#------------------------------------------------------------------------------
#$Date: 2024-12-06 21:04:53 +0100 (Fri 06 de Dec de 2024) $
#$Revision: 296617 $
#$URL: svn://www.crystallography.net/cod/cif/1/57/28/1572855.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1572855
loop_
_publ_author_name
'Zheng, Minling'
'Liu, Yubo'
'Zhang, Qifu'
'Li, Wenjing'
'Zhang, Yong'
'Feng, Guangxue'
'Hu, Yating'
'Huang, Shaoming'
_publ_section_title
;
 Dual metal centers within a water-stable Co/Ni bimetallic
 metal-triazolate framework contribute to durable photocatalysis for water
 treatment.
;
_journal_issue                   43
_journal_name_full               Nanoscale
_journal_page_first              20082
_journal_page_last               20088
_journal_paper_doi               10.1039/d4nr03940h
_journal_volume                  16
_journal_year                    2024
_chemical_formula_sum            'C24 H24 Co N36 Ni2'
_chemical_formula_weight         993.04
_space_group_IT_number           227
_space_group_name_Hall           '-F 4vw 2vw 3'
_space_group_name_H-M_alt        'F d -3 m :2'
_symmetry_cell_setting           cubic
_symmetry_space_group_name_H-M   'F d -3 m :2'
_audit_update_record
;
2024-08-24 deposited with the CCDC.	2024-10-10 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   17.0812(29)
_cell_length_b                   17.0812
_cell_length_c                   17.0812
_cell_measurement_temperature    300
_cell_volume                     4983.7(8)
_diffrn_ambient_pressure         100
_diffrn_ambient_temperature      300
_diffrn_measurement_device_type  'SmartLabTM 9kW'
_diffrn_radiation_polarisn_ratio 0.7000
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_exptl_crystal_density_diffrn    2.6470
_pd_instr_location               ' ?'
_pd_meas_2theta_range_inc        0.02000
_pd_meas_2theta_range_max        80.00000
_pd_meas_2theta_range_min        5.00000
_pd_phase_name                   MET-4
_pd_proc_2theta_range_inc        0.02000
_pd_proc_2theta_range_max        80.01244
_pd_proc_2theta_range_min        5.01244
_pd_proc_info_excluded_regions   ' ?'
_pd_proc_ls_background_function
;
Background function: "chebyschev-1" function with 36 terms:
    1.6803(20)e5, 2.540(22)e4, -3.427(18)e4, 2.289(11)e4, -1.157(9)e4, 
    3.90(11)e3, 1.6(11)e2, -2.35(11)e3, 2.11(11)e3, -1.03(9)e3, 
    2.3(8)e2, 2.7(8)e2, -2.5(8)e2, -1.1(10)e2, 3.9(12)e2, 8.1(12)e2, 
    -1.9(8)e2, 2.2(7)e2, -5.8(8)e2, -2.6(8)e2, 2.1(8)e2, 1.5(9)e2, 
    -3.0(7)e2, -2.9(7)e2, 7.6(7)e2, 3.2(7)e2, -6.0(8)e2, -2.5(7)e2, 
    5.1(9)e2, 7(6)e1, -3.9(7)e2, -3.9(7)e2, -8(6)e1, 7.9(7)e2, 
    3.4(7)e2, -1.8(7)e2, 
;
_pd_proc_ls_pref_orient_corr
;
Simple spherical harmonic correction Order = 34
    Coefficients:  0:0:C(4,1) = 2.04(12); 0:0:C(6,1) = -1.33(4); 
    0:0:C(8,1) = 1.07(20); 0:0:C(10,1) = 4.03(7); 0:0:C(12,1) = 4.8(6); 
    0:0:C(12,2) = 3.23(24); 0:0:C(14,1) = 2.75(25); 0:0:C(16,1) = -4.9(4); 
    0:0:C(16,2) = 0.03(11); 0:0:C(18,1) = -2.6(4); 0:0:C(18,2) = 14.4(9); 
    0:0:C(20,1) = 0.4(5); 0:0:C(20,2) = -0.26(24); 0:0:C(22,1) = -5.4(12); 
    0:0:C(22,2) = 4.46(21); 0:0:C(24,1) = -26.7(5); 0:0:C(24,2) = -1.57(26); 
    0:0:C(24,3) = -2.8(10); 0:0:C(26,1) = -17.1(19); 0:0:C(26,2) = 5.48(15); 
    0:0:C(28,1) = -12.9(15); 0:0:C(28,2) = -7.9(4); 0:0:C(28,3) = -4.7(9); 
    0:0:C(30,1) = -8.2(10); 0:0:C(30,2) = 6.96(18); 0:0:C(30,3) = -23.4(21); 
    0:0:C(32,1) = 44.1(9); 0:0:C(32,2) = -7.4(5); 0:0:C(32,3) = 1.05(17); 
    0:0:C(34,1) = -2.1(7); 0:0:C(34,2) = -8.91(17); 0:0:C(34,3) = 13(4); 
;
_pd_proc_ls_profile_function
;
Finger-Cox-Jephcoat function parameters U, V, W, X, Y, SH/L:
  peak variance(Gauss) = Utan(Th)^2^+Vtan(Th)+W:
  peak HW(Lorentz) = X/cos(Th)+Ytan(Th); SH/L = S/L+H/L
  U, V, W in (centideg)^2^, X & Y in centideg
    -9.14(7)e4, -6.50(16)e3, 610(21), 238.1(11), 701(20), 0.002, 

;
_pd_proc_ls_prof_R_factor        0.00603
_pd_proc_ls_prof_wR_expected     0.00230
_pd_proc_ls_prof_wR_factor       0.00787
_pd_proc_number_of_points        3751
_pd_spec_mounting                ' ?'
