#------------------------------------------------------------------------------
#$Date: 2025-08-21 13:21:36 +0200 (Thu 21 de Aug de 2025) $
#$Revision: 301847 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/38/7013880.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7013880
loop_
_publ_author_name
'Bezombes, Jean-Philippe'
'Hitchcock, Peter B.'
'Lappert, Michael F.'
'Nycz, Jacek E.'
_publ_section_title
;
 Synthesis and P-P cleavage reactions of [P(X)X']2; X-ray structures of
 [Co[P(X)X'](CO)3] and P4[P(X)X']2[X = N(SiMe3)2, X'= NPri2].
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              499
_journal_page_last               501
_journal_paper_doi               10.1039/b315793h
_journal_year                    2004
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C24 H64 N4 P6 Si4'
_chemical_formula_structural     'C24 H64 N4 P6 SI4'
_chemical_formula_sum            'C24 H64 N4 P6 Si4'
_chemical_formula_weight         706.97
_chemical_name_common            (P4(P(NiPr2)(N(SiMe3)2))2)
_space_group_IT_number           7
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      7
_symmetry_space_group_name_Hall  'P -2ya'
_symmetry_space_group_name_H-M   'P 1 a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/cifdics/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.1
_audit_creation_date             2001-03-19T14:38:41-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 112.336(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   13.8004(7)
_cell_length_b                   11.0049(5)
_cell_length_c                   14.7827(7)
_cell_measurement_reflns_used    7324
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      25.028
_cell_measurement_theta_min      3.705
_cell_measurement_wavelength     0.71073
_cell_volume                     2076.63(17)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_reduction
'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device       KappaCCD
_diffrn_measurement_method       CCD
_diffrn_orient_matrix_UB_33      0.01
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.042
_diffrn_reflns_av_unetI/netI     0.0586
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            9087
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         3.91
_exptl_absorpt_coefficient_mu    0.394
_exptl_absorpt_correction_T_max  0.8909
_exptl_absorpt_correction_T_min  0.8909
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.131
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             764
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.3
_refine_diff_density_max         0.688
_refine_diff_density_min         -0.252
_refine_diff_density_rms         0.055
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.08(18)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     398
_refine_ls_number_reflns         5552
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0587
_refine_ls_R_factor_gt           0.0495
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0512P)²+2.2740P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1207
_refine_ls_wR_factor_ref         0.1273
_reflns_number_gt                4876
_reflns_number_total             5552
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b315793h.txt
_cod_data_source_block           mar1901
_cod_original_sg_symbol_H-M      Pa
_cod_database_code               7013880
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x+1/2, -y, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Si1 Si 0.61148(13) 0.45443(14) 0.39967(13) 0.0399(4) Uani 1 1 d . . .
Si2 Si 0.67551(13) 0.26465(16) 0.28601(11) 0.0400(4) Uani 1 1 d . . .
Si3 Si 1.16901(13) 0.03503(15) 0.93412(13) 0.0421(4) Uani 1 1 d . C .
Si4 Si 1.11631(13) 0.23839(15) 1.04620(12) 0.0400(4) Uani 1 1 d . C .
N1 N 0.6514(3) 0.3037(4) 0.3912(3) 0.0303(10) Uani 1 1 d . C .
N2 N 0.5911(4) 0.1131(4) 0.4834(4) 0.0398(12) Uani 1 1 d . . .
N3 N 1.1318(4) 0.1874(4) 0.9394(3) 0.0321(10) Uani 1 1 d . . .
N4 N 1.1807(4) 0.3930(4) 0.8494(3) 0.0372(11) Uani 1 1 d . . .
C1 C 0.5418(6) 0.4819(6) 0.4836(5) 0.0523(17) Uani 1 1 d . C .
H1A H 0.4802 0.429 0.4654 0.078 Uiso 1 1 calc R . .
H1B H 0.5195 0.567 0.4788 0.078 Uiso 1 1 calc R . .
H1C H 0.5889 0.4642 0.551 0.078 Uiso 1 1 calc R . .
C2 C 0.7286(6) 0.5591(6) 0.4418(6) 0.062(2) Uani 1 1 d . C .
H2A H 0.7687 0.5479 0.4001 0.093 Uiso 1 1 calc R . .
H2B H 0.7732 0.5401 0.5097 0.093 Uiso 1 1 calc R . .
H2C H 0.7048 0.6436 0.4375 0.093 Uiso 1 1 calc R . .
C3 C 0.5140(6) 0.5043(7) 0.2793(5) 0.0584(19) Uani 1 1 d . C .
