#------------------------------------------------------------------------------
#$Date: 2026-03-28 01:07:07 +0100 (Sat 28 de Mar de 2026) $
#$Revision: 305203 $
#$URL: svn://www.crystallography.net/cod/cif/7/72/07/7720762.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7720762
loop_
_publ_author_name
'Yang, Yue'
'Shao, Xueying'
'Pan, Jian-Xu'
'Dong, Xiaofang'
'Wang, Shen'
'Liang, Yulu'
'Zhang, Yi-Quan'
'Wang, Yu-Xia'
'Cheng, Peng'
_publ_section_title
;
 Programming magnetization dynamics in a Dy-croconic acid system
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D6DT00588H
_journal_year                    2026
_chemical_formula_moiety         'C41 H72 Dy O10 P2, C18 H33 O P, Cl, 3(H2 O)'
_chemical_formula_sum            'C59 H111 Cl Dy O14 P3'
_chemical_formula_weight         1335.33
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_audit_creation_date             2025-11-12
_audit_creation_method
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_audit_update_record
;
2025-11-13 deposited with the CCDC.	2026-03-27 downloaded from the CCDC.
;
_cell_angle_alpha                107.052(2)
_cell_angle_beta                 94.261(2)
_cell_angle_gamma                117.435(3)
_cell_formula_units_Z            2
_cell_length_a                   15.2125(4)
_cell_length_b                   15.5239(4)
_cell_length_c                   16.9589(5)
_cell_measurement_reflns_used    25209
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      74.4380
_cell_measurement_theta_min      2.8100
_cell_volume                     3293.2(2)
_computing_cell_refinement       'CrysAlisPro 1.171.41.122a (Rigaku OD, 2021)'
_computing_data_collection       'CrysAlisPro 1.171.41.122a (Rigaku OD, 2021)'
_computing_data_reduction        'CrysAlisPro 1.171.41.122a (Rigaku OD, 2021)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            'HyPix-Arc 150'
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.944
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     64.00 106.00   0.50    0.05    --   55.73  30.00 -90.00   84
  2  ω     64.00  90.00   0.50    0.05    --   55.73  45.00 -30.00   52
  3  ω     96.00 121.00   0.50    0.05    --   87.28  30.00   0.00   50
  4  ω     85.00 111.00   0.50    0.05    --   55.73  30.00  30.00   52
  5  ω     66.00 100.00   0.50    0.05    --   55.73  45.00 150.00   68
  6  ω     42.00  93.00   0.50    0.05    --   87.28 -95.00 -30.00  102
  7  ω     50.00  93.00   0.50    0.05    --   87.28 -95.00  30.00   86
  8  ω     38.00  93.00   0.50    0.05    --   83.67 -98.00 103.76  110
  9  ω     59.00  93.00   0.50    0.05    --   87.28 -95.00   0.00   68
 10  ω     39.00  96.00   0.50    0.05    --   87.28-112.00 -60.00  114
 11  ω     57.00  93.00   0.50    0.05    --   87.28 -95.00 -60.00   72
 12  ω     43.00  68.00   0.50    0.05    --   87.28 -95.00-150.00   50
 13  ω     20.00  61.00   0.50    0.05    --   66.80 -95.00 -60.00   82
 14  ω     44.00  69.00   0.50    0.05    --   87.28 -95.00 150.00   50
 15  ω     95.00 134.00   0.50    0.05    --   87.28 112.00  30.00   78
 16  ω     95.00 140.00   0.50    0.05    --   87.28 112.00 -30.00   90
 17  ω    107.00 140.00   0.50    0.05    --   87.28 112.00 -60.00   66
 18  ω     95.00 120.00   0.50    0.05    --   87.28 112.00-120.00   50
 19  ω     97.00 139.00   0.50    0.05    --   87.28 112.00-180.00   84
 20  ω     96.00 121.00   0.50    0.05    --   87.28 112.00 -90.00   50
 21  ω    100.00 131.00   0.50    0.05    --   87.28 112.00 120.00   62
 22  ω    -32.00  -3.00   0.50    0.05    --  -56.42  45.00 120.00   58
 23  ω    -32.00  -7.00   0.50    0.05    --  -56.42  45.00 150.00   50
 24  ω    -32.00  -4.00   0.50    0.05    --  -56.42  45.00  90.00   56
 25  ω    -29.00  -3.00   0.50    0.05    --  -56.42  45.00  30.00   52
 26  ω    -70.00 -26.00   0.50    0.05    --  -77.48 112.00 -30.00   88
 27  ω    -96.00 -28.00   0.50    0.05    --  -77.48 112.00-150.00  136
 28  ω    -97.00 -71.00   0.50    0.05    --  -82.00 112.00 -90.00   52
 29  ω    -97.00 -54.00   0.50    0.05    --  -82.00 112.00-180.00   86
 30  ω    -69.00 -25.00   0.50    0.05    --  -77.48 112.00  30.00   88
 31  ω    -94.00 -46.00   0.50    0.05    --  -82.00 103.00 -31.79   96
 32  ω    -96.00 -28.00   0.50    0.05    --  -77.48 112.00  90.00  136
 33  ω    -97.00 -69.00   0.50    0.05    --  -82.00 112.00  60.00   56
 34  ω    -97.00 -72.00   0.50    0.05    --  -82.00 112.00 120.00   50
 35  ω    -94.00 -34.00   0.50    0.05    --  -82.00 101.00 159.85  120
 36  ω   -134.00-102.00   0.50    0.05    --  -82.00 -30.00  90.00   64
 37  ω   -135.00 -92.00   0.50    0.05    --  -82.00 -45.00 150.00   86
 38  ω   -124.00 -90.00   0.50    0.05    --  -82.00 -45.00  30.00   68
 39  ω   -129.00 -87.00   0.50    0.05    --  -77.48 -45.00 -60.00   84
 40  ω   -110.00 -65.00   0.50    0.05    --  -56.42 -45.00 -60.00   90
 41  ω   -130.00 -81.00   0.50    0.05    --  -77.48 -30.00-120.00   98
 42  ω   -133.00 -81.00   0.50    0.05    --  -77.48 -30.00-180.00  104
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'ROD, Synergy Custom system, HyPix-Arc 150'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0559735000
_diffrn_orient_matrix_UB_12      0.0002519000
_diffrn_orient_matrix_UB_13      0.0720583000
_diffrn_orient_matrix_UB_21      -0.0658324000
_diffrn_orient_matrix_UB_22      -0.1200221000
_diffrn_orient_matrix_UB_23      -0.0401752000
_diffrn_orient_matrix_UB_31      0.0799797000
_diffrn_orient_matrix_UB_32      -0.0089393000
_diffrn_orient_matrix_UB_33      0.0529869000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0456
_diffrn_reflns_av_unetI/netI     0.0464
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.944
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            40438
_diffrn_reflns_point_group_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.944
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         74.696
_diffrn_reflns_theta_min         2.812
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    7.604
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.65377
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.122a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear light yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.347
_exptl_crystal_description       block
_exptl_crystal_F_000             1410
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.11
_refine_diff_density_max         1.863
_refine_diff_density_min         -1.831
_refine_diff_density_rms         0.089
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     738
_refine_ls_number_reflns         12738
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.029
_refine_ls_R_factor_all          0.0522
_refine_ls_R_factor_gt           0.0458
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0662P)²+4.6017P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1187
_refine_ls_wR_factor_ref         0.1227
_reflns_Friedel_coverage         0.000
_reflns_number_gt                11354
_reflns_number_total             12738
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d6dt00588h2.cif
_cod_data_source_block           DyCA
_cod_original_cell_volume        3293.17(18)
_cod_database_code               7720762
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 99.32
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Restrained distances
 Dy1-H2a \\sim Dy1-H2b
 with sigma of 0.02
3. Others
 1*[Sof(O14A)+Sof(H14e)+Sof(H14f)]+1*[Sof(O14B)+Sof(H14c)+Sof(H14d)]+1*
 [Sof(O13)+Sof(H13c)+Sof(H13d)]=1 with esd of 0.0001
 Sof(O14A)=Sof(H14e)=Sof(H14f)=FVAR(1)
 Sof(O14B)=Sof(H14c)=Sof(H14d)=FVAR(2)
 Sof(O13)=Sof(H13c)=Sof(H13d)=FVAR(3)
4.a Riding coordinates:
 O12(H12c,H12d), O14B(H14c,H14d)
4.b Free rotating group:
 O2(H2a,H2b), O11(H11c,H11d), O14A(H14e,H14f), O13(H13c,H13d)
4.c Rotating group:
 O3(H3a,H3b), O1(H1a,H1b)
4.d Ternary CH refined with riding coordinates:
 C42(H42), C17(H17), C48(H48), C36(H36), C54(H54), C6(H6), C18(H18), C24(H24),
 C30(H30)
4.e Secondary CH2 refined with riding coordinates:
 C43(H43a,H43b), C55(H55a,H55b), C7(H7a,H7b), C59(H59a,H59b), C47(H47a,H47b),
 C56(H56a,H56b), C19(H19a,H19b), C25(H25a,H25b), C57(H57a,H57b), C41(H41a,H41b),
  C49(H49a,H49b), C12(H12a,H12b), C29(H29a,H29b), C23(H23a,H23b), C44(H44a,
 H44b), C16(H16a,H16b), C15(H15a,H15b), C11(H11a,H11b), C46(H46a,H46b),
 C58(H58a,H58b), C8(H8a,H8b), C39(H39a,H39b), C27(H27a,H27b), C40(H40a,H40b),
 C31(H31a,H31b), C22(H22a,H22b), C28(H28a,H28b), C10(H10a,H10b), C9(H9a,H9b),
 C14(H14a,H14b), C13(H13a,H13b), C26(H26a,H26b), C20(H20a,H20b), C53(H53a,H53b),
  C52(H52a,H52b), C21(H21a,H21b), C32(H32a,H32b), C45(H45a,H45b), C50(H50a,
 H50b), C37(H37a,H37b), C34(H34a,H34b), C51(H51a,H51b), C38(H38a,H38b),
 C35(H35a,H35b), C33(H33a,H33b)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.440
_oxdiff_exptl_absorpt_empirical_full_min 0.621
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.53867(2) 0.52927(2) 0.25879(2) 0.02216(8) Uani 1 1 d D . . . .
