#------------------------------------------------------------------------------
#$Date: 2026-03-07 02:13:00 +0100 (Sat 07 de Mar de 2026) $
#$Revision: 304991 $
#$URL: svn://www.crystallography.net/cod/cif/7/72/05/7720598.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7720598
loop_
_publ_author_name
'Kopp, Richard Otto'
'Coles, Nathan'
'Ernst, Moritz J.'
'Weber, Manuela'
'Ward, Benjamin D.'
'Muller, Christian'
_publ_section_title
;
 Janus-faced coordination chemistry of pyridyl-functionalized phosphinines
 with Cu(I) and Au(I)
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D6DT00083E
_journal_year                    2026
_chemical_formula_moiety         'C21 H27 Cl Cu N2 P Si2, C2 H3 N'
_chemical_formula_sum            'C23 H30 Cl Cu N3 P Si2'
_chemical_formula_weight         534.64
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2025-11-03
_audit_creation_method
;
Olex2 1.5
(compiled 2025.07.13 svn.rb7424aed for OlexSys, GUI svn.r7314)
;
_audit_update_record
;
2025-11-14 deposited with the CCDC.	2026-03-02 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 94.5610(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.9412(3)
_cell_length_b                   20.8529(6)
_cell_length_c                   10.5592(3)
_cell_measurement_reflns_used    9841
_cell_measurement_temperature    150.00
_cell_measurement_theta_max      25.34
_cell_measurement_theta_min      2.66
_cell_volume                     2621.01(12)
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      150.00
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0442
_diffrn_reflns_av_unetI/netI     0.0253
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            40713
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.381
_diffrn_reflns_theta_min         2.167
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.103
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.5562
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1602 before and 0.0631 after correction.
The Ratio of minimum to maximum transmission is 0.7464.
The λ/2 correction factor is Not present.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.355
_exptl_crystal_description       needle
_exptl_crystal_F_000             1112
_exptl_crystal_size_max          0.415
_exptl_crystal_size_mid          0.072
_exptl_crystal_size_min          0.051
_refine_diff_density_max         0.290
_refine_diff_density_min         -0.297
_refine_diff_density_rms         0.048
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.117
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     287
_refine_ls_number_reflns         4801
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.117
_refine_ls_R_factor_all          0.0300
_refine_ls_R_factor_gt           0.0274
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0184P)²+2.1603P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0673
_refine_ls_wR_factor_ref         0.0687
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4477
_reflns_number_total             4801
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d6dt00083e3.cif
_cod_data_source_block           rok4482_mje
_cod_database_code               7720598
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.946
_shelx_estimated_absorpt_t_min   0.657
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C22(H22), C23(H23), C24(H24), C25(H25), C32(H32), C33(H33), C34(H34),
 C35(H35)
2.b Idealised Me refined as rotating group:
 C11(H11A,H11B,H11C), C12(H12A,H12B,H12C), C13(H13A,H13B,H13C), C41(H41A,H41B,
 H41C), C42(H42A,H42B,H42C), C43(H43A,H43B,H43C), C102(H10A,H10B,H10C)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.08033(2) 0.34669(2) 0.57776(2) 0.02245(8) Uani 1 1 d . . . . .
Cl1 Cl -0.09550(4) 0.37758(3) 0.52382(6) 0.03876(14) Uani 1 1 d . . . . .
P1 P 0.18129(4) 0.21381(2) 0.96457(5) 0.02176(11) Uani 1 1 d . . . . .
Si1 Si 0.02923(5) 0.33053(3) 0.99319(5) 0.02683(13) Uani 1 1 d . . . . .
Si2 Si 0.31826(5) 0.09630(3) 0.88287(6) 0.02756(13) Uani 1 1 d . . . . .
N1 N 0.13973(13) 0.40747(7) 0.71848(15) 0.0214(3) Uani 1 1 d . . . . .
N2 N 0.54359(15) 0.18489(9) 0.87185(17) 0.0320(4) Uani 1 1 d . . . . .
C1 C 0.15961(16) 0.29442(9) 0.92793(18) 0.0212(4) Uani 1 1 d . . . . .
