Information card for entry 7719849

Structure parameters

• Chemical name: 20221222L1CuI
• Formula: C32 H48 Cu4 I4 N4 Si4
• Calculated formula: C32 H48 Cu4 I4 N4 Si4
• Title of publication: Disilane-bonded bis(methylpyridine) Cu(I) complex exhibiting reversible trigonal–tetrahedral switch with stimuli-responsive luminescence
• Authors of publication: Yamanoi, Yoshinori; Zhao, Yongjin; Nakae, Toyotaka; Segawa, Kaito; Yoshida, Masaki; Kato, Masako; Kikuchi, Kazuma; Imoto, Hiroaki; Naka, Kensuke; Kitajima, Showa; Oka, Kouki; Kasai, Hitoshi; Ito, Suguru
• Journal of publication: Dalton Transactions
• Year of publication: 2025
• a: 8.7364 ± 0.0009 Å
• b: 10.2213 ± 0.0009 Å
• c: 14.6413 ± 0.0013 Å
• α: 103.505 ± 0.002°
• β: 96.261 ± 0.003°
• γ: 114.33 ± 0.002°
• Cell volume: 1126.86 ± 0.19 ų
• Cell temperature: 102 ± 2 K
• Ambient diffraction temperature: 102 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0839
• Residual factor for significantly intense reflections: 0.0525
• Weighted residual factors for significantly intense reflections: 0.1169
• Weighted residual factors for all reflections included in the refinement: 0.1324
• Goodness-of-fit parameter for all reflections included in the refinement: 1.056
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No