P1 P 0.66571(7) 0.81976(6) 0.36311(5) 0.02210(19) Uani 1 1 d . . . . .
P2 P 0.41382(7) 0.24003(6) 0.15866(5) 0.02150(18) Uani 1 1 d . . . . .
P3 P 0.92076(7) 0.56333(7) 0.24716(6) 0.0259(2) Uani 1 1 d . . . . .
Cl1 Cl 0.58494(9) 0.68149(8) 0.55869(6) 0.0434(3) Uani 1 1 d . . . . .
O3 O 0.6557(2) 0.54733(19) 0.17350(16) 0.0294(6) Uani 1 1 d . . . . .
H3A H 0.714713 0.559756 0.199013 0.044 Uiso 1 1 d R U . . .
H3B H 0.672444 0.581058 0.138734 0.044 Uiso 1 1 d R U . . .
O2 O 0.6736(2) 0.5266(2) 0.33228(16) 0.0282(6) Uani 1 1 d G . . . .
H2A H 0.728096 0.531959 0.315316 0.042 Uiso 1 1 d DG U . . .
H2B H 0.691506 0.545691 0.388766 0.042 Uiso 1 1 d DG U . . .
O9 O 0.6204(2) 0.70248(18) 0.32689(16) 0.0254(5) Uani 1 1 d . . . . .
O5 O 0.3785(2) 0.5205(2) 0.26673(16) 0.0307(6) Uani 1 1 d . . . . .
O10 O 0.46016(19) 0.35700(18) 0.19383(15) 0.0240(5) Uani 1 1 d . . . . .
O4 O 0.4611(2) 0.5279(2) 0.12956(17) 0.0309(6) Uani 1 1 d . . . . .
O15 O 0.8143(2) 0.5465(2) 0.24572(18) 0.0335(6) Uani 1 1 d . . . . .
O1 O 0.4979(2) 0.5066(2) 0.38482(18) 0.0355(6) Uani 1 1 d . . . . .
H1A H 0.543404 0.561224 0.428741 0.053 Uiso 1 1 d R U . . .
H1B H 0.503970 0.455034 0.389600 0.053 Uiso 1 1 d R U . . .
O8 O 0.3031(3) 0.4868(3) -0.01615(19) 0.0516(9) Uani 1 1 d . . . . .
O6 O 0.1644(2) 0.4808(3) 0.2250(2) 0.0421(7) Uani 1 1 d . . . . .
O7 O 0.1220(3) 0.4643(3) 0.0471(2) 0.0504(8) Uani 1 1 d . . . . .
O12 O 0.7325(3) 0.5888(3) 0.50336(19) 0.0482(8) Uani 1 1 d . . . . .
H12C H 0.702633 0.620557 0.526106 0.072 Uiso 1 1 d R U . . .
H12D H 0.718963 0.539327 0.522956 0.072 Uiso 1 1 d R U . . .
C42 C 0.4567(3) 0.2032(3) 0.2396(2) 0.0252(7) Uani 1 1 d . . . . .
H42 H 0.448051 0.243306 0.293537 0.030 Uiso 1 1 calc R U . . .
C43 C 0.5712(3) 0.2407(3) 0.2567(2) 0.0291(8) Uani 1 1 d . . . . .
H43A H 0.584999 0.200004 0.207379 0.035 Uiso 1 1 calc R U . . .
H43B H 0.610176 0.315200 0.263606 0.035 Uiso 1 1 calc R U . . .
C17 C 0.7350(3) 0.8713(3) 0.4730(2) 0.0245(7) Uani 1 1 d . . . . .
H17 H 0.684195 0.835786 0.503384 0.029 Uiso 1 1 calc R U . . .
C48 C 0.2758(3) 0.1776(3) 0.1375(2) 0.0274(8) Uani 1 1 d . . . . .
H48 H 0.246766 0.100277 0.116882 0.033 Uiso 1 1 calc R U . . .
C36 C 0.9182(3) 0.4396(3) 0.2128(2) 0.0274(8) Uani 1 1 d . . . . .
H36 H 0.989769 0.453681 0.226297 0.033 Uiso 1 1 calc R U . . .
C54 C 0.4481(3) 0.2028(3) 0.0587(2) 0.0251(8) Uani 1 1 d . . . . .
H54 H 0.408529 0.214283 0.017103 0.030 Uiso 1 1 calc R U . . .
C6 C 0.5643(3) 0.8501(3) 0.3586(2) 0.0286(8) Uani 1 1 d . . . . .
H6 H 0.595824 0.926314 0.369463 0.034 Uiso 1 1 calc R U . . .
C55 C 0.5620(3) 0.2739(3) 0.0635(2) 0.0282(8) Uani 1 1 d . . . . .
H55A H 0.579844 0.347892 0.085709 0.034 Uiso 1 1 calc R U . . .
H55B H 0.605267 0.264721 0.103074 0.034 Uiso 1 1 calc R U . . .
O11 O 0.5746(3) 0.6419(3) 0.0289(3) 0.0625(10) Uani 1 1 d G . . . .
H11C H 0.553151 0.618786 0.068638 0.094 Uiso 1 1 d G U . . .
H11D H 0.550386 0.585842 -0.016663 0.094 Uiso 1 1 d G U . . .
C7 C 0.4923(3) 0.7886(3) 0.2689(3) 0.0315(9) Uani 1 1 d . . . . .
H7A H 0.531248 0.809724 0.227142 0.038 Uiso 1 1 calc R U . . .
H7B H 0.466145 0.713092 0.254747 0.038 Uiso 1 1 calc R U . . .
C18 C 0.7554(3) 0.8815(3) 0.3037(2) 0.0274(8) Uani 1 1 d . . . . .
H18 H 0.823613 0.897859 0.333365 0.033 Uiso 1 1 calc R U . . .
C59 C 0.4160(3) 0.0864(3) 0.0199(2) 0.0289(8) Uani 1 1 d . . . . .
H59A H 0.452859 0.070200 0.058594 0.035 Uiso 1 1 calc R U . . .
