#------------------------------------------------------------------------------
#$Date: 2016-03-21 00:21:50 +0100 (Mon 21 de Mar de 2016) $
#$Revision: 178377 $
#$URL: svn://www.crystallography.net/cod/cif/4/00/09/4000934.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4000934
loop_
_publ_author_name
'Xia, Sheng-Qing'
'Bobev, Svilen'
_publ_section_title
;
 New Manganese-Bearing Antimonides and Bismuthides with Complex
 Structures. Synthesis, Structural Characterization, and Electronic
 Properties of Yb9Mn4+xPn9(Pn= Sb or Bi)†
;
_journal_issue                   3
_journal_name_full               'Chemistry of Materials'
_journal_page_first              840
_journal_paper_doi               10.1021/cm901633r
_journal_volume                  22
_journal_year                    2010
_chemical_formula_moiety         'Bi9 Ca9 Mn4'
_chemical_formula_sum            'Bi9 Ca9 Mn4'
_chemical_formula_weight         2461.30
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           55
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2 2ab'
_symmetry_space_group_name_H-M   'P b a m'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   22.367(5)
_cell_length_b                   12.499(3)
_cell_length_c                   4.7060(10)
_cell_measurement_reflns_used    9999
_cell_measurement_temperature    90(2)
_cell_measurement_theta_max      27.1
_cell_measurement_theta_min      1.8
_cell_volume                     1315.6(5)
_computing_cell_refinement       'SMART (Bruker, 2000)'
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 1999)'
_computing_molecular_graphics    'SHELXTL 5.1 (Sheldrick, 1994)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      90(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker Smart'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0521
_diffrn_reflns_av_sigmaI/netI    0.0278
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_limit_l_min       -5
_diffrn_reflns_number            14122
_diffrn_reflns_theta_full        27.10
_diffrn_reflns_theta_max         27.10
_diffrn_reflns_theta_min         1.82
_exptl_absorpt_coefficient_mu    63.525
_exptl_absorpt_correction_T_max  0.2516
_exptl_absorpt_correction_T_min  0.1334
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2003)'
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    6.213
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2054
_exptl_crystal_size_max          0.05
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_refine_diff_density_max         3.041
_refine_diff_density_min         -2.266
_refine_diff_density_rms         0.342
_refine_ls_extinction_coef       0.000093(19)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.078
_refine_ls_matrix_type           full
_refine_ls_number_parameters     70
_refine_ls_number_reflns         1618
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.078
_refine_ls_R_factor_all          0.0275
_refine_ls_R_factor_gt           0.0231
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0233P)²+4.9298P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0509
_refine_ls_wR_factor_ref         0.0520
_reflns_number_gt                1455
_reflns_number_total             1618
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cm901633r_si_002.cif
_cod_data_source_block           CaMnBi
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1315.7(5)
_cod_database_code               4000934
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x+1/2, y+1/2, -z'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x, y, -z'
'x-1/2, -y-1/2, z'
'-x-1/2, y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ca1 Ca 0.0000 0.0000 0.5000 0.0191(7) Uani 1 4 d S
Ca2 Ca 0.13627(10) 0.13740(18) 0.0000 0.0176(5) Uani 1 2 d S
Ca3 Ca 0.09135(10) 0.44179(18) 0.0000 0.0158(5) Uani 1 2 d S
Ca4 Ca 0.26422(10) 0.38039(17) 0.0000 0.0149(5) Uani 1 2 d S
Ca5 Ca 0.39729(10) 0.21718(18) 0.5000 0.0173(5) Uani 1 2 d S
Bi1 Bi 0.0000 0.5000 0.5000 0.01407(14) Uani 1 4 d S
Bi2 Bi 0.494898(19) 0.30734(3) 0.0000 0.01521(11) Uani 1 2 d S
Bi3 Bi 0.309164(18) 0.12655(3) 0.0000 0.01485(11) Uani 1 2 d S
Bi4 Bi 0.353300(18) 0.46280(3) 0.5000 0.01388(11) Uani 1 2 d S
Bi5 Bi 0.169482(18) 0.31515(3) 0.5000 0.01313(11) Uani 1 2 d S
Mn1 Mn 0.04533(7) 0.27893(14) 0.5000 0.0168(4) Uani 1 2 d S
Mn2 Mn 0.24113(7) 0.11704(14) 0.5000 0.0167(4) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ca Ca 0.2262 0.3064 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Bi4 Ca1 Bi4 180.0 7_565 3_546
Bi4 Ca1 Bi2 82.309(9) 7_565 7_566
Bi4 Ca1 Bi2 97.691(9) 3_546 7_566
Bi4 Ca1 Bi2 97.691(9) 7_565 3_545
Bi4 Ca1 Bi2 82.309(9) 3_546 3_545
Bi2 Ca1 Bi2 180.0 7_566 3_545
Bi4 Ca1 Bi2 82.309(9) 7_565 7_565
Bi4 Ca1 Bi2 97.691(9) 3_546 7_565
Bi2 Ca1 Bi2 88.61(2) 7_566 7_565
Bi2 Ca1 Bi2 91.39(2) 3_545 7_565
Bi4 Ca1 Bi2 97.691(9) 7_565 3_546
Bi4 Ca1 Bi2 82.309(9) 3_546 3_546
Bi2 Ca1 Bi2 91.39(2) 7_566 3_546
Bi2 Ca1 Bi2 88.61(2) 3_545 3_546
Bi2 Ca1 Bi2 180.000(10) 7_565 3_546
Bi4 Ca1 Mn1 98.15(3) 7_565 .
Bi4 Ca1 Mn1 81.85(3) 3_546 .
Bi2 Ca1 Mn1 47.395(13) 7_566 .
Bi2 Ca1 Mn1 132.605(14) 3_545 .
Bi2 Ca1 Mn1 47.395(13) 7_565 .
