Information card for entry 7720197

Structure parameters

• Chemical name: oxo-n-propoxo-[N''-(2-oxo-3-methoxybenzylidene)nicotinoylhydrazonato]vanadium(v) tetramer
• Formula: C68 H72 N12 O20 V4
• Calculated formula: C68 H72 N12 O20 V4
• Title of publication: Nicotinoyl Hydrazone-Directed Vanadium Assemblies: Metallosupramolecular Isomerism, Polymorphism, and Catalytic Oxidation Performance
• Authors of publication: Topic, Edi; Sarjanović, Josipa; Kuzman, Dino; Cocut, Andrea; Hrenar, Tomica; Pisk, Jana; Vrdoljak, Višnja
• Journal of publication: Dalton Transactions
• Year of publication: 2026
• a: 15.7349 ± 0.0002 Å
• b: 19.5409 ± 0.0003 Å
• c: 26.1973 ± 0.0004 Å
• α: 102.874 ± 0.001°
• β: 100.023 ± 0.001°
• γ: 108.932 ± 0.001°
• Cell volume: 7157.8 ± 0.2 ų
• Cell temperature: 173.4 ± 0.4 K
• Ambient diffraction temperature: 173.4 ± 0.4 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1618
• Residual factor for significantly intense reflections: 0.1521
• Weighted residual factors for significantly intense reflections: 0.4032
• Weighted residual factors for all reflections included in the refinement: 0.4076
• Goodness-of-fit parameter for all reflections included in the refinement: 1.084
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No