#------------------------------------------------------------------------------
#$Date: 2026-03-04 12:23:17 +0100 (Wed 04 de Mar de 2026) $
#$Revision: 304757 $
#$URL: svn://www.crystallography.net/cod/cif/7/72/04/7720487.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7720487
loop_
_publ_author_name
'Pattnaik, Archana Kumari'
'Behera, Gobinda Chandra'
_publ_section_title
;
 From discrete to polymeric assemblies: exploring supramolecular
 structural diversity in transition metal phosphinates with N-donor
 ligands.
;
_journal_issue                   2
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              694
_journal_page_last               709
_journal_paper_doi               10.1039/d5dt01622c
_journal_volume                  55
_journal_year                    2026
_chemical_formula_sum            'C34 H29 Cl Cu2 N2 O9 P2'
_chemical_formula_weight         834.06
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2025-09-10 deposited with the CCDC.	2025-12-01 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 113.557(4)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   25.424(3)
_cell_length_b                   11.3058(14)
_cell_length_c                   25.572(3)
_cell_measurement_reflns_used    9155
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.38
_cell_measurement_theta_min      2.41
_cell_volume                     6737.8(14)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0696
_diffrn_reflns_av_unetI/netI     0.0426
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.979
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            56626
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.979
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.756
_diffrn_reflns_theta_min         2.002
_exptl_absorpt_coefficient_mu    1.496
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.644
_exptl_crystal_description       rod
_exptl_crystal_F_000             3392
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.14
_refine_diff_density_max         0.604
_refine_diff_density_min         -0.481
_refine_diff_density_rms         0.077
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     455
_refine_ls_number_reflns         8575
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0476
_refine_ls_R_factor_gt           0.0335
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0299P)²+13.2372P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0793
_refine_ls_wR_factor_ref         0.0878
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7079
_reflns_number_total             8575
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5dt01622c2.cif
_cod_data_source_block           6_a
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7720487
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.41067(2) 0.68375(2) 0.67532(2) 0.01930(7) Uani 1 1 d . . . . .
Cl1 Cl 0.66490(3) 1.12065(7) 0.81199(4) 0.04707(18) Uani 1 1 d . . . . .
P1 P 0.40275(2) 0.86291(5) 0.57903(2) 0.01987(12) Uani 1 1 d . . . . .
O1 O 0.45294(6) 0.93368(14) 0.61927(6) 0.0230(3) Uani 1 1 d . . . . .
N1 N 0.57572(7) 0.92528(16) 0.67834(8) 0.0211(4) Uani 1 1 d . . . . .
C1 C 0.50346(10) 0.44983(19) 0.83142(10) 0.0237(4) Uani 1 1 d . . . . .
N2 N 0.83123(8) 1.12600(17) 0.66143(8) 0.0249(4) Uani 1 1 d . . . . .
Cu2 Cu 0.50715(2) 0.88465(2) 0.69551(2) 0.01713(7) Uani 1 1 d . . . . .
P2 P 0.46801(2) 0.58758(5) 0.80578(2) 0.01805(11) Uani 1 1 d . . . . .
O2 O 0.37772(6) 0.76979(15) 0.60481(7) 0.0274(4) Uani 1 1 d . . . . .
C2 C 0.55330(11) 0.4463(2) 0.88076(12) 0.0358(6) Uani 1 1 d . . . . .
H2 H 0.568732 0.515806 0.900366 0.043 Uiso 1 1 calc R U . . .
O3 O 0.60480(11) 1.1027(3) 0.78919(16) 0.0990(12) Uani 1 1 d . . . . .
C3 C 0.58009(13) 0.3388(3) 0.90079(15) 0.0510(8) Uani 1 1 d . . . . .
H3 H 0.613522 0.336152 0.933894 0.061 Uiso 1 1 calc R U . . .
O4 O 0.55461(7) 0.86136(15) 0.77666(7) 0.0198(3) Uani 1 1 d . . . . .