Bi2 Ca1 Mn1 132.605(13) 3_546 .
Bi4 Ca1 Mn1 81.85(3) 7_565 5_556
Bi4 Ca1 Mn1 98.15(3) 3_546 5_556
Bi2 Ca1 Mn1 132.604(13) 7_566 5_556
Bi2 Ca1 Mn1 47.396(13) 3_545 5_556
Bi2 Ca1 Mn1 132.604(13) 7_565 5_556
Bi2 Ca1 Mn1 47.396(13) 3_546 5_556
Mn1 Ca1 Mn1 180.0 . 5_556
Bi4 Ca1 Ca5 48.92(3) 7_565 7_565
Bi4 Ca1 Ca5 131.08(3) 3_546 7_565
Bi2 Ca1 Ca5 51.841(18) 7_566 7_565
Bi2 Ca1 Ca5 128.159(18) 3_545 7_565
Bi2 Ca1 Ca5 51.841(18) 7_565 7_565
Bi2 Ca1 Ca5 128.159(18) 3_546 7_565
Mn1 Ca1 Ca5 49.23(4) . 7_565
Mn1 Ca1 Ca5 130.77(4) 5_556 7_565
Bi4 Ca1 Ca5 131.08(3) 7_565 3_546
Bi4 Ca1 Ca5 48.92(3) 3_546 3_546
Bi2 Ca1 Ca5 128.159(18) 7_566 3_546
Bi2 Ca1 Ca5 51.841(18) 3_545 3_546
Bi2 Ca1 Ca5 128.159(18) 7_565 3_546
Bi2 Ca1 Ca5 51.841(18) 3_546 3_546
Mn1 Ca1 Ca5 130.77(4) . 3_546
Mn1 Ca1 Ca5 49.23(4) 5_556 3_546
Ca5 Ca1 Ca5 180.0 7_565 3_546
Bi4 Ca1 Ca2 131.20(3) 7_565 .
Bi4 Ca1 Ca2 48.80(3) 3_546 .
Bi2 Ca1 Ca2 97.07(3) 7_566 .
Bi2 Ca1 Ca2 82.93(3) 3_545 .
Bi2 Ca1 Ca2 48.97(3) 7_565 .
Bi2 Ca1 Ca2 131.03(3) 3_546 .
Mn1 Ca1 Ca2 53.63(3) . .
Mn1 Ca1 Ca2 126.37(3) 5_556 .
Ca5 Ca1 Ca2 93.00(4) 7_565 .
Ca5 Ca1 Ca2 87.00(4) 3_546 .
Bi4 Ca1 Ca2 48.80(3) 7_565 5
Bi4 Ca1 Ca2 131.20(3) 3_546 5
Bi2 Ca1 Ca2 131.03(3) 7_566 5
Bi2 Ca1 Ca2 48.97(3) 3_545 5
Bi2 Ca1 Ca2 82.93(3) 7_565 5
Bi2 Ca1 Ca2 97.07(3) 3_546 5
Mn1 Ca1 Ca2 126.37(3) . 5
Mn1 Ca1 Ca2 53.63(3) 5_556 5
Ca5 Ca1 Ca2 87.00(4) 7_565 5
Ca5 Ca1 Ca2 93.00(4) 3_546 5
Ca2 Ca1 Ca2 112.15(4) . 5
Bi4 Ca2 Bi4 93.99(6) 3_545 3_546
Bi4 Ca2 Bi2 102.45(5) 3_545 7_565
Bi4 Ca2 Bi2 102.45(5) 3_546 7_565
Bi4 Ca2 Bi5 85.38(2) 3_545 1_554
Bi4 Ca2 Bi5 162.91(8) 3_546 1_554
Bi2 Ca2 Bi5 94.35(5) 7_565 1_554
Bi4 Ca2 Bi5 162.91(8) 3_545 .
Bi4 Ca2 Bi5 85.38(2) 3_546 .
Bi2 Ca2 Bi5 94.35(5) 7_565 .
Bi5 Ca2 Bi5 90.25(6) 1_554 .
Bi4 Ca2 Mn2 51.74(4) 3_545 1_554
Bi4 Ca2 Mn2 114.43(7) 3_546 1_554
Bi2 Ca2 Mn2 134.75(4) 7_565 1_554
Bi5 Ca2 Mn2 52.64(4) 1_554 1_554
Bi5 Ca2 Mn2 113.21(7) . 1_554
Bi4 Ca2 Mn2 114.43(7) 3_545 .
Bi4 Ca2 Mn2 51.74(4) 3_546 .
Bi2 Ca2 Mn2 134.75(4) 7_565 .
Bi5 Ca2 Mn2 113.21(7) 1_554 .
Bi5 Ca2 Mn2 52.64(4) . .
Mn2 Ca2 Mn2 89.85(7) 1_554 .
Bi4 Ca2 Mn1 84.01(3) 3_545 1_554
Bi4 Ca2 Mn1 149.03(8) 3_546 1_554
Bi2 Ca2 Mn1 48.63(4) 7_565 1_554
Bi5 Ca2 Mn1 47.96(3) 1_554 1_554
Bi5 Ca2 Mn1 105.21(7) . 1_554
Mn2 Ca2 Mn1 88.48(4) 1_554 1_554
Mn2 Ca2 Mn1 154.46(8) . 1_554
Bi4 Ca2 Mn1 149.03(8) 3_545 .
Bi4 Ca2 Mn1 84.01(3) 3_546 .
Bi2 Ca2 Mn1 48.63(4) 7_565 .
Bi5 Ca2 Mn1 105.21(7) 1_554 .
Bi5 Ca2 Mn1 47.96(3) . .
Mn2 Ca2 Mn1 154.46(8) 1_554 .
Mn2 Ca2 Mn1 88.48(4) . .
Mn1 Ca2 Mn1 82.23(6) 1_554 .
Bi4 Ca2 Bi3 84.48(5) 3_545 .
