#------------------------------------------------------------------------------
#$Date: 2026-03-04 12:40:30 +0100 (Wed 04 de Mar de 2026) $
#$Revision: 304764 $
#$URL: svn://www.crystallography.net/cod/cif/7/72/05/7720525.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7720525
loop_
_publ_author_name
'Levina, Anastasia A.'
'Shmelev, Maxim A.'
'Lalov, Andrey V.'
'Chistyakov, Aleksandr S.'
'Voronina, Julia K.'
'Varaksina, Evgeniya A.'
'Taydakov, Ilya V.'
'Sidorov, Alexey A.'
'Eremenko, Igor L.'
_publ_section_title
;
 Effect of combining 1-naphthoate and pentafluorobenzoate anions in
 Eu(III) compounds on their structure and photoluminescent properties.
;
_journal_issue                   3
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1417
_journal_page_last               1435
_journal_paper_doi               10.1039/d5dt02665b
_journal_volume                  55
_journal_year                    2026
_chemical_formula_moiety         'C66 H16 Eu2 F30 N4 O12, 4(C H4 O)'
_chemical_formula_sum            'C70 H32 Eu2 F30 N4 O16'
_chemical_formula_weight         2058.91
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_date             2025-09-01
_audit_creation_method
;
Olex2 1.5
(compiled 2025.07.13 svn.rb7424aed for OlexSys, GUI svn.r7314)
;
_audit_update_record
;
2025-09-01 deposited with the CCDC.	2025-12-16 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 100.764(11)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   16.377(6)
_cell_length_b                   9.987(4)
_cell_length_c                   21.598(8)
_cell_measurement_reflns_used    7630
_cell_measurement_temperature    150
_cell_measurement_theta_max      30.31
_cell_measurement_theta_min      2.25
_cell_volume                     3470(2)
_computing_cell_refinement       'SAINT V8.35A (?, 2016)'
_computing_data_reduction        'SAINT V8.35A (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_diffrn_ambient_temperature      150
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1002
_diffrn_reflns_av_unetI/netI     0.0960
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            24928
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.998
_diffrn_reflns_theta_min         2.254
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.946
_exptl_absorpt_correction_T_max  0.1000
_exptl_absorpt_correction_T_min  0.0365
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.1494 before and 0.1001 after correction.
The Ratio of minimum to maximum transmission is 0.3650.
The λ/2 correction factor is 0.00150.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.970
_exptl_crystal_description       needle
_exptl_crystal_F_000             2008
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.856
_refine_diff_density_min         -1.251
_refine_diff_density_rms         0.194
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     553
_refine_ls_number_reflns         6782
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.0957
_refine_ls_R_factor_gt           0.0669
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0616P)²+28.9471P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1514
_refine_ls_wR_factor_ref         0.1764
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4951
_reflns_number_total             6782
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5dt02665b2.cif
_cod_data_source_block           101_a
_cod_database_code               7720525
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.909
_shelx_estimated_absorpt_t_min   0.759
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2.a Riding coordinates:
 O2S(H2S), O1S(H1S)
2.b Aromatic/amide H refined with riding coordinates:
 C31(H31), C29(H29), C30(H30), C22(H22), C32(H32), C23(H23), C24(H24), C33(H33)
2.c Idealised Me refined as rotating group:
 C2S(H2SA,H2SB,H2SC), C1S(H1SA,H1SB,H1SC)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.54423(3) 0.70737(4) 0.50122(2) 0.02313(16) Uani 1 1 d . . . . .
F3 F 0.3114(3) 0.9897(5) 0.4774(2) 0.0325(12) Uani 1 1 d . . . . .
F17 F 0.7277(3) 0.3431(6) 0.6530(2) 0.0349(12) Uani 1 1 d . . . . .
F10 F 0.3528(3) 0.5231(5) 0.6737(2) 0.0347(12) Uani 1 1 d . . . . .
F14 F 0.6461(3) 0.5244(5) 0.7232(3) 0.0378(13) Uani 1 1 d . . . . .
F21 F 0.7504(3) 0.4333(5) 0.4427(2) 0.0309(12) Uani 1 1 d . . . . .
F7 F 0.4378(3) 0.8585(5) 0.6825(2) 0.0368(13) Uani 1 1 d . . . . .