C2 C 0.23423(16) 0.32505(9) 0.85130(17) 0.0211(4) Uani 1 1 d . . . . .
C3 C 0.32997(16) 0.29634(9) 0.80979(18) 0.0234(4) Uani 1 1 d . . . . .
H3 H 0.378087 0.322611 0.764506 0.028 Uiso 1 1 calc R U . . .
C4 C 0.36167(16) 0.23228(9) 0.82878(18) 0.0232(4) Uani 1 1 d . . . . .
C5 C 0.29669(16) 0.18715(9) 0.89040(18) 0.0227(4) Uani 1 1 d . . . . .
C11 C -0.0974(2) 0.30335(17) 0.8947(3) 0.0558(8) Uani 1 1 d . . . . .
H11A H -0.101860 0.256445 0.897127 0.084 Uiso 1 1 calc R U . . .
H11B H -0.092701 0.317515 0.806748 0.084 Uiso 1 1 calc R U . . .
H11C H -0.164646 0.321732 0.928038 0.084 Uiso 1 1 calc R U . . .
C12 C 0.0234(2) 0.29997(11) 1.1576(2) 0.0348(5) Uani 1 1 d . . . . .
H12A H -0.024739 0.327984 1.204285 0.052 Uiso 1 1 calc R U . . .
H12B H 0.099306 0.299395 1.200336 0.052 Uiso 1 1 calc R U . . .
H12C H -0.007404 0.256390 1.154874 0.052 Uiso 1 1 calc R U . . .
C13 C 0.0318(3) 0.41961(12) 1.0006(3) 0.0680(10) Uani 1 1 d . . . . .
H13A H -0.030604 0.434783 1.047659 0.102 Uiso 1 1 calc R U . . .
H13B H 0.024129 0.437138 0.914229 0.102 Uiso 1 1 calc R U . . .
H13C H 0.103092 0.433873 1.043823 0.102 Uiso 1 1 calc R U . . .
C21 C 0.21786(16) 0.39417(9) 0.81402(18) 0.0214(4) Uani 1 1 d . . . . .
C22 C 0.28368(19) 0.44152(10) 0.8744(2) 0.0297(5) Uani 1 1 d . . . . .
H22 H 0.340576 0.430548 0.938739 0.036 Uiso 1 1 calc R U . . .
C23 C 0.2657(2) 0.50511(10) 0.8399(2) 0.0336(5) Uani 1 1 d . . . . .
H23 H 0.310361 0.538220 0.879836 0.040 Uiso 1 1 calc R U . . .
C24 C 0.18230(19) 0.51936(9) 0.7472(2) 0.0298(5) Uani 1 1 d . . . . .
H24 H 0.166613 0.562631 0.723893 0.036 Uiso 1 1 calc R U . . .
C25 C 0.12168(18) 0.47001(9) 0.68840(19) 0.0261(4) Uani 1 1 d . . . . .
H25 H 0.064565 0.480278 0.623784 0.031 Uiso 1 1 calc R U . . .
C31 C 0.47336(17) 0.21405(9) 0.78479(19) 0.0249(4) Uani 1 1 d . . . . .
C32 C 0.5029(2) 0.22880(11) 0.6639(2) 0.0368(5) Uani 1 1 d . . . . .
H32 H 0.450845 0.249535 0.604690 0.044 Uiso 1 1 calc R U . . .
C33 C 0.6089(2) 0.21295(12) 0.6308(3) 0.0441(6) Uani 1 1 d . . . . .
H33 H 0.630749 0.221917 0.548064 0.053 Uiso 1 1 calc R U . . .
C34 C 0.6822(2) 0.18391(12) 0.7201(3) 0.0423(6) Uani 1 1 d . . . . .
H34 H 0.756214 0.173149 0.700720 0.051 Uiso 1 1 calc R U . . .
C35 C 0.6465(2) 0.17074(12) 0.8377(2) 0.0388(5) Uani 1 1 d . . . . .