_refine_ls_R_Fsqd_factor         0.07926
_reflns_d_resolution_high        1.199
_reflns_d_resolution_low         9.861
_reflns_limit_h_max              14
_reflns_limit_h_min              1
_reflns_limit_k_max              10
_reflns_limit_k_min              0
_reflns_limit_l_max              8
_reflns_limit_l_min              0
_reflns_number_total             96
_cod_data_source_file            d4nr03940h2.cif
_cod_data_source_block           CoNi-MET(Co1Ni4)
_cod_depositor_comments
'Adding full bibliography for 1572855--1572856.cif.'
_cod_original_cell_volume        4983.7(26)
_cod_original_sg_symbol_H-M      'F d -3 m'
_cod_database_code               1572855
_gsas_gsasii_version             5775
_refine_ls_r_f_factor            0.08620
_gsas_proc_ls_prof_r_b_factor    0.00848
_gsas_proc_ls_prof_wr_b_factor   0.01283
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
'-x+3/4, -y+1/4, z+1/2'
'x+1/4, y+3/4, -z+1/2'
'-x+1/4, y+1/2, -z+3/4'
'x+3/4, -y+1/2, z+1/4'
'x+1/2, -y+3/4, -z+1/4'
'-x+1/2, y+1/4, z+3/4'
'z, x, y'
'-z, -x, -y'
'z+1/2, -x+3/4, -y+1/4'
'-z+1/2, x+1/4, y+3/4'
'-z+3/4, -x+1/4, y+1/2'
'z+1/4, x+3/4, -y+1/2'
'-z+1/4, x+1/2, -y+3/4'
'z+3/4, -x+1/2, y+1/4'
'y, z, x'
'-y, -z, -x'
'-y+1/4, z+1/2, -x+3/4'
'y+3/4, -z+1/2, x+1/4'
'y+1/2, -z+3/4, -x+1/4'
'-y+1/2, z+1/4, x+3/4'
'-y+3/4, -z+1/4, x+1/2'
'y+1/4, z+3/4, -x+1/2'
'y+3/4, x+1/4, -z+1/2'
'-y+1/4, -x+3/4, z+1/2'
'-y, -x, -z'
'y, x, z'
'y+1/4, -x+1/2, z+3/4'
'-y+3/4, x+1/2, -z+1/4'
'-y+1/2, x+3/4, z+1/4'
'y+1/2, -x+1/4, -z+3/4'
'x+3/4, z+1/4, -y+1/2'
'-x+1/4, -z+3/4, y+1/2'
'-x+1/2, z+3/4, y+1/4'
'x+1/2, -z+1/4, -y+3/4'
'-x, -z, -y'
'x, z, y'
'x+1/4, -z+1/2, y+3/4'
'-x+3/4, z+1/2, -y+1/4'
'z+3/4, y+1/4, -x+1/2'
'-z+1/4, -y+3/4, x+1/2'
'z+1/4, -y+1/2, x+3/4'
'-z+3/4, y+1/2, -x+1/4'
'-z+1/2, y+3/4, x+1/4'
'z+1/2, -y+1/4, -x+3/4'
'-z, -y, -x'
'z, y, x'
'x, y+1/2, z+1/2'
'-x, -y+1/2, -z+1/2'
'-x+3/4, -y+3/4, z'
'x+1/4, y+1/4, -z'
'-x+1/4, y, -z+1/4'
'x+3/4, -y, z+3/4'
'x+1/2, -y+1/4, -z+3/4'
'-x+1/2, y+3/4, z+1/4'
'z, x+1/2, y+1/2'
'-z, -x+1/2, -y+1/2'
'z+1/2, -x+1/4, -y+3/4'
'-z+1/2, x+3/4, y+1/4'
'-z+3/4, -x+3/4, y'
'z+1/4, x+1/4, -y'
'-z+1/4, x, -y+1/4'
'z+3/4, -x, y+3/4'
'y, z+1/2, x+1/2'
'-y, -z+1/2, -x+1/2'
'-y+1/4, z, -x+1/4'
'y+3/4, -z, x+3/4'
'y+1/2, -z+1/4, -x+3/4'
'-y+1/2, z+3/4, x+1/4'
'-y+3/4, -z+3/4, x'
'y+1/4, z+1/4, -x'
'y+3/4, x+3/4, -z'
'-y+1/4, -x+1/4, z'
'-y, -x+1/2, -z+1/2'
'y, x+1/2, z+1/2'
'y+1/4, -x, z+1/4'
'-y+3/4, x, -z+3/4'
'-y+1/2, x+1/4, z+3/4'
'y+1/2, -x+3/4, -z+1/4'
'x+3/4, z+3/4, -y'
'-x+1/4, -z+1/4, y'
'-x+1/2, z+1/4, y+3/4'
'x+1/2, -z+3/4, -y+1/4'
'-x, -z+1/2, -y+1/2'
'x, z+1/2, y+1/2'
'x+1/4, -z, y+1/4'
'-x+3/4, z, -y+3/4'
'z+3/4, y+3/4, -x'
'-z+1/4, -y+1/4, x'
'z+1/4, -y, x+1/4'
'-z+3/4, y, -x+3/4'
'-z+1/2, y+1/4, x+3/4'
'z+1/2, -y+3/4, -x+1/4'
'-z, -y+1/2, -x+1/2'
'z, y+1/2, x+1/2'
'x+1/2, y, z+1/2'
'-x+1/2, -y, -z+1/2'
'-x+1/4, -y+1/4, z'
'x+3/4, y+3/4, -z'
'-x+3/4, y+1/2, -z+1/4'
'x+1/4, -y+1/2, z+3/4'
'x, -y+3/4, -z+3/4'
'-x, y+1/4, z+1/4'
'z+1/2, x, y+1/2'
'-z+1/2, -x, -y+1/2'
'z, -x+3/4, -y+3/4'
'-z, x+1/4, y+1/4'
'-z+1/4, -x+1/4, y'
'z+3/4, x+3/4, -y'
'-z+3/4, x+1/2, -y+1/4'
'z+1/4, -x+1/2, y+3/4'
'y+1/2, z, x+1/2'
'-y+1/2, -z, -x+1/2'
'-y+3/4, z+1/2, -x+1/4'
'y+1/4, -z+1/2, x+3/4'
'y, -z+3/4, -x+3/4'
'-y, z+1/4, x+1/4'
'-y+1/4, -z+1/4, x'
'y+3/4, z+3/4, -x'
'y+1/4, x+1/4, -z'
'-y+3/4, -x+3/4, z'
'-y+1/2, -x, -z+1/2'
'y+1/2, x, z+1/2'
'y+3/4, -x+1/2, z+1/4'
'-y+1/4, x+1/2, -z+3/4'
'-y, x+3/4, z+3/4'
'y, -x+1/4, -z+1/4'
'x+1/4, z+1/4, -y'
'-x+3/4, -z+3/4, y'