H59B H 0.341818 0.042592 0.013603 0.035 Uiso 1 1 calc R U . . .
C47 C 0.3939(3) 0.0879(3) 0.2305(3) 0.0312(8) Uani 1 1 d . . . . .
H47A H 0.320387 0.065527 0.221619 0.037 Uiso 1 1 calc R U . . .
H47B H 0.402975 0.043016 0.180637 0.037 Uiso 1 1 calc R U . . .
C56 C 0.5831(3) 0.2466(3) -0.0248(2) 0.0289(8) Uani 1 1 d . . . . .
H56A H 0.543920 0.261123 -0.063154 0.035 Uiso 1 1 calc R U . . .
H56B H 0.656676 0.290992 -0.020386 0.035 Uiso 1 1 calc R U . . .
C19 C 0.7694(3) 0.9859(3) 0.3036(3) 0.0323(9) Uani 1 1 d . . . . .
H19A H 0.704519 0.974306 0.273001 0.039 Uiso 1 1 calc R U . . .
H19B H 0.786890 1.034392 0.362881 0.039 Uiso 1 1 calc R U . . .
C1 C 0.3692(3) 0.5117(3) 0.1261(2) 0.0294(8) Uani 1 1 d . . . . .
C25 C 0.9638(3) 0.7263(3) 0.1913(3) 0.0327(9) Uani 1 1 d . . . . .
H25A H 0.890171 0.703576 0.180251 0.039 Uiso 1 1 calc R U . . .
H25B H 0.996321 0.774690 0.251359 0.039 Uiso 1 1 calc R U . . .
C57 C 0.5527(3) 0.1317(3) -0.0621(2) 0.0327(9) Uani 1 1 d . . . . .
H57A H 0.595788 0.118556 -0.026186 0.039 Uiso 1 1 calc R U . . .
H57B H 0.564531 0.115112 -0.119869 0.039 Uiso 1 1 calc R U . . .
C5 C 0.2951(3) 0.4926(3) 0.0543(3) 0.0358(9) Uani 1 1 d . . . . .
C41 C 0.8556(4) 0.3731(3) 0.2613(3) 0.0353(9) Uani 1 1 d . . . . .
H41A H 0.887403 0.410879 0.323137 0.042 Uiso 1 1 calc R U . . .
H41B H 0.785627 0.362071 0.250888 0.042 Uiso 1 1 calc R U . . .
C49 C 0.2322(3) 0.2027(4) 0.0681(3) 0.0364(9) Uani 1 1 d . . . . .
H49A H 0.263906 0.279383 0.085645 0.044 Uiso 1 1 calc R U . . .
H49B H 0.249777 0.176547 0.014528 0.044 Uiso 1 1 calc R U . . .
C12 C 0.7781(3) 0.9894(3) 0.5187(2) 0.0328(9) Uani 1 1 d . . . . .
H12A H 0.830943 1.028874 0.492435 0.039 Uiso 1 1 calc R U . . .
H12B H 0.722655 1.005564 0.512824 0.039 Uiso 1 1 calc R U . . .
C3 C 0.2231(3) 0.4887(3) 0.1777(3) 0.0323(9) Uani 1 1 d . . . . .
C29 C 1.0872(3) 0.6574(3) 0.1813(3) 0.0342(9) Uani 1 1 d . . . . .
H29A H 1.090413 0.592464 0.165908 0.041 Uiso 1 1 calc R U . . .
H29B H 1.128909 0.702855 0.240281 0.041 Uiso 1 1 calc R U . . .
C23 C 0.7325(4) 0.8067(3) 0.2135(3) 0.0358(9) Uani 1 1 d . . . . .
H23A H 0.666506 0.789410 0.180031 0.043 Uiso 1 1 calc R U . . .
H23B H 0.726819 0.741100 0.215019 0.043 Uiso 1 1 calc R U . . .
C44 C 0.6066(3) 0.2277(3) 0.3369(3) 0.0346(9) Uani 1 1 d . . . . .
H44A H 0.598214 0.272937 0.387009 0.042 Uiso 1 1 calc R U . . .
H44B H 0.679926 0.249376 0.345589 0.042 Uiso 1 1 calc R U . . .
C16 C 0.8182(3) 0.8438(3) 0.4835(3) 0.0341(9) Uani 1 1 d . . . . .
H16A H 0.871481 0.878310 0.455273 0.041 Uiso 1 1 calc R U . . .
H16B H 0.788414 0.767353 0.455853 0.041 Uiso 1 1 calc R U . . .
C2 C 0.3278(3) 0.5081(3) 0.1975(2) 0.0282(8) Uani 1 1 d . . . . .
C24 C 0.9766(3) 0.6307(3) 0.1767(2) 0.0284(8) Uani 1 1 d . . . . .
H24 H 0.936642 0.580941 0.117360 0.034 Uiso 1 1 calc R U . . .
C15 C 0.8664(4) 0.8794(4) 0.5780(3) 0.0400(10) Uani 1 1 d . . . . .
H15A H 0.814549 0.839102 0.604610 0.048 Uiso 1 1 calc R U . . .
H15B H 0.922859 0.864652 0.583718 0.048 Uiso 1 1 calc R U . . .
C11 C 0.5054(3) 0.8276(4) 0.4261(3) 0.0389(10) Uani 1 1 d . . . . .
H11A H 0.552342 0.871432 0.483482 0.047 Uiso 1 1 calc R U . . .
H11B H 0.477220 0.753378 0.418993 0.047 Uiso 1 1 calc R U . . .
C46 C 0.4304(3) 0.0765(3) 0.3117(3) 0.0362(9) Uani 1 1 d . . . . .
H46A H 0.416960 0.118019 0.360667 0.043 Uiso 1 1 calc R U . . .
H46B H 0.391453 0.002370 0.305664 0.043 Uiso 1 1 calc R U . . .
C58 C 0.4401(3) 0.0610(3) -0.0668(2) 0.0343(9) Uani 1 1 d . . . . .
H58A H 0.396962 0.069294 -0.107222 0.041 Uiso 1 1 calc R U . . .
H58B H 0.423205 -0.012777 -0.088824 0.041 Uiso 1 1 calc R U . . .
C8 C 0.4025(3) 0.8068(3) 0.2616(3) 0.0372(10) Uani 1 1 d . . . . .
H8A H 0.427814 0.879943 0.266602 0.045 Uiso 1 1 calc R U . . .
H8B H 0.354902 0.760414 0.204757 0.045 Uiso 1 1 calc R U . . .
C39 C 0.8062(4) 0.2080(3) 0.1388(3) 0.0406(10) Uani 1 1 d . . . . .
H39A H 0.733509 0.188093 0.123882 0.049 Uiso 1 1 calc R U . . .
H39B H 0.809621 0.143160 0.122688 0.049 Uiso 1 1 calc R U . . .
C27 C 1.1229(4) 0.8109(3) 0.1402(3) 0.0396(10) Uani 1 1 d . . . . .
H27A H 1.150628 0.845351 0.099922 0.047 Uiso 1 1 calc R U . . .
H27B H 1.164033 0.860387 0.198548 0.047 Uiso 1 1 calc R U . . .
C40 C 0.8497(4) 0.2679(3) 0.2337(3) 0.0381(10) Uani 1 1 d . . . . .
H40A H 0.919024 0.278745 0.249635 0.046 Uiso 1 1 calc R U . . .
H40B H 0.806263 0.225954 0.264271 0.046 Uiso 1 1 calc R U . . .
C4 C 0.2015(3) 0.4803(3) 0.0868(3) 0.0358(9) Uani 1 1 d . . . . .
C31 C 1.0878(3) 0.6198(3) 0.3789(2) 0.0339(9) Uani 1 1 d . . . . .
H31A H 1.055003 0.548142 0.379284 0.041 Uiso 1 1 calc R U . . .
H31B H 1.128036 0.622593 0.335437 0.041 Uiso 1 1 calc R U . . .
C22 C 0.8175(3) 0.8564(3) 0.1710(3) 0.0346(9) Uani 1 1 d . . . . .
H22A H 0.881960 0.867187 0.201546 0.042 Uiso 1 1 calc R U . . .
H22B H 0.800074 0.808045 0.111661 0.042 Uiso 1 1 calc R U . . .