H35 H 0.697750 0.150421 0.898487 0.047 Uiso 1 1 calc R U . . .
C41 C 0.3914(2) 0.06623(11) 1.0328(2) 0.0392(5) Uani 1 1 d . . . . .
H41A H 0.394027 0.019270 1.030849 0.059 Uiso 1 1 calc R U . . .
H41B H 0.350727 0.080261 1.104928 0.059 Uiso 1 1 calc R U . . .
H41C H 0.468111 0.083274 1.041837 0.059 Uiso 1 1 calc R U . . .
C42 C 0.3936(3) 0.07281(12) 0.7415(3) 0.0511(7) Uani 1 1 d . . . . .
H42A H 0.474609 0.078768 0.760514 0.077 Uiso 1 1 calc R U . . .
H42B H 0.367659 0.099657 0.668845 0.077 Uiso 1 1 calc R U . . .
H42C H 0.378075 0.027679 0.721036 0.077 Uiso 1 1 calc R U . . .
C43 C 0.1762(2) 0.05813(10) 0.8583(2) 0.0384(5) Uani 1 1 d . . . . .
H43A H 0.183708 0.011490 0.866702 0.058 Uiso 1 1 calc R U . . .
H43B H 0.142411 0.068664 0.773243 0.058 Uiso 1 1 calc R U . . .
H43C H 0.128021 0.074256 0.922231 0.058 Uiso 1 1 calc R U . . .
N11 N 0.5782(3) 0.09942(16) 0.4051(3) 0.0827(9) Uani 1 1 d . . . . .
C101 C 0.6191(3) 0.10885(15) 0.3134(4) 0.0582(8) Uani 1 1 d . . . . .
C102 C 0.6701(3) 0.1204(2) 0.1954(4) 0.0816(11) Uani 1 1 d . . . . .
H10A H 0.615160 0.140740 0.134271 0.122 Uiso 1 1 calc R U . . .
H10B H 0.694316 0.079491 0.160793 0.122 Uiso 1 1 calc R U . . .
H10C H 0.735247 0.148619 0.211417 0.122 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0.00 -1.00 -3.00 0.2010
3.00 -3.00 -2.00 0.1260
-2.00 -3.00 0.00 0.0190
1.00 2.00 0.00 0.0190
1.00 3.00 0.00 0.0160
-1.00 2.00 0.00 0.0070
1.00 -2.00 0.00 0.0340
2.00 1.00 0.00 0.0320
-3.00 -1.00 0.00 0.0130
-3.00 3.00 2.00 0.0960
0.00 1.00 3.00 0.1590
-1.00 -1.00 3.00 0.1580
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Cu1 Cl1 125.56(2) 4_565 . ?
N1 Cu1 Cl1 105.85(5) . . ?
N1 Cu1 P1 125.97(5) . 4_565 ?
C1 P1 Cu1 127.24(7) . 4_566 ?
C5 P1 Cu1 124.08(7) . 4_566 ?
C5 P1 C1 108.64(9) . . ?
C11 Si1 C1 109.23(10) . . ?
C11 Si1 C12 109.28(13) . . ?
C11 Si1 C13 109.80(17) . . ?
C12 Si1 C1 107.14(10) . . ?
C12 Si1 C13 107.78(12) . . ?
C13 Si1 C1 113.50(12) . . ?
C41 Si2 C5 110.78(10) . . ?
C41 Si2 C42 111.66(13) . . ?
C41 Si2 C43 109.52(11) . . ?
C42 Si2 C5 111.57(10) . . ?
C42 Si2 C43 105.46(12) . . ?
C43 Si2 C5 107.63(10) . . ?
C21 N1 Cu1 126.75(12) . . ?
C21 N1 C25 117.47(16) . . ?
C25 N1 Cu1 112.84(13) . . ?
C31 N2 C35 116.91(19) . . ?
P1 C1 Si1 114.37(11) . . ?
C2 C1 P1 118.54(14) . . ?
C2 C1 Si1 127.04(14) . . ?
C1 C2 C21 120.80(17) . . ?
C3 C2 C1 124.10(17) . . ?
