#------------------------------------------------------------------------------
#$Date: 2025-08-21 00:01:10 +0200 (Thu 21 de Aug de 2025) $
#$Revision: 301838 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/26/4322630.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4322630
loop_
_publ_author_name
'Matteo Cusumano'
'Maria Letizia Di Pietro'
'Antonino Giannetto'
'Francesco Nicolò'
'Enrico Rotondo'
_publ_section_title
;
 Noncovalent Interactions of Platinum(II) Square Planar Complexes
 Containing Ligands Out-of-Plane with DNA
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              563
_journal_page_last               568
_journal_paper_doi               10.1021/ic9705406
_journal_volume                  37
_journal_year                    1998
_chemical_compound_source        'chemical synthesis'
_chemical_formula_moiety         'C36 H34 N4 Pt1 2+, 2 (P1 F6) 1- '
_chemical_formula_sum            'C36 H34 F12 N4 P2 Pt'
_chemical_formula_weight         1007.710
_chemical_name_systematic
;
(4,4'-diphenyl-2,2'-bipyridyl)-bis(3,5-dimethylpyridine)-platinum  
diesafluorophosphate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     Patterson
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                104.46(2)
_cell_angle_beta                 95.36(2)
_cell_angle_gamma                93.33(2)
_cell_formula_units_Z            2
_cell_length_a                   10.724(2)
_cell_length_b                   12.850(3)
_cell_length_c                   14.878(3)
_cell_measurement_radiation      'Mo K\a'
_cell_measurement_reflns_used    21
_cell_measurement_temperature    298
_cell_measurement_theta_max      11.37
_cell_measurement_theta_min      6.60
_cell_measurement_wavelength     0.710730
_cell_volume                     1969.6(7)
_computing_cell_refinement       'Siemens P3/V'
_computing_data_collection       'Siemens P3/V,(VMS vers 4.21, 1989)'
_computing_data_reduction        'Siemens SHELXTL-PLUS,(VMS vers 4.2 , 1991)'
_computing_molecular_graphics    'Siemens XPW'
_computing_publication_material  'Siemens SHELXTL-PLUS and PARST'
_computing_structure_refinement  'Siemens SHELXTL-PLUS'
_computing_structure_solution    'Siemens SHELXTL-PLUS'
_diffrn_ambient_temperature      298
_diffrn_measurement_device       'Siemens R3m/v diffractometer'
_diffrn_measurement_method       ω/2θ
_diffrn_radiation_monochromator  'highly oriented graphite crystal'
_diffrn_radiation_source         'fine-focus xray_tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.710730
_diffrn_reflns_av_R_equivalents  0.0266
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            7398
_diffrn_reflns_theta_max         25.0
_diffrn_reflns_theta_min         1.5
_diffrn_standards_decay_%        3.57
_diffrn_standards_interval_count 197
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    3.732
_exptl_absorpt_correction_T_max  0.9520
_exptl_absorpt_correction_T_min  0.7201
_exptl_absorpt_correction_type   '\y scan'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.699
_exptl_crystal_density_method    none
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             988
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.22
_refine_diff_density_min         -0.89
_refine_ls_extinction_expression
;
equ(22) p292 "Crystallographic Computing" (1970)  
;
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_obs   0.76
_refine_ls_hydrogen_treatment    'Riding model, fixed isotropic U'
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     496
_refine_ls_number_reflns         2945
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1069
_refine_ls_R_factor_obs          0.0493
_refine_ls_shift/esd_max         0.140
_refine_ls_shift/esd_mean        0.007
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/(σ²(F)+ 0.0037 F²)'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0873
_refine_ls_wR_factor_obs         0.0613
_reflns_number_observed          2945
_reflns_number_total             6991
_reflns_observed_criterion       'F > 5\s(F)'
_cod_data_source_file            ic9705406.cif
_cod_data_source_block           cusma6
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value '1/(\s^2^(F)+ 0.0037 F^2^)' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to 'w = 1/(\s^2^(F)+ 0.0037
F^2^)'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_formula_sum        'C36 H34 F12 N4 P2 Pt1'
_cod_database_code               4322630
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,-y,-z
loop_
_atom_site_label
_atom_site_occupancy
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_type_symbol
_atom_site_calc_flag
_atom_site_calc_attached_atom
_atom_site_disorder_group
Pt 1.00 0.73379(7) 0.66521(6) 0.70586(5) 0.0517(3) Uani Pt ? ? ?