C30 C 1.0047(3) 0.6447(3) 0.3552(2) 0.0317(9) Uani 1 1 d . . . . .
H30 H 1.041935 0.717826 0.356616 0.038 Uiso 1 1 calc R U . . .
C28 C 1.1308(3) 0.7134(4) 0.1206(3) 0.0364(9) Uani 1 1 d . . . . .
H28A H 1.203392 0.732655 0.126269 0.044 Uiso 1 1 calc R U . . .
H28B H 1.092832 0.665669 0.061180 0.044 Uiso 1 1 calc R U . . .
C10 C 0.4181(4) 0.8505(4) 0.4183(3) 0.0461(12) Uani 1 1 d . . . . .
H10A H 0.446803 0.925796 0.429530 0.055 Uiso 1 1 calc R U . . .
H10B H 0.379657 0.833773 0.461414 0.055 Uiso 1 1 calc R U . . .
C9 C 0.3455(3) 0.7861(4) 0.3294(3) 0.0419(10) Uani 1 1 d . . . . .
H9A H 0.312344 0.710897 0.319960 0.050 Uiso 1 1 calc R U . . .
H9B H 0.291312 0.804283 0.325239 0.050 Uiso 1 1 calc R U . . .
C14 C 0.9076(3) 0.9954(3) 0.6245(3) 0.0387(10) Uani 1 1 d . . . . .
H14A H 0.933884 1.014758 0.685961 0.046 Uiso 1 1 calc R U . . .
H14B H 0.964950 1.036186 0.602499 0.046 Uiso 1 1 calc R U . . .
C13 C 0.8244(3) 1.0220(3) 0.6124(3) 0.0379(10) Uani 1 1 d . . . . .
H13A H 0.853623 1.098258 0.641169 0.046 Uiso 1 1 calc R U . . .
H13B H 0.770098 0.986226 0.639245 0.046 Uiso 1 1 calc R U . . .
C26 C 1.0123(4) 0.7831(3) 0.1328(3) 0.0402(10) Uani 1 1 d . . . . .
H26A H 0.972793 0.738209 0.073218 0.048 Uiso 1 1 calc R U . . .
H26B H 1.008821 0.847892 0.147322 0.048 Uiso 1 1 calc R U . . .
C20 C 0.8539(4) 1.0345(3) 0.2606(3) 0.0382(10) Uani 1 1 d . . . . .
H20A H 0.920041 1.053049 0.294869 0.046 Uiso 1 1 calc R U . . .
H20B H 0.859026 1.099520 0.258153 0.046 Uiso 1 1 calc R U . . .
C53 C 0.2428(3) 0.2109(3) 0.2198(3) 0.0349(9) Uani 1 1 d . . . . .
H53A H 0.267660 0.190435 0.262797 0.042 Uiso 1 1 calc R U . . .
H53B H 0.274240 0.287789 0.243136 0.042 Uiso 1 1 calc R U . . .
C52 C 0.1266(3) 0.1599(4) 0.2027(3) 0.0449(11) Uani 1 1 d . . . . .
H52A H 0.107899 0.185306 0.255816 0.054 Uiso 1 1 calc R U . . .
H52B H 0.095522 0.083229 0.184903 0.054 Uiso 1 1 calc R U . . .
C21 C 0.8338(3) 0.9599(3) 0.1705(3) 0.0365(9) Uani 1 1 d . . . . .
H21A H 0.772477 0.948373 0.133999 0.044 Uiso 1 1 calc R U . . .
H21B H 0.892671 0.991571 0.146216 0.044 Uiso 1 1 calc R U . . .
C32 C 1.1592(4) 0.6975(4) 0.4664(3) 0.0437(11) Uani 1 1 d . . . . .
H32A H 1.209390 0.677507 0.481465 0.052 Uiso 1 1 calc R U . . .
H32B H 1.197421 0.768208 0.464348 0.052 Uiso 1 1 calc R U . . .
C45 C 0.5439(4) 0.1134(4) 0.3287(3) 0.0389(10) Uani 1 1 d . . . . .
H45A H 0.556896 0.068949 0.281551 0.047 Uiso 1 1 calc R U . . .
H45B H 0.565612 0.106424 0.381923 0.047 Uiso 1 1 calc R U . . .
C50 C 0.1163(4) 0.1529(4) 0.0524(3) 0.0468(12) Uani 1 1 d . . . . .
H50A H 0.091435 0.173895 0.009870 0.056 Uiso 1 1 calc R U . . .
H50B H 0.084337 0.075931 0.028635 0.056 Uiso 1 1 calc R U . . .
C37 C 0.8717(4) 0.3795(3) 0.1166(2) 0.0373(10) Uani 1 1 d . . . . .
H37A H 0.802552 0.369338 0.101994 0.045 Uiso 1 1 calc R U . . .
H37B H 0.914526 0.420719 0.085392 0.045 Uiso 1 1 calc R U . . .
C34 C 1.0157(4) 0.7229(4) 0.5112(3) 0.0447(11) Uani 1 1 d . . . . .
H34A H 1.047701 0.794948 0.511742 0.054 Uiso 1 1 calc R U . . .
H34B H 0.975350 0.718632 0.554550 0.054 Uiso 1 1 calc R U . . .
C51 C 0.0843(4) 0.1851(4) 0.1332(3) 0.0469(12) Uani 1 1 d . . . . .
H51A H 0.008737 0.147856 0.121104 0.056 Uiso 1 1 calc R U . . .
H51B H 0.109623 0.260992 0.153504 0.056 Uiso 1 1 calc R U . . .
C38 C 0.8650(4) 0.2733(3) 0.0894(3) 0.0477(12) Uani 1 1 d . . . . .
H38A H 0.831127 0.234638 0.027947 0.057 Uiso 1 1 calc R U . . .
H38B H 0.934963 0.284137 0.097857 0.057 Uiso 1 1 calc R U . . .
C35 C 0.9440(3) 0.6462(3) 0.4232(3) 0.0379(10) Uani 1 1 d . . . . .
H35A H 0.905193 0.575231 0.424493 0.046 Uiso 1 1 calc R U . . .
H35B H 0.894380 0.667105 0.408636 0.046 Uiso 1 1 calc R U . . .
C33 C 1.0989(4) 0.6995(4) 0.5341(3) 0.0489(12) Uani 1 1 d . . . . .
H33A H 1.067377 0.631038 0.540600 0.059 Uiso 1 1 calc R U . . .
H33B H 1.146155 0.753462 0.589273 0.059 Uiso 1 1 calc R U . . .
O14B O 0.7297(6) 0.4762(8) 0.6038(5) 0.0414(16) Uani 0.487(3) 1 d . . P A 2
H14C H 0.753389 0.487164 0.656244 0.062 Uiso 0.487(3) 1 d R U P A 2
H14D H 0.675029 0.472964 0.618654 0.062 Uiso 0.487(3) 1 d R U P A 2
O14A O 0.6541(9) 0.4163(8) 0.5605(6) 0.035(2) Uani 0.316(3) 1 d G . P B 1
H14E H 0.711312 0.466195 0.596756 0.052 Uiso 0.316(3) 1 d G U P B 1
H14F H 0.611334 0.438578 0.569303 0.052 Uiso 0.316(3) 1 d G U P B 1
O13 O 0.8971(11) 0.6288(13) 0.6576(10) 0.040(4) Uani 0.197(3) 1 d G . P C 3
H13C H 0.859039 0.590037 0.605950 0.060 Uiso 0.197(3) 1 d G U P C 3
H13D H 0.871058 0.590161 0.687218 0.060 Uiso 0.197(3) 1 d G U P C 3
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -9.8046 9.8477 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Dy1 O5 143.17(9) . . ?
O3 Dy1 O4 73.85(9) . . ?
O3 Dy1 O1 146.65(10) . . ?
O2 Dy1 O3 73.68(9) . . ?
O2 Dy1 O5 143.15(9) . . ?
O2 Dy1 O4 147.21(9) . . ?
O2 Dy1 O1 72.99(10) . . ?
O9 Dy1 O3 90.47(9) . . ?
O9 Dy1 O2 88.90(9) . . ?
O9 Dy1 O5 90.06(9) . . ?