C3 C2 C21 115.02(17) . . ?
C2 C3 H3 117.1 . . ?
C2 C3 C4 125.83(18) . . ?
C4 C3 H3 117.1 . . ?
C3 C4 C5 123.41(18) . . ?
C3 C4 C31 115.85(17) . . ?
C5 C4 C31 120.67(17) . . ?
P1 C5 Si2 116.84(11) . . ?
C4 C5 P1 118.77(14) . . ?
C4 C5 Si2 124.06(15) . . ?
Si1 C11 H11A 109.5 . . ?
Si1 C11 H11B 109.5 . . ?
Si1 C11 H11C 109.5 . . ?
H11A C11 H11B 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si1 C12 H12A 109.5 . . ?
Si1 C12 H12B 109.5 . . ?
Si1 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
Si1 C13 H13A 109.5 . . ?
Si1 C13 H13B 109.5 . . ?
Si1 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
N1 C21 C2 117.48(16) . . ?
N1 C21 C22 122.10(17) . . ?
C22 C21 C2 120.39(17) . . ?
C21 C22 H22 120.3 . . ?
C21 C22 C23 119.4(2) . . ?
C23 C22 H22 120.3 . . ?
C22 C23 H23 120.6 . . ?
C24 C23 C22 118.82(19) . . ?
C24 C23 H23 120.6 . . ?
C23 C24 H24 120.5 . . ?
C23 C24 C25 119.04(19) . . ?
C25 C24 H24 120.5 . . ?
N1 C25 C24 123.04(19) . . ?
N1 C25 H25 118.5 . . ?
C24 C25 H25 118.5 . . ?
N2 C31 C4 115.29(18) . . ?
N2 C31 C32 122.79(19) . . ?
C32 C31 C4 121.87(18) . . ?
C31 C32 H32 120.5 . . ?
C33 C32 C31 119.1(2) . . ?
C33 C32 H32 120.5 . . ?
C32 C33 H33 120.7 . . ?
C34 C33 C32 118.6(2) . . ?
C34 C33 H33 120.7 . . ?
C33 C34 H34 120.6 . . ?
C35 C34 C33 118.9(2) . . ?
C35 C34 H34 120.6 . . ?
N2 C35 C34 123.8(2) . . ?
N2 C35 H35 118.1 . . ?
C34 C35 H35 118.1 . . ?
Si2 C41 H41A 109.5 . . ?
Si2 C41 H41B 109.5 . . ?
Si2 C41 H41C 109.5 . . ?
H41A C41 H41B 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
Si2 C42 H42A 109.5 . . ?
Si2 C42 H42B 109.5 . . ?
Si2 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
Si2 C43 H43A 109.5 . . ?
Si2 C43 H43B 109.5 . . ?
Si2 C43 H43C 109.5 . . ?
H43A C43 H43B 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
N11 C101 C102 179.2(4) . . ?
C101 C102 H10A 109.5 . . ?
C101 C102 H10B 109.5 . . ?
C101 C102 H10C 109.5 . . ?
H10A C102 H10B 109.5 . . ?
H10A C102 H10C 109.5 . . ?
H10B C102 H10C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 Cl1 2.2266(6) . ?
Cu1 P1 2.1685(5) 4_565 ?
Cu1 N1 2.0371(16) . ?
P1 C1 1.7396(18) . ?
P1 C5 1.730(2) . ?
Si1 C1 1.907(2) . ?
Si1 C11 1.855(3) . ?
Si1 C12 1.855(2) . ?
Si1 C13 1.859(3) . ?
Si2 C5 1.9143(19) . ?
Si2 C41 1.856(2) . ?
Si2 C42 1.868(2) . ?
Si2 C43 1.874(2) . ?
N1 C21 1.347(2) . ?
N1 C25 1.355(2) . ?
N2 C31 1.340(3) . ?
N2 C35 1.341(3) . ?
C1 C2 1.404(3) . ?
C2 C3 1.392(3) . ?
C2 C21 1.503(3) . ?
C3 H3 0.9500 . ?