H4A H 0.5727(13) 0.907(3) 0.7865(13) 0.036(9) Uiso 1 1 d . . . . .
C4 C 0.55731(16) 0.2365(3) 0.87183(16) 0.0559(9) Uani 1 1 d . . . . .
H4 H 0.575826 0.164783 0.884940 0.067 Uiso 1 1 calc R U . . .
O5 O 0.51147(6) 0.68684(12) 0.82914(6) 0.0199(3) Uani 1 1 d . . . . .
C5 C 0.50767(17) 0.2392(2) 0.82391(15) 0.0544(9) Uani 1 1 d . . . . .
H5 H 0.492194 0.169103 0.805005 0.065 Uiso 1 1 calc R U . . .
C6 C 0.48010(14) 0.3453(2) 0.80312(12) 0.0379(6) Uani 1 1 d . . . . .
H6 H 0.446203 0.346667 0.770470 0.045 Uiso 1 1 calc R U . . .
O6 O 0.43659(6) 0.58223(14) 0.74197(6) 0.0236(3) Uani 1 1 d . . . . .
C7 C 0.42915(11) 0.6565(3) 0.88877(12) 0.0375(6) Uani 1 1 d . . . . .
H7 H 0.465782 0.686854 0.908553 0.045 Uiso 1 1 calc R U . . .
O7 O 0.68270(12) 1.1943(2) 0.86069(12) 0.0774(8) Uani 1 1 d . . . . .
C8 C 0.38799(13) 0.6673(3) 0.91166(14) 0.0484(8) Uani 1 1 d . . . . .
H8 H 0.397332 0.704536 0.946660 0.058 Uiso 1 1 calc R U . . .
O8 O 0.68315(15) 1.1695(3) 0.77113(13) 0.0892(9) Uani 1 1 d . . . . .
C9 C 0.33377(13) 0.6233(3) 0.88275(14) 0.0466(7) Uani 1 1 d . . . . .
H9 H 0.306044 0.632303 0.897588 0.056 Uiso 1 1 calc R U . . .
O9 O 0.69175(14) 1.0071(2) 0.82764(14) 0.0845(9) Uani 1 1 d . . . . .
C10 C 0.32073(12) 0.5662(3) 0.83207(14) 0.0521(8) Uani 1 1 d . . . . .
H10 H 0.284161 0.535132 0.812664 0.062 Uiso 1 1 calc R U . . .
C11 C 0.36158(11) 0.5541(3) 0.80938(12) 0.0434(7) Uani 1 1 d . . . . .
H11 H 0.352355 0.514014 0.775097 0.052 Uiso 1 1 calc R U . . .
C12 C 0.41601(9) 0.6011(2) 0.83714(10) 0.0242(4) Uani 1 1 d . . . . .
C14 C 0.29006(12) 0.9407(3) 0.53543(16) 0.0608(10) Uani 1 1 d . . . . .
H14 H 0.283077 0.877832 0.555215 0.073 Uiso 1 1 calc R U . . .
C13 C 0.34475(9) 0.9600(2) 0.53865(9) 0.0248(5) Uani 1 1 d . . . . .
C15 C 0.24536(14) 1.0143(4) 0.50295(18) 0.0717(12) Uani 1 1 d . . . . .
H15 H 0.208537 0.999898 0.500807 0.086 Uiso 1 1 calc R U . . .
C17 C 0.30850(14) 1.1269(3) 0.47693(15) 0.0560(9) Uani 1 1 d . . . . .
H17 H 0.315282 1.190360 0.457347 0.067 Uiso 1 1 calc R U . . .
C16 C 0.25485(13) 1.1079(3) 0.47404(13) 0.0491(8) Uani 1 1 d . . . . .
H16 H 0.224878 1.157857 0.452689 0.059 Uiso 1 1 calc R U . . .