O9 Dy1 O4 95.80(9) . . ?
O9 Dy1 O1 89.89(9) . . ?
O5 Dy1 O4 69.47(9) . . ?
O10 Dy1 O3 89.57(9) . . ?
O10 Dy1 O2 89.61(9) . . ?
O10 Dy1 O9 178.44(9) . . ?
O10 Dy1 O5 90.84(10) . . ?
O10 Dy1 O4 85.71(9) . . ?
O10 Dy1 O1 89.22(9) . . ?
O1 Dy1 O5 70.18(10) . . ?
O1 Dy1 O4 139.21(10) . . ?
O9 P1 C17 109.33(15) . . ?
O9 P1 C6 109.63(16) . . ?
O9 P1 C18 110.53(16) . . ?
C17 P1 C6 109.03(17) . . ?
C17 P1 C18 108.23(18) . . ?
C6 P1 C18 110.05(18) . . ?
O10 P2 C42 108.09(15) . . ?
O10 P2 C48 109.47(16) . . ?
O10 P2 C54 108.53(16) . . ?
C42 P2 C54 114.43(17) . . ?
C48 P2 C42 107.78(17) . . ?
C48 P2 C54 108.47(18) . . ?
O15 P3 C36 111.05(17) . . ?
O15 P3 C24 110.45(17) . . ?
O15 P3 C30 110.47(17) . . ?
C36 P3 C24 108.30(17) . . ?
C36 P3 C30 108.85(19) . . ?
C24 P3 C30 107.62(18) . . ?
Dy1 O3 H3A 114.1 . . ?
Dy1 O3 H3B 131.7 . . ?
H3A O3 H3B 102.6 . . ?
Dy1 O2 H2A 126.2 . . ?
Dy1 O2 H2B 124.8 . . ?
H2A O2 H2B 104.9 . . ?
P1 O9 Dy1 171.75(16) . . ?
C2 O5 Dy1 114.1(2) . . ?
P2 O10 Dy1 173.22(16) . . ?
C1 O4 Dy1 113.5(2) . . ?
Dy1 O1 H1A 109.6 . . ?
Dy1 O1 H1B 109.5 . . ?
H1A O1 H1B 104.4 . . ?
H12C O12 H12D 106.9 . . ?
P2 C42 H42 104.8 . . ?
C43 C42 P2 113.4(3) . . ?
C43 C42 H42 104.8 . . ?
C43 C42 C47 110.8(3) . . ?
C47 C42 P2 117.0(3) . . ?
C47 C42 H42 104.8 . . ?
C42 C43 H43A 109.5 . . ?
C42 C43 H43B 109.5 . . ?
H43A C43 H43B 108.1 . . ?
C44 C43 C42 110.7(3) . . ?
C44 C43 H43A 109.5 . . ?
C44 C43 H43B 109.5 . . ?
P1 C17 H17 106.2 . . ?
C12 C17 P1 114.0(3) . . ?
C12 C17 H17 106.2 . . ?
C16 C17 P1 112.7(3) . . ?
C16 C17 H17 106.2 . . ?
C16 C17 C12 110.8(3) . . ?
P2 C48 H48 108.2 . . ?
C49 C48 P2 111.5(3) . . ?
C49 C48 H48 108.2 . . ?
C49 C48 C53 110.1(3) . . ?
C53 C48 P2 110.6(3) . . ?
C53 C48 H48 108.2 . . ?
P3 C36 H36 108.8 . . ?
C41 C36 P3 109.5(3) . . ?
C41 C36 H36 108.8 . . ?
C41 C36 C37 109.6(3) . . ?
C37 C36 P3 111.3(3) . . ?
C37 C36 H36 108.8 . . ?
P2 C54 H54 105.8 . . ?
C55 C54 P2 113.0(2) . . ?
C55 C54 H54 105.8 . . ?
C59 C54 P2 114.5(3) . . ?
C59 C54 H54 105.8 . . ?
C59 C54 C55 111.1(3) . . ?
P1 C6 H6 108.1 . . ?
C7 C6 P1 109.3(3) . . ?
C7 C6 H6 108.1 . . ?
C11 C6 P1 112.0(3) . . ?
C11 C6 H6 108.1 . . ?
C11 C6 C7 111.0(3) . . ?
C54 C55 H55A 109.6 . . ?
C54 C55 H55B 109.6 . . ?
H55A C55 H55B 108.1 . . ?
C56 C55 C54 110.4(3) . . ?
C56 C55 H55A 109.6 . . ?
C56 C55 H55B 109.6 . . ?
H11C O11 H11D 104.5 . . ?
C6 C7 H7A 109.2 . . ?
C6 C7 H7B 109.2 . . ?
H7A C7 H7B 107.9 . . ?
C8 C7 C6 112.2(3) . . ?
C8 C7 H7A 109.2 . . ?
C8 C7 H7B 109.2 . . ?
P1 C18 H18 105.7 . . ?
C19 C18 P1 115.9(3) . . ?
C19 C18 H18 105.7 . . ?
C23 C18 P1 112.2(3) . . ?
C23 C18 H18 105.7 . . ?
C23 C18 C19 110.7(3) . . ?
C54 C59 H59A 109.5 . . ?
C54 C59 H59B 109.5 . . ?
H59A C59 H59B 108.1 . . ?
C58 C59 C54 110.6(3) . . ?
C58 C59 H59A 109.5 . . ?
C58 C59 H59B 109.5 . . ?
C42 C47 H47A 109.9 . . ?
C42 C47 H47B 109.9 . . ?
H47A C47 H47B 108.3 . . ?
C46 C47 C42 109.0(3) . . ?
C46 C47 H47A 109.9 . . ?
C46 C47 H47B 109.9 . . ?
C55 C56 H56A 109.5 . . ?
C55 C56 H56B 109.5 . . ?
H56A C56 H56B 108.1 . . ?
C57 C56 C55 110.7(3) . . ?
C57 C56 H56A 109.5 . . ?
C57 C56 H56B 109.5 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 108.1 . . ?
C20 C19 C18 110.6(3) . . ?
C20 C19 H19A 109.5 . . ?
C20 C19 H19B 109.5 . . ?
O4 C1 C5 128.5(4) . . ?
O4 C1 C2 120.5(3) . . ?
C2 C1 C5 111.0(4) . . ?
H25A C25 H25B 108.1 . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
C26 C25 H25A 109.5 . . ?
C26 C25 H25B 109.5 . . ?
C26 C25 C24 110.9(3) . . ?
C56 C57 H57A 109.5 . . ?
C56 C57 H57B 109.5 . . ?
C56 C57 C58 110.9(3) . . ?
H57A C57 H57B 108.1 . . ?
C58 C57 H57A 109.5 . . ?
C58 C57 H57B 109.5 . . ?
O8 C5 C1 129.0(4) . . ?
O8 C5 C4 125.4(4) . . ?
C1 C5 C4 105.6(4) . . ?
C36 C41 H41A 109.3 . . ?
C36 C41 H41B 109.3 . . ?
H41A C41 H41B 108.0 . . ?
C40 C41 C36 111.5(3) . . ?
C40 C41 H41A 109.3 . . ?
C40 C41 H41B 109.3 . . ?
C48 C49 H49A 109.3 . . ?
C48 C49 H49B 109.3 . . ?
H49A C49 H49B 108.0 . . ?
C50 C49 C48 111.4(3) . . ?
C50 C49 H49A 109.3 . . ?
C50 C49 H49B 109.3 . . ?
C17 C12 H12A 109.7 . . ?
C17 C12 H12B 109.7 . . ?
H12A C12 H12B 108.2 . . ?
C13 C12 C17 109.6(3) . . ?
C13 C12 H12A 109.7 . . ?
C13 C12 H12B 109.7 . . ?
O6 C3 C2 127.6(4) . . ?
O6 C3 C4 126.6(4) . . ?
C2 C3 C4 105.7(3) . . ?
H29A C29 H29B 108.1 . . ?
C24 C29 H29A 109.5 . . ?
C24 C29 H29B 109.5 . . ?
C24 C29 C28 110.7(3) . . ?
C28 C29 H29A 109.5 . . ?
C28 C29 H29B 109.5 . . ?