Bi4 Ca2 Bi3 84.48(5) 3_546 .
Bi2 Ca2 Bi3 169.69(7) 7_565 .
Bi5 Ca2 Bi3 78.46(4) 1_554 .
Bi5 Ca2 Bi3 78.45(4) . .
Mn2 Ca2 Bi3 45.08(4) 1_554 .
Mn2 Ca2 Bi3 45.08(4) . .
Mn1 Ca2 Bi3 125.83(5) 1_554 .
Mn1 Ca2 Bi3 125.83(5) . .
Bi4 Ca2 Ca4 53.22(4) 3_545 3_545
Bi4 Ca2 Ca4 53.22(4) 3_546 3_545
Bi2 Ca2 Ca4 137.04(8) 7_565 3_545
Bi5 Ca2 Ca4 115.00(5) 1_554 3_545
Bi5 Ca2 Ca4 115.00(5) . 3_545
Mn2 Ca2 Ca4 62.38(5) 1_554 3_545
Mn2 Ca2 Ca4 62.38(5) . 3_545
Mn1 Ca2 Ca4 136.90(4) 1_554 3_545
Mn1 Ca2 Ca4 136.90(4) . 3_545
Bi3 Ca2 Ca4 53.28(5) . 3_545
Bi4 Ca2 Ca3 132.40(3) 3_545 .
Bi4 Ca2 Ca3 132.40(3) 3_546 .
Bi2 Ca2 Ca3 62.89(5) 7_565 .
Bi5 Ca2 Ca3 53.85(4) 1_554 .
Bi5 Ca2 Ca3 53.86(4) . .
Mn2 Ca2 Ca3 104.69(6) 1_554 .
Mn2 Ca2 Ca3 104.69(6) . .
Mn1 Ca2 Ca3 51.45(4) 1_554 .
Mn1 Ca2 Ca3 51.45(4) . .
Bi3 Ca2 Ca3 106.80(6) . .
Ca4 Ca2 Ca3 160.08(8) 3_545 .
Bi1 Ca3 Bi1 94.66(6) 1_554 .
Bi1 Ca3 Bi3 106.22(5) 1_554 3
Bi1 Ca3 Bi3 106.22(5) . 3
Bi1 Ca3 Mn1 54.04(4) 1_554 1_554
Bi1 Ca3 Mn1 117.95(8) . 1_554
Bi3 Ca3 Mn1 131.70(4) 3 1_554
Bi1 Ca3 Mn1 117.95(8) 1_554 .
Bi1 Ca3 Mn1 54.04(4) . .
Bi3 Ca3 Mn1 131.70(4) 3 .
Mn1 Ca3 Mn1 91.78(7) 1_554 .
Bi1 Ca3 Bi5 85.619(19) 1_554 1_554
Bi1 Ca3 Bi5 164.24(8) . 1_554
Bi3 Ca3 Bi5 88.75(5) 3 1_554
Mn1 Ca3 Bi5 50.39(4) 1_554 1_554
Mn1 Ca3 Bi5 112.13(7) . 1_554
Bi1 Ca3 Bi5 164.24(8) 1_554 .
Bi1 Ca3 Bi5 85.620(19) . .
Bi3 Ca3 Bi5 88.75(5) 3 .
Mn1 Ca3 Bi5 112.13(7) 1_554 .
Mn1 Ca3 Bi5 50.39(4) . .
Bi5 Ca3 Bi5 89.88(6) 1_554 .
Bi1 Ca3 Bi2 79.82(5) 1_554 7_565
Bi1 Ca3 Bi2 79.82(5) . 7_565
Bi3 Ca3 Bi2 170.78(7) 3 7_565
Mn1 Ca3 Bi2 46.41(4) 1_554 7_565
Mn1 Ca3 Bi2 46.41(4) . 7_565
Bi5 Ca3 Bi2 84.73(5) 1_554 7_565
Bi5 Ca3 Bi2 84.73(5) . 7_565
Bi1 Ca3 Ca2 112.51(5) 1_554 .
Bi1 Ca3 Ca2 112.51(5) . .
Bi3 Ca3 Ca2 121.27(7) 3 .
Mn1 Ca3 Ca2 58.64(5) 1_554 .
Mn1 Ca3 Ca2 58.64(5) . .
Bi5 Ca3 Ca2 53.60(4) 1_554 .
Bi5 Ca3 Ca2 53.60(4) . .
Bi2 Ca3 Ca2 49.51(5) 7_565 .
Bi1 Ca3 Ca4 132.11(3) 1_554 .
Bi1 Ca3 Ca4 132.11(3) . .
Bi3 Ca3 Ca4 57.29(5) 3 .
Mn1 Ca3 Ca4 100.78(6) 1_554 .
Mn1 Ca3 Ca4 100.79(6) . .
Bi5 Ca3 Ca4 52.62(4) 1_554 .
Bi5 Ca3 Ca4 52.62(4) . .
Bi2 Ca3 Ca4 113.49(7) 7_565 .
Ca2 Ca3 Ca4 63.98(6) . .
Bi1 Ca3 Ca5 105.41(6) 1_554 3_556
Bi1 Ca3 Ca5 55.76(4) . 3_556
Bi3 Ca3 Ca5 50.53(4) 3 3_556
Mn1 Ca3 Ca5 159.29(7) 1_554 3_556
Mn1 Ca3 Ca5 97.27(4) . 3_556
Bi5 Ca3 Ca5 139.25(7) 1_554 3_556
Bi5 Ca3 Ca5 87.81(4) . 3_556
Bi2 Ca3 Ca5 135.40(5) 7_565 3_556
Ca2 Ca3 Ca5 141.37(4) . 3_556
Ca4 Ca3 Ca5 95.78(6) . 3_556
Bi1 Ca3 Ca5 55.76(4) 1_554 3
Bi1 Ca3 Ca5 105.41(6) . 3
Bi3 Ca3 Ca5 50.53(4) 3 3
Mn1 Ca3 Ca5 97.27(4) 1_554 3
Mn1 Ca3 Ca5 159.29(7) . 3
Bi5 Ca3 Ca5 87.81(4) 1_554 3
Bi5 Ca3 Ca5 139.25(7) . 3
Bi2 Ca3 Ca5 135.40(5) 7_565 3
Ca2 Ca3 Ca5 141.37(4) . 3
Ca4 Ca3 Ca5 95.78(6) . 3
Ca5 Ca3 Ca5 68.57(5) 3_556 3
Bi4 Ca4 Bi4 92.74(6) . 1_554
Bi4 Ca4 Bi5 87.441(18) . .