C19 C 0.42427(11) 0.7956(2) 0.52658(10) 0.0287(5) Uani 1 1 d . . . . .
C18 C 0.35335(12) 1.0533(3) 0.50852(14) 0.0453(7) Uani 1 1 d . . . . .
H18 H 0.389762 1.067010 0.509395 0.054 Uiso 1 1 calc R U . . .
C20 C 0.39555(16) 0.6994(3) 0.49613(15) 0.0555(9) Uani 1 1 d . . . . .
H20 H 0.364887 0.667905 0.502610 0.067 Uiso 1 1 calc R U . . .
C21 C 0.4121(2) 0.6478(4) 0.45520(18) 0.0801(13) Uani 1 1 d . . . . .
H21 H 0.392275 0.582772 0.434329 0.096 Uiso 1 1 calc R U . . .
C22 C 0.45754(19) 0.6935(4) 0.44602(16) 0.0667(11) Uani 1 1 d . . . . .
H22 H 0.468938 0.658124 0.419400 0.080 Uiso 1 1 calc R U . . .
C23 C 0.48595(14) 0.7892(3) 0.47509(12) 0.0485(8) Uani 1 1 d . . . . .
H23 H 0.516483 0.820274 0.468262 0.058 Uiso 1 1 calc R U . . .
C24 C 0.46939(11) 0.8409(3) 0.51522(11) 0.0360(6) Uani 1 1 d . . . . .
H24 H 0.488892 0.907305 0.534977 0.043 Uiso 1 1 calc R U . . .
C25 C 0.57406(9) 1.0126(2) 0.64241(10) 0.0259(5) Uani 1 1 d . . . . .
H25 H 0.539065 1.049044 0.621735 0.031 Uiso 1 1 calc R U . . .
C26 C 0.62640(9) 0.8715(2) 0.70600(10) 0.0239(4) Uani 1 1 d . . . . .
H26 H 0.628264 0.809784 0.730733 0.029 Uiso 1 1 calc R U . . .
C27 C 0.62191(10) 1.0509(2) 0.63468(11) 0.0310(5) Uani 1 1 d . . . . .
H27 H 0.618943 1.112779 0.609705 0.037 Uiso 1 1 calc R U . . .
C28 C 0.67575(9) 0.9032(2) 0.69956(10) 0.0263(5) Uani 1 1 d . . . . .
H28 H 0.709706 0.862022 0.718816 0.032 Uiso 1 1 calc R U . . .
C29 C 0.67444(9) 0.9970(2) 0.66417(10) 0.0240(4) Uani 1 1 d . . . . .
C30 C 0.72798(9) 1.0409(2) 0.66069(10) 0.0250(5) Uani 1 1 d . . . . .
C31 C 0.73701(10) 1.1614(2) 0.65693(12) 0.0353(6) Uani 1 1 d . . . . .
H31 H 0.708474 1.215415 0.654280 0.042 Uiso 1 1 calc R U . . .
C32 C 0.78878(10) 1.2005(2) 0.65716(12) 0.0332(6) Uani 1 1 d . . . . .
H32 H 0.794196 1.281152 0.654242 0.040 Uiso 1 1 calc R U . . .
C33 C 0.82201(9) 1.0102(2) 0.66331(10) 0.0258(5) Uani 1 1 d . . . . .
H33 H 0.850878 0.957997 0.664923 0.031 Uiso 1 1 calc R U . . .
C34 C 0.77154(9) 0.9645(2) 0.66298(10) 0.0264(5) Uani 1 1 d . . . . .
H34 H 0.766778 0.883108 0.664279 0.032 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Cu1 O6 172.85(7) . . ?
O2 Cu1 N2 88.18(7) . 3_445 ?
O6 Cu1 N2 85.86(7) . 3_445 ?
O2 Cu1 O5 90.44(6) . 2_656 ?
O6 Cu1 O5 93.62(6) . 2_656 ?
N2 Cu1 O5 158.11(7) 3_445 2_656 ?