'-x, z+3/4, y+3/4'
'x, -z+1/4, -y+1/4'
'-x+1/2, -z, -y+1/2'
'x+1/2, z, y+1/2'
'x+3/4, -z+1/2, y+1/4'
'-x+1/4, z+1/2, -y+3/4'
'z+1/4, y+1/4, -x'
'-z+3/4, -y+3/4, x'
'z+3/4, -y+1/2, x+1/4'
'-z+1/4, y+1/2, -x+3/4'
'-z, y+3/4, x+3/4'
'z, -y+1/4, -x+1/4'
'-z+1/2, -y, -x+1/2'
'z+1/2, y, x+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, -z'
'-x+1/4, -y+3/4, z+1/2'
'x+3/4, y+1/4, -z+1/2'
'-x+3/4, y, -z+3/4'
'x+1/4, -y, z+1/4'
'x, -y+1/4, -z+1/4'
'-x, y+3/4, z+3/4'
'z+1/2, x+1/2, y'
'-z+1/2, -x+1/2, -y'
'z, -x+1/4, -y+1/4'
'-z, x+3/4, y+3/4'
'-z+1/4, -x+3/4, y+1/2'
'z+3/4, x+1/4, -y+1/2'
'-z+3/4, x, -y+3/4'
'z+1/4, -x, y+1/4'
'y+1/2, z+1/2, x'
'-y+1/2, -z+1/2, -x'
'-y+3/4, z, -x+3/4'
'y+1/4, -z, x+1/4'
'y, -z+1/4, -x+1/4'
'-y, z+3/4, x+3/4'
'-y+1/4, -z+3/4, x+1/2'
'y+3/4, z+1/4, -x+1/2'
'y+1/4, x+3/4, -z+1/2'
'-y+3/4, -x+1/4, z+1/2'
'-y+1/2, -x+1/2, -z'
'y+1/2, x+1/2, z'
'y+3/4, -x, z+3/4'
'-y+1/4, x, -z+1/4'
'-y, x+1/4, z+1/4'
'y, -x+3/4, -z+3/4'
'x+1/4, z+3/4, -y+1/2'
'-x+3/4, -z+1/4, y+1/2'
'-x, z+1/4, y+1/4'
'x, -z+3/4, -y+3/4'
'-x+1/2, -z+1/2, -y'
'x+1/2, z+1/2, y'
'x+3/4, -z, y+3/4'
'-x+1/4, z, -y+1/4'
'z+1/4, y+3/4, -x+1/2'
'-z+3/4, -y+1/4, x+1/2'
'z+3/4, -y, x+3/4'
'-z+1/4, y, -x+1/4'
'-z, y+1/4, x+1/4'
'z, -y+3/4, -x+3/4'
'-z+1/2, -y+1/2, -x'
'z+1/2, y+1/2, x'
loop_
_atom_site_label
_atom_site_occupancy
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_adp_type
_atom_site_U_iso_or_equiv
_atom_site_type_symbol
H 1.0 0.932190 0.817810 0.580600 Uiso ? H
Ni1 1.0 0.000000 0.000000 0.000000 Uiso ? Ni
Co2 1.0 0.125000 0.125000 0.125000 Uiso ? Co
N1 1.0 0.670900 0.290360 0.579100 Uiso ? N
C1 1.0 0.654210 0.367800 0.595790 Uiso ? C
N2 1.0 0.625000 0.244960 0.625000 Uiso ? N
loop_
_atom_type_symbol
_atom_type_number_in_cell
_atom_type_scat_Cromer_Mann_a1
_atom_type_scat_Cromer_Mann_a2
_atom_type_scat_Cromer_Mann_a3
_atom_type_scat_Cromer_Mann_a4
_atom_type_scat_Cromer_Mann_b1
_atom_type_scat_Cromer_Mann_b2
_atom_type_scat_Cromer_Mann_b3
_atom_type_scat_Cromer_Mann_b4
_atom_type_scat_Cromer_Mann_c
_atom_type_scat_length_neutron
_atom_type_scat_source
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_dispersion_source
C 192 2.31 1.02 1.5886 0.865 20.8439 10.2075 0.5687 51.6512 0.2156 0.6648
https://github.com/AdvancedPhotonSource/GSAS-II/blob/master/GSASII/atmdata.py
0.018 0.009
https://github.com/AdvancedPhotonSource/GSAS-II/blob/master/GSASII/atmdata.py
H 192 0.493 0.3229 0.1402 0.0408 10.5109 26.1257 3.1424 57.7997 0.003 -0.3741
https://github.com/AdvancedPhotonSource/GSAS-II/blob/master/GSASII/atmdata.py
0.000 0.000
https://github.com/AdvancedPhotonSource/GSAS-II/blob/master/GSASII/atmdata.py
Co 8 12.2841 7.3409 4.0034 2.3488 4.2791 0.2784 13.5359 71.1692 1.0118 0.249
https://github.com/AdvancedPhotonSource/GSAS-II/blob/master/GSASII/atmdata.py
-2.365 3.614
https://github.com/AdvancedPhotonSource/GSAS-II/blob/master/GSASII/atmdata.py
N 288 12.2126 3.1322 2.0125 1.1663 0.0057 9.8933 28.9975 0.5826 -11.529 0.936
https://github.com/AdvancedPhotonSource/GSAS-II/blob/master/GSASII/atmdata.py
0.031 0.018
https://github.com/AdvancedPhotonSource/GSAS-II/blob/master/GSASII/atmdata.py
Ni 16 12.8376 7.292 4.4438 2.38 3.8785 0.2565 12.1763 66.3421 1.0341 1.03
https://github.com/AdvancedPhotonSource/GSAS-II/blob/master/GSASII/atmdata.py
-3.004 0.509
https://github.com/AdvancedPhotonSource/GSAS-II/blob/master/GSASII/atmdata.py
loop_
_diffrn_radiation_wavelength
_diffrn_radiation_wavelength_wt
_diffrn_radiation_wavelength_id
1.54050 1.0 1
1.54430 0.5000 2