H3A H 0.5434 0.4935 0.229 0.088 Uiso 1 1 calc R . .
H3B H 0.4972 0.5902 0.2828 0.088 Uiso 1 1 calc R . .
H3C H 0.4502 0.4555 0.2626 0.088 Uiso 1 1 calc R . .
C4 C 0.7352(7) 0.3910(8) 0.2425(6) 0.077(2) Uani 1 1 d . C .
H4A H 0.7999 0.4171 0.2955 0.115 Uiso 1 1 calc R . .
H4B H 0.686 0.4593 0.2223 0.115 Uiso 1 1 calc R . .
H4C H 0.7514 0.3635 0.1868 0.115 Uiso 1 1 calc R . .
C5 C 0.5535(6) 0.2175(7) 0.1853(5) 0.070(2) Uani 1 1 d . C .
H5A H 0.5213 0.1503 0.2074 0.104 Uiso 1 1 calc R . .
H5B H 0.5697 0.1909 0.1294 0.104 Uiso 1 1 calc R . .
H5C H 0.5048 0.2862 0.1659 0.104 Uiso 1 1 calc R . .
C6 C 0.7730(7) 0.1392(8) 0.3088(5) 0.072(2) Uani 1 1 d . C .
H6A H 0.8386 0.1627 0.3617 0.109 Uiso 1 1 calc R . .
H6B H 0.786 0.1237 0.2491 0.109 Uiso 1 1 calc R . .
H6C H 0.7454 0.0654 0.3275 0.109 Uiso 1 1 calc R . .
C7 C 0.5053(4) 0.1776(6) 0.5059(5) 0.0531(16) Uani 1 1 d . C .
H7 H 0.5258 0.2652 0.5166 0.064 Uiso 1 1 calc R A 2
C8 C 0.4041(6) 0.1724(8) 0.4169(7) 0.088(3) Uani 1 1 d . . .
H8A H 0.4156 0.2052 0.3602 0.133 Uiso 1 1 calc R C .
H8B H 0.3505 0.2207 0.4288 0.133 Uiso 1 1 calc R . .
H8C H 0.3806 0.0878 0.404 0.133 Uiso 1 1 calc R . .
C9 C 0.4965(7) 0.1333(8) 0.5980(7) 0.080(3) Uani 1 1 d . . .
H9A H 0.5643 0.1421 0.6524 0.12 Uiso 1 1 calc R C .
H9B H 0.4758 0.0476 0.5906 0.12 Uiso 1 1 calc R . .
H9C H 0.4435 0.1813 0.6114 0.12 Uiso 1 1 calc R . .
C10 C 0.5736(5) -0.0192(5) 0.4653(5) 0.0546(15) Uani 1 1 d . C .
H10 H 0.5066 -0.0407 0.4726 0.065 Uiso 1 1 calc R . .
C11 C 0.5651(7) -0.0584(8) 0.3666(6) 0.076(2) Uani 1 1 d . . .
H11A H 0.5082 -0.0136 0.3169 0.114 Uiso 1 1 calc R C .
H11B H 0.5502 -0.1457 0.359 0.114 Uiso 1 1 calc R . .
H11C H 0.6312 -0.0417 0.3587 0.114 Uiso 1 1 calc R . .
C12 C 0.6645(6) -0.0906(6) 0.5452(6) 0.068(2) Uani 1 1 d . . .
H12A H 0.6693 -0.0652 0.6103 0.101 Uiso 1 1 calc R C .
H12B H 0.7308 -0.0733 0.5381 0.101 Uiso 1 1 calc R . .
H12C H 0.65 -0.178 0.5373 0.101 Uiso 1 1 calc R . .
C13 C 1.2321(7) 0.0069(6) 0.8454(6) 0.065(2) Uani 1 1 d . . .
H13A H 1.1848 0.0324 0.78 0.098 Uiso 1 1 calc R C .
H13B H 1.2475 -0.0799 0.8445 0.098 Uiso 1 1 calc R . .
H13C H 1.2975 0.0535 0.8647 0.098 Uiso 1 1 calc R . .
C14 C 1.0550(6) -0.0670(6) 0.9006(6) 0.066(2) Uani 1 1 d . . .
H14A H 1.0025 -0.0422 0.8372 0.099 Uiso 1 1 calc R C .
H14B H 1.0246 -0.0625 0.9506 0.099 Uiso 1 1 calc R . .
H14C H 1.0772 -0.1506 0.8961 0.099 Uiso 1 1 calc R . .