Bi4 Ca4 Bi5 175.63(8) 1_554 .
Bi4 Ca4 Bi5 175.63(8) . 1_554
Bi4 Ca4 Bi5 87.442(18) 1_554 1_554
Bi5 Ca4 Bi5 92.04(6) . 1_554
Bi4 Ca4 Bi3 96.72(5) . .
Bi4 Ca4 Bi3 96.72(5) 1_554 .
Bi5 Ca4 Bi3 87.59(5) . .
Bi5 Ca4 Bi3 87.59(5) 1_554 .
Bi4 Ca4 Bi3 90.51(5) . 3
Bi4 Ca4 Bi3 90.51(5) 1_554 3
Bi5 Ca4 Bi3 85.13(5) . 3
Bi5 Ca4 Bi3 85.12(5) 1_554 3
Bi3 Ca4 Bi3 169.50(7) . 3
Bi4 Ca4 Mn2 47.25(3) . 3_556
Bi4 Ca4 Mn2 102.82(6) 1_554 3_556
Bi5 Ca4 Mn2 74.15(3) . 3_556
Bi5 Ca4 Mn2 128.48(7) 1_554 3_556
Bi3 Ca4 Mn2 139.05(4) . 3_556
Bi3 Ca4 Mn2 45.17(3) 3 3_556
Bi4 Ca4 Mn2 102.82(6) . 3
Bi4 Ca4 Mn2 47.25(3) 1_554 3
Bi5 Ca4 Mn2 128.49(7) . 3
Bi5 Ca4 Mn2 74.15(3) 1_554 3
Bi3 Ca4 Mn2 139.05(4) . 3
Bi3 Ca4 Mn2 45.17(3) 3 3
Mn2 Ca4 Mn2 76.96(5) 3_556 3
Bi4 Ca4 Ca2 52.45(3) . 3
Bi4 Ca4 Ca2 52.44(3) 1_554 3
Bi5 Ca4 Ca2 125.03(4) . 3
Bi5 Ca4 Ca2 125.03(4) 1_554 3
Bi3 Ca4 Ca2 127.71(7) . 3
Bi3 Ca4 Ca2 62.79(5) 3 3
Mn2 Ca4 Ca2 51.32(4) 3_556 3
Mn2 Ca4 Ca2 51.32(4) 3 3
Bi4 Ca4 Ca3 122.65(5) . .
Bi4 Ca4 Ca3 122.65(5) 1_554 .
Bi5 Ca4 Ca3 54.05(4) . .
Bi5 Ca4 Ca3 54.05(4) 1_554 .
Bi3 Ca4 Ca3 118.81(7) . .
Bi3 Ca4 Ca3 50.69(5) 3 .
Mn2 Ca4 Ca3 79.44(5) 3_556 .
Mn2 Ca4 Ca3 79.44(5) 3 .
Ca2 Ca4 Ca3 113.49(7) 3 .
Bi4 Ca4 Ca2 130.61(4) . .
Bi4 Ca4 Ca2 130.61(4) 1_554 .
Bi5 Ca4 Ca2 51.25(3) . .
Bi5 Ca4 Ca2 51.25(3) 1_554 .
Bi3 Ca4 Ca2 60.88(5) . .
Bi3 Ca4 Ca2 108.62(6) 3 .
Mn2 Ca4 Ca2 123.20(5) 3_556 .
Mn2 Ca4 Ca2 123.20(5) 3 .
Ca2 Ca4 Ca2 171.42(7) 3 .
Ca3 Ca4 Ca2 57.93(6) . .
Bi4 Ca4 Ca5 97.01(6) . 1_554
Bi4 Ca4 Ca5 48.03(4) 1_554 1_554
Bi5 Ca4 Ca5 136.28(7) . 1_554
Bi5 Ca4 Ca5 86.36(4) 1_554 1_554
Bi3 Ca4 Ca5 48.69(4) . 1_554
Bi3 Ca4 Ca5 137.99(4) 3 1_554
Mn2 Ca4 Ca5 137.07(7) 3_556 1_554
Mn2 Ca4 Ca5 93.01(4) 3 1_554
Ca2 Ca4 Ca5 89.76(6) 3 1_554
Ca3 Ca4 Ca5 140.34(4) . 1_554
Ca2 Ca4 Ca5 97.42(6) . 1_554
Bi4 Ca5 Bi3 98.39(5) . .
Bi4 Ca5 Bi3 98.39(5) . 1_556
Bi3 Ca5 Bi3 91.97(6) . 1_556
Bi4 Ca5 Mn1 106.93(7) . 7_665
Bi3 Ca5 Mn1 127.40(4) . 7_665
Bi3 Ca5 Mn1 127.40(4) 1_556 7_665
Bi4 Ca5 Bi2 83.13(5) . 1_556
Bi3 Ca5 Bi2 177.12(6) . 1_556
Bi3 Ca5 Bi2 90.223(17) 1_556 1_556
Mn1 Ca5 Bi2 49.72(3) 7_665 1_556
Bi4 Ca5 Bi2 83.13(5) . .
Bi3 Ca5 Bi2 90.223(18) . .
