#------------------------------------------------------------------------------
#$Date: 2025-10-06 11:28:13 +0200 (Mon 06 de Oct de 2025) $
#$Revision: 302650 $
#$URL: svn://www.crystallography.net/cod/cif/1/57/54/1575446.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1575446
loop_
_publ_author_name
'Losev, Mikhail A.'
'Yessengazin, Azamat'
'Fayzullin, Robert R.'
'Khaskin, Eugene'
_publ_section_title
;
 Synthesis of a series of PNC pincer ligand-supported Pt complexes, and an
 initial exploration of their reactivity.
;
_journal_issue                   36
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13712
_journal_page_last               13721
_journal_paper_doi               10.1039/d5dt01800e
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety
'C40 H60 Ag N2 O3 P2 Pt2, 3(B F4), C H2 Cl2, 2(H2 O)'
_chemical_formula_sum            'C41 H66 Ag B3 Cl2 F12 N2 O5 P2 Pt2'
_chemical_formula_weight         1558.27
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2025-03-17 deposited with the CCDC.	2025-08-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90.2558(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   13.82467(8)
_cell_length_b                   16.86122(13)
_cell_length_c                   22.93789(15)
_cell_measurement_reflns_used    51720
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      79.3450
_cell_measurement_theta_min      3.2000
_cell_volume                     5346.79(6)
_computing_cell_refinement       'CrysAlisPro 1.171.44.98a (Rigaku OD, 2025)'
_computing_data_collection       'CrysAlisPro 1.171.44.98a (Rigaku OD, 2025)'
_computing_data_reduction        'CrysAlisPro 1.171.44.98a (Rigaku OD, 2025)'
_computing_molecular_graphics
;
WinGX (Farrugia, 2012); ORTEP-3 (Farrugia, 2012);
PLATON (Spek, 2009); Olex2 (Dolomanov et al., 2009)
;
_computing_publication_material
;
WinGX (Farrugia, 2012); ORTEP-3 (Farrugia, 2012);
PLATON (Spek, 2009); Olex2 (Dolomanov et al., 2009)
;
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT-2018/2 (Sheldrick, 2015)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Rigaku XtaLAB Pro: Kappa dual offset/far'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0606
_diffrn_reflns_av_unetI/netI     0.0348
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            88930
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         74.498
_diffrn_reflns_theta_min         3.197
_diffrn_source                   'microfocus sealed X-ray tube'
_exptl_absorpt_coefficient_mu    14.733
_exptl_absorpt_correction_T_max  0.810
_exptl_absorpt_correction_T_min  0.271
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.44.98a (Rigaku Oxford Diffraction, 2025).
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model. Empirical absorption correction using
spherical harmonics, frame scaling and detector area scaling,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_density_diffrn    1.936
_exptl_crystal_description       prism
_exptl_crystal_F_000             3024
_exptl_crystal_size_max          0.148
_exptl_crystal_size_mid          0.045
_exptl_crystal_size_min          0.038
_refine_diff_density_max         2.338
_refine_diff_density_min         -1.970
_refine_diff_density_rms         0.140
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.123
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     755
_refine_ls_number_reflns         10937
_refine_ls_number_restraints     1034
_refine_ls_restrained_S_all      1.088
_refine_ls_R_factor_all          0.0447
_refine_ls_R_factor_gt           0.0432
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0312P)²+39.7295P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1060
_refine_ls_wR_factor_ref         0.1069
_reflns_Friedel_coverage         0.000
_reflns_number_gt                10475
_reflns_number_total             10937
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5dt01800e2.cif
_cod_data_source_block           rjk1794
_cod_depositor_comments
'Adding full bibliography for 1575440--1575446.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               1575446
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.219
_shelx_estimated_absorpt_t_max   0.604
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.25441(2) 0.23854(2) 0.66702(2) 0.03273(8) Uani 1 1 d . . . . .
Pt2 Pt 0.62732(2) 0.17707(2) 0.56125(2) 0.02812(8) Uani 1 1 d . . . . .
Ag1 Ag 0.45628(3) 0.21794(3) 0.62836(2) 0.04184(12) Uani 1 1 d D . . . .
P1 P 0.15422(12) 0.17089(10) 0.72963(7) 0.0343(3) Uani 1 1 d . . . . .
P2 P 0.71983(10) 0.26625(8) 0.50852(6) 0.0273(3) Uani 1 1 d . . . . .
O1 O 0.3088(4) 0.3172(3) 0.7286(2) 0.0473(12) Uani 1 1 d . . . . .
H1A H 0.286117 0.364480 0.721835 0.071 Uiso 1 1 d R U . . .
H1B H 0.371077 0.321969 0.724086 0.071 Uiso 1 1 d R U . . .
O2 O 0.7193(4) 0.1678(4) 0.6324(3) 0.0587(16) Uani 1 1 d . . . . .
H2A H 0.686245 0.174047 0.664278 0.088 Uiso 1 1 d R U . . .
H2B H 0.741422 0.119561 0.634614 0.088 Uiso 1 1 d R U . . .
O3 O 0.5011(6) 0.3155(6) 0.7045(4) 0.044(3) Uani 0.59(2) 1 d D . P A 1
H3A H 0.549616 0.346296 0.692320 0.066 Uiso 0.59(2) 1 d R U P A 1
H3B H 0.526118 0.291128 0.735765 0.066 Uiso 0.59(2) 1 d R U P A 1
O3' O 0.4994(10) 0.2690(13) 0.7281(6) 0.053(6) Uani 0.41(2) 1 d D . P A 2
H3'A H 0.508665 0.226441 0.761456 0.080 Uiso 0.41(2) 1 d R U P A 2
H3'B H 0.567333 0.295981 0.732989 0.080 Uiso 0.41(2) 1 d R U P A 2
N1 N 0.2043(4) 0.1627(3) 0.6067(2) 0.0308(10) Uani 1 1 d . . . . .