C18 C23 H23A 109.6 . . ?
C18 C23 H23B 109.6 . . ?
C18 C23 C22 110.2(3) . . ?
H23A C23 H23B 108.1 . . ?
C22 C23 H23A 109.6 . . ?
C22 C23 H23B 109.6 . . ?
C43 C44 H44A 109.6 . . ?
C43 C44 H44B 109.6 . . ?
C43 C44 C45 110.2(3) . . ?
H44A C44 H44B 108.1 . . ?
C45 C44 H44A 109.6 . . ?
C45 C44 H44B 109.6 . . ?
C17 C16 H16A 109.6 . . ?
C17 C16 H16B 109.6 . . ?
C17 C16 C15 110.3(3) . . ?
H16A C16 H16B 108.1 . . ?
C15 C16 H16A 109.6 . . ?
C15 C16 H16B 109.6 . . ?
O5 C2 C1 121.6(4) . . ?
O5 C2 C3 128.2(4) . . ?
C1 C2 C3 110.1(3) . . ?
P3 C24 H24 106.6 . . ?
C25 C24 P3 111.3(3) . . ?
C25 C24 H24 106.6 . . ?
C29 C24 P3 112.5(3) . . ?
C29 C24 C25 112.6(3) . . ?
C29 C24 H24 106.6 . . ?
C16 C15 H15A 109.3 . . ?
C16 C15 H15B 109.3 . . ?
H15A C15 H15B 108.0 . . ?
C14 C15 C16 111.6(4) . . ?
C14 C15 H15A 109.3 . . ?
C14 C15 H15B 109.3 . . ?
C6 C11 H11A 109.6 . . ?
C6 C11 H11B 109.6 . . ?
C6 C11 C10 110.4(4) . . ?
H11A C11 H11B 108.1 . . ?
C10 C11 H11A 109.6 . . ?
C10 C11 H11B 109.6 . . ?
C47 C46 H46A 109.4 . . ?
C47 C46 H46B 109.4 . . ?
H46A C46 H46B 108.0 . . ?
C45 C46 C47 111.3(3) . . ?
C45 C46 H46A 109.4 . . ?
C45 C46 H46B 109.4 . . ?
C59 C58 C57 111.9(3) . . ?
C59 C58 H58A 109.2 . . ?
C59 C58 H58B 109.2 . . ?
C57 C58 H58A 109.2 . . ?
C57 C58 H58B 109.2 . . ?
H58A C58 H58B 107.9 . . ?
C7 C8 H8A 109.2 . . ?
C7 C8 H8B 109.2 . . ?
H8A C8 H8B 107.9 . . ?
C9 C8 C7 112.1(4) . . ?
C9 C8 H8A 109.2 . . ?
C9 C8 H8B 109.2 . . ?
H39A C39 H39B 108.0 . . ?
C40 C39 H39A 109.4 . . ?
C40 C39 H39B 109.4 . . ?
C40 C39 C38 111.0(4) . . ?
C38 C39 H39A 109.4 . . ?
C38 C39 H39B 109.4 . . ?
H27A C27 H27B 108.1 . . ?
C28 C27 H27A 109.6 . . ?
C28 C27 H27B 109.6 . . ?
C28 C27 C26 110.3(4) . . ?
C26 C27 H27A 109.6 . . ?
C26 C27 H27B 109.6 . . ?
C41 C40 H40A 109.2 . . ?
C41 C40 H40B 109.2 . . ?
C39 C40 C41 112.0(4) . . ?
C39 C40 H40A 109.2 . . ?
C39 C40 H40B 109.2 . . ?
H40A C40 H40B 107.9 . . ?
O7 C4 C5 127.0(4) . . ?
O7 C4 C3 125.5(4) . . ?
C3 C4 C5 107.5(3) . . ?
H31A C31 H31B 108.0 . . ?
C30 C31 H31A 109.4 . . ?
C30 C31 H31B 109.4 . . ?
C32 C31 H31A 109.4 . . ?
C32 C31 H31B 109.4 . . ?
C32 C31 C30 111.1(3) . . ?
C23 C22 H22A 109.1 . . ?
C23 C22 H22B 109.1 . . ?
H22A C22 H22B 107.9 . . ?
C21 C22 C23 112.3(4) . . ?
C21 C22 H22A 109.1 . . ?
C21 C22 H22B 109.1 . . ?
P3 C30 H30 106.0 . . ?
C31 C30 P3 115.1(3) . . ?
C31 C30 H30 106.0 . . ?
C35 C30 P3 112.1(3) . . ?
C35 C30 C31 111.0(3) . . ?
C35 C30 H30 106.0 . . ?
C29 C28 H28A 109.5 . . ?
C29 C28 H28B 109.5 . . ?
C27 C28 C29 110.8(4) . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 108.1 . . ?
C11 C10 H10A 109.4 . . ?
C11 C10 H10B 109.4 . . ?
C11 C10 C9 111.0(4) . . ?
H10A C10 H10B 108.0 . . ?
C9 C10 H10A 109.4 . . ?
C9 C10 H10B 109.4 . . ?
C8 C9 C10 110.9(4) . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
C10 C9 H9A 109.5 . . ?
C10 C9 H9B 109.5 . . ?
H9A C9 H9B 108.1 . . ?
C15 C14 H14A 109.5 . . ?
C15 C14 H14B 109.5 . . ?
H14A C14 H14B 108.1 . . ?
C13 C14 C15 110.8(3) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
C12 C13 H13A 109.3 . . ?
C12 C13 H13B 109.3 . . ?
C14 C13 C12 111.6(4) . . ?
C14 C13 H13A 109.3 . . ?
C14 C13 H13B 109.3 . . ?
H13A C13 H13B 108.0 . . ?
C25 C26 H26A 109.1 . . ?
C25 C26 H26B 109.1 . . ?
C27 C26 C25 112.3(4) . . ?
C27 C26 H26A 109.1 . . ?
C27 C26 H26B 109.1 . . ?
H26A C26 H26B 107.9 . . ?
C19 C20 H20A 109.3 . . ?
C19 C20 H20B 109.3 . . ?
C19 C20 C21 111.7(3) . . ?
H20A C20 H20B 107.9 . . ?
C21 C20 H20A 109.3 . . ?
C21 C20 H20B 109.3 . . ?
C48 C53 H53A 109.4 . . ?
C48 C53 H53B 109.4 . . ?
H53A C53 H53B 108.0 . . ?
C52 C53 C48 111.2(4) . . ?
C52 C53 H53A 109.4 . . ?
C52 C53 H53B 109.4 . . ?
C53 C52 H52A 109.4 . . ?
C53 C52 H52B 109.4 . . ?
C53 C52 C51 111.1(4) . . ?
H52A C52 H52B 108.0 . . ?
C51 C52 H52A 109.4 . . ?
C51 C52 H52B 109.4 . . ?
C22 C21 C20 110.7(3) . . ?
C22 C21 H21A 109.5 . . ?
C22 C21 H21B 109.5 . . ?
C20 C21 H21A 109.5 . . ?
C20 C21 H21B 109.5 . . ?
H21A C21 H21B 108.1 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 108.1 . . ?
C33 C32 C31 110.8(4) . . ?
C33 C32 H32A 109.5 . . ?
C33 C32 H32B 109.5 . . ?
C44 C45 H45A 109.5 . . ?
C44 C45 H45B 109.5 . . ?
C46 C45 C44 110.8(3) . . ?
C46 C45 H45A 109.5 . . ?
C46 C45 H45B 109.5 . . ?
H45A C45 H45B 108.1 . . ?
C49 C50 H50A 109.2 . . ?
C49 C50 H50B 109.2 . . ?
H50A C50 H50B 107.9 . . ?
C51 C50 C49 111.9(4) . . ?
C51 C50 H50A 109.2 . . ?
C51 C50 H50B 109.2 . . ?
C36 C37 H37A 109.5 . . ?
C36 C37 H37B 109.5 . . ?
H37A C37 H37B 108.1 . . ?
C38 C37 C36 110.8(3) . . ?
C38 C37 H37A 109.5 . . ?
C38 C37 H37B 109.5 . . ?
H34A C34 H34B 107.9 . . ?