Bi3 Ca5 Bi2 177.12(6) 1_556 .
Mn1 Ca5 Bi2 49.72(3) 7_665 .
Bi2 Ca5 Bi2 87.53(5) 1_556 .
Bi4 Ca5 Bi1 157.53(7) . 3_546
Bi3 Ca5 Bi1 97.17(5) . 3_546
Bi3 Ca5 Bi1 97.17(5) 1_556 3_546
Mn1 Ca5 Bi1 50.60(4) 7_665 3_546
Bi2 Ca5 Bi1 80.69(4) 1_556 3_546
Bi2 Ca5 Bi1 80.69(4) . 3_546
Bi4 Ca5 Mn2 91.95(6) . .
Bi3 Ca5 Mn2 46.85(3) . .
Bi3 Ca5 Mn2 46.85(3) 1_556 .
Mn1 Ca5 Mn2 161.12(8) 7_665 .
Bi2 Ca5 Mn2 135.72(3) 1_556 .
Bi2 Ca5 Mn2 135.72(3) . .
Bi1 Ca5 Mn2 110.52(7) 3_546 .
Bi4 Ca5 Ca3 143.45(4) . 3_545
Bi3 Ca5 Ca3 49.18(4) . 3_545
Bi3 Ca5 Ca3 99.00(6) 1_556 3_545
Mn1 Ca5 Ca3 87.20(6) 7_665 3_545
Bi2 Ca5 Ca3 128.57(7) 1_556 3_545
Bi2 Ca5 Ca3 81.04(4) . 3_545
Bi1 Ca5 Ca3 48.06(4) 3_546 3_545
Mn2 Ca5 Ca3 77.25(5) . 3_545
Bi4 Ca5 Ca3 143.45(4) . 3_546
Bi3 Ca5 Ca3 99.00(6) . 3_546
Bi3 Ca5 Ca3 49.18(4) 1_556 3_546
Mn1 Ca5 Ca3 87.20(6) 7_665 3_546
Bi2 Ca5 Ca3 81.04(4) 1_556 3_546
Bi2 Ca5 Ca3 128.57(7) . 3_546
Bi1 Ca5 Ca3 48.06(4) 3_546 3_546
Mn2 Ca5 Ca3 77.25(5) . 3_546
Ca3 Ca5 Ca3 68.57(5) 3_545 3_546
Bi4 Ca5 Ca1 50.79(4) . 3_556
Bi3 Ca5 Ca1 128.21(4) . 3_556
Bi3 Ca5 Ca1 128.21(4) 1_556 3_556
Mn1 Ca5 Ca1 56.14(4) 7_665 3_556
Bi2 Ca5 Ca1 51.14(3) 1_556 3_556
Bi2 Ca5 Ca1 51.14(3) . 3_556
Bi1 Ca5 Ca1 106.74(5) 3_546 3_556
Mn2 Ca5 Ca1 142.73(7) . 3_556
Ca3 Ca5 Ca1 131.13(5) 3_545 3_556
Ca3 Ca5 Ca1 131.13(5) 3_546 3_556
Bi4 Ca5 Ca4 48.56(4) . .
Bi3 Ca5 Ca4 49.83(4) . .
Bi3 Ca5 Ca4 98.08(6) 1_556 .
Mn1 Ca5 Ca4 133.15(5) 7_665 .
Bi2 Ca5 Ca4 131.63(7) 1_556 .
Bi2 Ca5 Ca4 84.76(4) . .
Bi1 Ca5 Ca4 143.88(4) 3_546 .
Mn2 Ca5 Ca4 60.62(5) . .
Ca3 Ca5 Ca4 97.16(4) 3_545 .
Ca3 Ca5 Ca4 137.73(7) 3_546 .
Ca1 Ca5 Ca4 88.82(5) 3_556 .
Mn1 Bi1 Mn1 180.0 . 5_566
Mn1 Bi1 Ca3 115.68(4) . 5_565
Mn1 Bi1 Ca3 64.32(4) 5_566 5_565
Mn1 Bi1 Ca3 64.32(4) . 1_556
Mn1 Bi1 Ca3 115.68(4) 5_566 1_556
Ca3 Bi1 Ca3 180.0 5_565 1_556
Mn1 Bi1 Ca3 115.68(4) . 5_566
Mn1 Bi1 Ca3 64.32(4) 5_566 5_566
Ca3 Bi1 Ca3 94.67(6) 5_565 5_566
Ca3 Bi1 Ca3 85.33(6) 1_556 5_566
Mn1 Bi1 Ca3 64.32(4) . .
Mn1 Bi1 Ca3 115.68(4) 5_566 .
Ca3 Bi1 Ca3 85.33(6) 5_565 .
Ca3 Bi1 Ca3 94.67(6) 1_556 .
Ca3 Bi1 Ca3 180.0 5_566 .
Mn1 Bi1 Ca5 119.61(5) . 3_556
Mn1 Bi1 Ca5 60.39(5) 5_566 3_556
Ca3 Bi1 Ca5 103.82(5) 5_565 3_556
Ca3 Bi1 Ca5 76.18(5) 1_556 3_556
Ca3 Bi1 Ca5 103.82(5) 5_566 3_556
Ca3 Bi1 Ca5 76.18(5) . 3_556
Mn1 Bi1 Ca5 60.39(5) . 7_565
Mn1 Bi1 Ca5 119.61(5) 5_566 7_565
Ca3 Bi1 Ca5 76.18(5) 5_565 7_565
Ca3 Bi1 Ca5 103.82(5) 1_556 7_565
Ca3 Bi1 Ca5 76.18(5) 5_566 7_565
Ca3 Bi1 Ca5 103.82(5) . 7_565
Ca5 Bi1 Ca5 180.0 3_556 7_565
Mn1 Bi2 Mn1 112.89(6) 7_665 7_664
Mn1 Bi2 Ca2 72.01(4) 7_665 7_665
Mn1 Bi2 Ca2 72.01(4) 7_664 7_665
Mn1 Bi2 Ca1 71.18(3) 7_665 3_556
Mn1 Bi2 Ca1 147.31(4) 7_664 3_556
Ca2 Bi2 Ca1 79.30(3) 7_665 3_556
Mn1 Bi2 Ca1 147.31(4) 7_665 3
Mn1 Bi2 Ca1 71.18(3) 7_664 3
Ca2 Bi2 Ca1 79.30(3) 7_665 3
Ca1 Bi2 Ca1 88.61(2) 3_556 3
Mn1 Bi2 Ca5 63.48(5) 7_665 .