C3 C4 1.399(3) . ?
C4 C5 1.411(3) . ?
C4 C31 1.496(3) . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C21 C22 1.385(3) . ?
C22 H22 0.9500 . ?
C22 C23 1.387(3) . ?
C23 H23 0.9500 . ?
C23 C24 1.373(3) . ?
C24 H24 0.9500 . ?
C24 C25 1.377(3) . ?
C25 H25 0.9500 . ?
C31 C32 1.385(3) . ?
C32 H32 0.9500 . ?
C32 C33 1.380(3) . ?
C33 H33 0.9500 . ?
C33 C34 1.375(4) . ?
C34 H34 0.9500 . ?
C34 C35 1.372(4) . ?
C35 H35 0.9500 . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 H41C 0.9800 . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
N11 C101 1.137(4) . ?
C101 C102 1.449(5) . ?
C102 H10A 0.9800 . ?
C102 H10B 0.9800 . ?
C102 H10C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cu1 P1 C1 Si1 -1.78(14) 4_566 . . . ?
Cu1 P1 C1 C2 -179.18(11) 4_566 . . . ?
Cu1 P1 C5 Si2 11.90(14) 4_566 . . . ?
Cu1 P1 C5 C4 -174.40(12) 4_566 . . . ?
Cu1 N1 C21 C2 -23.6(2) . . . . ?
Cu1 N1 C21 C22 154.56(16) . . . . ?
Cu1 N1 C25 C24 -159.17(17) . . . . ?
P1 C1 C2 C3 -4.9(3) . . . . ?
P1 C1 C2 C21 178.48(14) . . . . ?
Si1 C1 C2 C3 178.07(15) . . . . ?
Si1 C1 C2 C21 1.5(3) . . . . ?
N1 C21 C22 C23 3.0(3) . . . . ?
N2 C31 C32 C33 0.0(4) . . . . ?
C1 P1 C5 Si2 -166.12(10) . . . . ?
C1 P1 C5 C4 7.59(18) . . . . ?
C1 C2 C3 C4 5.3(3) . . . . ?
C1 C2 C21 N1 -79.1(2) . . . . ?
C1 C2 C21 C22 102.7(2) . . . . ?
C2 C3 C4 C5 2.2(3) . . . . ?
C2 C3 C4 C31 -174.97(18) . . . . ?
C2 C21 C22 C23 -178.9(2) . . . . ?
C3 C2 C21 N1 104.0(2) . . . . ?
C3 C2 C21 C22 -74.2(2) . . . . ?
C3 C4 C5 P1 -8.6(3) . . . . ?
C3 C4 C5 Si2 164.58(15) . . . . ?
C3 C4 C31 N2 127.3(2) . . . . ?
C3 C4 C31 C32 -50.3(3) . . . . ?
C4 C31 C32 C33 177.4(2) . . . . ?
C5 P1 C1 Si1 176.15(10) . . . . ?
C5 P1 C1 C2 -1.25(18) . . . . ?
C5 C4 C31 N2 -50.0(3) . . . . ?
C5 C4 C31 C32 132.4(2) . . . . ?
C21 N1 C25 C24 2.7(3) . . . . ?
C21 C2 C3 C4 -177.86(18) . . . . ?
C21 C22 C23 C24 0.4(3) . . . . ?
C22 C23 C24 C25 -2.1(3) . . . . ?
C23 C24 C25 N1 0.6(3) . . . . ?
C25 N1 C21 C2 177.31(17) . . . . ?
C25 N1 C21 C22 -4.5(3) . . . . ?
C31 N2 C35 C34 -0.6(4) . . . . ?
C31 C4 C5 P1 168.45(15) . . . . ?
C31 C4 C5 Si2 -18.3(3) . . . . ?
C31 C32 C33 C34 -1.0(4) . . . . ?
C32 C33 C34 C35 1.2(4) . . . . ?
C33 C34 C35 N2 -0.4(4) . . . . ?
C35 N2 C31 C4 -176.77(19) . . . . ?
C35 N2 C31 C32 0.8(3) . . . . ?