C15 C 1.2665(6) -0.0147(7) 1.0549(5) 0.070(2) Uani 1 1 d . . .
H15A H 1.3277 0.0391 1.0745 0.105 Uiso 1 1 calc R C .
H15B H 1.2885 -0.0982 1.0497 0.105 Uiso 1 1 calc R . .
H15C H 1.2348 -0.0111 1.1039 0.105 Uiso 1 1 calc R . .
C16 C 1.0548(8) 0.1173(8) 1.0953(6) 0.078(3) Uani 1 1 d . . .
H16A H 1.0984 0.044 1.1089 0.117 Uiso 1 1 calc R C .
H16B H 0.9849 0.0986 1.0469 0.117 Uiso 1 1 calc R . .
H16C H 1.0489 0.1459 1.1558 0.117 Uiso 1 1 calc R . .
C17 C 1.2462(7) 0.2811(8) 1.1420(5) 0.074(2) Uani 1 1 d . . .
H17A H 1.2947 0.2124 1.1539 0.111 Uiso 1 1 calc R C .
H17B H 1.2372 0.3022 1.2027 0.111 Uiso 1 1 calc R . .
H17C H 1.2748 0.3512 1.1194 0.111 Uiso 1 1 calc R . .
C18 C 1.0265(6) 0.3696(7) 1.0260(5) 0.0607(19) Uani 1 1 d . . .
H18A H 1.0538 0.4384 1.0008 0.091 Uiso 1 1 calc R C .
H18B H 1.0211 0.3925 1.088 0.091 Uiso 1 1 calc R . .
H18C H 0.957 0.3474 0.9785 0.091 Uiso 1 1 calc R . .
C19 C 1.2775(5) 0.3949(7) 0.8362(5) 0.0640(19) Uani 1 1 d . C .
H19 H 1.2963 0.483 0.8398 0.077 Uiso 1 1 calc R . .
C20 C 1.3695(6) 0.3365(7) 0.9179(6) 0.070(2) Uani 1 1 d . . .
H20A H 1.3711 0.3651 0.9813 0.105 Uiso 1 1 calc R C .
H20B H 1.4349 0.359 0.9109 0.105 Uiso 1 1 calc R . .
H20C H 1.3615 0.248 0.9142 0.105 Uiso 1 1 calc R . .
C21 C 1.2711(6) 0.3560(7) 0.7365(6) 0.068(2) Uani 1 1 d . . .
H21A H 1.2122 0.3974 0.6863 0.101 Uiso 1 1 calc R C .
H21B H 1.2605 0.2679 0.7297 0.101 Uiso 1 1 calc R . .
H21C H 1.3364 0.3774 0.7286 0.101 Uiso 1 1 calc R . .
C22 C 1.1329(5) 0.5118(5) 0.8657(4) 0.0471(14) Uani 1 1 d . C .
H22 H 1.0677 0.4923 0.8772 0.056 Uiso 1 1 calc R B 2
C23 C 1.1038(6) 0.5936(5) 0.7776(5) 0.0561(18) Uani 1 1 d . . .
H23A H 1.054 0.5516 0.7203 0.084 Uiso 1 1 calc R C .
H23B H 1.1669 0.6145 0.7655 0.084 Uiso 1 1 calc R . .
H23C H 1.0716 0.6681 0.7896 0.084 Uiso 1 1 calc R . .
C24 C 1.2111(7) 0.5758(6) 0.9588(5) 0.063(2) Uani 1 1 d . . .
H24A H 1.2283 0.521 1.0149 0.094 Uiso 1 1 calc R C .
H24B H 1.179 0.65 0.9714 0.094 Uiso 1 1 calc R . .
H24C H 1.2752 0.5968 0.9485 0.094 Uiso 1 1 calc R . .