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 N1 C1 52.5(7) 40_665 1_555 1_555 yes
N1 N1 C1 81.9(16) 40_665 1_555 40_665 yes
C1 N1 C1 29.4(19) 1_555 1_555 40_665 yes
N1 C1 N1 45.7(17) 1_555 1_555 40_665 yes
N1 C1 C1 109.4(7) 1_555 1_555 14_555 yes
N1 C1 C1 149.9(9) 40_665 1_555 14_555 yes
N1 C1 C1 81.8(23) 1_555 1_555 29_566 yes
N1 C1 C1 126.4(30) 40_665 1_555 29_566 yes
C1 C1 C1 29.0(20) 14_555 1_555 29_566 yes
N1 C1 C1 52.5(7) 1_555 1_555 40_665 yes
N1 C1 C1 98.1(16) 40_665 1_555 40_665 yes
C1 C1 C1 60 14_555 1_555 40_665 yes
C1 C1 C1 31.0(20) 29_566 1_555 40_665 yes
N1 C1 C1 138.2(19) 1_555 1_555 56_554 yes
N1 C1 C1 156.2(20) 40_665 1_555 56_554 yes
C1 C1 C1 31.0(20) 14_555 1_555 56_554 yes
C1 C1 C1 60 29_566 1_555 56_554 yes
C1 C1 C1 91.0(20) 40_665 1_555 56_554 yes
N1 C1 C1 160.2(7) 1_555 1_555 165_455 yes
N1 C1 C1 136.4(18) 40_665 1_555 165_455 yes
C1 C1 C1 60 14_555 1_555 165_455 yes
C1 C1 C1 89.0(20) 29_566 1_555 165_455 yes
C1 C1 C1 120 40_665 1_555 165_455 yes
C1 C1 C1 29.0(20) 56_554 1_555 165_455 yes
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
H H 1.5167 1_555 181_666 yes
Ni2 N2 2.062(14) 1_555 51_544 yes
Ni2 N2 2.062(14) 1_555 75_555 yes
Ni2 N2 2.062(14) 1_555 97_454 yes
Ni2 N2 2.062(14) 1_555 121_555 yes
Ni2 N2 2.062(14) 1_555 146_445 yes
Ni2 N2 2.062(14) 1_555 170_555 yes
N1 N1 1.058(31) 1_555 40_555 yes
N1 C1 1.465(22) 1_555 1_555 yes
N1 C1 1.815(27) 1_555 29_555 yes
N1 C1 1.174(12) 1_555 40_555 yes
N1 N2 1.503(17) 1_555 1_555 yes
C1 N1 1.465(22) 1_555 1_555 yes
C1 N1 1.174(12) 1_555 40_555 yes
C1 N1 1.815(27) 1_555 56_555 yes
C1 C1 1.502(22) 1_555 14_555 yes
C1 C1 1.301(18) 1_555 29_555 yes
C1 C1 0.73(5) 1_555 40_555 yes
C1 C1 1.301(18) 1_555 56_555 yes
C1 C1 0.77(4) 1_555 165_555 yes
C1 N2 1.696(27) 1_555 40_555 yes
N2 Ni2 2.062(14) 1_555 97_555 yes
N2 N1 1.503(17) 1_555 1_555 yes
N2 N1 1.503(16) 1_555 14_555 yes
N2 C1 1.696(27) 1_555 29_555 yes
N2 C1 1.696(27) 1_555 40_555 yes
loop_
_pd_meas_intensity_total
_pd_calc_intensity_total
_pd_proc_intensity_bkg_calc
_pd_proc_ls_weight
76002.8672 75888.6603 74501.6054 0.0000131574
76262.9531 76217.8327 74817.8462 0.00001311253
76848.5859 76539.8738 75126.7639 0.0000130126
76207.0156 76855.1682 75428.7378 0.00001312215
77836.4453 77164.0979 75724.1471 0.00001284745
76787.3438 77467.0453 76013.3691 0.00001302298
77641.9688 77764.3862 76296.7762 0.00001287963
77832.7656 78056.4917 76574.7346 0.00001284806
79077.3203 78343.7381 76847.6022 0.00001264585
78933.1875 78626.4498 77115.7274 0.00001266894
77965.1094 78904.9833 77379.4478 0.00001282625
78330.3984 79179.6688 77639.0887 0.00001276644
80711.2969 79450.8242 77894.9632 0.00001238984
79207.2031 79718.7537 78147.3704 0.00001262511
80575.9141 79983.7479 78396.5958 0.00001241066
79967.5312 80246.0829 78642.9102 0.00001250508
80845.2109 80506.0204 78886.5698 0.00001236932
79776.7266 80763.8074 79127.816 0.00001253498
81477.875 81019.6765 79366.8751 0.00001227327
81954.0391 81273.8335 79603.9588 0.00001220196
81811.9844 81526.5036 79839.2639 0.00001222315
81180.4766 81777.8635 80072.9725 0.00001231823
82079.1172 82028.0889 80305.2526 0.00001218337
82800.0938 82277.3389 80536.2581 0.00001207728
81500.3047 82525.7622 80766.1294 0.00001226989
83623.8984 82773.4915 80994.9938 0.0000119583
83251.6797 83020.6446 81222.9655 0.00001201177
83962.8516 83267.3399 81450.1469 0.00001191003
84495.8828 83513.6859 81676.6284 0.0000118349
85171.3047 83759.7403 81902.4893 0.00001174104
84505.1094 84005.5954 82127.7983 0.0000118336
82127.8516 84251.3167 82352.6141 0.00001217614
