1 d . . . . .
H3 H 0.355277 0.906312 0.126148 0.021 Uiso 1 1 calc R U . . .
C4 C 0.42658(11) 1.07003(11) 0.11589(9) 0.0194(2) Uani 1 1 d . . . . .
H4 H 0.356078 1.062348 0.078893 0.023 Uiso 1 1 calc R U . . .
C5 C 0.63176(10) 1.18306(10) 0.19749(8) 0.0150(2) Uani 1 1 d . . . . .
C6 C 0.53085(11) 1.17323(11) 0.14068(9) 0.0181(2) Uani 1 1 d . . . . .
H6 H 0.533141 1.235824 0.119248 0.022 Uiso 1 1 calc R U . . .
C7 C 0.58948(12) 0.75082(11) 0.15370(9) 0.0204(2) Uani 1 1 d . . . . .
C8 C 0.65620(13) 0.84361(13) 0.10801(11) 0.0264(3) Uani 1 1 d . . . . .
H8A H 0.722882 0.836701 0.095686 0.040 Uiso 1 1 calc R U . . .
H8B H 0.685160 0.919080 0.150012 0.040 Uiso 1 1 calc R U . . .
H8C H 0.603078 0.834192 0.049197 0.040 Uiso 1 1 calc R U . . .
C9 C 0.54413(14) 0.63323(13) 0.08620(11) 0.0292(3) Uani 1 1 d . . . . .
H9A H 0.610423 0.628505 0.070597 0.044 Uiso 1 1 calc R U . . .
H9B H 0.487642 0.623125 0.029169 0.044 Uiso 1 1 calc R U . . .
H9C H 0.505452 0.573215 0.115868 0.044 Uiso 1 1 calc R U . . .
C10 C 0.67104(14) 0.76512(14) 0.24587(10) 0.0287(3) Uani 1 1 d . . . . .
H10A H 0.742511 0.767347 0.235390 0.043 Uiso 1 1 calc R U . . .
H10B H 0.630781 0.700709 0.270920 0.043 Uiso 1 1 calc R U . . .
H10C H 0.692162 0.836478 0.290438 0.043 Uiso 1 1 calc R U . . .
C11 C 0.37687(12) 0.68928(12) 0.23657(10) 0.0232(3) Uani 1 1 d . . . . .
C12 C 0.27461(14) 0.71478(14) 0.22973(13) 0.0326(3) Uani 1 1 d . . . . .
H12A H 0.225344 0.674830 0.267046 0.049 Uiso 1 1 calc R U . . .
H12B H 0.227203 0.688623 0.164494 0.049 Uiso 1 1 calc R U . . .
H12C H 0.306074 0.797155 0.253304 0.049 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C23 Sn1 C27 107.25(6) . . ?
C23 Sn1 C31 105.27(5) . . ?
C27 Sn1 C31 118.35(6) . . ?
C23 Sn1 C1 108.87(5) . . ?
C27 Sn1 C1 111.45(5) . . ?
C31 Sn1 C1 105.23(5) . . ?
P2 Ag1 P1 166.054(11) 2_675 . ?
O3 S1 O4 115.37(10) . . ?
O3 S1 O5 114.97(9) . . ?
O4 S1 O5 114.55(8) . . ?
O3 S1 C35 102.93(11) . . ?
O4 S1 C35 103.16(10) . . ?
O5 S1 C35 103.45(9) . . ?
O1 P1 C7 102.93(6) . . ?
O1 P1 C11 100.46(6) . . ?
C7 P1 C11 115.60(6) . . ?
O1 P1 Ag1 117.88(3) . . ?
C7 P1 Ag1 106.62(4) . . ?
C11 P1 Ag1 113.24(5) . . ?
O2 P2 C15 101.98(5) . . ?
O2 P2 C19 102.67(6) . . ?
C15 P2 C19 115.16(6) . . ?
O2 P2 Ag1 114.93(3) . 2_675 ?
C15 P2 Ag1 110.61(4) . 2_675 ?
C19 P2 Ag1 111.10(5) . 2_675 ?
C5 O2 P2 121.42(8) . . ?
C5 C1 C2 114.85(11) . . ?
C5 C1 Sn1 120.55(9) . . ?
C2 C1 Sn1 122.84(9) . . ?
C3 C2 C1 123.33(11) . . ?
C3 C2 O1 119.64(11) . . ?
C1 C2 O1 116.98(10) . . ?
C17 C15 C18 110.33(11) . . ?
C17 C15 C16 108.94(11) . . ?
C18 C15 C16 109.31(11) . . ?
C17 C15 P2 115.03(10) . . ?
C18 C15 P2 108.80(9) . . ?
C16 C15 P2 104.17(9) . . ?