N1 1.00 0.612(1) 0.745(1) 0.6454(9) 0.052(5) Uani N ? ? ?
C1 1.00 0.606(1) 0.754(1) 0.558(1) 0.060(7) Uani C ? ? ?
C2 1.00 0.519(1) 0.812(1) 0.520(1) 0.053(7) Uani C ? ? ?
C3 1.00 0.439(1) 0.872(1) 0.579(1) 0.040(6) Uani C ? ? ?
C4 1.00 0.448(1) 0.866(1) 0.669(1) 0.043(6) Uani C ? ? ?
C5 1.00 0.535(1) 0.804(1) 0.702(1) 0.045(6) Uani C ? ? ?
C6 1.00 0.550(1) 0.791(1) 0.799(1) 0.043(6) Uani C ? ? ?
C7 1.00 0.477(1) 0.837(1) 0.867(1) 0.047(6) Uani C ? ? ?
C8 1.00 0.496(1) 0.820(1) 0.957(1) 0.052(7) Uani C ? ? ?
C9 1.00 0.590(2) 0.756(1) 0.971(1) 0.073(8) Uani C ? ? ?
C10 1.00 0.662(2) 0.711(2) 0.901(1) 0.10(1) Uani C ? ? ?
N2 1.00 0.639(1) 0.727(1) 0.813(1) 0.055(6) Uani N ? ? ?
C11 1.00 0.347(1) 0.936(1) 0.540(1) 0.052(7) Uani C ? ? ?
C12 1.00 0.294(1) 0.901(1) 0.447(1) 0.061(7) Uani C ? ? ?
C13 1.00 0.201(2) 0.955(2) 0.413(1) 0.078(8) Uani C ? ? ?
C14 1.00 0.161(2) 1.046(2) 0.470(1) 0.076(9) Uani C ? ? ?
C15 1.00 0.211(2) 1.081(2) 0.560(2) 0.082(9) Uani C ? ? ?
C16 1.00 0.308(1) 1.026(1) 0.596(1) 0.061(7) Uani C ? ? ?
C17 1.00 0.422(1) 0.873(1) 1.032(1) 0.045(6) Uani C ? ? ?
C18 1.00 0.320(2) 0.930(2) 1.012(1) 0.068(8) Uani C ? ? ?
C19 1.00 0.243(2) 0.973(1) 1.084(1) 0.054(7) Uani C ? ? ?
C20 1.00 0.278(2) 0.964(1) 1.173(1) 0.064(7) Uani C ? ? ?
C21 1.00 0.379(2) 0.911(1) 1.191(1) 0.060(8) Uani C ? ? ?
C22 1.00 0.451(2) 0.865(1) 1.121(1) 0.065(8) Uani C ? ? ?
N3 1.00 0.852(1) 0.585(1) 0.772(1) 0.053(6) Uani N ? ? ?
C23 1.00 0.962(2) 0.632(2) 0.815(1) 0.064(8) Uani C ? ? ?
C24 1.00 1.052(2) 0.583(2) 0.861(1) 0.070(9) Uani C ? ? ?
C25 1.00 1.018(2) 0.478(2) 0.861(1) 0.08(1) Uani C ? ? ?
C26 1.00 0.909(2) 0.426(2) 0.816(1) 0.08(1) Uani C ? ? ?
C27 1.00 0.826(2) 0.484(2) 0.773(1) 0.063(8) Uani C ? ? ?
C28 1.00 1.176(2) 0.645(2) 0.909(2) 0.15(1) Uani C ? ? ?
C29 1.00 0.863(2) 0.308(2) 0.812(1) 0.11(1) Uani C ? ? ?
N4 1.00 0.813(1) 0.607(1) 0.5878(9) 0.045(6) Uani N ? ? ?
C30 1.00 0.904(2) 0.666(1) 0.562(1) 0.053(7) Uani C ? ? ?
C31 1.00 0.947(1) 0.638(1) 0.475(1) 0.052(7) Uani C ? ? ?