O2 Cu1 O4 89.40(7) . 2_656 ?
O6 Cu1 O4 97.05(6) . 2_656 ?
N2 Cu1 O4 120.88(7) 3_445 2_656 ?
O5 Cu1 O4 80.93(6) 2_656 2_656 ?
O7 Cl1 O8 109.69(19) . . ?
O7 Cl1 O3 111.11(18) . . ?
O8 Cl1 O3 111.8(2) . . ?
O7 Cl1 O9 109.42(19) . . ?
O8 Cl1 O9 107.19(19) . . ?
O3 Cl1 O9 107.5(2) . . ?
O1 P1 O2 117.44(9) . . ?
O1 P1 C13 110.12(10) . . ?
O2 P1 C13 106.53(10) . . ?
O1 P1 C19 107.75(10) . . ?
O2 P1 C19 109.62(11) . . ?
C13 P1 C19 104.65(11) . . ?
P1 O1 Cu2 126.41(9) . . ?
C25 N1 C26 117.16(18) . . ?
C25 N1 Cu2 121.72(15) . . ?
C26 N1 Cu2 120.93(15) . . ?
C2 C1 C6 119.7(2) . . ?
C2 C1 P2 120.14(19) . . ?
C6 C1 P2 120.1(2) . . ?
C33 N2 C32 118.19(19) . . ?
C33 N2 Cu1 119.34(15) . 3 ?
C32 N2 Cu1 121.97(16) . 3 ?
O4 Cu2 O1 168.77(7) . . ?
O4 Cu2 O4 80.95(7) . 2_656 ?
O1 Cu2 O4 92.95(6) . 2_656 ?
O4 Cu2 N1 92.37(7) . . ?
O1 Cu2 N1 92.54(7) . . ?
O4 Cu2 N1 170.74(7) 2_656 . ?
O4 Cu2 O5 97.52(6) . 2_656 ?
O1 Cu2 O5 90.93(6) . 2_656 ?
O4 Cu2 O5 82.23(6) 2_656 2_656 ?
N1 Cu2 O5 105.13(6) . 2_656 ?
O4 Cu2 Cu2 41.85(4) . 2_656 ?
O1 Cu2 Cu2 129.40(5) . 2_656 ?
O4 Cu2 Cu2 41.17(5) 2_656 2_656 ?
N1 Cu2 Cu2 130.55(5) . 2_656 ?
O5 Cu2 Cu2 99.66(4) 2_656 2_656 ?
O6 P2 O5 116.33(9) . . ?
O6 P2 C1 109.52(10) . . ?
O5 P2 C1 108.56(10) . . ?
O6 P2 C12 108.63(10) . . ?
O5 P2 C12 108.01(10) . . ?
C1 P2 C12 105.21(10) . . ?
P1 O2 Cu1 131.34(10) . . ?
C1 C2 C3 119.8(3) . . ?
C1 C2 H2 120.1 . . ?
C3 C2 H2 120.1 . . ?
C4 C3 C2 120.1(3) . . ?
C4 C3 H3 120.0 . . ?
C2 C3 H3 120.0 . . ?
Cu2 O4 Cu2 96.98(7) . 2_656 ?
Cu2 O4 Cu1 128.06(8) . 2_656 ?
Cu2 O4 Cu1 96.47(6) 2_656 2_656 ?
Cu2 O4 H4A 110(3) . . ?
Cu2 O4 H4A 107(3) 2_656 . ?
Cu1 O4 H4A 114(3) 2_656 . ?
C5 C4 C3 120.4(3) . . ?
C5 C4 H4 119.8 . . ?
C3 C4 H4 119.8 . . ?
P2 O5 Cu1 122.54(8) . 2_656 ?
P2 O5 Cu2 124.58(8) . 2_656 ?
Cu1 O5 Cu2 95.69(6) 2_656 2_656 ?
C4 C5 C6 120.6(3) . . ?