O1 O 0.5165(4) 0.8944(5) 0.5612(3) 0.0249(13) Uani 1 1 d . . . . .
F11 F 0.3459(4) 0.5475(6) 0.7964(3) 0.0443(14) Uani 1 1 d . . . . .
F18 F 0.8954(3) 0.3517(6) 0.6871(3) 0.0423(14) Uani 1 1 d . . . . .
F5 F 0.1479(4) 0.8170(6) 0.6151(3) 0.0513(16) Uani 1 1 d . . . . .
F13 F 0.6402(4) 0.5609(6) 0.8465(2) 0.0427(14) Uani 1 1 d . . . . .
F20 F 0.9181(3) 0.4345(5) 0.4766(3) 0.0403(13) Uani 1 1 d . . . . .
O3 O 0.5125(4) 0.6165(6) 0.5977(3) 0.0268(13) Uani 1 1 d . . . . .
F6 F 0.2877(4) 0.7892(6) 0.7070(3) 0.0478(15) Uani 1 1 d . . . . .
F4 F 0.1609(3) 0.9159(5) 0.5008(3) 0.0425(14) Uani 1 1 d . . . . .
O5 O 0.6036(4) 0.4927(5) 0.5124(3) 0.0290(14) Uani 1 1 d . . . . .
O4 O 0.4923(4) 0.3924(5) 0.6018(3) 0.0251(13) Uani 1 1 d . . . . .
O6 O 0.6060(4) 0.2731(6) 0.5282(3) 0.0293(14) Uani 1 1 d . . . . .
F19 F 0.9915(3) 0.3956(6) 0.5995(3) 0.0449(14) Uani 1 1 d . . . . .
F12 F 0.4903(4) 0.5677(6) 0.8837(2) 0.0496(16) Uani 1 1 d . . . . .
O2S O 0.5730(5) 0.1916(7) 0.6934(3) 0.0423(17) Uani 1 1 d . . . . .
H2S H 0.5362 0.2265 0.6530 0.09(5) Uiso 1 1 d R . . . .
O2 O 0.4710(4) 1.1036(5) 0.5670(3) 0.0281(14) Uani 1 1 d . . . . .
N1 N 0.6798(5) 0.7330(7) 0.4553(4) 0.0280(17) Uani 1 1 d . . . . .
N2 N 0.6809(5) 0.7427(7) 0.5806(3) 0.0270(17) Uani 1 1 d . . . . .
O1S O 0.4466(5) 0.2206(7) 0.7642(4) 0.055(2) Uani 1 1 d . . . . .
H1S H 0.4820 0.2004 0.7435 0.083 Uiso 1 1 d R U . . .
C2 C 0.3788(5) 0.9283(8) 0.5802(4) 0.0242(18) Uani 1 1 d . . . . .
C10 C 0.4242(6) 0.5297(9) 0.7155(4) 0.0269(19) Uani 1 1 d . . . . .
C9 C 0.4995(5) 0.5221(8) 0.6949(4) 0.0236(18) Uani 1 1 d . . . . .
C26 C 0.7548(5) 0.7384(8) 0.4949(4) 0.0256(19) Uani 1 1 d . . . . .
C3 C 0.3068(6) 0.9420(8) 0.5343(4) 0.029(2) Uani 1 1 d . . . . .
C16 C 0.7348(5) 0.3890(8) 0.5473(4) 0.0248(18) Uani 1 1 d . . . . .
C17 C 0.7738(6) 0.3672(8) 0.6091(4) 0.028(2) Uani 1 1 d . . . . .
C1 C 0.4620(5) 0.9797(8) 0.5675(4) 0.0260(19) Uani 1 1 d . . . . .
C27 C 0.7562(6) 0.7425(9) 0.5617(4) 0.029(2) Uani 1 1 d . . . . .
C8 C 0.5025(5) 0.5081(8) 0.6258(4) 0.028(2) Uani 1 1 d . . . . .
C14 C 0.5713(6) 0.5321(9) 0.7401(4) 0.030(2) Uani 1 1 d . . . . .
C7 C 0.3704(6) 0.8759(9) 0.6371(4) 0.030(2) Uani 1 1 d . . . . .
C13 C 0.5681(7) 0.5479(9) 0.8039(5) 0.038(2) Uani 1 1 d . . . . .