N2 N 0.5410(3) 0.1749(3) 0.4919(2) 0.0266(10) Uani 1 1 d . . . . .
C11 C 0.0327(5) 0.2180(4) 0.7371(3) 0.0370(14) Uani 1 1 d . . . . .
C12 C -0.0114(5) 0.2216(5) 0.6758(3) 0.0431(16) Uani 1 1 d . . . . .
H12A H 0.034003 0.247741 0.649371 0.065 Uiso 1 1 calc R U . . .
H12B H -0.071997 0.251626 0.676979 0.065 Uiso 1 1 calc R U . . .
H12C H -0.024339 0.167620 0.661963 0.065 Uiso 1 1 calc R U . . .
C13 C 0.0446(5) 0.3026(4) 0.7602(3) 0.0441(16) Uani 1 1 d . . . . .
H13A H 0.080368 0.301479 0.797128 0.066 Uiso 1 1 calc R U . . .
H13B H -0.019347 0.326162 0.766419 0.066 Uiso 1 1 calc R U . . .
H13C H 0.080291 0.334403 0.731692 0.066 Uiso 1 1 calc R U . . .
C14 C -0.0355(6) 0.1709(5) 0.7770(3) 0.0507(19) Uani 1 1 d . . . . .
H14A H -0.038871 0.115720 0.763750 0.076 Uiso 1 1 calc R U . . .
H14B H -0.100232 0.194508 0.775653 0.076 Uiso 1 1 calc R U . . .
H14C H -0.010841 0.172445 0.817149 0.076 Uiso 1 1 calc R U . . .
C21 C 0.2069(7) 0.1331(6) 0.7993(4) 0.058(2) Uani 1 1 d . . . . .
C22 C 0.3124(7) 0.1132(7) 0.7856(5) 0.076(3) Uani 1 1 d . . . . .
H22A H 0.314640 0.071296 0.755973 0.113 Uiso 1 1 calc R U . . .
H22B H 0.345084 0.094865 0.821099 0.113 Uiso 1 1 calc R U . . .
H22C H 0.345121 0.160636 0.770798 0.113 Uiso 1 1 calc R U . . .
C23 C 0.2028(10) 0.1990(8) 0.8450(4) 0.089(4) Uani 1 1 d . . . . .
H23A H 0.231513 0.247406 0.829009 0.133 Uiso 1 1 calc R U . . .
H23B H 0.238902 0.182585 0.879797 0.133 Uiso 1 1 calc R U . . .
H23C H 0.135232 0.209143 0.855382 0.133 Uiso 1 1 calc R U . . .
C24 C 0.1561(8) 0.0593(6) 0.8217(4) 0.071(3) Uani 1 1 d . . . . .
H24A H 0.087748 0.071250 0.828615 0.106 Uiso 1 1 calc R U . . .
H24B H 0.186547 0.042123 0.858266 0.106 Uiso 1 1 calc R U . . .
H24C H 0.161261 0.016821 0.792704 0.106 Uiso 1 1 calc R U . . .
C31 C 0.8293(5) 0.2237(4) 0.4728(3) 0.0350(13) Uani 1 1 d . . . . .
C32 C 0.7892(6) 0.1527(5) 0.4376(4) 0.0511(19) Uani 1 1 d . . . . .
H32A H 0.758088 0.115092 0.464154 0.077 Uiso 1 1 calc R U . . .
H32B H 0.842415 0.126211 0.417288 0.077 Uiso 1 1 calc R U . . .
H32C H 0.741712 0.171732 0.409004 0.077 Uiso 1 1 calc R U . . .
C33 C 0.8993(5) 0.1916(5) 0.5188(4) 0.0485(17) Uani 1 1 d . . . . .
H33A H 0.927740 0.235977 0.540523 0.073 Uiso 1 1 calc R U . . .
H33B H 0.950740 0.161487 0.499632 0.073 Uiso 1 1 calc R U . . .
H33C H 0.864311 0.156914 0.545691 0.073 Uiso 1 1 calc R U . . .
C34 C 0.8801(5) 0.2801(5) 0.4315(3) 0.0426(16) Uani 1 1 d . . . . .
H34A H 0.833353 0.301054 0.403184 0.064 Uiso 1 1 calc R U . . .
H34B H 0.931442 0.251668 0.410847 0.064 Uiso 1 1 calc R U . . .
H34C H 0.908422 0.324041 0.453736 0.064 Uiso 1 1 calc R U . . .
C41 C 0.7399(5) 0.3654(4) 0.5431(3) 0.0364(14) Uani 1 1 d . . . . .
C42 C 0.6506(6) 0.3844(6) 0.5789(4) 0.063(2) Uani 1 1 d . . . . .
H42A H 0.638743 0.341310 0.606661 0.095 Uiso 1 1 calc R U . . .
H42B H 0.594575 0.390094 0.552941 0.095 Uiso 1 1 calc R U . . .
H42C H 0.660937 0.434048 0.600279 0.095 Uiso 1 1 calc R U . . .
C43 C 0.8266(6) 0.3587(5) 0.5859(3) 0.0516(18) Uani 1 1 d . . . . .
H43A H 0.832812 0.408147 0.608056 0.077 Uiso 1 1 calc R U . . .