84885.7656 84496.9628 82576.9857 0.00001178054
84403.2188 84742.5819 82800.9535 0.00001184789
83159.4844 84988.2159 83024.5492 0.00001202509
84808.25 85233.8977 83247.7972 0.00001179131
85567.9297 85479.6542 83470.7146 0.00001168662
86621.1094 85725.5054 83693.3116 0.00001154453
86031.7891 85971.4667 83915.5929 0.00001162361
85749.0156 86217.5541 84137.5575 0.00001166194
86966.6953 86463.7583 84359.1994 0.00001149865
86482.3438 86710.0881 84580.5084 0.00001156305
85135.8203 86956.5403 84801.4703 0.00001174594
86886.1562 87203.1096 85022.0677 0.00001150931
88718.1797 87449.7869 85242.2801 0.00001127165
87202.3594 87696.564 85462.0848 0.00001146758
88242.6406 87943.427 85681.457 0.00001133239
86839.9219 88190.3653 85900.3703 0.00001151544
88039.6328 88437.3629 86118.7973 0.00001135852
88711.8359 88684.4089 86336.7097 0.00001127245
90018.2266 88931.4863 86554.079 0.00001110886
89363.6094 89178.5851 86770.8764 0.00001119024
89773.4844 89425.6898 86987.0735 0.00001113915
89279.9375 89672.7918 87202.6424 0.00001120072
90573.4531 89919.8782 87417.5563 0.00001104076
89597.0391 90166.9438 87631.7893 0.00001116108
89997.6016 90413.9797 87845.3168 0.00001111141
91795.3438 90660.9832 88058.1158 0.0000108938
90940.7656 90907.9518 88270.1654 0.00001099617
90985.1875 91154.8878 88481.4463 0.0000109908
91475.1719 91401.7933 88691.9413 0.00001093193
92695.0312 91648.6762 88901.6358 0.00001078806
91106.9844 91895.5464 89110.5174 0.00001097611
92071.3984 92142.4166 89318.5761 0.00001086114
92198.6797 92389.3044 89525.8047 0.00001084614
93473.6719 92636.2297 89732.1986 0.0000106982
93229.6562 92883.2165 89937.7559 0.0000107262
93987.6484 93130.2923 90142.4776 0.0000106397
93821.0312 93377.49 90346.3674 0.00001065859
92548.9609 93624.8424 90549.4319 0.00001080509
92793.8359 93872.3921 90751.6805 0.00001077658
94116.0703 94120.1986 90953.1254 0.00001062518
93844.2969 94368.2739 91153.7819 0.00001065595
93955.4297 94616.6847 91353.6677 0.00001064334
95788.9062 94865.491 91552.8035 0.00001043962
95388.6562 95114.7483 91751.2127 0.00001048343
94859.6797 95364.5159 91948.9211 0.00001054189
95922.9141 95614.8733 92145.9574 0.00001042504
95587.6328 95865.8901 92342.3525 0.0000104616
95431.6641 96117.636 92538.1401 0.0000104787
96671.9609 96370.1967 92733.3557 0.00001034426
97002.8672 96623.6515 92928.0376 0.00001030897
96380.4531 96878.0912 93122.2257 0.00001037555
98158.4375 97133.5464 93315.9624 0.00001018761
97152.7578 97390.2344 93509.2917 0.00001029307
98612.0938 97648.1903 93702.2594 0.00001014074
99444.2578 97907.5276 93894.9132 0.00001005588
98583.3984 98168.3488 94087.3022 0.0000101437
98930.7656 98430.7677 94279.4769 0.00001010808
98665.1953 98694.9002 94471.4893 0.00001013529
97888.8828 98960.8656 94663.3924 0.00001021566
99732.8438 99228.7891 94855.2402 0.00001002679
98203.9297 99498.7983 95047.0879 0.00001018289
100624.375 99771.0284 95238.9913 0.00000993795
101053.5 100045.5767 95431.0069 0.00000989575
100741.1562 100322.6592 95623.1917 0.00000992643
100224.4688 100602.3814 95815.6032 0.0000099776
102482.7188 100884.8992 96008.2991 0.00000975774
101254.5625 101170.359 96201.3373 0.0000098761
100898.7578 101458.9282 96394.7757 0.00000991092
101504.4141 101750.8043 96588.6723 0.00000985179
101346.2734 102046.0819 96783.0845 0.00000986716
102672.9297 102344.9695 96978.0697 0.00000973967
102643.6094 102647.6505 97173.6848 0.00000974245
101826.625 102954.3069 97369.9861 0.00000982061
101743.4531 103265.1333 97567.0291 0.00000982864
103290.0312 103580.3241 97764.8689 0.00000968148