C31 C 0.6809(6) 0.7555(8) 0.6416(4) 0.030(2) Uani 1 1 d . . . . .
H31 H 0.6301 0.7606 0.6548 0.037 Uiso 1 1 calc R U . . .
C15 C 0.6411(5) 0.3853(8) 0.5267(4) 0.0247(19) Uani 1 1 d . . . . .
C21 C 0.7851(5) 0.4148(8) 0.5037(4) 0.0263(19) Uani 1 1 d . . . . .
C12 C 0.4922(7) 0.5519(9) 0.8229(4) 0.040(3) Uani 1 1 d . . . . .
C28 C 0.8323(6) 0.7485(8) 0.6034(5) 0.030(2) Uani 1 1 d . . . . .
C18 C 0.8597(6) 0.3716(9) 0.6275(4) 0.034(2) Uani 1 1 d . . . . .
C11 C 0.4207(6) 0.5420(9) 0.7784(5) 0.035(2) Uani 1 1 d . . . . .
C29 C 0.8295(6) 0.7555(9) 0.6686(5) 0.034(2) Uani 1 1 d . . . . .
H29 H 0.8786 0.7558 0.6983 0.041 Uiso 1 1 calc R U . . .
C30 C 0.7547(6) 0.7618(9) 0.6878(5) 0.034(2) Uani 1 1 d . . . . .
H30 H 0.7523 0.7702 0.7303 0.040 Uiso 1 1 calc R U . . .
C22 C 0.6786(6) 0.7377(8) 0.3935(4) 0.0247(19) Uani 1 1 d . . . . .
H22 H 0.6274 0.7362 0.3662 0.030 Uiso 1 1 calc R U . . .
C6 C 0.2939(7) 0.8381(9) 0.6505(5) 0.035(2) Uani 1 1 d . . . . .
C19 C 0.9076(6) 0.3937(9) 0.5816(5) 0.034(2) Uani 1 1 d . . . . .
C32 C 0.9085(6) 0.7517(9) 0.5792(5) 0.034(2) Uani 1 1 d . . . . .
H32 H 0.9591 0.7539 0.6072 0.041 Uiso 1 1 calc R U . . .
C20 C 0.8712(6) 0.4152(9) 0.5200(4) 0.030(2) Uani 1 1 d . . . . .
C23 C 0.7501(6) 0.7448(9) 0.3679(5) 0.034(2) Uani 1 1 d . . . . .
H23 H 0.7467 0.7484 0.3244 0.040 Uiso 1 1 calc R U . . .
C25 C 0.8301(6) 0.7439(9) 0.4732(5) 0.032(2) Uani 1 1 d . . . . .
C5 C 0.2235(6) 0.8548(9) 0.6047(5) 0.039(2) Uani 1 1 d . . . . .
C24 C 0.8259(6) 0.7463(9) 0.4077(5) 0.035(2) Uani 1 1 d . . . . .
H24 H 0.8745 0.7489 0.3912 0.042 Uiso 1 1 calc R U . . .
C4 C 0.2284(6) 0.9046(9) 0.5454(5) 0.037(2) Uani 1 1 d . . . . .
C2S C 0.6212(7) 0.0757(10) 0.6856(5) 0.047(3) Uani 1 1 d . . . . .
H2SA H 0.6483 0.0885 0.6503 0.071 Uiso 1 1 calc R U . . .
H2SB H 0.5854 -0.0011 0.6782 0.071 Uiso 1 1 calc R U . . .
H2SC H 0.6621 0.0617 0.7230 0.071 Uiso 1 1 calc R U . . .
C33 C 0.9075(6) 0.7517(9) 0.5170(5) 0.033(2) Uani 1 1 d . . . . .
H33 H 0.9572 0.7567 0.5022 0.039 Uiso 1 1 calc R U . . .
C1S C 0.4053(8) 0.1032(11) 0.7783(6) 0.060(3) Uani 1 1 d . . . . .
H1SA H 0.3644 0.0779 0.7423 0.090 Uiso 1 1 calc R U . . .
H1SB H 0.3785 0.1199 0.8134 0.090 Uiso 1 1 calc R U . . .
H1SC H 0.4449 0.0320 0.7887 0.090 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O3 74.31(19) . . ?
O1 Eu1 O5 109.46(18) . 3_666 ?