H43B H 0.886045 0.349328 0.563828 0.077 Uiso 1 1 calc R U . . .
H43C H 0.815672 0.314504 0.612765 0.077 Uiso 1 1 calc R U . . .
C44 C 0.7592(6) 0.4313(4) 0.4995(4) 0.0522(19) Uani 1 1 d . . . . .
H44A H 0.705477 0.434181 0.471503 0.078 Uiso 1 1 calc R U . . .
H44B H 0.819407 0.420172 0.478637 0.078 Uiso 1 1 calc R U . . .
H44C H 0.765029 0.481934 0.520111 0.078 Uiso 1 1 calc R U . . .
C101 C 0.1351(5) 0.0818(4) 0.6843(3) 0.0391(14) Uani 1 1 d . . . . .
H10A H 0.181172 0.039944 0.696403 0.047 Uiso 1 1 calc R U . . .
H10B H 0.068710 0.061516 0.690437 0.047 Uiso 1 1 calc R U . . .
C102 C 0.1491(4) 0.1001(4) 0.6207(3) 0.0324(13) Uani 1 1 d . . . . .
C103 C 0.1098(5) 0.0534(4) 0.5774(3) 0.0419(16) Uani 1 1 d . . . . .
H103 H 0.070606 0.009144 0.587205 0.050 Uiso 1 1 calc R U . . .
C104 C 0.1274(5) 0.0711(5) 0.5202(3) 0.0421(16) Uani 1 1 d . . . . .
H104 H 0.099262 0.039912 0.490071 0.050 Uiso 1 1 calc R U . . .
C105 C 0.1863(5) 0.1346(4) 0.5063(3) 0.0400(15) Uani 1 1 d . . . . .
H105 H 0.199673 0.146372 0.466615 0.048 Uiso 1 1 calc R U . . .
C106 C 0.2258(4) 0.1810(4) 0.5502(3) 0.0339(13) Uani 1 1 d . . . . .
C107 C 0.2885(5) 0.2507(4) 0.5436(3) 0.0408(16) Uani 1 1 d . . . . .
C108 C 0.3131(6) 0.2809(5) 0.4887(4) 0.053(2) Uani 1 1 d . . . . .
H108 H 0.292832 0.254274 0.454276 0.063 Uiso 1 1 calc R U . . .
C109 C 0.3673(6) 0.3500(5) 0.4852(5) 0.062(3) Uani 1 1 d . . . . .
H109 H 0.384693 0.370366 0.448108 0.075 Uiso 1 1 calc R U . . .
C110 C 0.3957(6) 0.3889(5) 0.5344(5) 0.061(2) Uani 1 1 d . . . . .
H110 H 0.431320 0.436921 0.531376 0.073 Uiso 1 1 calc R U . . .
C111 C 0.3728(6) 0.3586(4) 0.5894(4) 0.057(2) Uani 1 1 d . . . . .
H111 H 0.393600 0.385927 0.623380 0.068 Uiso 1 1 calc R U . . .
C112 C 0.3196(5) 0.2886(4) 0.5950(3) 0.0404(15) Uani 1 1 d . . . . .
C201 C 0.6320(5) 0.2848(4) 0.4495(3) 0.0374(14) Uani 1 1 d . . . . .
H20A H 0.598850 0.335819 0.456836 0.045 Uiso 1 1 calc R U . . .
H20B H 0.667086 0.289524 0.412119 0.045 Uiso 1 1 calc R U . . .
C202 C 0.5578(4) 0.2204(4) 0.4442(3) 0.0300(12) Uani 1 1 d . . . . .
C203 C 0.5038(4) 0.2089(4) 0.3939(3) 0.0335(13) Uani 1 1 d . . . . .
H203 H 0.515363 0.240671 0.360451 0.040 Uiso 1 1 calc R U . . .
C204 C 0.4332(4) 0.1511(4) 0.3925(3) 0.0342(13) Uani 1 1 d . . . . .
H204 H 0.396845 0.142029 0.357882 0.041 Uiso 1 1 calc R U . . .
C205 C 0.4156(4) 0.1063(4) 0.4423(3) 0.0305(12) Uani 1 1 d . . . . .
H205 H 0.366596 0.066771 0.441926 0.037 Uiso 1 1 calc R U . . .
C206 C 0.4695(4) 0.1192(3) 0.4923(3) 0.0285(12) Uani 1 1 d . . . . .
C207 C 0.4576(4) 0.0784(3) 0.5485(3) 0.0292(12) Uani 1 1 d . . . . .
C208 C 0.3846(4) 0.0234(3) 0.5600(3) 0.0321(13) Uani 1 1 d . . . . .
H208 H 0.340386 0.008374 0.530104 0.038 Uiso 1 1 calc R U . . .
C209 C 0.3772(5) -0.0091(4) 0.6153(3) 0.0352(14) Uani 1 1 d . . . . .
H209 H 0.326749 -0.045709 0.623266 0.042 Uiso 1 1 calc R U . . .
C210 C 0.4418(5) 0.0108(4) 0.6589(3) 0.0359(14) Uani 1 1 d . . . . .
H210 H 0.435560 -0.011787 0.696608 0.043 Uiso 1 1 calc R U . . .
C211 C 0.5164(5) 0.0643(4) 0.6473(3) 0.0336(13) Uani 1 1 d . . . . .
H211 H 0.561681 0.076987 0.677142 0.040 Uiso 1 1 calc R U . . .
C212 C 0.5253(4) 0.0996(3) 0.5922(3) 0.0277(11) Uani 1 1 d . . . . .