C20 C19 C22 109.29(13) . . ?
C20 C19 C21 110.19(14) . . ?
C22 C19 C21 108.11(13) . . ?
C20 C19 P2 114.77(11) . . ?
C22 C19 P2 105.86(9) . . ?
C21 C19 P2 108.35(10) . . ?
C24 C23 Sn1 114.12(10) . . ?
C23 C24 C25 113.24(15) . . ?
C26 C25 C24 114.13(16) . . ?
C28 C27 Sn1 114.34(10) . . ?
C29 C28 C27 112.84(13) . . ?
C30 C29 C28 112.97(16) . . ?
C32 C31 Sn1 112.23(9) . . ?
C33 C32 C31 114.67(14) . . ?
C34 C33 C32 113.18(17) . . ?
F2 C35 F1 103.1(9) . . ?
F2A C35 F1A 108.0(7) . . ?
F2A C35 F3A 107.0(4) . . ?
F1A C35 F3A 110.9(7) . . ?
F2 C35 F3 105.1(6) . . ?
F1 C35 F3 108.3(10) . . ?
F2 C35 S1 120.5(6) . . ?
F2A C35 S1 114.2(4) . . ?
F1 C35 S1 113.3(9) . . ?
F1A C35 S1 110.8(6) . . ?
F3A C35 S1 106.0(6) . . ?
F3 C35 S1 105.9(7) . . ?
Cl2A C36 Cl1 124.7(3) . . ?
Cl1 C36 Cl2 104.98(15) . . ?
C2 O1 P1 122.57(8) . . ?
C4 C3 C2 119.04(11) . . ?
C3 C4 C6 120.01(12) . . ?
C6 C5 C1 123.67(11) . . ?
C6 C5 O2 119.91(11) . . ?
C1 C5 O2 116.38(10) . . ?
C4 C6 C5 118.68(11) . . ?
C10 C7 C8 110.01(12) . . ?
C10 C7 C9 110.41(12) . . ?
C8 C7 C9 108.50(12) . . ?
C10 C7 P1 114.40(10) . . ?
C8 C7 P1 103.58(9) . . ?
C9 C7 P1 109.61(10) . . ?
C13 C11 C14 111.81(14) . . ?
C13 C11 C12 108.48(13) . . ?
C14 C11 C12 108.09(14) . . ?
C13 C11 P1 109.06(11) . . ?
C14 C11 P1 113.95(10) . . ?
C12 C11 P1 105.11(10) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sn1 C23 2.1574(14) . ?
Sn1 C27 2.1597(14) . ?
Sn1 C31 2.1657(14) . ?
Sn1 C1 2.1799(12) . ?
Ag1 P2 2.4017(3) 2_675 ?
Ag1 P1 2.4044(3) . ?
Cl1 C36 1.757(2) . ?
F1 C35 1.324(16) . ?
F2 C35 1.246(13) . ?
F3 C35 1.464(12) . ?
Cl2 C36 1.807(3) . ?
F1A C35 1.347(11) . ?
F2A C35 1.262(9) . ?
F3A C35 1.399(7) . ?
Cl2A C36 1.675(4) . ?
S1 O3 1.4259(13) . ?
S1 O4 1.4356(13) . ?
S1 O5 1.4406(13) . ?
S1 C35 1.816(2) . ?
P1 O1 1.6418(9) . ?
P1 C7 1.8474(14) . ?
P1 C11 1.8509(14) . ?
P2 O2 1.6407(9) . ?
P2 C15 1.8539(13) . ?
P2 C19 1.8578(14) . ?
O2 C5 1.4067(14) . ?
C1 C5 1.3942(17) . ?
C1 C2 1.3966(17) . ?
C2 C3 1.3895(17) . ?
C2 O1 1.4025(14) . ?
C13 C11 1.522(2) . ?
C14 C11 1.529(2) . ?
C15 C17 1.5339(18) . ?
C15 C18 1.5354(19) . ?
C15 C16 1.5416(19) . ?
C19 C20 1.528(2) . ?
C19 C22 1.536(2) . ?
C19 C21 1.539(2) . ?
C23 C24 1.526(2) . ?
C24 C25 1.532(2) . ?
C25 C26 1.502(3) . ?
C27 C28 1.5242(19) . ?
C28 C29 1.520(2) . ?
C29 C30 1.518(2) . ?
C31 C32 1.525(2) . ?
C32 C33 1.523(2) . ?
C33 C34 1.518(3) . ?
C3 C4 1.3884(18) . ?
C4 C6 1.3894(18) . ?
C5 C6 1.3905(17) . ?
C7 C10 1.5269(18) . ?
C7 C8 1.538(2) . ?
C7 C9 1.5394(19) . ?
C11 C12 1.537(2) . ?