103541.0391 103900.0835 97963.5593 0.00000965801
104235.7578 104224.6233 98163.1535 0.00000959364
104606.3125 104554.1801 98363.7033 0.00000955965
105828.9609 104888.9401 98565.2596 0.00000944921
106041.2656 105229.1562 98767.872 0.00000943029
106301.0391 105575.0719 98971.5887 0.00000940725
105392.8203 105926.9379 99176.4566 0.00000948831
107245.5312 106285.0177 99382.5209 0.0000093244
107030.2031 106649.5814 99589.8254 0.00000934316
106406.125 107020.9143 99798.4124 0.00000939796
108462.6328 107399.3103 100008.3224 0.00000921977
108540.9688 107785.0787 100219.594 0.00000921311
108000.5781 108178.5441 100432.2642 0.00000925921
108302.4297 108580.0427 100646.3681 0.0000092334
109310.5234 108989.9291 100861.939 0.00000914825
109184.9922 109408.5787 101079.008 0.00000915877
110667.5625 109836.3718 101297.6046 0.00000903607
111118.2578 110273.7349 101517.7559 0.00000899942
110561.7578 110721.0902 101739.4873 0.00000904472
110609.2812 111178.9012 101962.8219 0.00000904083
111142.8125 111647.6402 102187.7809 0.00000899743
112335.4453 112127.8299 102414.3834 0.00000890191
112818.9688 112620.0046 102642.6461 0.00000886376
112400.8203 113124.7477 102872.584 0.00000889673
112640.6094 113642.6647 103104.2097 0.00000887779
115161.9922 114174.4106 103337.5338 0.00000868342
112603.4766 114720.6767 103572.5647 0.00000888072
113353.8125 115282.2083 103809.3087 0.00000882194
115119.2344 115859.7984 104047.7701 0.00000868665
115419.125 116454.302 104287.951 0.00000866408
116000.4844 117066.633 104529.8514 0.00000862065
118322.7734 117697.7799 104773.4693 0.00000845146
117544.4297 118348.8039 105018.8007 0.00000850742
117950.5625 119020.8581 105265.8394 0.00000847813
118838.5547 119715.1865 105514.5775 0.00000841478
119166.4219 120433.1427 105765.005 0.00000839163
119506.7188 121176.1999 106017.1099 0.00000836773
120816.5859 121945.9638 106270.8785 0.00000827701
122072.1719 122744.1851 106526.295 0.00000819188
123051.8516 123572.7814 106783.3421 0.00000812666
122476.7344 124433.8678 107042.0005 0.00000816482
124481.6562 125329.7233 107302.2492 0.00000803331
126976.1875 126262.9262 107564.0657 0.00000787549
126344.75 127236.229 107827.4256 0.00000791485
127369.5469 128252.76 108092.3033 0.00000785117
128950.5312 129315.843 108358.6712 0.00000775491
128312.8672 130429.2888 108626.5006 0.00000779345
130980.8203 131597.1402 108895.7613 0.00000763471
133165.4844 132824.0128 109166.4216 0.00000750945
134964.5469 134114.8034 109438.4486 0.00000740935
134188.25 135475.0975 109711.8082 0.00000745222
136044.0156 136910.8045 109986.4648 0.00000735056
139170 138428.6188 110262.3822 0.00000718546
138475.9219 140035.6754 110539.5225 0.00000722147
142428.1562 141739.8064 110817.8474 0.00000702108
144266.2031 143549.5407 111097.3171 0.00000693163
145539.0156 145474.2189 111377.8912 0.00000687101
148262.5781 147523.7517 111659.5284 0.00000674479
153612.875 149708.7799 111942.1867 0.00000650987
153218.3281 152040.9609 112225.8232 0.00000652663
156783.4844 154532.4652 112510.3944 0.00000637822
159721.6719 157196.4401 112795.8564 0.00000626089
162735.2812 160046.4673 113082.1645 0.00000614495
166450.0781 163097.2577 113369.2737 0.00000600781
169675.7969 166363.6359 113657.1385 0.00000589359
171659.0312 169861.5132 113945.713 0.0000058255
176443.7031 173606.5994 114234.9512 0.00000566753
181993.5625 177615.4771 114524.8067 0.0000054947
186175.4219 181903.9749 114815.2328 0.00000537128
187850.5156 186488.3431 115106.183 0.00000532338
196053.375 191383.2147 115397.6104 0.00000510065
199174.3438 196602.7246 115689.4683 0.00000502073