B1 B 0.5633(4) 0.0554(4) 0.8409(3) 0.054(2) Uani 1 1 d D . . . .
F11 F 0.5410(4) 0.1235(3) 0.8098(3) 0.0828(17) Uani 1 1 d D . . . .
F12 F 0.6618(3) 0.0544(3) 0.8531(2) 0.0666(14) Uani 1 1 d D . . . .
F13 F 0.5132(4) 0.0550(4) 0.8928(2) 0.0759(16) Uani 1 1 d D . . . .
F14 F 0.5392(4) -0.0101(3) 0.8079(2) 0.0699(14) Uani 1 1 d D . . . .
B2 B 0.7320(8) 0.3645(7) 0.7680(5) 0.056(3) Uani 0.54(2) 1 d D U P B 1
F21 F 0.6717(10) 0.3244(9) 0.8060(5) 0.076(4) Uani 0.54(2) 1 d D U P B 1
F22 F 0.6759(11) 0.4088(9) 0.7300(6) 0.083(4) Uani 0.54(2) 1 d D U P B 1
F23 F 0.7924(10) 0.4132(8) 0.8001(6) 0.068(3) Uani 0.54(2) 1 d D U P B 1
F24 F 0.7865(9) 0.3104(8) 0.7373(6) 0.065(3) Uani 0.54(2) 1 d D U P B 1
B2' B 0.7304(9) 0.3408(9) 0.7637(5) 0.062(3) Uani 0.46(2) 1 d D U P B 2
F21' F 0.7096(13) 0.2850(10) 0.8061(5) 0.079(4) Uani 0.46(2) 1 d D U P B 2
F22' F 0.6458(9) 0.3765(10) 0.7450(7) 0.076(4) Uani 0.46(2) 1 d D U P B 2
F23' F 0.7936(11) 0.3964(11) 0.7861(8) 0.075(4) Uani 0.46(2) 1 d D U P B 2
F24' F 0.7735(12) 0.3028(10) 0.7172(7) 0.068(4) Uani 0.46(2) 1 d D U P B 2
B3 B 0.1543(7) 0.4697(5) 0.8612(4) 0.048(3) Uani 0.585(12) 1 d D U P C 1
F31 F 0.0735(6) 0.4346(6) 0.8856(3) 0.056(2) Uani 0.585(12) 1 d D U P C 1
F32 F 0.1293(8) 0.5051(5) 0.8088(3) 0.065(3) Uani 0.585(12) 1 d D U P C 1
F33 F 0.1900(10) 0.5264(7) 0.8993(4) 0.073(3) Uani 0.585(12) 1 d D U P C 1
F34 F 0.2236(10) 0.4122(7) 0.8520(7) 0.056(3) Uani 0.585(12) 1 d D U P C 1
B3' B 0.1819(8) 0.4893(7) 0.8675(5) 0.050(3) Uani 0.415(12) 1 d D U P C 2
F31' F 0.0839(7) 0.4832(10) 0.8783(6) 0.066(3) Uani 0.415(12) 1 d D U P C 2
F32' F 0.1988(11) 0.5400(8) 0.8212(5) 0.068(4) Uani 0.415(12) 1 d D U P C 2
F33' F 0.2281(8) 0.5206(8) 0.9160(5) 0.044(3) Uani 0.415(12) 1 d D U P C 2
F34' F 0.2185(14) 0.4149(8) 0.8556(10) 0.056(5) Uani 0.415(12) 1 d D U P C 2
Cl11 Cl 0.09192(15) 0.37399(15) 0.51981(14) 0.0765(7) Uani 1 1 d . . . . .
Cl12 Cl 0.04830(19) 0.49409(17) 0.60531(16) 0.0898(9) Uani 1 1 d . . . . .
C1 C 0.1277(6) 0.4192(5) 0.5848(5) 0.063(2) Uani 1 1 d . . . . .
H1C H 0.130940 0.378837 0.616089 0.075 Uiso 1 1 calc R U . . .
H1D H 0.193298 0.441871 0.580017 0.075 Uiso 1 1 calc R U . . .
O4 O 0.2283(5) 0.4521(3) 0.7133(3) 0.0564(14) Uani 1 1 d G . . . .
H4A H 0.206985 0.472979 0.745482 0.085 Uiso 1 1 d G U . . .
H4B H 0.260691 0.490128 0.696735 0.085 Uiso 1 1 d G U . . .
O5 O 0.6449(11) 0.1916(7) 0.7333(4) 0.136(5) Uani 1 1 d G . . . .
H5A H 0.666159 0.238628 0.742307 0.205 Uiso 1 1 d G U . . .
H5B H 0.631156 0.169835 0.766607 0.205 Uiso 1 1 d G U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 C112 81.9(3) . . ?
N1 Pt1 O1 178.9(2) . . ?
C112 Pt1 O1 97.2(3) . . ?
N1 Pt1 P1 84.70(15) . . ?
C112 Pt1 P1 165.3(2) . . ?
O1 Pt1 P1 96.26(15) . . ?
N1 Pt1 Ag1 92.39(14) . . ?
C112 Pt1 Ag1 52.51(19) . . ?
O1 Pt1 Ag1 86.52(14) . . ?
P1 Pt1 Ag1 134.53(4) . . ?
N2 Pt2 C212 81.6(2) . . ?
N2 Pt2 O2 174.5(2) . . ?
C212 Pt2 O2 95.7(2) . . ?
N2 Pt2 P2 85.70(14) . . ?
C212 Pt2 P2 167.28(17) . . ?