Mn1 Bi2 Ca5 134.93(5) 7_664 .
Ca2 Bi2 Ca5 134.24(3) 7_665 .
Ca1 Bi2 Ca5 77.02(3) 3_556 .
Ca1 Bi2 Ca5 137.87(4) 3 .
Mn1 Bi2 Ca5 134.93(5) 7_665 1_554
Mn1 Bi2 Ca5 63.48(5) 7_664 1_554
Ca2 Bi2 Ca5 134.24(3) 7_665 1_554
Ca1 Bi2 Ca5 137.87(4) 3_556 1_554
Ca1 Bi2 Ca5 77.02(3) 3 1_554
Ca5 Bi2 Ca5 87.52(5) . 1_554
Mn1 Bi2 Ca3 57.22(3) 7_665 7_665
Mn1 Bi2 Ca3 57.22(3) 7_664 7_665
Ca2 Bi2 Ca3 67.61(5) 7_665 7_665
Ca1 Bi2 Ca3 124.63(2) 3_556 7_665
Ca1 Bi2 Ca3 124.63(2) 3 7_665
Ca5 Bi2 Ca3 95.34(5) . 7_665
Ca5 Bi2 Ca3 95.34(5) 1_554 7_665
Mn2 Bi3 Mn2 114.06(6) . 1_554
Mn2 Bi3 Ca3 110.24(4) . 3_545
Mn2 Bi3 Ca3 110.24(4) 1_554 3_545
Mn2 Bi3 Ca5 160.89(5) . 1_554
Mn2 Bi3 Ca5 74.82(4) 1_554 1_554
Ca3 Bi3 Ca5 80.29(5) 3_545 1_554
Mn2 Bi3 Ca5 74.82(4) . .
Mn2 Bi3 Ca5 160.89(5) 1_554 .
Ca3 Bi3 Ca5 80.29(5) 3_545 .
Ca5 Bi3 Ca5 91.97(6) 1_554 .
Mn2 Bi3 Ca4 82.91(4) . .
Mn2 Bi3 Ca4 82.91(4) 1_554 .
Ca3 Bi3 Ca4 153.64(6) 3_545 .
Ca5 Bi3 Ca4 81.48(5) 1_554 .
Ca5 Bi3 Ca4 81.48(5) . .
Mn2 Bi3 Ca4 72.98(4) . 3_545
Mn2 Bi3 Ca4 72.98(4) 1_554 3_545
Ca3 Bi3 Ca4 72.02(6) 3_545 3_545
Ca5 Bi3 Ca4 126.09(4) 1_554 3_545
Ca5 Bi3 Ca4 126.09(4) . 3_545
Ca4 Bi3 Ca4 134.344(19) . 3_545
Mn2 Bi3 Ca2 57.27(3) . .
Mn2 Bi3 Ca2 57.27(3) 1_554 .
Ca3 Bi3 Ca2 135.95(5) 3_545 .
Ca5 Bi3 Ca2 126.15(4) 1_554 .
Ca5 Bi3 Ca2 126.15(4) . .
Ca4 Bi3 Ca2 70.41(5) . .
Ca4 Bi3 Ca2 63.93(5) 3_545 .
Mn2 Bi4 Ca2 66.19(5) 3_556 3_556
Mn2 Bi4 Ca2 66.19(5) 3_556 3
Ca2 Bi4 Ca2 93.98(6) 3_556 3
Mn2 Bi4 Ca5 150.16(5) 3_556 .
Ca2 Bi4 Ca5 128.59(4) 3_556 .
Ca2 Bi4 Ca5 128.59(4) 3 .
Mn2 Bi4 Ca4 76.17(5) 3_556 .
Ca2 Bi4 Ca4 142.06(6) 3_556 .
Ca2 Bi4 Ca4 74.34(5) 3 .
Ca5 Bi4 Ca4 83.41(5) . .
Mn2 Bi4 Ca4 76.17(5) 3_556 1_556
Ca2 Bi4 Ca4 74.34(5) 3_556 1_556
Ca2 Bi4 Ca4 142.06(6) 3 1_556
Ca5 Bi4 Ca4 83.41(5) . 1_556
Ca4 Bi4 Ca4 92.74(6) . 1_556
Mn2 Bi4 Ca1 129.54(4) 3_556 3_556
Ca2 Bi4 Ca1 80.39(4) 3_556 3_556
Ca2 Bi4 Ca1 80.39(4) 3 3_556
Ca5 Bi4 Ca1 80.30(4) . 3_556
Ca4 Bi4 Ca1 130.64(3) . 3_556
Ca4 Bi4 Ca1 130.64(3) 1_556 3_556
Mn1 Bi5 Mn2 113.65(5) . .
Mn1 Bi5 Ca4 132.82(3) . 1_556
Mn2 Bi5 Ca4 81.79(5) . 1_556
Mn1 Bi5 Ca4 132.82(3) . .
Mn2 Bi5 Ca4 81.79(5) . .
Ca4 Bi5 Ca4 92.04(6) 1_556 .
Mn1 Bi5 Ca2 70.83(5) . 1_556
Mn2 Bi5 Ca2 63.88(4) . 1_556
Ca4 Bi5 Ca2 78.57(5) 1_556 1_556
Ca4 Bi5 Ca2 145.27(6) . 1_556
Mn1 Bi5 Ca2 70.82(5) . .