O1 Eu1 O4 142.43(19) . 3_666 ?
O1 Eu1 O6 78.0(2) . 3_666 ?
O1 Eu1 O2 72.78(19) . 3_676 ?
O1 Eu1 N1 113.3(2) . . ?
O1 Eu1 N2 76.1(2) . . ?
O3 Eu1 O5 63.35(18) . 3_666 ?
O3 Eu1 O6 83.4(2) . 3_666 ?
O3 Eu1 N1 134.5(2) . . ?
O3 Eu1 N2 77.2(2) . . ?
O5 Eu1 O1 141.5(2) . . ?
O5 Eu1 O3 73.7(2) . . ?
O5 Eu1 O5 74.0(2) . 3_666 ?
O5 Eu1 O4 75.2(2) . 3_666 ?
O5 Eu1 O6 118.7(2) . 3_666 ?
O5 Eu1 O2 141.4(2) . 3_676 ?
O5 Eu1 N1 76.3(2) . . ?
O5 Eu1 N2 76.4(2) . . ?
O4 Eu1 O3 125.78(19) 3_666 . ?
O4 Eu1 O5 65.92(17) 3_666 3_666 ?
O4 Eu1 O6 74.1(2) 3_666 3_666 ?
O4 Eu1 N1 76.8(2) 3_666 . ?
O4 Eu1 N2 134.9(2) 3_666 . ?
O6 Eu1 O5 45.15(17) 3_666 3_666 ?
O6 Eu1 N1 141.7(2) 3_666 . ?
O6 Eu1 N2 150.9(2) 3_666 . ?
O2 Eu1 O3 144.81(19) 3_676 . ?
O2 Eu1 O5 117.47(19) 3_676 3_666 ?
O2 Eu1 O4 77.13(19) 3_676 3_666 ?
O2 Eu1 O6 77.9(2) 3_676 3_666 ?
O2 Eu1 N1 71.6(2) 3_676 . ?
O2 Eu1 N2 106.3(2) 3_676 . ?
N1 Eu1 O5 136.90(18) . 3_666 ?
N2 Eu1 O5 135.65(19) . 3_666 ?
N2 Eu1 N1 62.9(2) . . ?
C1 O1 Eu1 143.7(6) . . ?
C8 O3 Eu1 143.3(5) . . ?
Eu1 O5 Eu1 106.0(2) . 3_666 ?
C15 O5 Eu1 79.0(5) . 3_666 ?
C15 O5 Eu1 170.8(6) . . ?
C8 O4 Eu1 138.4(5) . 3_666 ?
C15 O6 Eu1 111.4(5) . 3_666 ?
C2S O2S H2S 115.2 . . ?
C1 O2 Eu1 142.6(6) . 3_676 ?
C26 N1 Eu1 119.9(6) . . ?
C22 N1 Eu1 122.1(6) . . ?
C22 N1 C26 118.0(8) . . ?
C27 N2 Eu1 121.4(6) . . ?
C31 N2 Eu1 120.9(6) . . ?
C31 N2 C27 117.6(8) . . ?
C1S O1S H1S 109.1 . . ?
C3 C2 C1 120.1(8) . . ?
C7 C2 C3 117.6(8) . . ?
C7 C2 C1 122.2(8) . . ?
F10 C10 C9 119.8(7) . . ?
F10 C10 C11 118.6(8) . . ?
C11 C10 C9 121.6(8) . . ?
C10 C9 C8 121.0(8) . . ?
C14 C9 C10 117.2(8) . . ?
C14 C9 C8 121.7(8) . . ?
N1 C26 C27 118.3(8) . . ?
N1 C26 C25 122.7(8) . . ?
C25 C26 C27 118.9(8) . . ?
F3 C3 C2 120.3(8) . . ?
F3 C3 C4 117.7(8) . . ?
C2 C3 C4 122.0(9) . . ?
C17 C16 C15 122.5(8) . . ?
C21 C16 C17 117.4(8) . . ?
C21 C16 C15 120.2(7) . . ?
F17 C17 C16 119.4(8) . . ?
F17 C17 C18 118.6(8) . . ?
C18 C17 C16 122.0(8) . . ?
O1 C1 C2 117.8(7) . . ?
O2 C1 O1 125.6(8) . . ?