C35 C34 H34A 109.3 . . ?
C35 C34 H34B 109.3 . . ?
C33 C34 H34A 109.3 . . ?
C33 C34 H34B 109.3 . . ?
C33 C34 C35 111.8(4) . . ?
C52 C51 H51A 109.4 . . ?
C52 C51 H51B 109.4 . . ?
C50 C51 C52 111.1(4) . . ?
C50 C51 H51A 109.4 . . ?
C50 C51 H51B 109.4 . . ?
H51A C51 H51B 108.0 . . ?
C39 C38 C37 112.6(4) . . ?
C39 C38 H38A 109.1 . . ?
C39 C38 H38B 109.1 . . ?
C37 C38 H38A 109.1 . . ?
C37 C38 H38B 109.1 . . ?
H38A C38 H38B 107.8 . . ?
C30 C35 C34 110.8(4) . . ?
C30 C35 H35A 109.5 . . ?
C30 C35 H35B 109.5 . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
H35A C35 H35B 108.1 . . ?
C32 C33 H33A 109.3 . . ?
C32 C33 H33B 109.3 . . ?
C34 C33 C32 111.8(4) . . ?
C34 C33 H33A 109.3 . . ?
C34 C33 H33B 109.3 . . ?
H33A C33 H33B 107.9 . . ?
H14C O14B H14D 87.1 . . ?
H14E O14A H14F 104.5 . . ?
H13C O13 H13D 104.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O3 2.345(3) . ?
Dy1 O2 2.345(3) . ?
Dy1 O9 2.235(2) . ?
Dy1 O5 2.393(3) . ?
Dy1 O10 2.219(2) . ?
Dy1 O4 2.400(3) . ?
Dy1 O1 2.348(3) . ?
P1 O9 1.514(2) . ?
P1 C17 1.810(4) . ?
P1 C6 1.812(4) . ?
P1 C18 1.832(4) . ?
P2 O10 1.508(2) . ?
P2 C42 1.819(4) . ?
P2 C48 1.813(4) . ?
P2 C54 1.821(4) . ?
P3 O15 1.514(3) . ?
P3 C36 1.817(4) . ?
P3 C24 1.819(4) . ?
P3 C30 1.841(4) . ?
O3 H3A 0.8742 . ?
O3 H3B 0.8759 . ?
O2 H2A 0.8729 . ?
O2 H2B 0.8945 . ?
O5 C2 1.267(5) . ?
O4 C1 1.294(5) . ?
O1 H1A 0.8749 . ?
O1 H1B 0.8723 . ?
O8 C5 1.191(5) . ?
O6 C3 1.232(5) . ?
O7 C4 1.218(5) . ?
O12 H12C 0.8487 . ?
O12 H12D 0.8694 . ?
C42 H42 1.0000 . ?
C42 C43 1.533(5) . ?
C42 C47 1.543(5) . ?
C43 H43A 0.9900 . ?
C43 H43B 0.9900 . ?
C43 C44 1.529(5) . ?
C17 H17 1.0000 . ?
C17 C12 1.542(5) . ?
C17 C16 1.525(5) . ?
C48 H48 1.0000 . ?
C48 C49 1.539(5) . ?
C48 C53 1.545(6) . ?
C36 H36 1.0000 . ?
C36 C41 1.535(5) . ?
C36 C37 1.536(5) . ?
C54 H54 1.0000 . ?
C54 C55 1.547(5) . ?
C54 C59 1.542(5) . ?
C6 H6 1.0000 . ?
C6 C7 1.537(5) . ?
C6 C11 1.527(6) . ?
C55 H55A 0.9900 . ?
C55 H55B 0.9900 . ?
C55 C56 1.532(5) . ?
O11 H11C 0.8697 . ?
O11 H11D 0.8709 . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C7 C8 1.521(6) . ?
C18 H18 1.0000 . ?
C18 C19 1.535(5) . ?
C18 C23 1.523(5) . ?
C59 H59A 0.9900 . ?
C59 H59B 0.9900 . ?
C59 C58 1.526(5) . ?
C47 H47A 0.9900 . ?
C47 H47B 0.9900 . ?
C47 C46 1.534(6) . ?
C56 H56A 0.9900 . ?
C56 H56B 0.9900 . ?
C56 C57 1.527(5) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C19 C20 1.525(6) . ?
C1 C5 1.455(6) . ?
C1 C2 1.410(5) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C25 C24 1.536(5) . ?
C25 C26 1.525(6) . ?
C57 H57A 0.9900 . ?
C57 H57B 0.9900 . ?
C57 C58 1.529(6) . ?
C5 C4 1.515(6) . ?
C41 H41A 0.9900 . ?
C41 H41B 0.9900 . ?
C41 C40 1.518(6) . ?
C49 H49A 0.9900 . ?
C49 H49B 0.9900 . ?
C49 C50 1.527(6) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C12 C13 1.520(5) . ?
C3 C2 1.470(6) . ?
C3 C4 1.506(6) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C29 C24 1.525(6) . ?
C29 C28 1.534(6) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C23 C22 1.527(6) . ?
C44 H44A 0.9900 . ?
C44 H44B 0.9900 . ?
C44 C45 1.534(6) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C16 C15 1.532(6) . ?
C24 H24 1.0000 . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C15 C14 1.521(6) . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C11 C10 1.531(6) . ?
C46 H46A 0.9900 . ?
C46 H46B 0.9900 . ?
C46 C45 1.520(6) . ?
C58 H58A 0.9900 . ?
C58 H58B 0.9900 . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C8 C9 1.512(6) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C39 C40 1.514(6) . ?
C39 C38 1.518(6) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C27 C28 1.514(6) . ?
C27 C26 1.517(7) . ?
C40 H40A 0.9900 . ?
C40 H40B 0.9900 . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C31 C30 1.541(6) . ?
C31 C32 1.530(6) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C22 C21 1.511(6) . ?
C30 H30 1.0000 . ?
C30 C35 1.532(6) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C10 C9 1.531(6) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C14 C13 1.518(6) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C20 C21 1.528(6) . ?
C53 H53A 0.9900 . ?
C53 H53B 0.9900 . ?
C53 C52 1.528(6) . ?
C52 H52A 0.9900 . ?
C52 H52B 0.9900 . ?
C52 C51 1.533(6) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C32 C33 1.524(6) . ?
C45 H45A 0.9900 . ?
C45 H45B 0.9900 . ?
C50 H50A 0.9900 . ?
C50 H50B 0.9900 . ?
C50 C51 1.512(7) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C37 C38 1.526(6) . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C34 C35 1.533(6) . ?
C34 C33 1.523(7) . ?
C51 H51A 0.9900 . ?
C51 H51B 0.9900 . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
O14B H14C 0.8698 . ?
O14B H14D 0.8709 . ?
O14A H14E 0.8692 . ?
O14A H14F 0.8700 . ?
O13 H13C 0.8704 . ?
O13 H13D 0.8698 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O5 C2 C1 -6.9(4) . . . . ?
Dy1 O5 C2 C3 173.0(3) . . . . ?
Dy1 O4 C1 C5 -171.4(3) . . . . ?
Dy1 O4 C1 C2 6.9(4) . . . . ?
P1 C17 C12 C13 173.9(3) . . . . ?
P1 C17 C16 C15 -174.1(3) . . . . ?
P1 C6 C7 C8 177.6(3) . . . . ?
P1 C6 C11 C10 -178.0(3) . . . . ?
P1 C18 C19 C20 173.8(3) . . . . ?
P1 C18 C23 C22 -172.0(3) . . . . ?
P2 C42 C43 C44 168.2(3) . . . . ?
P2 C42 C47 C46 -170.5(3) . . . . ?
P2 C48 C49 C50 -178.2(3) . . . . ?
P2 C48 C53 C52 179.3(3) . . . . ?
P2 C54 C55 C56 -173.4(3) . . . . ?
P2 C54 C59 C58 175.4(3) . . . . ?
P3 C36 C41 C40 179.1(3) . . . . ?
P3 C36 C37 C38 -177.1(3) . . . . ?
P3 C30 C35 C34 -174.5(3) . . . . ?
O9 P1 C17 C12 -175.8(3) . . . . ?