207335.5 202157.959 115981.7099 0.0000048231
210622.3281 208057.9026 116274.2887 0.00000474783
217084.0312 214306.2083 116567.158 0.00000460651
224156.375 220901.7966 116860.2717 0.00000446117
230103.7188 227834.6977 117153.5836 0.00000434587
236885.1094 235086.2566 117447.0479 0.00000422146
245117.4531 242623.967 117740.6192 0.00000407968
250810.5469 250401.401 118034.2525 0.00000398707
257003.3125 258352.6979 118327.9031 0.000003891
266563.2812 266391.5987 118621.5268 0.00000375145
273545.6875 274409.1185 118915.08 0.0000036557
282542.3438 282272.0932 119208.5197 0.00000353929
286174.1875 289825.2615 119501.8032 0.00000349438
291575.7188 296893.4876 119794.8888 0.00000342964
300996.0938 303290.4306 120087.7352 0.0000033223
308498.7188 308826.0925 120380.3019 0.0000032415
311892.6875 313321.4846 120672.5492 0.00000320623
313950.875 316620.7006 120964.438 0.00000318521
319390.0625 318606.2143 121255.9301 0.00000313097
322351.8438 319209.0782 121546.9882 0.0000031022
319379.625 318416.5645 121837.5756 0.00000313107
316045.6875 316273.2822 122127.6568 0.0000031641
314691.25 312876.2083 122417.1969 0.00000317772
311576.9688 308366.0554 122706.1621 0.00000320948
306696.25 302912.8332 122994.5196 0.00000326056
300358.2188 296703.6472 123282.2373 0.00000332936
292540.25 289927.1824 123569.2843 0.00000341833
287377.2812 282765.0083 123855.6307 0.00000347975
280046.5312 275380.894 124141.2476 0.00000357084
269642.5938 267918.7767 124426.1068 0.00000370861
261544.2969 260497.5358 124710.1817 0.00000382344
251997.1562 253214.0596 124993.4464 0.0000039683
243587.2344 246141.9447 125275.8759 0.00000410531
237108.4688 239336.7066 125557.4468 0.00000421748
228067.9688 232835.8969 125838.1362 0.00000438466
222414.8438 226664.4592 126117.9226 0.0000044961
215665.8906 220835.7915 126396.7855 0.0000046368
211253.3438 215354.3969 126674.7054 0.00000473365
204230.3594 210218.8771 126951.6641 0.00000489643
198668.0312 205421.9278 127227.6442 0.00000503352
194811.4531 200953.6422 127502.6295 0.00000513317
192354.5938 196800.6754 127776.605 0.00000519873
190147.6719 192948.8711 128049.5565 0.00000525907
182163.7344 189382.2241 128321.4712 0.00000548957
182281.8906 186084.9552 128592.3369 0.00000548601
178619.1719 183040.3993 128862.1429 0.0000055985
175498.5938 180232.6836 129130.8794 0.00000569805
174348.875 177645.6353 129398.5374 0.00000573563
170275.5938 175264.1507 129665.1093 0.00000587283
169136.7188 173073.1461 129930.5881 0.00000591238
170898.7188 171058.7295 130194.9681 0.00000585142
166702.7188 169207.2794 130458.2445 0.0000059987
167142.75 167506.3202 130720.4135 0.00000598291
165066.75 165943.7771 130981.472 0.00000605816
163884.0469 164508.7048 131241.4182 0.00000610188
162444.4844 163190.5803 131500.2509 0.00000615595
162956.8906 161979.9155 131757.9701 0.00000613659
161301.7812 160867.8123 132014.5763 0.00000619956
158885.1875 159846.0864 132270.0712 0.00000629385
159147.6094 158907.146 132524.4572 0.00000628347
159870.4062 158044.1619 132777.7375 0.00000625507
157989.7188 157250.8799 133029.9161 0.00000632953
157359.4375 156521.4789 133280.9978 0.00000635488
158173.7969 155850.767 133530.9882 0.00000632216
155091.6562 155233.9509 133779.8935 0.0000064478
158333.6719 154666.7716 134027.7206 0.00000631578
154711.4844 154145.2295 134274.4773 0.00000646364
154640.6562 153665.8369 134520.1719 0.0000064666
153863.5781 153225.2964 134764.8133 0.00000649926
154077.5312 152820.7386 135008.411 0.00000649024
153862.9844 152449.4424 135250.9752 0.00000649929
153176.1719 152109.0478 135492.5167 0.00000652843