O2 Pt2 P2 97.02(14) . . ?
N2 Pt2 Ag1 86.63(13) . . ?
C212 Pt2 Ag1 53.59(16) . . ?
O2 Pt2 Ag1 95.7(2) . . ?
P2 Pt2 Ag1 125.02(4) . . ?
C112 Ag1 C212 129.5(2) . . ?
C112 Ag1 O3 95.2(3) . . ?
C212 Ag1 O3 135.1(3) . . ?
C112 Ag1 O3' 108.0(4) . . ?
C212 Ag1 O3' 120.9(4) . . ?
C112 Ag1 Pt2 126.83(16) . . ?
C212 Ag1 Pt2 44.29(13) . . ?
O3 Ag1 Pt2 109.2(2) . . ?
O3' Ag1 Pt2 111.9(3) . . ?
C112 Ag1 Pt1 44.05(16) . . ?
C212 Ag1 Pt1 126.04(13) . . ?
O3 Ag1 Pt1 86.8(2) . . ?
O3' Ag1 Pt1 84.7(3) . . ?
Pt2 Ag1 Pt1 163.36(2) . . ?
C101 P1 C21 105.0(4) . . ?
C101 P1 C11 105.8(3) . . ?
C21 P1 C11 114.5(3) . . ?
C101 P1 Pt1 97.9(2) . . ?
C21 P1 Pt1 118.0(3) . . ?
C11 P1 Pt1 113.0(2) . . ?
C201 P2 C31 106.0(3) . . ?
C201 P2 C41 104.9(3) . . ?
C31 P2 C41 114.2(3) . . ?
C201 P2 Pt2 97.5(2) . . ?
C31 P2 Pt2 115.4(2) . . ?
C41 P2 Pt2 116.1(2) . . ?
Pt1 O1 H1A 109.5 . . ?
Pt1 O1 H1B 109.5 . . ?
H1A O1 H1B 104.4 . . ?
Pt2 O2 H2A 109.3 . . ?
Pt2 O2 H2B 109.4 . . ?
H2A O2 H2B 104.5 . . ?
Ag1 O3 H3A 110.5 . . ?
Ag1 O3 H3B 110.7 . . ?
H3A O3 H3B 103.3 . . ?
Ag1 O3' H3'A 117.0 . . ?
Ag1 O3' H3'B 117.0 . . ?
H3'A O3' H3'B 96.4 . . ?
C102 N1 C106 122.0(5) . . ?
C102 N1 Pt1 122.1(4) . . ?
C106 N1 Pt1 115.8(4) . . ?
C202 N2 C206 121.5(5) . . ?
C202 N2 Pt2 122.0(4) . . ?
C206 N2 Pt2 116.1(4) . . ?
C13 C11 C12 108.8(6) . . ?
C13 C11 C14 109.9(5) . . ?
C12 C11 C14 108.9(6) . . ?
C13 C11 P1 109.5(5) . . ?
C12 C11 P1 106.7(4) . . ?
C14 C11 P1 112.9(5) . . ?
C11 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C11 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C11 C13 H13A 109.5 . . ?
C11 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C11 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C11 C14 H14A 109.5 . . ?
C11 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C11 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C24 C21 C23 110.2(8) . . ?
C24 C21 C22 109.4(8) . . ?
C23 C21 C22 109.8(9) . . ?
C24 C21 P1 112.9(7) . . ?
C23 C21 P1 108.8(6) . . ?
C22 C21 P1 105.5(6) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C21 C24 H24A 109.5 . . ?
C21 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C21 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C34 C31 C33 111.0(6) . . ?
C34 C31 C32 109.0(6) . . ?
C33 C31 C32 108.1(6) . . ?
C34 C31 P2 114.3(5) . . ?
C33 C31 P2 110.2(5) . . ?
C32 C31 P2 103.8(5) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C31 C34 H34A 109.5 . . ?
C31 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C31 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C44 C41 C42 110.3(7) . . ?
C44 C41 C43 109.4(6) . . ?
C42 C41 C43 107.5(7) . . ?
C44 C41 P2 113.6(5) . . ?
C42 C41 P2 107.4(5) . . ?
C43 C41 P2 108.5(5) . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C41 C43 H43A 109.5 . . ?
C41 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C41 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C41 C44 H44A 109.5 . . ?
C41 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C41 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C102 C101 P1 111.2(5) . . ?
C102 C101 H10A 109.4 . . ?
P1 C101 H10A 109.4 . . ?
C102 C101 H10B 109.4 . . ?
P1 C101 H10B 109.4 . . ?
H10A C101 H10B 108.0 . . ?
N1 C102 C103 120.0(6) . . ?
N1 C102 C101 117.9(6) . . ?
C103 C102 C101 122.0(6) . . ?
C104 C103 C102 119.7(7) . . ?
C104 C103 H103 120.1 . . ?
C102 C103 H103 120.1 . . ?
C103 C104 C105 119.8(6) . . ?
C103 C104 H104 120.1 . . ?
C105 C104 H104 120.1 . . ?
C104 C105 C106 120.0(6) . . ?
C104 C105 H105 120.0 . . ?
C106 C105 H105 120.0 . . ?
N1 C106 C105 118.4(6) . . ?
N1 C106 C107 114.1(6) . . ?
C105 C106 C107 127.5(6) . . ?
C108 C107 C112 120.9(7) . . ?
C108 C107 C106 121.9(8) . . ?
C112 C107 C106 117.1(6) . . ?
C109 C108 C107 119.3(9) . . ?
C109 C108 H108 120.3 . . ?