C4 C5 H5 119.7 . . ?
C6 C5 H5 119.7 . . ?
C5 C6 C1 119.5(3) . . ?
C5 C6 H6 120.3 . . ?
C1 C6 H6 120.3 . . ?
P2 O6 Cu1 140.93(10) . . ?
C12 C7 C8 120.5(2) . . ?
C12 C7 H7 119.7 . . ?
C8 C7 H7 119.7 . . ?
C9 C8 C7 120.2(3) . . ?
C9 C8 H8 119.9 . . ?
C7 C8 H8 119.9 . . ?
C10 C9 C8 119.6(3) . . ?
C10 C9 H9 120.2 . . ?
C8 C9 H9 120.2 . . ?
C9 C10 C11 120.4(3) . . ?
C9 C10 H10 119.8 . . ?
C11 C10 H10 119.8 . . ?
C10 C11 C12 120.7(3) . . ?
C10 C11 H11 119.6 . . ?
C12 C11 H11 119.6 . . ?
C7 C12 C11 118.4(2) . . ?
C7 C12 P2 121.63(18) . . ?
C11 C12 P2 119.93(19) . . ?
C13 C14 C15 120.5(3) . . ?
C13 C14 H14 119.8 . . ?
C15 C14 H14 119.8 . . ?
C18 C13 C14 118.1(2) . . ?
C18 C13 P1 120.88(19) . . ?
C14 C13 P1 121.0(2) . . ?
C16 C15 C14 120.6(3) . . ?
C16 C15 H15 119.7 . . ?
C14 C15 H15 119.7 . . ?
C16 C17 C18 121.0(3) . . ?
C16 C17 H17 119.5 . . ?
C18 C17 H17 119.5 . . ?
C17 C16 C15 119.0(3) . . ?
C17 C16 H16 120.5 . . ?
C15 C16 H16 120.5 . . ?
C20 C19 C24 118.1(3) . . ?
C20 C19 P1 120.4(2) . . ?
C24 C19 P1 121.4(2) . . ?
C13 C18 C17 120.7(3) . . ?
C13 C18 H18 119.6 . . ?
C17 C18 H18 119.6 . . ?
C19 C20 C21 120.3(3) . . ?
C19 C20 H20 119.8 . . ?
C21 C20 H20 119.8 . . ?
C22 C21 C20 119.8(3) . . ?
C22 C21 H21 120.1 . . ?
C20 C21 H21 120.1 . . ?
C23 C22 C21 120.8(3) . . ?
C23 C22 H22 119.6 . . ?
C21 C22 H22 119.6 . . ?
C22 C23 C24 119.5(3) . . ?
C22 C23 H23 120.2 . . ?
C24 C23 H23 120.2 . . ?
C23 C24 C19 121.4(3) . . ?
C23 C24 H24 119.3 . . ?
C19 C24 H24 119.3 . . ?
N1 C25 C27 122.9(2) . . ?
N1 C25 H25 118.6 . . ?
C27 C25 H25 118.6 . . ?
N1 C26 C28 123.2(2) . . ?
N1 C26 H26 118.4 . . ?
C28 C26 H26 118.4 . . ?
C25 C27 C29 119.9(2) . . ?
C25 C27 H27 120.1 . . ?
C29 C27 H27 120.1 . . ?
C26 C28 C29 119.5(2) . . ?
C26 C28 H28 120.3 . . ?
C29 C28 H28 120.3 . . ?
C27 C29 C28 117.3(2) . . ?
C27 C29 C30 121.8(2) . . ?
C28 C29 C30 120.8(2) . . ?
C34 C30 C31 117.5(2) . . ?
C34 C30 C29 121.6(2) . . ?
C31 C30 C29 120.8(2) . . ?
C32 C31 C30 119.6(2) . . ?
C32 C31 H31 120.2 . . ?
C30 C31 H31 120.2 . . ?
N2 C32 C31 122.2(2) . . ?
