Information card for entry 7719651

Structure parameters

• Formula: C48 H47 Br0.26 Cl0.74 Co F6 N2 P4
• Calculated formula: C48 H47 Br0.257 Cl0.743 Co F6 N2 P4
• Title of publication: Catalytic olefin hydrosilylation with an original bis(iminophosphorane)phosphine NPN Co^II complex.
• Authors of publication: Popovici, Ingrid; Chen, Yujia; Bourcier, Sophie; Casaretto, Nicolas; Auffrant, Audrey
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2025
• Journal volume: 54
• Journal issue: 42
• Pages of publication: 15705 - 15709
• a: 10.1288 ± 0.0006 Å
• b: 31.464 ± 0.002 Å
• c: 14.14 ± 0.0008 Å
• α: 90°
• β: 96.761 ± 0.004°
• γ: 90°
• Cell volume: 4475 ± 0.5 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0739
• Residual factor for significantly intense reflections: 0.0399
• Weighted residual factors for significantly intense reflections: 0.0795
• Weighted residual factors for all reflections included in the refinement: 0.085
• Goodness-of-fit parameter for all reflections included in the refinement: 0.932
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No