O2 C1 C2 116.5(7) . . ?
N2 C27 C26 116.9(8) . . ?
N2 C27 C28 123.6(9) . . ?
C28 C27 C26 119.6(8) . . ?
O3 C8 C9 115.1(7) . . ?
O4 C8 O3 127.1(8) . . ?
O4 C8 C9 117.7(7) . . ?
F14 C14 C9 120.0(8) . . ?
F14 C14 C13 118.6(8) . . ?
C9 C14 C13 121.4(9) . . ?
F7 C7 C2 119.9(8) . . ?
F7 C7 C6 117.6(8) . . ?
C2 C7 C6 122.5(9) . . ?
F13 C13 C14 119.4(9) . . ?
F13 C13 C12 120.8(9) . . ?
C12 C13 C14 119.8(9) . . ?
N2 C31 H31 118.4 . . ?
N2 C31 C30 123.1(9) . . ?
C30 C31 H31 118.4 . . ?
O5 C15 Eu1 78.0(5) . 3_666 ?
O5 C15 O6 124.4(8) . . ?
O5 C15 C16 118.4(7) . . ?
O6 C15 Eu1 46.5(4) . 3_666 ?
O6 C15 C16 117.0(7) . . ?
C16 C15 Eu1 163.3(5) . 3_666 ?
F21 C21 C16 119.7(8) . . ?
F21 C21 C20 118.1(8) . . ?
C16 C21 C20 122.2(8) . . ?
F12 C12 C13 119.1(10) . . ?
F12 C12 C11 121.7(10) . . ?
C11 C12 C13 119.2(9) . . ?
C27 C28 C29 116.8(9) . . ?
C27 C28 C32 119.8(9) . . ?
C29 C28 C32 123.4(9) . . ?
F18 C18 C17 120.9(9) . . ?
F18 C18 C19 120.6(9) . . ?
C17 C18 C19 118.5(9) . . ?
F11 C11 C10 119.6(9) . . ?
F11 C11 C12 119.7(9) . . ?
C12 C11 C10 120.7(9) . . ?
C28 C29 H29 120.0 . . ?
C30 C29 C28 120.0(9) . . ?
C30 C29 H29 120.0 . . ?
C31 C30 H30 120.7 . . ?
C29 C30 C31 118.7(9) . . ?
C29 C30 H30 120.7 . . ?
N1 C22 H22 118.5 . . ?
N1 C22 C23 123.1(9) . . ?
C23 C22 H22 118.5 . . ?
F6 C6 C7 121.0(9) . . ?
F6 C6 C5 120.2(9) . . ?
C5 C6 C7 118.8(9) . . ?
F19 C19 C18 118.4(9) . . ?
F19 C19 C20 120.5(9) . . ?
C20 C19 C18 121.1(9) . . ?
C28 C32 H32 119.5 . . ?
C33 C32 C28 121.0(9) . . ?
C33 C32 H32 119.5 . . ?
F20 C20 C21 120.9(8) . . ?
F20 C20 C19 120.2(8) . . ?
C19 C20 C21 118.8(9) . . ?
C22 C23 H23 120.5 . . ?
C24 C23 C22 118.9(9) . . ?
C24 C23 H23 120.5 . . ?
C26 C25 C24 117.2(9) . . ?
C26 C25 C33 120.4(9) . . ?
C24 C25 C33 122.3(9) . . ?
F5 C5 C6 121.0(9) . . ?
F5 C5 C4 117.7(10) . . ?
C6 C5 C4 121.2(9) . . ?
C23 C24 C25 120.0(9) . . ?
C23 C24 H24 120.0 . . ?
C25 C24 H24 120.0 . . ?
F4 C4 C3 121.1(9) . . ?
F4 C4 C5 121.0(9) . . ?
C5 C4 C3 117.8(9) . . ?
O2S C2S H2SA 109.5 . . ?
O2S C2S H2SB 109.5 . . ?
O2S C2S H2SC 109.5 . . ?
H2SA C2S H2SB 109.5 . . ?
H2SA C2S H2SC 109.5 . . ?
H2SB C2S H2SC 109.5 . . ?
C32 C33 C25 120.3(9) . . ?
C32 C33 H33 119.9 . . ?
C25 C33 H33 119.9 . . ?
O1S C1S H1SA 109.5 . . ?