O9 P1 C17 C16 56.8(3) . . . . ?
O9 P1 C6 C7 -49.1(3) . . . . ?
O9 P1 C6 C11 74.3(3) . . . . ?
O9 P1 C18 C19 153.1(3) . . . . ?
O9 P1 C18 C23 24.5(3) . . . . ?
O10 P2 C42 C43 -68.2(3) . . . . ?
O10 P2 C42 C47 160.9(3) . . . . ?
O10 P2 C48 C49 63.8(3) . . . . ?
O10 P2 C48 C53 -59.1(3) . . . . ?
O10 P2 C54 C55 45.0(3) . . . . ?
O10 P2 C54 C59 173.6(3) . . . . ?
O4 C1 C5 O8 0.9(7) . . . . ?
O4 C1 C5 C4 -179.4(4) . . . . ?
O4 C1 C2 O5 0.0(6) . . . . ?
O4 C1 C2 C3 -180.0(3) . . . . ?
O15 P3 C36 C41 -49.2(3) . . . . ?
O15 P3 C36 C37 72.1(3) . . . . ?
O15 P3 C24 C25 47.9(3) . . . . ?
O15 P3 C24 C29 175.4(3) . . . . ?
O15 P3 C30 C31 147.4(3) . . . . ?
O15 P3 C30 C35 19.3(4) . . . . ?
O8 C5 C4 O7 -1.0(7) . . . . ?
O8 C5 C4 C3 177.6(4) . . . . ?
O6 C3 C2 O5 0.0(7) . . . . ?
O6 C3 C2 C1 179.9(4) . . . . ?
O6 C3 C4 O7 0.1(7) . . . . ?
O6 C3 C4 C5 -178.5(4) . . . . ?
C42 P2 C48 C49 -178.9(3) . . . . ?
C42 P2 C48 C53 58.3(3) . . . . ?
C42 P2 C54 C55 -75.7(3) . . . . ?
C42 P2 C54 C59 52.8(3) . . . . ?
C42 C43 C44 C45 56.9(4) . . . . ?
C42 C47 C46 C45 -57.8(4) . . . . ?
C43 C42 C47 C46 57.5(4) . . . . ?
C43 C44 C45 C46 -56.9(5) . . . . ?
C17 P1 C6 C7 -168.8(3) . . . . ?
C17 P1 C6 C11 -45.3(3) . . . . ?
C17 P1 C18 C19 -87.2(3) . . . . ?
C17 P1 C18 C23 144.2(3) . . . . ?
C17 C12 C13 C14 57.5(5) . . . . ?
C17 C16 C15 C14 -55.8(5) . . . . ?
C48 P2 C42 C43 173.5(3) . . . . ?
C48 P2 C42 C47 42.7(3) . . . . ?
C48 P2 C54 C55 163.9(3) . . . . ?
C48 P2 C54 C59 -67.6(3) . . . . ?
C48 C49 C50 C51 55.7(5) . . . . ?
C48 C53 C52 C51 -56.2(5) . . . . ?
C36 P3 C24 C25 169.7(3) . . . . ?
C36 P3 C24 C29 -62.8(3) . . . . ?
C36 P3 C30 C31 25.3(4) . . . . ?
C36 P3 C30 C35 -102.8(3) . . . . ?
C36 C41 C40 C39 -56.3(5) . . . . ?
C36 C37 C38 C39 55.4(6) . . . . ?
C54 P2 C42 C43 52.8(3) . . . . ?
C54 P2 C42 C47 -78.0(3) . . . . ?
C54 P2 C48 C49 -54.5(3) . . . . ?
C54 P2 C48 C53 -177.3(3) . . . . ?
C54 C55 C56 C57 -57.2(4) . . . . ?
C54 C59 C58 C57 55.2(4) . . . . ?
C6 P1 C17 C12 -55.9(3) . . . . ?
C6 P1 C17 C16 176.6(3) . . . . ?
C6 P1 C18 C19 31.9(3) . . . . ?
C6 P1 C18 C23 -96.7(3) . . . . ?
C6 C7 C8 C9 -53.3(5) . . . . ?
C6 C11 C10 C9 57.6(5) . . . . ?
C55 C54 C59 C58 -55.1(4) . . . . ?
C55 C56 C57 C58 57.1(4) . . . . ?
C7 C6 C11 C10 -55.5(5) . . . . ?
C7 C8 C9 C10 54.6(5) . . . . ?
C18 P1 C17 C12 63.8(3) . . . . ?
C18 P1 C17 C16 -63.7(3) . . . . ?
C18 P1 C6 C7 72.6(3) . . . . ?
C18 P1 C6 C11 -163.9(3) . . . . ?
C18 C19 C20 C21 55.7(5) . . . . ?
C18 C23 C22 C21 -56.5(5) . . . . ?
C59 C54 C55 C56 56.3(4) . . . . ?
C47 C42 C43 C44 -57.9(4) . . . . ?
C47 C46 C45 C44 58.1(5) . . . . ?
C56 C57 C58 C59 -56.5(4) . . . . ?
C19 C18 C23 C22 56.7(5) . . . . ?
C19 C20 C21 C22 -54.6(5) . . . . ?
C1 C5 C4 O7 179.2(4) . . . . ?
C1 C5 C4 C3 -2.2(4) . . . . ?
C5 C1 C2 O5 178.5(3) . . . . ?
C5 C1 C2 C3 -1.4(4) . . . . ?
C41 C36 C37 C38 -55.9(5) . . . . ?
C49 C48 C53 C52 55.6(4) . . . . ?
C49 C50 C51 C52 -55.6(5) . . . . ?
C12 C17 C16 C15 56.8(4) . . . . ?
C23 C18 C19 C20 -56.9(5) . . . . ?
C23 C22 C21 C20 55.1(5) . . . . ?
C16 C17 C12 C13 -57.6(4) . . . . ?
C16 C15 C14 C13 55.4(5) . . . . ?
C2 C1 C5 O8 -177.5(4) . . . . ?
C2 C1 C5 C4 2.2(4) . . . . ?
C2 C3 C4 O7 180.0(4) . . . . ?
C2 C3 C4 C5 1.4(4) . . . . ?
C24 P3 C36 C41 -170.6(3) . . . . ?
C24 P3 C36 C37 -49.3(3) . . . . ?
C24 P3 C30 C31 -91.9(3) . . . . ?
C24 P3 C30 C35 140.0(3) . . . . ?
C24 C25 C26 C27 -53.5(5) . . . . ?
C24 C29 C28 C27 56.8(5) . . . . ?
C15 C14 C13 C12 -56.7(5) . . . . ?
C11 C6 C7 C8 53.6(5) . . . . ?
C11 C10 C9 C8 -57.0(5) . . . . ?
C40 C39 C38 C37 -53.8(6) . . . . ?
C4 C3 C2 O5 -179.9(4) . . . . ?
C4 C3 C2 C1 0.0(4) . . . . ?
C31 C30 C35 C34 55.3(5) . . . . ?
C31 C32 C33 C34 -55.4(6) . . . . ?
C30 P3 C36 C41 72.6(3) . . . . ?
C30 P3 C36 C37 -166.0(3) . . . . ?
C30 P3 C24 C25 -72.8(3) . . . . ?
C30 P3 C24 C29 54.7(3) . . . . ?
C30 C31 C32 C33 56.0(5) . . . . ?
C28 C29 C24 P3 179.7(3) . . . . ?
C28 C29 C24 C25 -53.6(4) . . . . ?
C28 C27 C26 C25 57.4(5) . . . . ?
C26 C25 C24 P3 179.1(3) . . . . ?
C26 C25 C24 C29 51.7(5) . . . . ?
C26 C27 C28 C29 -58.5(5) . . . . ?
C53 C48 C49 C50 -55.1(5) . . . . ?
C53 C52 C51 C50 55.9(6) . . . . ?
C32 C31 C30 P3 174.9(3) . . . . ?
C32 C31 C30 C35 -56.4(5) . . . . ?
C37 C36 C41 C40 56.7(5) . . . . ?
C38 C39 C40 C41 53.9(6) . . . . ?
C35 C34 C33 C32 55.1(6) . . . . ?
C33 C34 C35 C30 -54.8(5) . . . . ?