Mn2 Bi5 Ca2 63.88(4) . .
Ca4 Bi5 Ca2 145.27(6) 1_556 .
Ca4 Bi5 Ca2 78.57(5) . .
Ca2 Bi5 Ca2 90.25(6) 1_556 .
Mn1 Bi5 Ca3 63.81(4) . .
Mn2 Bi5 Ca3 133.16(3) . .
Ca4 Bi5 Ca3 136.87(5) 1_556 .
Ca4 Bi5 Ca3 73.33(5) . .
Ca2 Bi5 Ca3 134.52(6) 1_556 .
Ca2 Bi5 Ca3 72.54(5) . .
Mn1 Bi5 Ca3 63.81(4) . 1_556
Mn2 Bi5 Ca3 133.16(3) . 1_556
Ca4 Bi5 Ca3 73.33(5) 1_556 1_556
Ca4 Bi5 Ca3 136.87(5) . 1_556
Ca2 Bi5 Ca3 72.54(5) 1_556 1_556
Ca2 Bi5 Ca3 134.52(6) . 1_556
Ca3 Bi5 Ca3 89.88(6) . 1_556
Bi5 Mn1 Bi2 117.11(4) . 7_565
Bi5 Mn1 Bi2 117.11(4) . 7_566
Bi2 Mn1 Bi2 112.89(6) 7_565 7_566
Bi5 Mn1 Bi1 100.89(5) . .
Bi2 Mn1 Bi1 102.77(4) 7_565 .
Bi2 Mn1 Bi1 102.77(4) 7_566 .
Bi5 Mn1 Ca3 65.80(5) . 1_556
Bi2 Mn1 Ca3 163.96(7) 7_565 1_556
Bi2 Mn1 Ca3 76.37(3) 7_566 1_556
Bi1 Mn1 Ca3 61.64(5) . 1_556
Bi5 Mn1 Ca3 65.80(5) . .
Bi2 Mn1 Ca3 76.37(3) 7_565 .
Bi2 Mn1 Ca3 163.96(7) 7_566 .
Bi1 Mn1 Ca3 61.64(5) . .
Ca3 Mn1 Ca3 91.78(7) 1_556 .
Bi5 Mn1 Ca5 169.90(8) . 7_565
Bi2 Mn1 Ca5 66.81(4) 7_565 7_565
Bi2 Mn1 Ca5 66.81(4) 7_566 7_565
Bi1 Mn1 Ca5 69.01(5) . 7_565
Ca3 Mn1 Ca5 107.75(6) 1_556 7_565
Ca3 Mn1 Ca5 107.75(6) . 7_565
Bi5 Mn1 Ca2 61.22(5) . .
Bi2 Mn1 Ca2 59.35(4) 7_565 .
Bi2 Mn1 Ca2 125.89(6) 7_566 .
Bi1 Mn1 Ca2 131.30(4) . .
Ca3 Mn1 Ca2 126.92(7) 1_556 .
Ca3 Mn1 Ca2 69.90(5) . .
Ca5 Mn1 Ca2 125.15(5) 7_565 .
Bi5 Mn1 Ca2 61.21(5) . 1_556
Bi2 Mn1 Ca2 125.89(6) 7_565 1_556
Bi2 Mn1 Ca2 59.35(4) 7_566 1_556
Bi1 Mn1 Ca2 131.30(4) . 1_556
Ca3 Mn1 Ca2 69.90(5) 1_556 1_556
Ca3 Mn1 Ca2 126.92(7) . 1_556
Ca5 Mn1 Ca2 125.15(5) 7_565 1_556
Ca2 Mn1 Ca2 82.23(6) . 1_556
Bi5 Mn1 Ca1 115.47(5) . .
Bi2 Mn1 Ca1 61.42(3) 7_565 .
Bi2 Mn1 Ca1 61.42(3) 7_566 .
Bi1 Mn1 Ca1 143.64(6) . .
Ca3 Mn1 Ca1 133.17(4) 1_556 .
Ca3 Mn1 Ca1 133.17(4) . .
Ca5 Mn1 Ca1 74.63(5) 7_565 .
Ca2 Mn1 Ca1 71.58(5) . .
Ca2 Mn1 Ca1 71.58(5) 1_556 .
Bi3 Mn2 Bi3 114.06(6) 1_556 .
Bi3 Mn2 Bi4 115.42(4) 1_556 3_546
Bi3 Mn2 Bi4 115.42(4) . 3_546
Bi3 Mn2 Bi5 105.02(4) 1_556 .
Bi3 Mn2 Bi5 105.02(4) . .
Bi4 Mn2 Bi5 99.48(5) 3_546 .
Bi3 Mn2 Ca2 77.66(3) 1_556 1_556
Bi3 Mn2 Ca2 166.20(6) . 1_556
Bi4 Mn2 Ca2 62.07(5) 3_546 1_556
Bi5 Mn2 Ca2 63.48(5) . 1_556
Bi3 Mn2 Ca2 166.20(6) 1_556 .
Bi3 Mn2 Ca2 77.66(3) . .
Bi4 Mn2 Ca2 62.07(5) 3_546 .
Bi5 Mn2 Ca2 63.48(5) . .
Ca2 Mn2 Ca2 89.85(7) 1_556 .
Bi3 Mn2 Ca5 58.33(3) 1_556 .
Bi3 Mn2 Ca5 58.33(3) . .
Bi4 Mn2 Ca5 157.33(7) 3_546 .
Bi5 Mn2 Ca5 103.19(6) . .
Ca2 Mn2 Ca5 129.56(5) 1_556 .
Ca2 Mn2 Ca5 129.56(5) . .