C107 C108 H108 120.3 . . ?
C110 C109 C108 120.7(8) . . ?
C110 C109 H109 119.7 . . ?
C108 C109 H109 119.7 . . ?
C109 C110 C111 120.3(8) . . ?
C109 C110 H110 119.8 . . ?
C111 C110 H110 119.8 . . ?
C112 C111 C110 120.9(9) . . ?
C112 C111 H111 119.5 . . ?
C110 C111 H111 119.5 . . ?
C111 C112 C107 117.8(7) . . ?
C111 C112 Pt1 130.5(6) . . ?
C107 C112 Pt1 110.6(5) . . ?
C111 C112 Ag1 92.0(5) . . ?
C107 C112 Ag1 106.5(4) . . ?
Pt1 C112 Ag1 83.4(2) . . ?
C202 C201 P2 112.7(4) . . ?
C202 C201 H20A 109.1 . . ?
P2 C201 H20A 109.1 . . ?
C202 C201 H20B 109.1 . . ?
P2 C201 H20B 109.1 . . ?
H20A C201 H20B 107.8 . . ?
N2 C202 C203 119.8(5) . . ?
N2 C202 C201 117.7(5) . . ?
C203 C202 C201 122.4(6) . . ?
C204 C203 C202 119.8(6) . . ?
C204 C203 H203 120.1 . . ?
C202 C203 H203 120.1 . . ?
C203 C204 C205 119.4(6) . . ?
C203 C204 H204 120.3 . . ?
C205 C204 H204 120.3 . . ?
C206 C205 C204 120.0(6) . . ?
C206 C205 H205 120.0 . . ?
C204 C205 H205 120.0 . . ?
N2 C206 C205 119.3(5) . . ?
N2 C206 C207 114.4(5) . . ?
C205 C206 C207 126.3(5) . . ?
C208 C207 C212 120.7(6) . . ?
C208 C207 C206 124.0(6) . . ?
C212 C207 C206 115.2(5) . . ?
C209 C208 C207 119.4(6) . . ?
C209 C208 H208 120.3 . . ?
C207 C208 H208 120.3 . . ?
C210 C209 C208 121.2(6) . . ?
C210 C209 H209 119.4 . . ?
C208 C209 H209 119.4 . . ?
C209 C210 C211 119.7(6) . . ?
C209 C210 H210 120.2 . . ?
C211 C210 H210 120.2 . . ?
C210 C211 C212 120.9(6) . . ?
C210 C211 H211 119.6 . . ?
C212 C211 H211 119.6 . . ?
C211 C212 C207 118.1(5) . . ?
C211 C212 Pt2 130.2(5) . . ?
C207 C212 Pt2 111.7(4) . . ?
C211 C212 Ag1 90.3(4) . . ?
C207 C212 Ag1 101.2(4) . . ?
Pt2 C212 Ag1 82.12(19) . . ?
F14 B1 F13 110.3(5) . . ?
F14 B1 F11 109.2(5) . . ?
F13 B1 F11 109.8(5) . . ?
F14 B1 F12 109.6(5) . . ?
F13 B1 F12 108.7(5) . . ?
F11 B1 F12 109.2(5) . . ?
F24 B2 F23 109.6(8) . . ?
F24 B2 F22 110.0(8) . . ?
F23 B2 F22 110.7(8) . . ?
F24 B2 F21 109.2(8) . . ?
F23 B2 F21 108.5(8) . . ?
F22 B2 F21 108.9(8) . . ?
F23' B2' F22' 110.7(9) . . ?
F23' B2' F24' 109.1(9) . . ?
F22' B2' F24' 109.4(9) . . ?
F23' B2' F21' 109.4(9) . . ?
F22' B2' F21' 109.6(9) . . ?
F24' B2' F21' 108.5(9) . . ?
F34 B3 F32 109.9(8) . . ?
F34 B3 F31 108.8(8) . . ?
F32 B3 F31 109.7(7) . . ?
F34 B3 F33 109.6(8) . . ?
F32 B3 F33 109.8(7) . . ?
F31 B3 F33 109.0(7) . . ?
F34' B3' F31' 109.2(9) . . ?
F34' B3' F33' 109.7(9) . . ?
F31' B3' F33' 109.5(8) . . ?
F34' B3' F32' 110.3(9) . . ?
F31' B3' F32' 110.6(9) . . ?
F33' B3' F32' 107.6(8) . . ?
Cl12 C1 Cl11 111.8(5) . . ?
Cl12 C1 H1C 109.3 . . ?
Cl11 C1 H1C 109.3 . . ?
Cl12 C1 H1D 109.3 . . ?
Cl11 C1 H1D 109.3 . . ?
H1C C1 H1D 107.9 . . ?
H4A O4 H4B 104.5 . . ?
H5A O5 H5B 104.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N1 2.004(5) . ?
Pt1 C112 2.066(7) . ?
Pt1 O1 2.076(5) . ?
Pt1 P1 2.3021(16) . ?
Pt1 Ag1 2.9525(5) . ?
Pt2 N2 1.985(5) . ?
Pt2 C212 2.052(5) . ?
Pt2 O2 2.070(5) . ?
Pt2 P2 2.3181(14) . ?
Pt2 Ag1 2.9100(5) . ?
Ag1 C112 2.358(7) . ?
Ag1 C212 2.364(6) . ?
Ag1 O3 2.477(8) . ?
Ag1 O3' 2.514(9) . ?
P1 C101 1.845(7) . ?
P1 C21 1.866(8) . ?
P1 C11 1.866(7) . ?