C32 1.00 0.894(2) 0.544(2) 0.415(1) 0.056(7) Uani C ? ? ?
C33 1.00 0.804(2) 0.481(1) 0.440(1) 0.054(7) Uani C ? ? ?
C34 1.00 0.766(1) 0.515(1) 0.528(1) 0.054(7) Uani C ? ? ?
C35 1.00 1.046(2) 0.710(1) 0.450(1) 0.071(7) Uani C ? ? ?
C36 1.00 0.741(2) 0.375(2) 0.375(1) 0.09(1) Uani C ? ? ?
P1 1.00 1.0909(4) 0.9432(4) 0.7784(3) 0.065(2) Uani P ? ? ?
F1 1.00 1.069(1) 0.983(1) 0.8837(8) 0.130(7) Uani F ? ? ?
F2 1.00 1.148(1) 0.838(1) 0.799(1) 0.121(6) Uani F ? ? ?
F3 1.00 1.114(1) 0.894(1) 0.6715(8) 0.116(6) Uani F ? ? ?
F4 1.00 1.038(1) 1.042(1) 0.754(1) 0.137(7) Uani F ? ? ?
F5 1.00 1.2303(9) 1.0005(8) 0.7992(7) 0.078(4) Uani F ? ? ?
F6 1.00 0.9511(9) 0.8802(9) 0.7539(7) 0.087(5) Uani F ? ? ?
P2 1.00 0.4363(7) 0.3877(5) 0.7454(5) 0.094(3) Uani P ? ? ?
F7 1.00 0.540(2) 0.428(3) 0.822(2) 0.28(2) Uani F ? ? ?
F8 1.00 0.374(2) 0.339(2) 0.811(2) 0.32(2) Uani F ? ? ?
F9 1.00 0.346(2) 0.347(2) 0.657(1) 0.20(1) Uani F ? ? ?
F10 1.00 0.507(2) 0.442(3) 0.683(2) 0.31(2) Uani F ? ? ?
F11 1.00 0.508(3) 0.291(2) 0.714(1) 0.28(2) Uani F ? ? ?
F12 1.00 0.353(3) 0.470(2) 0.775(1) 0.32(2) Uani F ? ? ?
H29A 1.00 0.927(2) 0.277(2) 0.844(1) 0.085 Uiso H calc C29 ?
H29B 1.00 0.847(2) 0.267(2) 0.748(1) 0.085 Uiso H calc C29 ?
H29C 1.00 0.788(2) 0.307(2) 0.842(1) 0.085 Uiso H calc C29 ?
H12 1.00 0.323(1) 0.839(1) 0.407(1) 0.085 Uiso H calc C12 ?
H19 1.00 0.169(2) 1.007(1) 1.071(1) 0.085 Uiso H calc C19 ?
H30 1.00 0.940(2) 0.732(1) 0.606(1) 0.085 Uiso H calc C30 ?
H9 1.00 0.606(2) 0.741(1) 1.031(1) 0.085 Uiso H calc C9 ?
H20 1.00 0.231(2) 0.997(1) 1.223(1) 0.085 Uiso H calc C20 ?
H32 1.00 0.921(2) 0.522(2) 0.354(1) 0.085 Uiso H calc C32 ?
H13 1.00 0.164(2) 0.930(2) 0.350(1) 0.085 Uiso H calc C13 ?
H21 1.00 0.401(2) 0.904(1) 1.253(1) 0.085 Uiso H calc C21 ?
H34 1.00 0.704(1) 0.471(1) 0.546(1) 0.085 Uiso H calc C34 ?
H4 1.00 0.394(1) 0.905(1) 0.711(1) 0.085 Uiso H calc C4 ?
H35A 1.00 1.066(2) 0.679(1) 0.388(1) 0.085 Uiso H calc C35 ?
H35B 1.00 1.121(2) 0.719(1) 0.493(1) 0.085 Uiso H calc C35 ?
H35C 1.00 1.015(2) 0.779(1) 0.453(1) 0.085 Uiso H calc C35 ?
H22 1.00 0.522(2) 0.828(1) 1.136(1) 0.085 Uiso H calc C22 ?
H36A 1.00 0.777(2) 0.362(2) 0.316(1) 0.085 Uiso H calc C36 ?