153292.75 151797.2953 135733.0466 0.00000652347
153160.0312 151512.2365 135972.5766 0.00000652912
150578.0625 151251.9938 136211.1191 0.00000664107
153080.5 151014.9397 136448.6866 0.00000653251
150132.625 150799.5046 136685.2923 0.00000666078
151330.9219 150604.3298 136920.9497 0.00000660803
150983.2969 150428.0843 137155.6727 0.00000662325
149762.2969 150269.6274 137389.4756 0.00000667725
152372.8125 150127.8262 137622.3728 0.00000656285
150121.5781 150001.6997 137854.3794 0.00000666127
149721.25 149890.3153 138085.5104 0.00000667908
149973.875 149792.8109 138315.7812 0.00000666783
150962.4844 149708.363 138545.2076 0.00000662416
150700.8906 149636.2465 138773.8052 0.00000663566
149375.75 149575.781 139001.5902 0.00000669453
150093.4375 149526.2989 139228.5787 0.00000666252
150100.0156 149487.2168 139454.787 0.00000666222
150185.7031 149457.9575 139680.2314 0.00000665842
150139.4062 149438.0201 139904.9284 0.00000666048
151301.5625 149426.8905 140128.8947 0.00000660932
151425.6094 149424.134 140352.1467 0.0000066039
151418.7344 149429.2995 140574.7009 0.0000066042
151509.5 149442.0049 140796.5741 0.00000660025
151499.0625 149461.8535 141017.7826 0.0000066007
151830.8125 149488.5099 141238.343 0.00000658628
149344.5625 149521.6222 141458.2716 0.00000669593
151044.5781 149560.8977 141677.5848 0.00000662056
152292.9844 149606.0239 141896.2988 0.00000656629
150477.75 149656.7409 142114.4295 0.0000066455
150468.5938 149712.7717 142331.9929 0.00000664591
150017.3281 149773.8869 142549.0047 0.0000066659
150735.4219 149839.8405 142765.4804 0.00000663414
150558.7344 149910.4296 142981.4353 0.00000664193
149735.0312 149985.4313 143196.8845 0.00000667846
150520.9531 150064.6646 143411.8429 0.00000664359
151224.2969 150147.9417 143626.325 0.00000661269
151094.875 150235.0912 143840.3451 0.00000661836
150766.4531 150325.9419 144053.9173 0.00000663278
148900.0781 150420.3423 144267.0553 0.00000671591
150520.0156 150518.1521 144479.7724 0.00000664363
150073.625 150619.2228 144692.0817 0.0000066634
151022.2969 150723.4277 144903.9959 0.00000662154
152776.0312 150830.6358 145115.5275 0.00000654553
151510.0625 150940.7378 145326.6884 0.00000660022
151982.3594 151053.6102 145537.4902 0.00000657971
152758.0625 151169.1555 145747.9441 0.0000065463
151989.6094 151287.2624 145958.061 0.0000065794
151889.6562 151407.8432 146167.8514 0.00000658373
150732.8594 151530.7966 146377.3252 0.00000663425
150843.8438 151656.0428 146586.492 0.00000662937
152632.6562 151783.4905 146795.361 0.00000655168
151735.3125 151913.0666 147003.9409 0.00000659042
151596.375 152044.6883 147212.24 0.00000659646
151298.7031 152178.2884 147420.2662 0.00000660944
151854.4375 152313.791 147628.0268 0.00000658525
153298.1406 152451.1336 147835.5288 0.00000652324
152224.4219 152590.2525 148042.7786 0.00000656925
154608.4844 152731.086 148249.7823 0.00000646795
153419.1562 152873.5713 148456.5454 0.00000651809
151827.2188 153017.655 148663.0731 0.00000658643
154170.8906 153163.2857 148869.3698 0.00000648631
152748.5781 153310.4073 149075.4398 0.00000654671
154586.2188 153458.9681 149281.2868 0.00000646888
150899.5469 153608.9224 149486.9139 0.00000662693
154381.6406 153760.2256 149692.3239 0.00000647745
152619.2031 153912.8304 149897.5191 0.00000655226
153879.2031 154066.6899 150102.5014 0.0000064986
152035.2656 154221.7657 150307.272 0.00000657742
154741.6094 154378.0187 150511.8318 0.00000646239
153785.9688 154535.4065 150716.1814 0.00000650254
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