P2 C201 1.841(7) . ?
P2 C31 1.867(7) . ?
P2 C41 1.870(7) . ?
O1 H1A 0.8710 . ?
O1 H1B 0.8709 . ?
O2 H2A 0.8702 . ?
O2 H2B 0.8701 . ?
O3 H3A 0.8935 . ?
O3 H3B 0.8942 . ?
O3' H3'A 1.0553 . ?
O3' H3'B 1.0495 . ?
N1 C102 1.343(8) . ?
N1 C106 1.367(8) . ?
N2 C202 1.357(8) . ?
N2 C206 1.363(7) . ?
C11 C13 1.530(10) . ?
C11 C12 1.531(10) . ?
C11 C14 1.538(9) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C21 C24 1.520(13) . ?
C21 C23 1.528(14) . ?
C21 C22 1.531(13) . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C31 C34 1.518(9) . ?
C31 C33 1.527(10) . ?
C31 C32 1.546(9) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C41 C44 1.519(10) . ?
C41 C42 1.520(10) . ?
C41 C43 1.549(10) . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C101 C102 1.504(9) . ?
C101 H10A 0.9900 . ?
C101 H10B 0.9900 . ?
C102 C103 1.377(10) . ?
C103 C104 1.370(10) . ?
C103 H103 0.9500 . ?
C104 C105 1.382(11) . ?
C104 H104 0.9500 . ?
C105 C106 1.386(10) . ?
C105 H105 0.9500 . ?
C106 C107 1.469(10) . ?
C107 C108 1.401(10) . ?
C107 C112 1.405(11) . ?
C108 C109 1.388(13) . ?
C108 H108 0.9500 . ?
C109 C110 1.362(15) . ?
C109 H109 0.9500 . ?
C110 C111 1.399(13) . ?
C110 H110 0.9500 . ?
C111 C112 1.396(10) . ?
C111 H111 0.9500 . ?
C201 C202 1.497(8) . ?
C201 H20A 0.9900 . ?
C201 H20B 0.9900 . ?
C202 C203 1.385(9) . ?
C203 C204 1.379(9) . ?
C203 H203 0.9500 . ?
C204 C205 1.393(9) . ?
C204 H204 0.9500 . ?
C205 C206 1.383(9) . ?
C205 H205 0.9500 . ?
C206 C207 1.470(9) . ?
C207 C208 1.396(8) . ?
C207 C212 1.415(9) . ?
C208 C209 1.386(9) . ?
C208 H208 0.9500 . ?
C209 C210 1.380(10) . ?
C209 H209 0.9500 . ?
C210 C211 1.397(8) . ?
C210 H210 0.9500 . ?
C211 C212 1.402(8) . ?
C211 H211 0.9500 . ?
B1 F14 1.379(6) . ?
B1 F13 1.381(6) . ?
B1 F11 1.385(6) . ?
B1 F12 1.389(6) . ?
B2 F24 1.379(7) . ?
B2 F23 1.382(7) . ?
B2 F22 1.383(7) . ?
B2 F21 1.385(7) . ?
B2' F23' 1.380(7) . ?
B2' F22' 1.381(7) . ?
B2' F24' 1.381(7) . ?
B2' F21' 1.384(7) . ?
B3 F34 1.381(7) . ?
B3 F32 1.384(7) . ?
B3 F31 1.384(7) . ?
B3 F33 1.385(7) . ?
B3' F34' 1.380(7) . ?
B3' F31' 1.383(7) . ?
B3' F33' 1.385(7) . ?
B3' F32' 1.385(7) . ?
Cl11 C1 1.745(11) . ?
Cl12 C1 1.739(9) . ?
C1 H1C 0.9900 . ?
C1 H1D 0.9900 . ?
O4 H4A 0.8700 . ?
O4 H4B 0.8700 . ?
O5 H5A 0.8700 . ?
O5 H5B 0.8700 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C101 P1 C11 C13 -165.4(5) . . . . ?
C21 P1 C11 C13 79.5(6) . . . . ?
Pt1 P1 C11 C13 -59.5(5) . . . . ?
C101 P1 C11 C12 -47.8(5) . . . . ?
C21 P1 C11 C12 -163.0(5) . . . . ?
Pt1 P1 C11 C12 58.1(5) . . . . ?
C101 P1 C11 C14 71.8(6) . . . . ?
C21 P1 C11 C14 -43.3(7) . . . . ?
Pt1 P1 C11 C14 177.7(5) . . . . ?
C101 P1 C21 C24 -43.7(7) . . . . ?
C11 P1 C21 C24 71.8(7) . . . . ?
Pt1 P1 C21 C24 -151.4(5) . . . . ?
C101 P1 C21 C23 -166.4(8) . . . . ?
C11 P1 C21 C23 -50.9(9) . . . . ?
Pt1 P1 C21 C23 85.9(8) . . . . ?
C101 P1 C21 C22 75.7(7) . . . . ?
C11 P1 C21 C22 -168.7(6) . . . . ?
Pt1 P1 C21 C22 -31.9(8) . . . . ?
C201 P2 C31 C34 64.8(6) . . . . ?
C41 P2 C31 C34 -50.1(6) . . . . ?
Pt2 P2 C31 C34 171.4(4) . . . . ?
C201 P2 C31 C33 -169.3(5) . . . . ?
C41 P2 C31 C33 75.7(5) . . . . ?
Pt2 P2 C31 C33 -62.7(5) . . . . ?
C201 P2 C31 C32 -53.7(5) . . . . ?