H36B 1.00 0.652(2) 0.381(2) 0.364(1) 0.085 Uiso H calc C36 ?
H36C 1.00 0.755(2) 0.317(2) 0.403(1) 0.085 Uiso H calc C36 ?
H14 1.00 0.097(2) 1.084(2) 0.446(1) 0.085 Uiso H calc C14 ?
H10 1.00 0.729(2) 0.668(2) 0.913(1) 0.085 Uiso H calc C10 ?
H23 1.00 0.981(2) 0.706(2) 0.814(1) 0.085 Uiso H calc C23 ?
H15 1.00 0.181(2) 1.143(2) 0.601(2) 0.085 Uiso H calc C15 ?
H7 1.00 0.412(1) 0.881(1) 0.853(1) 0.085 Uiso H calc C7 ?
H25 1.00 1.074(2) 0.441(2) 0.893(1) 0.085 Uiso H calc C25 ?
H16 1.00 0.346(1) 1.053(1) 0.659(1) 0.085 Uiso H calc C16 ?
H1 1.00 0.664(1) 0.718(1) 0.518(1) 0.085 Uiso H calc C1 ?
H27 1.00 0.747(2) 0.448(2) 0.743(1) 0.085 Uiso H calc C27 ?
H2 1.00 0.513(1) 0.811(1) 0.455(1) 0.085 Uiso H calc C2 ?
H28A 1.00 1.179(2) 0.717(2) 0.900(2) 0.085 Uiso H calc C28 ?
H28B 1.00 1.245(2) 0.609(2) 0.882(2) 0.085 Uiso H calc C28 ?
H28C 1.00 1.183(2) 0.649(2) 0.974(2) 0.085 Uiso H calc C28 ?
H18 1.00 0.302(2) 0.940(2) 0.951(1) 0.085 Uiso H calc C18 ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_oxidation_number
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C Carbon 0 72 0.0020 0.0020 Internat_Tables_Vol_IV_Table_2.3.1
H Hydrogen 0 68 0.0000 0.0000 Internat_Tables_Vol_IV_Table_2.3.1
N Nitrogen 0 8 0.0040 0.0030 Internat_Tables_Vol_IV_Table_2.3.1
F Fluorine 0 24 0.0140 0.0100 Internat_Tables_Vol_IV_Table_2.3.1
P Phosphorus 0 4 0.0900 0.0950 Internat_Tables_Vol_IV_Table_2.3.1
Pt Platinum 0 2 -2.3520 8.3880 Internat_Tables_Vol_IV_Table_2.3.1
loop_
_diffrn_attenuator_code
_diffrn_attenuator_scale
? ?
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
3 -2 3
-3 0 3
-3 -3 1
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Pt N4 88.8(6) . . . ?
N2 Pt N4 173.2(5) . . . ?
N2 Pt N3 97.7(6) . . . ?
N1 Pt N4 93.7(5) . . . ?
N1 Pt N3 177.4(6) . . . ?
N1 Pt N2 79.8(5) . . . ?
Pt N1 C5 116(1) . . . ?
Pt N1 C1 127(1) . . . ?
C1 N1 C5 117(1) . . . ?
N1 C1 C2 124(1) . . . ?
C1 C2 C3 119(1) . . . ?
C2 C3 C11 120(1) . . . ?
C2 C3 C4 117(1) . . . ?
C4 C3 C11 123(1) . . . ?
C3 C4 C5 120(1) . . . ?
N1 C5 C4 122(1) . . . ?
C4 C5 C6 124(1) . . . ?
N1 C5 C6 114(1) . . . ?
C5 C6 N2 113(1) . . . ?
C5 C6 C7 124(1) . . . ?
C7 C6 N2 122(1) . . . ?
C6 C7 C8 121(1) . . . ?
C7 C8 C17 121(1) . . . ?
C7 C8 C9 116(1) . . . ?
C9 C8 C17 123(1) . . . ?
C8 C9 C10 122(2) . . . ?
C9 C10 N2 120(2) . . . ?
C6 N2 C10 119(1) . . . ?
Pt N2 C10 124(1) . . . ?
Pt N2 C6 117(1) . . . ?