P1 P 0.8776(3) 0.1528(3) 0.6941(2) 0.0333(7) Uani 0.753(4) 1 d P C 1
P2 P 0.9146(2) 0.3066(3) 0.6218(2) 0.0381(7) Uani 0.753(4) 1 d P C 1
P3 P 0.75359(15) 0.28475(18) 0.61700(14) 0.0343(5) Uani 0.753(4) 1 d P C 1
P4 P 0.94571(16) 0.31793(19) 0.77954(15) 0.0363(6) Uani 0.753(4) 1 d P C 1
P5 P 0.69132(15) 0.1825(2) 0.47573(14) 0.0283(5) Uani 0.753(4) 1 d P C 1
P6 P 1.11362(16) 0.2578(2) 0.83018(15) 0.0304(5) Uani 0.753(4) 1 d P C 1
P1A P 0.9002(8) 0.3551(9) 0.6435(7) 0.039(2) Uani 0.247(4) 1 d P C 2
P2A P 0.8664(9) 0.2013(10) 0.7128(7) 0.038(2) Uani 0.247(4) 1 d P C 2
P3A P 0.8351(4) 0.1851(5) 0.5543(4) 0.0295(17) Uani 0.247(4) 1 d P C 2
P4A P 1.0271(4) 0.2169(5) 0.7149(4) 0.0313(17) Uani 0.247(4) 1 d P C 2
P5A P 1.0902(5) 0.3197(6) 0.8578(4) 0.0252(15) Uani 0.247(4) 1 d P C 2
P6A P 0.6659(4) 0.2431(6) 0.5026(4) 0.0253(15) Uani 0.247(4) 1 d P C 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Si1 C3 109.9(3) . . ?
N1 Si1 C1 117.0(3) . . ?
C3 Si1 C1 102.8(3) . . ?
N1 Si1 C2 110.2(3) . . ?
C3 Si1 C2 110.7(3) . . ?
C1 Si1 C2 106.0(3) . . ?
N1 Si1 P6A 37.9(2) . . ?
C3 Si1 P6A 137.1(3) . . ?
C1 Si1 P6A 82.5(3) . . ?
C2 Si1 P6A 108.5(3) . . ?
N1 Si2 C5 111.1(3) . . ?
N1 Si2 C4 112.4(3) . . ?
C5 Si2 C4 108.7(4) . . ?
N1 Si2 C6 112.7(3) . . ?
C5 Si2 C6 108.1(4) . . ?
C4 Si2 C6 103.5(4) . . ?
N3 Si3 C14 111.0(3) . . ?
N3 Si3 C13 114.4(3) . . ?
C14 Si3 C13 106.9(4) . . ?
N3 Si3 C15 110.7(3) . . ?
C14 Si3 C15 108.1(4) . . ?
C13 Si3 C15 105.4(4) . . ?
N3 Si4 C18 113.9(3) . . ?
N3 Si4 C16 110.4(3) . . ?
C18 Si4 C16 104.1(4) . . ?
N3 Si4 C17 110.5(3) . . ?
C18 Si4 C17 108.4(4) . . ?
C16 Si4 C17 109.3(4) . . ?
P6A N1 Si2 139.4(4) . . ?
P6A N1 Si1 102.9(4) . . ?
Si2 N1 Si1 117.4(3) . . ?
P6A N1 P5 30.3(2) . . ?
Si2 N1 P5 109.1(3) . . ?
Si1 N1 P5 132.9(3) . . ?
C10 N2 C7 114.2(5) . . ?
C10 N2 P5 122.3(4) . . ?
C7 N2 P5 123.4(4) . . ?
C10 N2 P6A 153.0(5) . . ?
C7 N2 P6A 92.5(4) . . ?
P5 N2 P6A 31.5(2) . . ?
P6 N3 Si4 132.3(3) . . ?
P6 N3 Si3 109.1(3) . . ?
Si4 N3 Si3 118.6(3) . . ?
P6 N3 P5A 29.5(2) . . ?
Si4 N3 P5A 102.8(3) . . ?
Si3 N3 P5A 138.3(4) . . ?
C19 N4 C22 119.6(5) . . ?
C19 N4 P5A 148.9(6) . . ?
C22 N4 P5A 91.4(5) . . ?
C19 N4 P6 117.7(5) . . ?
C22 N4 P6 122.1(4) . . ?
P5A N4 P6 32.0(3) . . ?
C9 C7 C8 114.3(7) . . ?
C9 C7 N2 112.7(6) . . ?
C8 C7 N2 109.3(6) . . ?
C9 C7 P6A 121.6(5) . . ?
C8 C7 P6A 124.1(6) . . ?
N2 C7 P6A 47.2(3) . . ?
C11 C10 N2 114.2(6) . . ?
C11 C10 C12 109.7(6) . . ?
N2 C10 C12 109.1(5) . . ?
N4 C19 C21 114.9(6) . . ?
N4 C19 C20 115.3(6) . . ?
C21 C19 C20 112.2(7) . . ?
C23 C22 N4 111.4(5) . . ?
C23 C22 C24 111.1(5) . . ?
N4 C22 C24 109.4(5) . . ?
C23 C22 P5A 123.6(4) . . ?
N4 C22 P5A 44.4(3) . . ?
C24 C22 P5A 124.6(4) . . ?
P2 P1 P3 60.77(13) . . ?