C41 P2 C31 C32 -168.7(5) . . . . ?
Pt2 P2 C31 C32 52.9(5) . . . . ?
C201 P2 C41 C44 -47.9(6) . . . . ?
C31 P2 C41 C44 67.7(6) . . . . ?
Pt2 P2 C41 C44 -154.1(5) . . . . ?
C201 P2 C41 C42 74.3(6) . . . . ?
C31 P2 C41 C42 -170.1(6) . . . . ?
Pt2 P2 C41 C42 -31.9(6) . . . . ?
C201 P2 C41 C43 -169.8(5) . . . . ?
C31 P2 C41 C43 -54.2(6) . . . . ?
Pt2 P2 C41 C43 83.9(5) . . . . ?
C21 P1 C101 C102 -147.0(5) . . . . ?
C11 P1 C101 C102 91.5(5) . . . . ?
Pt1 P1 C101 C102 -25.1(5) . . . . ?
C106 N1 C102 C103 -2.0(9) . . . . ?
Pt1 N1 C102 C103 174.6(5) . . . . ?
C106 N1 C102 C101 176.0(5) . . . . ?
Pt1 N1 C102 C101 -7.4(8) . . . . ?
P1 C101 C102 N1 23.6(7) . . . . ?
P1 C101 C102 C103 -158.4(5) . . . . ?
N1 C102 C103 C104 0.1(10) . . . . ?
C101 C102 C103 C104 -177.8(6) . . . . ?
C102 C103 C104 C105 1.5(10) . . . . ?
C103 C104 C105 C106 -1.2(10) . . . . ?
C102 N1 C106 C105 2.2(9) . . . . ?
Pt1 N1 C106 C105 -174.6(4) . . . . ?
C102 N1 C106 C107 -179.0(5) . . . . ?
Pt1 N1 C106 C107 4.2(7) . . . . ?
C104 C105 C106 N1 -0.6(9) . . . . ?
C104 C105 C106 C107 -179.2(6) . . . . ?
N1 C106 C107 C108 -176.0(6) . . . . ?
C105 C106 C107 C108 2.6(10) . . . . ?
N1 C106 C107 C112 1.1(8) . . . . ?
C105 C106 C107 C112 179.8(6) . . . . ?
C112 C107 C108 C109 -1.3(10) . . . . ?
C106 C107 C108 C109 175.7(6) . . . . ?
C107 C108 C109 C110 -0.7(11) . . . . ?
C108 C109 C110 C111 1.7(12) . . . . ?
C109 C110 C111 C112 -0.7(12) . . . . ?
C110 C111 C112 C107 -1.2(10) . . . . ?
C110 C111 C112 Pt1 -168.2(6) . . . . ?
C110 C111 C112 Ag1 108.7(7) . . . . ?
C108 C107 C112 C111 2.2(10) . . . . ?
C106 C107 C112 C111 -175.0(6) . . . . ?
C108 C107 C112 Pt1 171.7(5) . . . . ?
C106 C107 C112 Pt1 -5.5(7) . . . . ?
C108 C107 C112 Ag1 -99.2(6) . . . . ?
C106 C107 C112 Ag1 83.6(6) . . . . ?
C31 P2 C201 C202 98.8(5) . . . . ?
C41 P2 C201 C202 -140.0(5) . . . . ?
Pt2 P2 C201 C202 -20.4(5) . . . . ?
C206 N2 C202 C203 -2.1(8) . . . . ?
Pt2 N2 C202 C203 171.0(4) . . . . ?
C206 N2 C202 C201 174.8(5) . . . . ?
Pt2 N2 C202 C201 -12.1(7) . . . . ?
P2 C201 C202 N2 22.9(7) . . . . ?
P2 C201 C202 C203 -160.3(5) . . . . ?
N2 C202 C203 C204 -0.1(9) . . . . ?
C201 C202 C203 C204 -176.8(6) . . . . ?
C202 C203 C204 C205 1.5(9) . . . . ?
C203 C204 C205 C206 -0.8(9) . . . . ?
C202 N2 C206 C205 2.8(8) . . . . ?
Pt2 N2 C206 C205 -170.7(4) . . . . ?
C202 N2 C206 C207 -176.7(5) . . . . ?
Pt2 N2 C206 C207 9.8(6) . . . . ?
C204 C205 C206 N2 -1.3(8) . . . . ?
C204 C205 C206 C207 178.1(5) . . . . ?
N2 C206 C207 C208 175.3(5) . . . . ?
C205 C206 C207 C208 -4.2(9) . . . . ?
N2 C206 C207 C212 -3.6(7) . . . . ?
C205 C206 C207 C212 176.9(5) . . . . ?
C212 C207 C208 C209 1.7(9) . . . . ?
C206 C207 C208 C209 -177.2(5) . . . . ?
C207 C208 C209 C210 -1.2(9) . . . . ?
C208 C209 C210 C211 -0.3(9) . . . . ?
C209 C210 C211 C212 1.4(9) . . . . ?
C210 C211 C212 C207 -1.0(9) . . . . ?
C210 C211 C212 Pt2 -178.2(5) . . . . ?
C210 C211 C212 Ag1 101.9(6) . . . . ?
C208 C207 C212 C211 -0.6(8) . . . . ?
C206 C207 C212 C211 178.4(5) . . . . ?
C208 C207 C212 Pt2 177.2(4) . . . . ?
C206 C207 C212 Pt2 -3.9(6) . . . . ?
C208 C207 C212 Ag1 -96.9(5) . . . . ?
C206 C207 C212 Ag1 82.0(5) . . . . ?