Bi3 Mn2 Ca4 124.91(6) 1_556 3_545
Bi3 Mn2 Ca4 61.86(3) . 3_545
Bi4 Mn2 Ca4 56.58(4) 3_546 3_545
Bi5 Mn2 Ca4 129.75(5) . 3_545
Ca2 Mn2 Ca4 118.48(7) 1_556 3_545
Ca2 Mn2 Ca4 66.30(5) . 3_545
Ca5 Mn2 Ca4 107.08(6) . 3_545
Bi3 Mn2 Ca4 61.86(3) 1_556 3_546
Bi3 Mn2 Ca4 124.91(6) . 3_546
Bi4 Mn2 Ca4 56.58(4) 3_546 3_546
Bi5 Mn2 Ca4 129.75(5) . 3_546
Ca2 Mn2 Ca4 66.30(5) 1_556 3_546
Ca2 Mn2 Ca4 118.48(7) . 3_546
Ca5 Mn2 Ca4 107.08(6) . 3_546
Ca4 Mn2 Ca4 76.96(5) 3_545 3_546
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ca1 Bi4 3.3140(8) 7_565
Ca1 Bi4 3.3140(8) 3_546
Ca1 Bi2 3.3688(6) 7_566
Ca1 Bi2 3.3688(6) 3_545
Ca1 Bi2 3.3688(6) 7_565
Ca1 Bi2 3.3688(6) 3_546
Ca1 Mn1 3.6309(19) .
Ca1 Mn1 3.6309(19) 5_556
Ca1 Ca5 4.216(2) 7_565
Ca1 Ca5 4.216(2) 3_546
Ca1 Ca2 4.216(2) .
Ca1 Ca2 4.216(2) 5
Ca2 Bi4 3.2177(16) 3_545
Ca2 Bi4 3.2177(16) 3_546
Ca2 Bi2 3.237(2) 7_565
Ca2 Bi5 3.3203(17) 1_554
Ca2 Bi5 3.3203(17) .
Ca2 Mn2 3.332(2) 1_554
Ca2 Mn2 3.332(2) .
Ca2 Mn1 3.578(2) 1_554
Ca2 Mn1 3.578(2) .
Ca2 Bi3 3.869(2) .
Ca2 Ca4 3.908(3) 3_545
Ca2 Ca3 3.935(3) .
Ca3 Bi1 3.2001(16) 1_554
Ca3 Bi1 3.2001(16) .
Ca3 Bi3 3.207(2) 3
Ca3 Mn1 3.277(2) 1_554
Ca3 Mn1 3.277(2) .
Ca3 Bi5 3.3311(17) 1_554
Ca3 Bi5 3.3312(17) .
Ca3 Bi2 3.788(2) 7_565
Ca3 Ca4 3.942(3) .
Ca3 Ca5 4.177(3) 3_556
Ca3 Ca5 4.177(3) 3
Ca4 Bi4 3.2507(16) .
Ca4 Bi4 3.2508(16) 1_554
Ca4 Bi5 3.2699(16) .
Ca4 Bi5 3.2699(16) 1_554
Ca4 Bi3 3.328(2) .
Ca4 Bi3 3.487(2) 3
Ca4 Mn2 3.782(2) 3_556
Ca4 Mn2 3.782(2) 3
Ca4 Ca2 3.908(3) 3
Ca4 Ca5 4.308(3) 1_554
Ca5 Bi4 3.224(2) .
Ca5 Bi3 3.2719(16) .
Ca5 Bi3 3.2718(16) 1_556
Ca5 Mn1 3.312(3) 7_665
Ca5 Bi2 3.4019(17) 1_556
Ca5 Bi2 3.4019(17) .
Ca5 Bi1 3.556(2) 3_546
Ca5 Mn2 3.710(3) .
Ca5 Ca3 4.177(3) 3_545
Ca5 Ca3 4.177(3) 3_546
Ca5 Ca1 4.216(2) 3_556
Bi1 Mn1 2.9433(18) .
Bi1 Mn1 2.9434(18) 5_566
Bi1 Ca3 3.2000(16) 5_565
Bi1 Ca3 3.2000(16) 1_556
Bi1 Ca3 3.2000(16) 5_566
Bi1 Ca5 3.556(2) 3_556
Bi1 Ca5 3.556(2) 7_565
Bi2 Mn1 2.8235(10) 7_665
Bi2 Mn1 2.8235(10) 7_664
Bi2 Ca2 3.237(2) 7_665
Bi2 Ca1 3.3688(6) 3_556
Bi2 Ca1 3.3688(6) 3
Bi2 Ca5 3.4020(17) 1_554
Bi2 Ca3 3.788(2) 7_665
Bi3 Mn2 2.8047(10) .
Bi3 Mn2 2.8047(10) 1_554
Bi3 Ca3 3.207(2) 3_545
Bi3 Ca5 3.2718(16) 1_554
Bi3 Ca4 3.487(2) 3_545
Bi4 Mn2 2.8597(17) 3_556
Bi4 Ca2 3.2177(16) 3_556
Bi4 Ca2 3.2177(16) 3
Bi4 Ca4 3.2508(16) 1_556
Bi4 Ca1 3.3140(8) 3_556
Bi5 Mn1 2.8136(18) .
Bi5 Mn2 2.9495(18) .
Bi5 Ca4 3.2698(16) 1_556
Bi5 Ca2 3.3203(17) 1_556
Bi5 Ca3 3.3312(17) 1_556
Mn1 Bi2 2.8235(10) 7_565
Mn1 Bi2 2.8235(10) 7_566
Mn1 Ca3 3.277(2) 1_556
Mn1 Ca5 3.312(3) 7_565
Mn1 Ca2 3.578(2) 1_556
Mn2 Bi3 2.8047(10) 1_556
Mn2 Bi4 2.8597(17) 3_546
Mn2 Ca2 3.332(2) 1_556
Mn2 Ca4 3.782(2) 3_545
Mn2 Ca4 3.782(2) 3_546