N2 C32 H32 118.9 . . ?
C31 C32 H32 118.9 . . ?
N2 C33 C34 123.0(2) . . ?
N2 C33 H33 118.5 . . ?
C34 C33 H33 118.5 . . ?
C33 C34 C30 119.4(2) . . ?
C33 C34 H34 120.3 . . ?
C30 C34 H34 120.3 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 O2 1.9215(16) . ?
Cu1 O6 1.9387(15) . ?
Cu1 N2 2.0143(18) 3_445 ?
Cu1 O5 2.0283(14) 2_656 ?
Cu1 O4 2.3351(17) 2_656 ?
Cl1 O7 1.414(2) . ?
Cl1 O8 1.414(3) . ?
Cl1 O3 1.415(3) . ?
Cl1 O9 1.434(3) . ?
P1 O1 1.5093(16) . ?
P1 O2 1.5109(16) . ?
P1 C13 1.797(2) . ?
P1 C19 1.807(2) . ?
O1 Cu2 1.9647(15) . ?
N1 C25 1.338(3) . ?
N1 C26 1.342(3) . ?
N1 Cu2 2.0135(17) . ?
C1 C2 1.386(3) . ?
C1 C6 1.389(3) . ?
C1 P2 1.788(2) . ?
N2 C33 1.334(3) . ?
N2 C32 1.338(3) . ?
Cu2 O4 1.9571(16) . ?
Cu2 O4 1.9836(15) 2_656 ?
Cu2 O5 2.3204(15) 2_656 ?
Cu2 Cu2 2.9510(6) 2_656 ?
P2 O6 1.5043(16) . ?
P2 O5 1.5197(15) . ?
P2 C12 1.806(2) . ?
C2 C3 1.388(4) . ?
C2 H2 0.9300 . ?
C3 C4 1.371(5) . ?
C3 H3 0.9300 . ?
O4 H4A 0.67(3) . ?
C4 C5 1.364(5) . ?
C4 H4 0.9300 . ?
C5 C6 1.384(4) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C7 C12 1.376(3) . ?
C7 C8 1.393(4) . ?
C7 H7 0.9300 . ?
C8 C9 1.371(4) . ?
C8 H8 0.9300 . ?
C9 C10 1.365(4) . ?
C9 H9 0.9300 . ?
C10 C11 1.384(4) . ?
C10 H10 0.9300 . ?
C11 C12 1.384(3) . ?
C11 H11 0.9300 . ?
C14 C13 1.377(4) . ?
C14 C15 1.385(4) . ?
C14 H14 0.9300 . ?
C13 C18 1.374(3) . ?
C15 C16 1.366(5) . ?
C15 H15 0.9300 . ?
C17 C16 1.353(5) . ?
C17 C18 1.381(4) . ?
C17 H17 0.9300 . ?
C16 H16 0.9300 . ?
C19 C20 1.368(4) . ?
C19 C24 1.389(4) . ?
C18 H18 0.9300 . ?
C20 C21 1.402(5) . ?
C20 H20 0.9300 . ?
C21 C22 1.369(6) . ?
C21 H21 0.9300 . ?
C22 C23 1.347(5) . ?
C22 H22 0.9300 . ?
C23 C24 1.385(4) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
C25 C27 1.378(3) . ?
C25 H25 0.9300 . ?
C26 C28 1.377(3) . ?
C26 H26 0.9300 . ?
C27 C29 1.385(3) . ?
C27 H27 0.9300 . ?
C28 C29 1.386(3) . ?
C28 H28 0.9300 . ?
C29 C30 1.485(3) . ?
C30 C34 1.388(3) . ?
C30 C31 1.391(3) . ?
C31 C32 1.386(3) . ?
C31 H31 0.9300 . ?
C32 H32 0.9300 . ?
C33 C34 1.380(3) . ?
C33 H33 0.9300 . ?
C34 H34 0.9300 . ?