C3 C11 C16 121(1) . . . ?
C3 C11 C12 120(1) . . . ?
C12 C11 C16 119(2) . . . ?
C11 C12 C13 120(2) . . . ?
C12 C13 C14 120(2) . . . ?
C13 C14 C15 121(2) . . . ?
C14 C15 C16 120(2) . . . ?
C11 C16 C15 120(2) . . . ?
C8 C17 C22 120(1) . . . ?
C8 C17 C18 121(1) . . . ?
C18 C17 C22 119(1) . . . ?
C17 C18 C19 120(1) . . . ?
C18 C19 C20 118(2) . . . ?
C19 C20 C21 121(2) . . . ?
C20 C21 C22 121(2) . . . ?
C17 C22 C21 120(1) . . . ?
Pt N3 C27 123(1) . . . ?
Pt N3 C23 120(1) . . . ?
C23 N3 C27 117(2) . . . ?
N3 C23 C24 125(2) . . . ?
C23 C24 C28 121(2) . . . ?
C23 C24 C25 115(2) . . . ?
C25 C24 C28 124(2) . . . ?
C24 C25 C26 122(2) . . . ?
C25 C26 C29 126(2) . . . ?
C25 C26 C27 117(2) . . . ?
C27 C26 C29 117(2) . . . ?
N3 C27 C26 124(2) . . . ?
Pt N4 C34 121(1) . . . ?
Pt N4 C30 121(1) . . . ?
C30 N4 C34 118(2) . . . ?
N4 C30 C31 123(2) . . . ?
C30 C31 C35 120(2) . . . ?
C30 C31 C32 117(2) . . . ?
C32 C31 C35 123(2) . . . ?
C31 C32 C33 122(2) . . . ?
C32 C33 C36 124(2) . . . ?
C32 C33 C34 118(2) . . . ?
C34 C33 C36 119(2) . . . ?
N4 C34 C33 123(2) . . . ?
F5 P1 F6 177.4(6) . . . ?
F4 P1 F6 89.6(7) . . . ?
F4 P1 F5 91.9(6) . . . ?
F3 P1 F6 88.0(6) . . . ?
F3 P1 F5 89.8(6) . . . ?
F3 P1 F4 90.6(8) . . . ?
F2 P1 F6 90.4(6) . . . ?
F2 P1 F5 88.0(6) . . . ?
F2 P1 F4 177.1(8) . . . ?
F2 P1 F3 86.5(7) . . . ?
F1 P1 F6 90.4(6) . . . ?
F1 P1 F5 91.6(6) . . . ?
F1 P1 F4 93.1(8) . . . ?
F1 P1 F3 175.9(7) . . . ?
F1 P1 F2 89.8(8) . . . ?
F11 P2 F12 172(2) . . . ?
F10 P2 F12 98(1) . . . ?
F10 P2 F11 89(1) . . . ?
F9 P2 F12 87(1) . . . ?
F9 P2 F11 89(1) . . . ?
F9 P2 F10 82(1) . . . ?
F8 P2 F12 82(1) . . . ?
F8 P2 F11 92(1) . . . ?
F8 P2 F10 176(2) . . . ?
F8 P2 F9 102(1) . . . ?
F7 P2 F12 98(1) . . . ?
F7 P2 F11 87(1) . . . ?
F7 P2 F10 90(1) . . . ?
F7 P2 F9 171(1) . . . ?
F7 P2 F8 87(1) . . . ?
P2 F8 F12 48(1) . . . ?
P2 F12 F8 50(1) . . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt N1 1.99(1) . . ?
Pt N2 1.99(1) . . ?
Pt N3 2.01(2) . . ?
Pt N4 2.02(1) . . ?
N1 C1 1.33(2) . . ?
N1 C5 1.35(2) . . ?
C1 C2 1.38(2) . . ?
C2 C3 1.40(2) . . ?
C3 C4 1.37(2) . . ?
C3 C11 1.48(2) . . ?
C4 C5 1.40(2) . . ?
C5 C6 1.48(2) . . ?
C6 C7 1.38(2) . . ?
C6 N2 1.33(2) . . ?
C7 C8 1.41(2) . . ?
C8 C9 1.37(2) . . ?