O1S C1S H1SB 109.5 . . ?
O1S C1S H1SC 109.5 . . ?
H1SA C1S H1SB 109.5 . . ?
H1SA C1S H1SC 109.5 . . ?
H1SB C1S H1SC 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.365(5) . ?
Eu1 O3 2.418(6) . ?
Eu1 O5 3.110(6) 3_666 ?
Eu1 O5 2.348(5) . ?
Eu1 O4 2.410(6) 3_666 ?
Eu1 O6 2.431(6) 3_666 ?
Eu1 O2 2.379(6) 3_676 ?
Eu1 N1 2.607(8) . ?
Eu1 N2 2.577(8) . ?
F3 C3 1.333(10) . ?
F17 C17 1.338(9) . ?
F10 C10 1.338(10) . ?
F14 C14 1.345(10) . ?
F21 C21 1.347(10) . ?
F7 C7 1.344(10) . ?
O1 C1 1.259(10) . ?
F11 C11 1.354(11) . ?
F18 C18 1.326(10) . ?
F5 C5 1.351(11) . ?
F13 C13 1.360(11) . ?
F20 C20 1.331(10) . ?
O3 C8 1.267(10) . ?
F6 C6 1.336(11) . ?
F4 C4 1.329(11) . ?
O5 Eu1 3.110(6) 3_666 ?
O5 C15 1.245(10) . ?
O4 Eu1 2.410(6) 3_666 ?
O4 C8 1.264(10) . ?
O6 Eu1 2.431(6) 3_666 ?
O6 C15 1.262(10) . ?
F19 C19 1.355(10) . ?
F12 C12 1.329(10) . ?
O2S H2S 1.0236 . ?
O2S C2S 1.428(12) . ?
O2 Eu1 2.379(6) 3_676 ?
O2 C1 1.247(10) . ?
N1 C26 1.360(11) . ?
N1 C22 1.333(11) . ?
N2 C27 1.369(11) . ?
N2 C31 1.323(11) . ?
O1S H1S 0.8200 . ?
O1S C1S 1.415(13) . ?
C2 C3 1.398(12) . ?
C2 C1 1.528(12) . ?
C2 C7 1.366(12) . ?
C10 C9 1.390(12) . ?
C10 C11 1.375(12) . ?
C9 C8 1.509(12) . ?
C9 C14 1.384(12) . ?
C26 C27 1.440(12) . ?
C26 C25 1.400(13) . ?
C3 C4 1.401(13) . ?
C16 C17 1.386(12) . ?
C16 C15 1.517(12) . ?
C16 C21 1.386(12) . ?
C17 C18 1.389(13) . ?
C27 C28 1.396(13) . ?
C14 C13 1.396(13) . ?
C7 C6 1.390(13) . ?
C13 C12 1.380(15) . ?
C31 H31 0.9300 . ?
C31 C30 1.418(13) . ?
C15 Eu1 3.122(9) 3_666 ?
C21 C20 1.389(12) . ?
C12 C11 1.373(14) . ?
C28 C29 1.420(13) . ?
C28 C32 1.440(13) . ?
C18 C19 1.392(14) . ?
C29 H29 0.9300 . ?
C29 C30 1.364(14) . ?
C30 H30 0.9300 . ?
C22 H22 0.9300 . ?
C22 C23 1.387(12) . ?
C6 C5 1.383(15) . ?
C19 C20 1.370(13) . ?
C32 H32 0.9300 . ?
C32 C33 1.341(14) . ?
C23 H23 0.9300 . ?
C23 C24 1.371(14) . ?
C25 C24 1.404(13) . ?
C25 C33 1.436(13) . ?
C5 C4 1.389(14) . ?
C24 H24 0.9300 . ?
C2S H2SA 0.9600 . ?
C2S H2SB 0.9600 . ?
C2S H2SC 0.9600 . ?
C33 H33 0.9300 . ?
C1S H1SA 0.9600 . ?
C1S H1SB 0.9600 . ?
C1S H1SC 0.9600 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1 C1 O2 -124.7(9) . . . . ?
Eu1 O1 C1 C2 58.6(12) . . . . ?
Eu1 O3 C8 O4 -14.4(16) . . . . ?
Eu1 O3 C8 C9 167.9(6) . . . . ?