P2 P1 P4 60.65(12) . . ?
P3 P1 P4 80.30(13) . . ?
P1 P2 P4 60.67(13) . . ?
P1 P2 P3 60.48(14) . . ?
P4 P2 P3 80.18(13) . . ?
P1 P3 P2 58.75(14) . . ?
P1 P3 P5 95.65(13) . . ?
P2 P3 P5 96.29(13) . . ?
P2 P4 P1 58.68(14) . . ?
P2 P4 P6 95.58(13) . . ?
P1 P4 P6 96.28(13) . . ?
N2 P5 N1 111.1(2) . . ?
N2 P5 P3 101.9(2) . . ?
N1 P5 P3 100.72(19) . . ?
N4 P6 N3 110.9(3) . . ?
N4 P6 P4 102.9(2) . . ?
N3 P6 P4 102.1(2) . . ?
P2A P1A P4A 60.7(4) . . ?
P2A P1A P3A 60.7(4) . . ?
P4A P1A P3A 77.4(4) . . ?
P1A P2A P4A 62.7(5) . . ?
P1A P2A P3A 63.0(4) . . ?
P4A P2A P3A 79.2(4) . . ?
P2A P3A P6A 95.5(4) . . ?
P2A P3A P1A 56.3(4) . . ?
P6A P3A P1A 95.4(4) . . ?
P2A P4A P1A 56.6(4) . . ?
P2A P4A P5A 94.6(4) . . ?
P1A P4A P5A 93.1(4) . . ?
N4 P5A N3 114.2(4) . . ?
N4 P5A C22 44.2(3) . . ?
N3 P5A C22 136.1(4) . . ?
N4 P5A P4A 103.0(4) . . ?
N3 P5A P4A 97.5(4) . . ?
C22 P5A P4A 122.3(3) . . ?
N1 P6A N2 108.7(4) . . ?
N1 P6A P3A 99.4(4) . . ?
N2 P6A P3A 107.4(4) . . ?
N1 P6A C7 111.9(3) . . ?
N2 P6A C7 40.4(3) . . ?
P3A P6A C7 140.3(4) . . ?
N1 P6A Si1 39.2(2) . . ?
N2 P6A Si1 126.6(3) . . ?
P3A P6A Si1 117.5(3) . . ?
C7 P6A Si1 102.2(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Si1 N1 1.767(5) . ?
Si1 C3 1.860(7) . ?
Si1 C1 1.862(7) . ?
Si1 C2 1.887(7) . ?
Si1 P6A 2.724(6) . ?
Si2 N1 1.762(5) . ?
Si2 C5 1.848(7) . ?
Si2 C4 1.852(8) . ?
Si2 C6 1.867(7) . ?
Si3 N3 1.764(5) . ?
Si3 C14 1.841(7) . ?
Si3 C13 1.856(8) . ?
Si3 C15 1.863(7) . ?
Si4 N3 1.763(5) . ?
Si4 C18 1.852(7) . ?
Si4 C16 1.868(8) . ?
Si4 C17 1.874(8) . ?
N1 P6A 1.717(7) . ?
N1 P5 1.767(5) . ?
N2 C10 1.483(7) . ?
N2 C7 1.522(8) . ?
N2 P5 1.621(5) . ?
N2 P6A 1.724(7) . ?
N3 P6 1.722(5) . ?
N3 P5A 1.838(7) . ?
N4 C19 1.422(8) . ?
N4 C22 1.524(7) . ?
N4 P5A 1.531(7) . ?
N4 P6 1.717(5) . ?
C7 C9 1.494(10) . ?
C7 C8 1.513(10) . ?
C7 P6A 2.349(8) . ?
C10 C11 1.482(9) . ?
C10 C12 1.569(9) . ?
C19 C21 1.504(9) . ?
C19 C20 1.523(10) . ?
C22 C23 1.507(8) . ?
C22 C24 1.557(9) . ?
C22 P5A 2.187(8) . ?
P1 P2 2.165(5) . ?
P1 P3 2.203(4) . ?
P1 P4 2.209(4) . ?
P2 P4 2.209(4) . ?
P2 P3 2.209(4) . ?
P3 P5 2.237(3) . ?
P4 P6 2.247(3) . ?
P1A P2A 2.120(16) . ?
P1A P4A 2.256(11) . ?
P1A P3A 2.269(11) . ?
P2A P4A 2.213(13) . ?
P2A P3A 2.222(11) . ?
P3A P6A 2.255(8) . ?
P4A P5A 2.258(9) . ?
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 PubChem 139155554