C8 C17 1.47(2) . . ?
C9 C10 1.39(3) . . ?
C10 N2 1.37(3) . . ?
C11 C12 1.39(2) . . ?
C11 C16 1.36(2) . . ?
C12 C13 1.38(3) . . ?
C13 C14 1.37(3) . . ?
C14 C15 1.35(3) . . ?
C15 C16 1.42(3) . . ?
C17 C18 1.40(2) . . ?
C17 C22 1.37(2) . . ?
C18 C19 1.44(2) . . ?
C19 C20 1.37(3) . . ?
C20 C21 1.36(3) . . ?
C21 C22 1.38(2) . . ?
N3 C23 1.32(2) . . ?
N3 C27 1.31(3) . . ?
C23 C24 1.41(3) . . ?
C24 C25 1.37(3) . . ?
C24 C28 1.53(3) . . ?
C25 C26 1.34(3) . . ?
C26 C27 1.41(3) . . ?
C26 C29 1.55(3) . . ?
N4 C30 1.34(2) . . ?
N4 C34 1.33(2) . . ?
C30 C31 1.39(3) . . ?
C31 C32 1.37(2) . . ?
C31 C35 1.51(3) . . ?
C32 C33 1.36(3) . . ?
C33 C34 1.38(3) . . ?
C33 C36 1.53(2) . . ?
P1 F1 1.57(1) . . ?
P1 F2 1.60(1) . . ?
P1 F3 1.61(1) . . ?
P1 F4 1.53(2) . . ?
P1 F5 1.60(1) . . ?
P1 F6 1.63(1) . . ?
P2 F7 1.49(2) . . ?
P2 F8 1.47(3) . . ?
P2 F9 1.52(2) . . ?
P2 F10 1.52(3) . . ?
P2 F11 1.49(3) . . ?
P2 F12 1.44(3) . . ?
F8 F12 1.92(4) . . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N3 Pt N4 C30 -97(1) . . . . ?
N2 Pt N4 C30 99(5) . . . . ?
N1 Pt N4 C30 84(1) . . . . ?
N3 Pt N4 C34 91(1) . . . . ?
N2 Pt N4 C34 -72(5) . . . . ?
N1 Pt N4 C34 -88(1) . . . . ?
N2 Pt N3 C23 -91(1) . . . . ?
N1 Pt N3 C23 -104(13) . . . . ?
N2 Pt N3 C27 91(1) . . . . ?
N1 Pt N3 C27 78(13) . . . . ?
N4 Pt N2 C6 -18(5) . . . . ?
N3 Pt N2 C6 178(1) . . . . ?
N1 Pt N2 C6 -2(1) . . . . ?
N4 Pt N2 C10 164(4) . . . . ?
N3 Pt N2 C10 0(1) . . . . ?
N1 Pt N2 C10 180(1) . . . . ?
N2 Pt N1 C5 4(1) . . . . ?
N2 Pt N1 C1 178(1) . . . . ?
N3 Pt N1 C5 17(13) . . . . ?
N3 Pt N1 C1 -168(12) . . . . ?
N4 Pt N1 C5 -178(1) . . . . ?
N4 Pt N1 C1 -4(1) . . . . ?
N4 Pt N3 C27 -87(1) . . . . ?
N4 Pt N3 C23 91(1) . . . . ?
Pt N1 C5 C6 -4(2) . . . . ?
Pt N1 C5 C4 178(1) . . . . ?
Pt N1 C1 C2 -180(1) . . . . ?
C1 N1 C5 C6 -179(1) . . . . ?
C1 N1 C5 C4 3(2) . . . . ?
C5 N1 C1 C2 -5(2) . . . . ?
N1 C1 C2 C3 5(2) . . . . ?
C1 C2 C3 C4 -3(2) . . . . ?
C1 C2 C3 C11 179(1) . . . . ?
C2 C3 C11 C12 32(2) . . . . ?
C2 C3 C11 C16 -152(2) . . . . ?
C2 C3 C4 C5 1(2) . . . . ?
C4 C3 C11 C12 -147(2) . . . . ?
C4 C3 C11 C16 30(2) . . . . ?
C11 C3 C4 C5 180(1) . . . . ?
C3 C4 C5 N1 -1(2) . . . . ?