Eu1 O5 C15 O6 -0.3(8) 3_666 . . . ?
Eu1 O5 C15 C16 -176.9(7) 3_666 . . . ?
Eu1 O4 C8 O3 -16.6(15) 3_666 . . . ?
Eu1 O4 C8 C9 161.1(6) 3_666 . . . ?
Eu1 O6 C15 O5 0.4(11) 3_666 . . . ?
Eu1 O6 C15 C16 177.0(5) 3_666 . . . ?
Eu1 O2 C1 O1 90.1(12) 3_676 . . . ?
Eu1 O2 C1 C2 -93.1(10) 3_676 . . . ?
Eu1 N1 C26 C27 -5.9(10) . . . . ?
Eu1 N1 C26 C25 176.0(6) . . . . ?
Eu1 N1 C22 C23 -176.8(6) . . . . ?
Eu1 N2 C27 C26 7.5(10) . . . . ?
Eu1 N2 C27 C28 -173.7(6) . . . . ?
Eu1 N2 C31 C30 173.6(6) . . . . ?
F3 C3 C4 F4 0.2(12) . . . . ?
F3 C3 C4 C5 -180.0(8) . . . . ?
F17 C17 C18 F18 0.3(13) . . . . ?
F17 C17 C18 C19 178.6(8) . . . . ?
F10 C10 C9 C8 0.7(12) . . . . ?
F10 C10 C9 C14 178.8(7) . . . . ?
F10 C10 C11 F11 -0.2(13) . . . . ?
F10 C10 C11 C12 -178.6(8) . . . . ?
F14 C14 C13 F13 2.8(12) . . . . ?
F14 C14 C13 C12 -177.9(8) . . . . ?
F21 C21 C20 F20 0.6(12) . . . . ?
F21 C21 C20 C19 -178.6(7) . . . . ?
F7 C7 C6 F6 1.4(12) . . . . ?
F7 C7 C6 C5 -180.0(8) . . . . ?
F18 C18 C19 F19 -0.6(13) . . . . ?
F18 C18 C19 C20 -179.5(8) . . . . ?
F5 C5 C4 F4 0.6(13) . . . . ?
F5 C5 C4 C3 -179.1(8) . . . . ?
F13 C13 C12 F12 -0.4(13) . . . . ?
F13 C13 C12 C11 178.3(8) . . . . ?
F6 C6 C5 F5 -2.7(14) . . . . ?
F6 C6 C5 C4 -179.5(8) . . . . ?
F19 C19 C20 F20 1.9(13) . . . . ?
F19 C19 C20 C21 -178.9(8) . . . . ?
F12 C12 C11 F11 -0.4(14) . . . . ?
F12 C12 C11 C10 178.0(8) . . . . ?
N1 C26 C27 N2 -1.0(12) . . . . ?
N1 C26 C27 C28 -179.7(8) . . . . ?
N1 C26 C25 C24 1.1(13) . . . . ?
N1 C26 C25 C33 178.9(8) . . . . ?
N1 C22 C23 C24 0.4(13) . . . . ?
N2 C27 C28 C29 -0.2(13) . . . . ?
N2 C27 C28 C32 -178.1(8) . . . . ?
N2 C31 C30 C29 0.5(13) . . . . ?
C2 C3 C4 F4 -178.7(8) . . . . ?
C2 C3 C4 C5 1.1(13) . . . . ?
C2 C7 C6 F6 -178.9(8) . . . . ?
C2 C7 C6 C5 -0.3(13) . . . . ?
C10 C9 C8 O3 96.7(10) . . . . ?
C10 C9 C8 O4 -81.3(11) . . . . ?
C10 C9 C14 F14 179.4(7) . . . . ?
C10 C9 C14 C13 0.5(13) . . . . ?
C9 C10 C11 F11 -179.3(8) . . . . ?
C9 C10 C11 C12 2.2(14) . . . . ?
C9 C14 C13 F13 -178.2(8) . . . . ?
C9 C14 C13 C12 1.0(14) . . . . ?
C26 N1 C22 C23 1.4(12) . . . . ?
C26 C27 C28 C29 178.5(8) . . . . ?
C26 C27 C28 C32 0.5(13) . . . . ?
C26 C25 C24 C23 0.7(13) . . . . ?
C26 C25 C33 C32 1.0(13) . . . . ?