C3 C4 C5 C6 -179(1) . . . . ?
C4 C5 C6 C7 1(2) . . . . ?
N1 C5 C6 C7 -176(1) . . . . ?
C4 C5 C6 N2 179(1) . . . . ?
N1 C5 C6 N2 2(2) . . . . ?
C5 C6 N2 Pt 1(2) . . . . ?
C7 C6 N2 Pt 179(1) . . . . ?
C5 C6 N2 C10 179(1) . . . . ?
C5 C6 C7 C8 180(1) . . . . ?
C7 C6 N2 C10 -3(2) . . . . ?
N2 C6 C7 C8 2(2) . . . . ?
C6 C7 C8 C9 -0(2) . . . . ?
C6 C7 C8 C17 178(1) . . . . ?
C7 C8 C17 C18 8(2) . . . . ?
C7 C8 C17 C22 -173(2) . . . . ?
C7 C8 C9 C10 1(3) . . . . ?
C9 C8 C17 C18 -174(2) . . . . ?
C9 C8 C17 C22 5(2) . . . . ?
C17 C8 C9 C10 -177(2) . . . . ?
C8 C9 C10 N2 -2(3) . . . . ?
C9 C10 N2 C6 3(3) . . . . ?
C9 C10 N2 Pt -179(1) . . . . ?
C3 C11 C16 C15 -174(2) . . . . ?
C3 C11 C12 C13 174(2) . . . . ?
C12 C11 C16 C15 3(3) . . . . ?
C16 C11 C12 C13 -2(3) . . . . ?
C11 C12 C13 C14 2(3) . . . . ?
C12 C13 C14 C15 -2(3) . . . . ?
C13 C14 C15 C16 2(3) . . . . ?
C14 C15 C16 C11 -2(3) . . . . ?
C8 C17 C22 C21 -178(2) . . . . ?
C8 C17 C18 C19 175(2) . . . . ?
C18 C17 C22 C21 2(2) . . . . ?
C22 C17 C18 C19 -4(2) . . . . ?
C17 C18 C19 C20 6(3) . . . . ?
C18 C19 C20 C21 -4(3) . . . . ?
C19 C20 C21 C22 2(3) . . . . ?
C20 C21 C22 C17 -0(3) . . . . ?
Pt N3 C27 C26 178(2) . . . . ?
Pt N3 C23 C24 -179(2) . . . . ?
C23 N3 C27 C26 -0(3) . . . . ?
C27 N3 C23 C24 -0(3) . . . . ?
N3 C23 C24 C25 -1(3) . . . . ?
N3 C23 C24 C28 -180(2) . . . . ?
C23 C24 C25 C26 2(3) . . . . ?
C28 C24 C25 C26 -178(2) . . . . ?
C24 C25 C26 C27 -3(3) . . . . ?
C24 C25 C26 C29 180(2) . . . . ?
C25 C26 C27 N3 2(3) . . . . ?
C29 C26 C27 N3 179(2) . . . . ?
Pt N4 C34 C33 169(1) . . . . ?
Pt N4 C30 C31 -170(1) . . . . ?
C30 N4 C34 C33 -2(3) . . . . ?
C34 N4 C30 C31 2(3) . . . . ?
N4 C30 C31 C32 -0(3) . . . . ?
N4 C30 C31 C35 178(2) . . . . ?
C30 C31 C32 C33 -1(3) . . . . ?
C35 C31 C32 C33 -179(2) . . . . ?
C31 C32 C33 C34 1(3) . . . . ?
C31 C32 C33 C36 180(2) . . . . ?
C32 C33 C34 N4 1(3) . . . . ?
C36 C33 C34 N4 -178(2) . . . . ?
F11 P2 F12 F8 41(11) . . . . ?
F10 P2 F12 F8 -176(2) . . . . ?
F9 P2 F12 F8 102(1) . . . . ?
F7 P2 F12 F8 -86(2) . . . . ?
F7 P2 F8 F12 99(2) . . . . ?
F9 P2 F8 F12 -86(1) . . . . ?
F10 P2 F8 F12 87(26) . . . . ?
F11 P2 F8 F12 -175(2) . . . . ?
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 PubChem 139134676