C3 C2 C1 O1 -111.2(9) . . . . ?
C3 C2 C1 O2 71.8(11) . . . . ?
C3 C2 C7 F7 178.9(7) . . . . ?
C3 C2 C7 C6 -0.8(13) . . . . ?
C16 C17 C18 F18 179.3(8) . . . . ?
C16 C17 C18 C19 -2.4(13) . . . . ?
C16 C21 C20 F20 177.0(8) . . . . ?
C16 C21 C20 C19 -2.1(13) . . . . ?
C17 C16 C15 Eu1 -61(2) . . . 3_666 ?
C17 C16 C15 O5 108.6(10) . . . . ?
C17 C16 C15 O6 -68.3(11) . . . . ?
C17 C16 C21 F21 178.3(7) . . . . ?
C17 C16 C21 C20 1.9(12) . . . . ?
C17 C18 C19 F19 -178.8(8) . . . . ?
C17 C18 C19 C20 2.2(14) . . . . ?
C1 C2 C3 F3 5.5(11) . . . . ?
C1 C2 C3 C4 -175.6(8) . . . . ?
C1 C2 C7 F7 -5.3(12) . . . . ?
C1 C2 C7 C6 175.1(8) . . . . ?
C27 N2 C31 C30 -3.3(12) . . . . ?
C27 C26 C25 C24 -176.9(8) . . . . ?
C27 C26 C25 C33 0.8(12) . . . . ?
C27 C28 C29 C30 -2.8(12) . . . . ?
C27 C28 C32 C33 1.3(13) . . . . ?
C8 C9 C14 F14 -2.5(12) . . . . ?
C8 C9 C14 C13 178.6(8) . . . . ?
C14 C9 C8 O3 -81.4(11) . . . . ?
C14 C9 C8 O4 100.7(10) . . . . ?
C14 C13 C12 F12 -179.7(8) . . . . ?
C14 C13 C12 C11 -0.9(14) . . . . ?
C7 C2 C3 F3 -178.5(7) . . . . ?
C7 C2 C3 C4 0.4(12) . . . . ?
C7 C2 C1 O1 73.1(11) . . . . ?
C7 C2 C1 O2 -104.0(10) . . . . ?
C7 C6 C5 F5 178.6(8) . . . . ?
C7 C6 C5 C4 1.8(14) . . . . ?
C13 C12 C11 F11 -179.1(8) . . . . ?
C13 C12 C11 C10 -0.7(14) . . . . ?
C31 N2 C27 C26 -175.6(8) . . . . ?
C31 N2 C27 C28 3.2(13) . . . . ?
C15 C16 C17 F17 -0.6(12) . . . . ?
C15 C16 C17 C18 -179.6(8) . . . . ?
C15 C16 C21 F21 -1.6(12) . . . . ?
C15 C16 C21 C20 -178.1(8) . . . . ?
C21 C16 C17 F17 179.4(7) . . . . ?
C21 C16 C17 C18 0.5(13) . . . . ?
C21 C16 C15 Eu1 119.2(18) . . . 3_666 ?
C21 C16 C15 O5 -71.5(11) . . . . ?
C21 C16 C15 O6 111.7(9) . . . . ?
C28 C29 C30 C31 2.6(13) . . . . ?
C28 C32 C33 C25 -2.1(13) . . . . ?
C18 C19 C20 F20 -179.1(8) . . . . ?
C18 C19 C20 C21 0.0(14) . . . . ?
C11 C10 C9 C8 179.8(8) . . . . ?
C11 C10 C9 C14 -2.1(13) . . . . ?
C29 C28 C32 C33 -176.6(8) . . . . ?
C22 N1 C26 C27 175.9(7) . . . . ?
C22 N1 C26 C25 -2.2(12) . . . . ?
C22 C23 C24 C25 -1.5(14) . . . . ?
C6 C5 C4 F4 177.6(8) . . . . ?
C6 C5 C4 C3 -2.2(14) . . . . ?
C32 C28 C29 C30 175.1(8) . . . . ?
C25 C26 C27 N2 177.2(8) . . . . ?
C25 C26 C27 C28 -1.6(12) . . . . ?
C24 C25 C33 C32 178.7(9) . . . . ?
C33 C25 C24 C23 -177.0(9) . . . . ?
